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Adsorption Equilibrium, Kinetics and Thermodynamics Studies of Malachite Green Using Granular Activated Carbon (입상 활성탄을 이용한 말라카이트 그린의 흡착평형, 동력학 및 열역학 연구)

  • Lee, Jong-Jib
    • Applied Chemistry for Engineering
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    • v.24 no.2
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    • pp.184-189
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    • 2013
  • In the present study, batch experiments were carried out for the utilizatioin of activated carbon as a potential adsorbent to remove a hazardous malachite green from an aqueous solution. The effects of various parameters such as temperature, contact time, initial concentration on the adsorption system were investigated. On the basis of adsorption data Langmuir and Freundlich adsorption isotherm model were also confirmed. The equilibrium process was described well by Langmuir isotherm model. From determined separation factor, the activated carbon could be employed as an effective treatment for removal of malachite green. From kinetic experiments, the adsorption process followed the pseudo second order model, and the adsorption rate constant ($k_2$) decreased with increasing both the initial concentration of malachite green and the adsoprtion temperature. Thermodynamic parameters like that activation energy, change of free energy, enthalpy, and entropy were also calculated to predict the adsorption nature. The activation energy calculated from Arrhenius equation indicated that the adsortpion of malachite green on the zeolite was physical process. The negative Gibbs free energy change ($\Delta$G = -3.68~-7.76 kJ/mol) and the positive enthalpy change ($\Delta$H = +26.34 kJ/mol) indicated the spontaneous and endothermic nature of the adsorption in the temperature range of 298~318 K.

Assessment of Genetic Diversity of Horse Breeds Using Microsatellite Makers (Microsatellite makers를 이용한 마품종 간의 평가 및 유전적 다양성)

  • Jung, Ji-Hye;Lee, Mi-Rang;Ha, Tae-Yong;Kim, Seon-Ku;Shin, Teak-Soon;Kang, Han-Seok;Lee, Hong-Gu;Cho, Gil-Jae;Park, Kyung-Do;Cho, Byung-Wook
    • Journal of Life Science
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    • v.19 no.2
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    • pp.169-173
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    • 2009
  • To assist in selection schemes we estimate the genetic diversity of the horse breeds. Genetic diversity at 13 microsatellite loci was compared in six horse breeds : Jeju Native Horse, American Quarter, Jeju Racing Horse, Mongolian Horse, Japanese Horse and Thoroughbred. All of the equine microsatellite used in this study were amplified and were polymorphic. The expected total heterozygosity over all the populations varied between 0.669 and 0.869 and the expected heterozygosity within population range from 0.569 to 0.219 in this study. The low coefficient of gene differentiation value showed that only 0.118 of the diversity was between horses breeds. The constructed dendrogram from the genetic distance matrix showed little differentiation between horse breeds using DISPAN program. The genetic distance using 13 microsatellites ranged between 0.137 and 0.414 for the six horse breeds. These results confirm the potential use of equine microsatellite loci as a tool for genetic studies in horse populations. The genetic diversity of the six horse breeds to each other closed to their geographical distribution. Suggesting that the loci would be suitable for horse breeds parentage testing. Therefore, Microsatellite marker seems to be very useful for clarifying the evolutionary relationships of closely related populations.

Enzyme Kinetics Based Modeling of Respiration Rate for 'Fuyu' Persimmon (Diospyros kaki) Fruits (효소반응속도론에 기초한 단감의 호흡 모델에 관한 연구)

  • Ahn, Gwang-Hwan;Lee, Dong-Sun
    • Korean Journal of Food Science and Technology
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    • v.36 no.4
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    • pp.580-585
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    • 2004
  • Respiration of 'Fuyu' persimmon (Diospyros kaki) fruits were measured in terms of oxygen consumption rate and carbon dioxide evolution by closed system experiments at 0, 5, and $20^{\circ}C$. Enzyme kinetics-based respiration model was used to describe respiration rate as function of $O_2\;and\;CO_2$ gas concentrations $(R=V_m[O_2]/K_m+(1+[CO_2]/K_i)[O_2])$, and Arrhenius equation was applied to analyze temperature effect. $V_m\;and\;K_m$ increased, while $K_i$ decreased, with increasing temperature. $K_m\;of\;O_2$ consumption was greater than that of $CO_2$ evolution at equal temperature. Inhibitory effect of reduced $O_2$ level on $O_2$ consumption was more prominent than that on $CO_2$ evolution. Activation energy of respiration decreased with reduced $O_2$ and elevated $CO_2$ concentrations. Activation energy of $CO_2$ evolution was greater than that of $O_2$ consumption. Permeable package experiments verified respiration model parameters by showing good agreement between predicted and experimental gas concentrations in package.

