• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.317-322
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• 2002

In modern times, the environment preservation is global tendency and self social awareness is arise. Measures to the environment preservation and pollution is going on study. One measure is recycling and reuse of by product and it is already developed in some advanced country. There is 7 hundred thousand tons of copper slag production from copper refining process in domestic. The purpose of this study is reusing copper slag -by product which produced L cooperation in domestic-as fine aggregate for producing high strength concrete and investigating the fundamental characteristics.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.10a
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• pp.383-388
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• 2000

In these days, there are out of natural sands in the construction field. It is required that development of substitute material for natural material. The blast-furnace slag could be a good alternative material in this situation. It can help resource recycling and the protection of environment. This study presents that the strength properties of mortar using air-cooled blast-furnace slag sand and water-cooled blast-furnace slag sand. The mixing design of this study have a few factors, three type of unit water, four types of W/C, five types of substitution rate. When air-cooled furnace slag sand used in mortar, as substitution rate is higher, 3, 7-days compression strength and flexural strength are going up. But, in case of water-cooled furnace slag sand mortar, strengths are going down.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.11a
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• pp.15-18
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• 2003

Development of the construction industry generally exhausts natural aggregate. Hence it is problem to the lack of supply and quality deterioration, so the resource saving and protection of environment is made an effort through recycling by-product. This study presents that fundamental properties of concrete which used cooper slag as alternate sand of low fineness modulus and plan of cooper slag as concrete aggregate. Testing factors are concrete's slump, air contents, unit weight and compressive strength. The results of this study are as follows; (1) Concrete slump is generally satisfied with the condition but is inferior to the others in substitution rates 30%. Also air contents are 3.1-4.1% and go up according to increase substitution rate. (2) Unit weight increase in 1.1% as the mixing ratio of cooper slag argument 10%. (3) compressive strength of cooper slag concrete is similar to plain and especially higher 11-15% in W/C 45%, 50%. So it seems that aggregate mixed cooper slag is suitable to low water-cement ratio mixture.

• Proceedings of the Korean Geotechical Society Conference
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• 2000.11a
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• pp.447-454
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• 2000

This paper presents fundamental characteristics of a copper slag when used geotechnical materials. For this study, it was conducted laboratory tests such as compaction, large direct shear, hydraulic conductivity, leaching, TDR, frost heave test and so on. The results of laboratory tests shown gradually increase in draining capacity and shearing resistance more slag mixing. The unfrozen water in temperature changes and frost heave amounts in condition of -17 $^{\circ}C$ appeared to decrease. Also, toxicity tests based on the domestic solid waste regulations were satisfied with nonhazardous. By this research results, a copper slag mixed with granite soil may been used as granular base and embankment materials, fill etc.

• Proceedings of the Korea Concrete Institute Conference
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• 1993.10a
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• pp.45-50
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• 1993

This paper describes some results of various tests which were carried out with varying the fineness of salg from 6000 to 10000$\textrm{cm}^2$/g and the slag content in cement from 30 to 50wt% for the perpose of utilizing finely ground blast-furnace slag as an ingredient for high-performance concrete. Test for heat of hydration, microstructural and hydration characteristics in paste, and fluidity and compressive strength in mortar were carried out. From these test results, it was found that, by properly determining the content and fineness of the slag, it is possible to manufacture high-performance concrete that has low heat of hydration, high early strength development, fine pore size and a highly densified microstructure.

• Proceedings of the KSR Conference
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• 2001.10a
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• pp.552-557
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• 2001

Copper slag is the by-producted material on the proceeding of refining the copper. To verify applications of copper slag to vertical drain material can substitute for the sands in ground improvement, laboratory soil tests and consolidation model tests were conducted. The results of consolidation model test was analyzed as the hyperbolic method. The hyperbolic method assumes that the settlement(s) versus time(t) behavior approaches a straight line describes a hyperbolic reaction. The inverse of the slope of the line would then yield the ultimate settlement. Through in this study, copper slag is compatible with vertical drain material as like sands. Copper slag compaction pile promote the consolidation settlement.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.04a
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• pp.263-268
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• 2000

