• Journal of the Korean Chemical Society
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• v.55 no.2
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• pp.177-182
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• 2011

A diketo-type ligand was synthesized by the Knoevenagel condensation reaction of thiophene-2-aldehyde with acetylacetone, subsequently its transition metal complexes with Cu(II), Ni(II), and Co(II) chlorides were also prepared. All the complexes were characterized by various physico-chemical methods. The molar conductivity data reveals ionic nature for the complexes. The electronic spectrum and the EPR values suggest square planar geometry for the Cu(II) ion. Interaction of the Cu(II) complex with CTDNA (calf thymus DNA) was studied by absorption spectral method and cyclic voltammetry. The $k_{obs}$ values versus [DNA] gave a linear plot suggesting psuedo-first order reaction kinetics. The cyclic voltammogram of the Cu(II) complex reveals a quasi-reversible wave attributed to Cu(II)/Cu(I) redox couple for one electron transfer with $E_{1/2}$ values -0.240 V and -0.194 V. respectively. On addition of CTDNA, there is a shift in the $E_{1/2}$ values 168 mV and 18 mV respectively and decrease in Ep values. The shift in $E_{1/2}$ values in the presence of CTDNA suggests strong binding of Cu(II) complex to the CTDNA.

• The Journal of The Korea Institute of Intelligent Transport Systems
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• v.8 no.5
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• pp.71-84
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• 2009

The communication between the center system and the local controller in the Traffic Signal Controller Specification has been specified by a communication line for the exclusive use and the analog modem serial protocol. Therefore, it can't be adapted in the ITS communication network of the TCP/IP protocol being constructed in the local city. The international and domestic ITS device's communication specification has adapted the DATEX-ASN data exchange technique based on the ethernet communication network. So, this study was performed by the purpose of developing the application communication protocol's standard draft based on the TCP/IP communication protocol for the traffic signal controller, to be able to constitute the traffic signal control system in the ITS communication network. The communication format for 23 items of control, status, and database request etc. which are specified in the standard traffic signal controller was developed by appling the DATEX-ASN data interface procedure and structure which are KS ISO X 14827 Part1, 2, ISO/ DIS 15784 Part-3. To test the developed protocol, the application program for the communication items was developed and according to the test result, the encoding and the decoding transection for all communication items was possible.

• Korean Journal of Social Welfare
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• v.63 no.1
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• pp.159-185
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• 2011

This study aims to find out the determinants of male police officers' investigative behavior(active investigation vs. secondary victimization) of sexual violence. For this purpose, a hypothetical model which explains the relationships among the 5 variables (knowledge of law about the investigative role, perception of the protective & connective role, prejudice against the sexual violence, active investigation, and secondary victimization) was developed. Using the data collected from 354 male police officers of 3 cities in Gyeongnam area, the hypothetical model was tested. For data analysis, a structural equation modeling was used, and the final model was found(CFI=0.947, IFI=0.948, RMSEA=0.048). As a result of analyzing the model, the followings were found: (1) Active investigation was increased by knowledge of law about the investigative role, and perception of the protective & connective role, while decreased by prejudice against the sexual violence. (2) Secondary vicimization was decreased by knowledge of law about the investigative role. (3) Prejudice against the sexual violence mediate the effects of knowledge of law about the investigative role, and perception of the protective & connective role on active investigation. (4) Prejudice against the sexual violence was found to have no significant effect on secondary victimization. Based on the findings, multi-educational programs, protocols on investigation of sexual violence, professionalization of the police, and changes in investigation environment as well as a system of collaboration and cooperation between police officer and social worker were suggested as a way to increase active investigation and to decrease secondary victimization.

• Journal of the Korean Chemical Society
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• v.42 no.4
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• pp.369-377
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• 1998

The palladium(II) and platinum(II) complexes(where, $([M(L)_2X_2]$, M=Pd(II), Pt(II); L=isoxazole(isox), 3,5-dimethylisoxazole(3,5-diMeisox), 3-methyl, 5-phenylisoxazole(3-Me, 5-Ph-isox), and 4-amino-3,5-dimethylisoxazole (4-ADI); X=Cl, Br) with isoxazole and its derivatives were investigated on antitumor activity by MM2 and EHMO calculation. Because for all the complexes the ${\sigma}MO$ energy level $(E_{{\sigma}(M-X)})$ between $d_x^{2-}_y^2$ orbital of central metal and px orbital of halogen atom is less than ${\sigma}MO$ energy level $(E_{{\sigma}(M-N)})$ between $d_x^{2-}_y^2$ orbital of central metal and px orbital of N atom, without exception. And judging, from the lower $(E_{\'{o}(m-x)})$ value in trans, the bonding strength was found to be weaker in trans isomer than in cis. For the Pd(II) and Pt(II) complexes which have planar ligands, it was shown that for all the complexes dissociation of X-atom in the Pd(II) complexes is easier than that of X-atom in the Pt(II) complexes in both cis- and trans-complexes. Therefore it suggests that the easier dissociation of $X^-$ ion has some relations with antitumor activity, and a linear equation with correlation coefficient of 0.96 was found between ${\Delta}E_{{\sigma}(N-X)}(E_{{\sigma}(M-N)}-E_{{\sigma}(M-X)})$ and inhibitory activity coefficient, logIA.