Development of the Handy Non-contact Surface Roughness Measurement Device by using the Optical Fiber Sensor (광섬유센서에 의한 간이 비접촉 표면조도 측정기의 개발)

  • Hong, Jun-Hee
    • 대한공업교육학회지
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    • v.34 no.2
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    • pp.346-362
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    • 2009
  • The purpose of this study was to develop the handy non-contact measurement device of the surface roughness by using the optical fiber sensor. The advantages of fiber optic sensors are high-speed responsibility, non-effect of the magnetic, convenience of the product and high precision. The measurement theory for surface roughness of optical fiber sensor is one to one correspondence between the reflected light intensity based on the surface roughness of the object and the measurement value of previously known for surface roughness. The reflected light intensity was determined using the distance to the surface from the sensor probe and the limit reflection angle based on the surface roughness. Therefore, in this study, the sensor probe was produced for determining the value of surface roughness only using the limit reflection angle based on the surface roughness with the fixed distance from the surface. A prototype measurement system was composed of a transmitting part, a receiving part and a signal processing circuit. The materials of standard measurement which was used in this experiment were SM45C, STS303 and Al60. According to the results of this study, approximation surface roughness formulas which was deduced from the correlation of between the standard surface roughness and the sensing output were verified that they were effect against the surface roughness measurement value of the option sample. And handy optical fiber surface roughness measurement device which was produced by an order was verified that it was effect for measuring of the precision surface roughness.

Implications on Sedimentological and Geochemical Changes in Late Quaternary Sediments and Pore Water of the Southwestern East Sea (동해 남서부 해역의 제4기 후기 퇴적물과 공극수에서의 퇴적학적 및 지화학적 변화의 의미)

  • Park, Myong-Ho;Kim, Ji-Hoon;Ryu, Byong-Jae;Lee, Song-Suk;Han, Sang-Geun;Kil, Young-Woo
    • The Korean Journal of Petroleum Geology
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    • v.12 no.1
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    • pp.20-26
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    • 2006
  • Late Quaternary stratigraphy and sedimentary environmental changes were studied based on four core sediments and their pore water taken from the southwestern part of the East Sea. The results of tephrostratigraphy and radiocarbon dates indicate that the cores cover the time interval from the middle stage of Marine Isotope Stage (MIS) 3 to MIS 1 (Holocene). The average of sedimentation rate in core sediments varies from 10 cm/kyr to 20 cm/kyr, but it fluctuates generally in particular time intervals such as MIS 2, which would be related with the sea-level changes at that time. On the other hand, the relations between ${\delta}^{13}C_{org}$ and C/N ratios suggest that the organic matter in the cores was originated mainly from marine algae. In addition, the value of ${\delta}^{13}C_{CH4}$ indicates bacterial origin rather than thermogenic one.

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The Roles and Importance of Critical Evidence (CE) and Critical Resource Models (CRMs) in Abductive Reasoning for Earth Scientific Problem Solving (지구과학 문제 해결을 위한 귀추적 추론에서 결정적 증거와 결정적 자원 모델의 역할과 중요성)

  • Oh, Phil Seok
    • Journal of Science Education
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    • v.41 no.3
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    • pp.426-446
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    • 2017
  • The purpose of this study was to analyze undergraduate students' reasoning for solving a problem about a rock and investigate the roles and importance of critical evidence (CE) and critical resource models (CRMs) in abductive reasoning. Participants were 20 senior undergraduate students enrolled in a science major course in a university of education. They were asked to abductively infer geologic processes of sedimentary rocks having a lot of holes and represent them with models. Their reasoning were analyzed according to a scheme for modeling-based abductive reasoning. As a result, successful student reasoning was characterized by using a diversity of grains and lots of holes as CE, activating the sedimentary rock formation and weathering as CRMs, and combining the CRMs into a scientifically sound explanatory model (SSEM). By contrast, in the reasoning unsuccessful in proposing a SSEM, students activated the igneous rock (basalt) formation and deposition as resource models (RMs) based on the evidence of the holes in the rocks and diverse grains, respectively, and used the RMs to construct their own explanatory models (EMs). It was suggested that to construct SSEMs to solve earth scientific problems about rocks, students need to know what could be CE in a particular problem situation, take an integrative or systemic approach to a rock problem, use multiple RMs, and evaluate RMs or EMs in light of evidence.