Recently, the recycling of the by-products was attempted to various fields. One of the major industry, the copper manufacturing industry produced a lot slags. in this study, the copper smelting slag was used to use practically application for the aggregate of concrete. To find the optimum mixing ratio of mortar with the copper smelting slag as substitution for sand, the mixing ratio was increased 1:2 to 1:5 step by step and every mixture was contained 5 steps sand substitutive ratio. The substitutive ratio of sand was increased 25% st대 by step from 0% to 100%. The result of this study was shown as follows. 1. In the every mixture, as the substitutive ratio was increased, the flow was decrease 3.64% from 18cm, and the unit content weigth was increased 5.5% in average. 2. The property of the strength was judged that it was more affected W/C and mixing ratio than the copper smelting slag.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.05a
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• pp.89-94
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• 2003

In this research, the physical properties of self compacting concrete using ground granulated blast furnace slag and fly ash as a part of cement were investigated. Concrete using ground granulated blast furnace slag and fly ash was prepared with various ground granulated blast furnace slag(30-50 volume %) and fly ash(10-20 volume %) replacement for cement. The effect of each of the materals, which have effects on self compacting concrete made by the basic mix proportion used granulated blast furnace slag and fly ash after hardening, has been checked. The workability, flowing characteristics, resistance of segregation of materals, air content, and compressive strength of concrete using ground granulated blast furnace slag and fly ash were tested and the results were compared with those of ordinary portland cement concrete. In the experiment, we acquired satisfactory results at the point of flowing characteristics and strengths of concrete using ground granulated blast furnace and slag fly ash within the replacement ratio of 65%

• Magazine of the Korea Concrete Institute
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• v.4 no.1
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• pp.97-106
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• 1992

Apparent diffusion coefficients of Cl- ions through hardened cement pastes(HCP), which were partly subs¬tituted blast furnace slag, fly ash and silicafume for ordinary Portland cement, were determined. Also. Cl- and OW concentration of pore solutions which were extracted from HCP and the capacities of the HCP to bind CI were determined. Diffusion coefficients of Cl- ions through HCP were increased with water cement ratio(WfC), but decreased with addition of the blending materials. On the contrary, Cl- and OH concentration of the pore solutions were reduced by adding the blending materials.

• Cement
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• s.192
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• pp.39-47
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• 2011

최근 온실가스 감축과 기후변화 그리고 녹색성장에 대한 관심증대와 더불어 시멘트 분야의 연구 생산분야는 천연자원 사용량을 줄이고, 소성공정을 도입하지 않은 새로운 개념의 무기바인더가 다시 고개를 들고 있다. 다른 용어로는 비소성, 무시멘트 등으로 표현되기도 하는데, 광의의 개념으로 보면 알칼리 활성화제를 사용한 비소성 무기결합재인 지오폴리머가 바로 그것이다. 지오폴리머 결합재는 1957년 우크라이나의 토목공학회에서 개발한 알칼리 활성 슬래그시멘트에 기원을 두고 있고, 1970년대 말 프랑스의 다비도비치에 의해 지오폴리머라는 용어가 처음 사용되기 시작했다. 알칼리 활성 무기결합재(Alkali-activated inorganic binder)의 정의이다. Alkali-activated inorganic binder는 원래는 결합능력이 없던 재료에 대해서 Alkali-activating 용액을 첨가했을 때, 시멘트처럼 결합능력을 가지게 되는 모든 종류의 결합시스템을 말한다. 국내에도 이미 2000년 초부터 지오폴리머의 개념을 도입한 제품이 상업화되어 오랫동안 품질검증을 거쳐 안정성이 확인되고 있다. 최근에 다시 전남대가 그 동안의 연구성과를 발 빠르게 중소기업에 기술 이전하여 소위 무시멘트 시대에 진입하는 분위기이다. 지난 9월 동아에스텍(주)과 조인트벤처 설립을 위해 손을 잡았고, 사업화가 곧 진행될 것으로 보인다. 이를 계기로 국내에도 무시멘트회사가 본격적으로 등장하게 된 것이다. 따라서 본 고는 무시멘트의 개념을 잘 표현한 문헌으로 일본콘크리트공학 연차논문집, 2010년 1월호를 번역 요약 발췌한 것이다.