• Title/Summary/Keyword: 딥 코팅

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NO and $SO_2$ Removal by Dielectric Barrier Discharge-Photocatalysts Hybrid Process (유전체 장벽 방전-광촉매 복합공정에 의한 NO와 $SO_2$ 제거)

  • Kim, Dong-Joo;Nasonova, Anna;Kim, Kyo-Seon
    • Clean Technology
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    • v.13 no.2
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    • pp.115-121
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    • 2007
  • In this study, we analyzed experimently the NO and $SO_2$ removal by the dielectric barrier discharge-photocatalysts hybrid process. The glass spheres were used as a dielectric material for dielectric barrier discharge and the $TiO_2$ photocatalysts were coated onto those spheres by the dip-coating method. The $TiO_2$ particles were coated in the sponge-shape, which has the larger surface area. As the voltage applied to the plasma reactor, the pulse frequency of applied voltage, or the residence time increases, the NO and $SO_2$ removal efficiencies increase. The increase in the supplied concentrations of NO and $SO_2$ leads to the higher energy for NO and $SO_2$ removal and the NO and $SO_2$ removal efficiencies decrease. These experimental results can be used as a basis to design the dielectric barrier discharge-photocatalysts hybrid process to remove NO and $SO_2$.

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Preparation of Eudragit Coated Superporous Hydrogels and Their pH Dependent Swelling Behavior (Eudragit으로 코팅된 초다공성 하이드로젤의 제조 및 pH 의존형 팽윤거동)

  • Kim, Bo-A;Baek, Eun-Jung;Huh, Kang-Moo
    • Polymer(Korea)
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    • v.35 no.6
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    • pp.520-525
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    • 2011
  • Superporous hydrogels (SPHs) with fast swelling and superabsorbent properties are useful materials in various biomedical fields, by improving the swelling properties of conventional hydrogels based on their unique porous structure. In this study, Eudragit polymers were used as coating materials to control the swelling properties of poly(acrylic acid-co-acrylamide) based SPHs by environmental pH. The SPHs were coated with Eudragit L100 and S100 that have different pH characteristics as enteric coating materials by a dip coating method, and their pH dependent swelling behaviors were observed in various pH environments. The swelling of SPHs was inhibited at a low pH range, but significantly enhanced above a characteristic pH of Eudragit polymers. This pH dependent swelling behavior of hydrogels could be modulated by the characteristics of the enteric coating polymers.

Hydrophilic Coating and Characterization of PVDF Membrane with Flower Type Cross-section made from Thermally Induced Phase Separation (열유도 상분리로 제조한 플라워 형태 단면을 갖는 PVDF 분리막의 친수성 코팅 및 특성평가)

  • Im, Kwang Seop;Lee, Jeong Woo;Jang, Jae Young;Nam, Sang Yong
    • Membrane Journal
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    • v.29 no.6
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    • pp.362-376
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    • 2019
  • In this study, hydrophilic coating characteristics of PVDF [poly(vinylidene fluoride)] hollow fiber membranes with flower type cross-section prepared by thermally induced phase separation were studied. The hollow fiber used in this study was provided from PureEnvitech Co. Ltd., and the hydrophilic coating experiment was performed with different concentration and number of coating of PEBAX 1657, 2533 and 3533 block copolymer solution using a dip coating method. The hydrophilic coated hollow fiber membrane was characterized to scanning microscope and contact angle measurements to determine the degree of hydrophilization. As a result of SEM characterization, it was confirmed that the thickness of the coating layer increased as the coating concentration increased and the number of coatings increased. Contact angle of surface of hollow fibers decreased as the concentration of the coating solution increased and the number of coatings increased. Gas permeance of oxygen gas was measured for the application of the hydrophilized hollow fiber to Membrane Areated Biofilm Reactor. As a result of gas permeation test, it was confirmed that gas permeance decreased with increasing coating concentration and number of coatings, and the more hydrophilized hollow fiber coated with PEBAX 1657 showed lower gas permeance than those coated with PEBAX 2533 and 3533.