Analysis of Hydraulic Characteristics for the Design Parameters of Culvert Outlet Facilities in Detention Pond (저류지 암거방류시설 설계인자의 수리학적 특성 분석)

  • Lee, Jae Joon;Jang, Joo Young;Lee, Hoo Sang;Jang, Hyun Min
    • 한국방재학회:학술대회논문집
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    • 2011.02a
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    • pp.213-213
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    • 2011
  • 근래 이상기후에 의한 강우량 증대와 도시화에 따른 첨두유출량의 증대 및 도달시간의 단축은 기존의 유수지만으로 도시홍수를 대처하는데 그 한계점에 다다르게 되었다. 1990년대에 들어 각종 우수유출 저감시설의 활용으로 이상의 문제를 해결하고자 하는 노력들이 시작되었으며, 현재 신규개발지에 저류지와 같은 우수유출저감시설 설치를 법제도적으로 의무화 하고 있어, 전국적으로 천여개소의 저류지가 시설되어 있거나 계획 중에 있다. 저류지는 개발로 인해 증가된 첨두유출량을 개발전의 상태로 저감시키기 위하여 임시 또는 상시 저류하거나 저류능력 이상의 유출량에 대해서는 암거방류시설을 통해 하류부의 하천 또는 하도로 방류시키는 역할을 수행하는 수공구조물로서 일반적으로 저류지 계획 및 설계는 첨두유출량 증가분에 대해 초점을 맞추고 있을 뿐 방류시설에 대한 구체적인 설계는 이루어지지 않고 있는 실정이다. 또한 현재 국내에는 저류지 방류시설로 주로 사용되는 암거에 관한 설계규정이나 기법은 미미한 상태로, 한국도로공사(1991)에서 발표한 "도로배수계획"을 이용하고 있으며, 이는 미국 연방도로국(FHWA, 1985)에서 발표한 설계기법을 그대로 인용하고 있다. 즉, 지형 또는 현장 여건에 따라 암거 흐름의 8형식 중 하나의 형식으로 결정하고, 그 형식에 따라 관련도표를 이용한 시산법 또는 도식해법을 적용하여 유입부 상류수위를 산정함으로써 암거설계가 이루어진다. 하지만 이러한 암거설계 방식은 도로 배수암거에 적합한 것으로 저류지 배수암거에 적용하기에는 무리가 있다고 본다. 따라서, 본 연구에서는 저류지의 일반적인 특성상 암거흐름 8형식 중 Class-II군의 암거 상류부 수위가 잠수된 조건 즉, 평상시 저류지가 일정수위 이상의 저류량을 유지하고 있는 상태에서 저류지 암거방류시설의 대표적인 설계인자인 암거직경, 암거경사, 암거경사, 하류단 수위조건의 변화에 따른 상류부 수위변화를 유량별로 분석해 보았다. 방류 암거의 개수를 고려하기 위하여 암거상류부 수위와 암거직경의 관계해석 시 암거단면적을 이용하여 분석하였으며, 각각의 유량별로 상류부 수위와 암거단면적의 관계를 회귀식으로 제시하였다. 암거상류부 수위와 암거경사의 관계를 분석한 결과 암거경사가 5~20%로 변화할 때 암거상류부 수위의 변화는 2~5%정도의 매우 작은 변화를 보임을 확인할 수 있었으며, 암거길이의 경우는 해석 조건의 특성상 상류부 수위에 영향이 전혀 나타나지 않았다. 암거상류부 수위와 암거하류단 수위의 관계에서 암거상류부 수위는 암거하류단 수위가 암거직경과 퇴사위 높이의 합보다 암거하류단의 수위가 높아지는 시점부터 암거하류단 수위에 비례해서 증가되는 결과를 알 수 있었다.