• Proceedings of the Korea Water Resources Association Conference
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• 2010.05a
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• pp.1429-1433
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• 2010

수공구조물의 설계, 수자원 관리계획의 수립, 재해영향 검토 등을 수행할 때, 재현기간에 따른 확률개념의 강우량, 홍수량, 저수량 등을 산정하여 사용하게 되며, 보통 대상지역의 장기 수문관측 자료를 이용하여 수문사상의 확률분포를 산정한 후 재현기간을 연장하여 원하는 설계빈도에 해당하는 양을 추정하게 된다. 미계측지역 또는 관측자료의 보유기간이 짧은 지역의 경우는 지역빈도 분석 결과를 이용하게 된다. 지역빈도해석을 위해서는 강우자료들의 동질성을 파악하는 것이 가장 기본적인 과정이 되며 이를 위해 통계학적인 범주화분석이 선행되어야 한다. 지점 빈도분석의 수문학적 동질성 판별을 위해 L-moment 방법, K-means 방법에 의한 군집분석 등이 주로 사용되며 관측소 위치좌표를 이용한 공간보간법을 적용하여 시각화하고 있다. 강수량은 시공간적으로 변하는 수문변량으로서 강수량의 시간적인 특성 또한 강수량의 특성을 정의하는데 매우 중요한 요소이다. 이러한 점에서 본 연구를 통해 강수지점의 공간적인 좌표 및 강수량의 양적인 범주화에 초점을 맞춘 기존 지역빈도분석의 범주화 과정에 덧붙여 시간적인 영향을 고려할 수 있는 요소들을 결정하고 이를 활용할 수 있는 범주화 과정을 제시하고자 한다. 즉, 극치강수량의 발생 시기에 대한 정량적인 분석이 가능한 순환통계기법을 이용하여 관측 지점별 시간 통계량을 산정하고, 이를 극치강수량과 결합하여 시 공간적인 특성자료를 생성한 후 이를 이용한 군집화 해석 모형을 개발하는데 연구의 목적이 있다. 분석 과정에 있어서 시간속성의 정량화 및 일반화는 순환통계기법을 사용하였으며, 극치강수량과 발생시점의 속성자료는 각각의 평균과 표준편차를 이용하였다. K-means 알고리즘을 이용해 결합자료를 군집화 하고, L-moment 방법으로 지역화 결과에 대한 검증을 수행하였다. 속성 결합 자료의 군집화 효과는 모의데이터 실험을 통해 확인하였으며, 우리 나라의 58개 기상관측소 자료를 이용하여 분석을 수행하였다. 예비해석 단계에서 100회의 군집분석을 통해 평균적인 centroid를 산정하고, 해당 값을 본 해석의 초기 centroid로 지정하여, 변동적인 클러스터링 경향을 안정화시켜 해석이 반복됨에 따라 군집화 결과가 달라지는 오류를 방지하였다. 또한 K-means 방법으로 계산된 군집별 공간거리 합의 크기에 따라 군집번호를 부여함으로써 군집의 번호순서대로 물리적인 연관성이 인접하도록 설정하였으며, 군집간의 경계선을 추출할 때 발생할 수 있는 오류를 방지하였다. 지역빈도분석 결과는 3차원 Spline 기법으로 도시하였다.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.20 no.2
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• pp.127-136
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• 2002

DEM(Digital Elevation Model) is used widely in image processing, water resources, construction, GIS, landscape architecture, telecommunication, military operations and other related areas. And it is used especially in producing ortho-photo based on specific DEM and developing 3D GIS database vividly. As LiDAR(Light and Detection And Ranging) system emerged recently, DEM could be developed in urban area more efficiently and more economically, compared to the conventional DEM Production. Traditional method using check points for elevation has tome limitations in structure's height accuracy by LiDAR, because it uses only terrain height. Accordingly after the downtown of Chungju city was selected as a test field in this paper and DEM and digital ortho images was produced by way of LiDar survey, the accuracy was evaluated through analytical plotting map. The result shows that in case of buildings in LiDAR DEM, the accuracy is 0.30 m in X, 0.62 m in Y and RMS is 1.17 m. The difference distribution between DEM and plotting map in range of $\pm$10 cm was 36.2% and $\pm$10 cm $\pm$20 cm was 43.53%. The accuracy of LiDAR in this study meets 1/5,000 which is the regulation for map of NGI(National Geography Institute) and LiDAR can be possibly used in many other applied area.