Optimization for Ammonia Decomposition over Ruthenium Alumina Catalyst Coated on Metallic Monolith Using Response Surface Methodology (반응표면분석법을 이용한 루테늄 알루미나 메탈모노리스 코팅촉매의 암모니아 분해 최적화)

  • Choi, Jae Hyung;Lee, Sung-Chan;Lee, Junhyeok;Kim, Gyeong-Min;Lim, Dong-Ha
    • Clean Technology
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    • v.28 no.3
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    • pp.218-226
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    • 2022
  • As a result of the recent social transformation towards a hydrogen economy and carbon-neutrality, the demands for hydrogen energy have been increasing rapidly worldwide. As such, eco-friendly hydrogen production technologies that do not produce carbon dioxide (CO2) emissions are being focused on. Among them, ammonia (NH3) is an economical hydrogen carrier that can easily produce hydrogen (H2). In this study, Ru/Al2O3 catalyst coated onmetallic monolith for hydrogen production from ammonia was prepared by a dip-coating method using a catalyst slurry mixture composed of Ru/Al2O3 catalyst, inorganic binder (alumina sol) and organic binder (methyl cellulose). At the optimized 1:1:0.1 weight ratio of catalyst/inorganic binder/organic binder, the amount of catalyst coated on the metallic monolith after one cycle coating was about 61.6 g L-1. The uniform thickness (about 42 ㎛) and crystal structure of the catalyst coated on the metallic monolith surface were confirmed through scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis. Also, a numerical optimization regression equation for NH3 conversion according to the independent variables of reaction temperature (400-600 ℃) and gas hourly space velocity (1,000-5,000 h-1) was calculated by response surface methodology (RSM). This model indicated a determination coefficient (R2) of 0.991 and had statistically significant predictors. This regression model could contribute to the commercial process design of hydrogen production by ammonia decomposition.

Low Voltage Operating OTFT with Hybrid Dielectrics

  • Hwang, Jin-A;Lee, Jin-Ho;Lee, Eun-Ju;Kim, Yeon-Ok;Kim, Hong-Doo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.76-76
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    • 2010
  • 유기박막트랜지스터의 특성을 개선하기 위해서는 유기반도체와의 좋은 접합과 유전상수가 주요한 요인으로 작용한다. 무기 산화물 전구체와 유기고분자를 이용하여 유기 고분자의 단정인 낮은 유전율을 개선하였다. 스핀코팅 방법이 아닌 딥코팅 방법을 이용하여 절연막 두께를 10nm정도로 낮추어 구동전압을 개선하였으며 무기 절연체의 높은 누설전류 또한 그 특성이 개선되어 우수한 절연 특성을 보였다. 유-무기 복합체를 이용한 게이트 절연막과 펜타센을 이용한 유기박막트랜지스터의 구동전압은 1V정도에서 구동가능하며, 점멸비, 이동도 모두 개선된 결과를 보였다.

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Preparation of Barium Ferrite Thin Film by Sol-Gel Method (졸겔법을 이용한 바륨페라이트 박막 제조)

  • 변태봉;조원덕;김태옥
    • Journal of the Korean Ceramic Society
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    • v.34 no.1
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    • pp.37-44
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    • 1997
  • Barium ferrite thin films on the thermal oxidized Si substrate were prepared by using sol-gel method (dip coating) from the sol of composition ratio of 5.25, designated by mole ratio 2Fe/Ba. The gelation process was largely divided into 4 step, and the sol prepared by reaction for 90 minutes at 8$0^{\circ}C$ was the suit-able for coating. Needle shaped particles formed on the coating layer were placed parallel to substrate and the inclination was increased with film thickness. The easy-direction of magnetization of needle shaped par-ticles was long-axis direction.

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Preparation of the Anti-Reflective(AR) Coating Film by Sol-Gel Method to Improve the Efficiency of Solar Cell (태양전지 효율 향상용 졸-겔 법에 의한 반사방지 코팅막의 제조)

  • Kim, Hyosub;Kim, Youngho;Choi, Jaeyune
    • Journal of Hydrogen and New Energy
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    • v.25 no.2
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    • pp.145-150
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    • 2014
  • This study investigates the preparation of anti-reflective (AR) coating film to improve the efficiency of solar cell. The AR coating film was successfully obtained by dip-coating with AR coatings prepared by sol-gel method. Fluoroalkylsilane was additionally introduced into the coatings to give the self-cleaning effect of AR coating film. We performed the abrasion test, pencil scratch hardness test and cross-cut test to identify the mechanical strength of AR coating film. As the results, the transmittance of AR coating films with 9.07, 18.13 and 27.20 of IPA/MTMS molar ratios were 93.1, 93.6 and 95.3%, respectively. The water contact angle and transmittance of AR coating film increased by the introduction of hydrophobicity. The prepared AR coating film shows the high level of abrasion, hardness and adhesion. The IPA/MTMS molar ratio of 27.20 and the withdrawing speed range of 0.20 ~ 0.28cm/sec are the optimal coating condition in terms of the transmittance and mechanical strength of AR coating film.