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A Study on Characteristic Analysis of Single-Stage High Frequency Resonant Inverter Link Type DC-DC Converter (단일 전력단 고주파 공진 인버터 링크형 DC-DC 컨버터의 특성해석에 관한 연구)

  • Won, Jae-Sun;Park, Jae-Wook;Seo, Cheol-Sik;Cho, Gyu-Pan;Jung, Do-Young;Kim, Dong-Hee
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.2
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    • pp.16-23
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    • 2006
  • This paper presents a novel single-stage high frequency resonant inverter link type DC-DC converter using zero voltage switching with high power-factor. The proposed topology is integrated half-bridge boost rectifier as power factor corrector(PFC) and half-bridge high frequency resonant converter into a single-stage. The input stage of the half-bridge boost rectifier works in discontinuous conduction mode(DCM) with constant duty cycle and variable switching frequency. So that a boost converter makes the line current follow naturally the sinusoidal line voltage waveform. Simulation results have demonstrated the feasibility of the proposed high frequency resonant converter. Characteristics values based on characteristics analysis through circuit analysis is given as basis data in design procedure. Also, experimental results are presented to verify theoretical discussion. This proposed inverter will be able to be practically used as a power supply in various fields as induction heating applications, fluorescent lamp and DC-DC converter etc.

Manufacturing Digital Map Version 2.0 Increased Visual Information (시각적 정보력이 향상된 수치지도 Ver. 2.0제작)

  • Park Kyeong Sik;Lee Jae Kee
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.23 no.3
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    • pp.221-231
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    • 2005
  • Though Digital Map Ver. 2.0 is adequate to GIS, the possibility to gain information from its external form and the ease of producing paper map had retrogressed. In this research, concerned with the problems, we plan to make Digital Map Ver. 2.0, which satisfies the conditions of GIS. It will have geometrical and logical data structure, and also possess informative ability as much as that of Ver. 1.0. For the study, the process to analyze the topographic code, color, code priority order, etc. of paper relief map, digital map Ver. 1.0, and digital map Ver. 2.0 was taken. For the topographical feature with diverse expression, we changed the portrayal of digital map Ver. 2.0 to make it fit the regulations of map portrayal. At the point of topographic code priority order, the rule is to arrange them in the same order as the real territory. However, we made a special code in the case of any change of the locational order. According to the property of this study, we observe the regulations of map portrayal, for the elements related to subjective sense, such as colors. And we give priority on the data construction when the portrayal of topographical feature and the schema of GIS database system are contradictory.

Study on of Process Parameters for Adsorption of Reactive Orange 16 Dye by Activated Carbon (활성탄에 의한 Reactive Orange 16 염료 흡착에 대한 공정 파라미터 연구)

  • Lee, Jong Jib
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.7
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    • pp.667-674
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    • 2020
  • The adsorption of reactive orange 16 (RO 16) dye by activated carbon was investigated using the amount of adsorbent, pH, initial concentration, contact time and temperature as adsorption variables. The investigated process parameters were separation coefficient, rate constant, rate controlling step, activation energy, enthalpy, entropy, and free energy. The adsorption of RO 16 was the highest at pH 3 due to the electrostatic attraction between the cations (H+) on the surface of the activated carbon and the sulfonate ions and hydroxy ions possessed by RO 16. Isotherm data were fitted into Langmuir, Freundlich and Temkin isotherm models by applying the evaluated separation factor of Langmuir (RL=0.459~0.491) and Freundlich (1/n=0.398~0.441). Therefore, the adsorption operation of RO 16 by activated carbon was confirmed as an appropriate removal method. Temkin's adsorption energy indicated that this adsorption process was physical adsorption. The adsorption kinetics studies showed that the adsorption of RO 16 follows the pseudo-second-order kinetic model and that the rate controlling step in the adsorption process was the intraparticle diffusion step. The positive enthalpy change indicated an endothermic process. The negative Gibbs free energy change decreased in the order of -3.16 <-11.60 <-14.01 kJ/mol as the temperature increased. Therefore, it was shown that the spontaneity of the adsorption process of RO 16 increases with increasing temperature.