• Journal of the Korean Society for Railway
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• v.19 no.2
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• pp.135-144
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• 2016

It is essential to lighten the weight of switch girders in order to reduce their costs of manufacturing and make it easier to use them in construction. Lightening the weight of switch is also important to the Maglev 3-way switches system, however, the design variables should be considered very carefully if lightening is to be applied to the system, because these variables are vitally related to the levitation stability. Because Urban Maglev trains have a structure in which train bogie wraps around the guiderail, the adjustment of a girder's height is a possible way to reduce the weight. The safety of the application of this concept is ensured by repeated experiments in a test bed, however, due to a lack of space and budget limits, the design parametric study for the system model can substitute for actual application. The purpose of this paper is to study the design parameters that are concerned with levitation stability while a Maglev train is running on the Maglev 3-way system depending on the weight of the switch girders. In this study, switch girder weight is reduced by adjustment of girder height and girders are and modeled as a flexible body. The effect of the adjustment of girder height on the levitation stability can be analyzed by comparing the velocity of the train when it passes the switch girders, with the lateral gap, and the levitation gap which are obtained from the co-simulation of the Maglev train's dynamics model and flexible switching system. The results of this research will be used to design a Maglev switch.

• Journal of the Korean Data and Information Science Society
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• v.28 no.4
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• pp.797-810
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• 2017

The Korean peninsula is exposed to typhoons every year. Typhoons cause huge socioeconomic damage because tropical cyclones tend to occur with strong winds and heavy precipitation. In order to understand the complex dependence structure between strong winds and heavy precipitation, the copula links a set of univariate distributions to a multivariate distribution and has been actively studied in the field of hydrology. In this study, we carried out analysis using data of wind speed and precipitation collected from the weather stations in Busan and Jeju. Log-Normal, Gamma, and Weibull distributions were considered to explain marginal distributions of the copula. Kolmogorov-Smirnov, Cramer-von-Mises, and Anderson-Darling test statistics were employed for testing the goodness-of-fit of marginal distribution. Observed pseudo data were calculated through inverse transformation method for establishing the copula. Elliptical, archimedean, and extreme copula were considered to explain the dependence structure between strong winds and heavy precipitation. In selecting the best copula, we employed the Cramer-von-Mises test and cross-validation. In Busan, precipitation according to average wind speed followed t copula and precipitation just as maximum wind speed adopted Clayton copula. In Jeju, precipitation according to maximum wind speed complied Normal copula and average wind speed as stated in precipitation followed Frank copula and maximum wind speed according to precipitation observed Husler-Reiss copula.

• Journal of the Korean Institute of Traditional Landscape Architecture
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• v.30 no.4
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• pp.32-43
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• 2012

Hangzhou, in China, is a city that has a history as long as 2,300 years and is renowned due to its natural scenery of a beautiful lake surrounded by gentle green hills. This world wide famous scenery, known as West Lake(西湖), in 2011, was included in the World Heritage Landscape List. Though this place experienced enormous development and changes during thousands of years, historic sceneries did not disappear with the passage of time. In contrary, they are refined and increased attributing to protection efforts from past dynasties. Therefore, research in landscape transition is significant for building livable environment and preserving historical landscape. This paper mainly focuses on history transition of city Hangzhou. First of all, its urban construction and guiding ideology is analyzed. Then, deep meticulous research is carried out on development and preservation achievements for dynasty Tang, Song, Yuan, Ming and Qing. In the end, from a historical point of view, this paper will provide a new perspective which would contribute to sustainable preservation of historical landscape. From the Song Dynasty to the Qing Dynasty, the West Lake through several times of the rectification and construction, the present landscape was completed during thousand years several times through the construction.

• Journal of the Korean Institute of Gas
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• v.4 no.3 s.11
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• pp.9-18
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• 2000

Accident analysis are useful in the design stage of chemical plants and their surrounding structures. Also, analysis results are required for safety management of existing plants. In this paper, the fire and explosion effect by BTX released was evaluated. The computer program was prepared for accident analysis and adopted for evaluating the magnitude of fire (pool fire) and explosion (UVCE) effect. The thermal radiation was used as a measure of fire magnitude and the overpressure as a measure of explosion magnitude. And probit analysis was made for each case. As a case study, benzene tank model was used. The simulation results of explosion of benzene showed that the damage within 20 meters from the accident spot was severe and the damage beyond 60 meters was negligible. The simulation results of fire of benzene showed that the damage in summer is bigger than that in winter. And the damage of city located inland seems to be bigger than that of city in seaside. And thermal radiation effects was negligible beyond 40 meters-distance from the accident spot.