Bond Strength of SrZrO3 Coatings on Ag Sheathed Bi(2223) Mono-core Tape (은이 피복된 단심 Bi(2223) 초전도 선재에 대한 SrZrO3 코팅층의 접착강도 특성)

  • Lee, Se-Jong;Ye, Kyung-Hwan;Lee, Deuk-Yong;Song, Yo-Seung
    • Journal of the Korean Ceramic Society
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    • v.39 no.10
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    • pp.1001-1006
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    • 2002
  • Bond strength of $SrZrO_3$ resistive oxide barrier on Ag sheathed Bi(2223) tapes prepared by the sol-gel and dip-coating method was evaluated with an aid of Taguchi method and $L_18(2^1{\times}3^7)$ orthogonal arrays to determine the optimal process combination of levels of factors that best satisfy the bigger is better quality characteristic. The observed optimal condition is as follows: Sr/Zr mol ratio(0.3/0.7), amount of organic vehicle(5 wt%), drying temperature and time(160${\circ}C$, 10 min), heat treatment temperature and time(500${\circ}C$, 20 min), respectively. ANOVA analysis suggested that the influence of the factors within ${\alpha}$=0.1 was significant with a 90% confidence level.

Continuous PTFE Coating Process on Basalt Sewing Thread (현무암 재봉사의 연속식 테프론 코팅 공정)

  • Lee, Soo
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.2
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    • pp.183-189
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    • 2014
  • On the basis of our previous research results concerning a batch Teflon coating process on the surface of basalt fiber which has superior fire-resistance and chemical resistance, we have tried to set up suitable operating conditions for continuous polytetrafluoroethylene(PTFE) coating process. The basalt fiber was continuously pre-treated with 7.5 wt%(6.5% of DPU) of triethoxytrifluoropropylsilane(TMTFPS) and then coated with 20 wt% of PTFE dispersions containing 0.25 wt% of penetrating agent sodium bis(2-ethylhexyl)sulfo succinate (DOS-Na) to get the highest tensile and loop strengths. After dipping process, the PTFE coated basalt fiber was dried under 2 m drying chamber at $120^{\circ}C$ with 12 m/min of winding speed and consequently sintered under 2 m sintering chamber at $380^{\circ}C$ for 40 s. Conclusively, PTFE coated basalt fiber whose tensile and loop strengths were to $3.4g_f/D$ and $2.3g_f/D$, respectively, applicable to high temperature sewing thread could be continuously prepared with our pilot scale process under optimum conditions.

Separation of Low Molecular Weight of Dye from Aqueous Solution Using the Prepared Nano-composite Hollow Fiber Membranes (중공사형 나노복합막 제조를 이용한 수용액으로부터 저분자량의 염료 분리 연구)

  • Park, Cheol Oh;Lee, Sung Jae;Rhim, Ji Won
    • Membrane Journal
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    • v.28 no.3
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    • pp.180-186
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    • 2018
  • The nano-composite membranes were prepared onto the polyvinylidene fluoride (PVDF) hollow fiber membranes through twice dip-coating known layer-by-layer method. For the first coating, poly(vinylsulfonic acid, sodium salt)(PVSA) and Poly(styrene sulfonic acid)(PSSA) were used with varying the concentration and ionic strength (IS) and the poly(ethyleneimine)(PEI) as the second coating material was fixed at 10,000 ppm and IS = 0.3. To characterize the prepared nano-composite membranes, the permeabilities and rejection ratio were measured for each 100 ppm NaCl, $CaSO_4$, $MgCl_2$, and 25 ppm MO aqueous solution. The rejections were increased as the concentrations of coating materials increased. And it was confirmed that the salt rejections for PSSA as the coating material were higher than for PVSA. Typically, the permeability, 1.848 LMH and the rejection for MO 76.3% were obtained at the coating conditions of PSSA 30,000 ppm and I.S = 1.0.