• Proceedings of the Korean Society of Marine Engineers Conference
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• 2011.10a
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• pp.88-89
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• 2011

The study on synthesis of carbon nanomaterials by H2 mixing in counterflow methane diffusion flames has been experimentally conducted. We have also investigated on effect of catalyst and temperature in flame. The counterflow flame was formed by many kind of gas (fuel side using $CH_4-H_2-N_2$ and oxidizer side $N_2-O_2$) and nitrogen shields discharge on each other side to cut off oxidizer of the atmosphere. Ferrocene was used as a metal catalyst for CNTs synthesis. substrate was used to deposit carbon nanomaterials and these were analyzed by FE-SEM. We could find that carbon nanotubes and many kind of carbon nano materials were formed in Cu wire substrate, through this experiment.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.10 s.253
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• pp.996-1002
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• 2006

Experiments in methane-air low strain rate counterflow diffusion flames diluted with nitrogen have been conducted to study the behavior of flame extinction and edge flame oscillation in which flame length is less than the burner diameter and thus lateral conduction heat loss in addition to radiative heat loss could be remarkable at low global strain rates. Critical mole fraction at flame extinction is examined with velocity ratio and global strain rate. Onset conditions of edge flame oscillation and flame oscillation modes are also provided with global strain rate and added nitrogen mole fraction to fuel stream (fuel Lewis number). It is seen that flame length is closely relevant to lateral heat loss, and this affects flame extinction and edge flame oscillation considerably. Edge flame oscillations in low strain rate flames are experimentally described well and are categorized into three: a growing oscillation mode, a decaying oscillation mode, and a harmonic oscillation mode. The regime of flame oscillation is also provided at low strain rate flames. Important contribution of lateral heat loss even to edge flame oscillation is clarified

• 한국연소학회:학술대회논문집
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• 2014.11a
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• pp.379-381
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• 2014

Influence of fuel concentration gradient was investigated near flame extinction limit in buoyancy-suppressed non-premixed counterflow flame with triple co-flow burner. The use of He curtain flow produced a microgravity level of $10^{-2}-10^{-3}g$ in He-diluted non-premixed counter triple co-flow flame experiments. Flame stability map was presented based on flame extinction and oscillation near extinction limit. The stability map via critical diluent mole fraction with global strain rate was represented by varying outer and inner He-diluted mole fractions. The flame extinction modes could be classified into five: an extinction through the shrinkage of the outmost edge flame forward the flame center with and without self-excitation, respectively ((I) and (II)), an extinction via the rapid expansion of a flame hole while the outmost edge flame is stationary (III), both the outermost and the center edge flames oscillate, and then a donut shaped flame is formed or the flame is entirely extinguished (IV), a shrinkage of the outermost edge flame without self-excitation followed by shrinking or sustain the inner flame (V).

• Journal of the Korean Society of Combustion
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• v.8 no.4
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• pp.9-14
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• 2003

High temperature air combustion technology has been utilized by using preheated air over 1100 K and excessive exhaust gas recirculation. Numerical analysis was performed to investigate the combustion characteristics with high temperature deficient oxygen air combustion by adopting a counterflow as a model problem accounting for detailed chemical kinetics. Methane($CH_4$) was used as a test fuel and calculated oxidizer conditions were low temperature high oxygen (300K, $X_{O2}=0.21$) and high temperature low oxygen (1300K, $X_{O2}=0.04$) conditions. The latter case showed that the flame temperature is lower than the former case and its profile showed monotonic decrease from oxidizer to fuel side, without having local maximum flame temperature at high stretch rate. Also, heat release rate was one order lower and it has one peak profile because of low oxygen concentration and heat release rate integral is almost same for stretch rate. High temperature low oxygen air combustion shows low NO emission characteristics.

• Journal of the Korean Society of Combustion
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• v.19 no.2
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• pp.8-14
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• 2014

Experiments were conducted to clarify role of the outermost edge flame on low-strain-rate flame extinction in buoyancy-suppressed non-premixed methane flames diluted with He and $N_2$. The use of He curtain flow produced a microgravity level of $10^{-2}-10^{-3}g$ in $N_2$- and He-diluted non-premixed counterflow flame experiments. The critical He and $N_2$ mole fractions at extinction with a global strain rate were examined at various burner diameters (10, 20, and 25 mm). The results showed that the extinction curves differed appreciably with burner diameter. Before the turning point along the extinction curve, low-strain-rate flames were extinguished via shrinkage of the outermost edge flame with and without self-excitation. High-strain-rate flames were extinguished via a flame hole while the outermost edge flame was stationary. These characteristics could be identified by the behavior of the outermost edge flame. The results also showed that the outermost edge flame was not influenced by radiative heat loss but by convective heat addition and conductive heat losses to the ambient He curtain flow. The numerical results were discussed in detail. The self-excitation before the extinction of a low-strain-rate flame was well described by a dependency of the Strouhal number on global strain rate and normalized nozzle exit velocity.

• Journal of the Korean Society of Combustion
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• v.21 no.1
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• pp.38-45
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• 2016

Flame characteristics and NO emission behavior in $CH_4$/air-air premixed counterflow flames with applying FIR and FGR with $CO_2$ and $H_2O$ were investigated numerically by varying the ratios of FIR and FGR as well as global strain rate. Chemical effects of added $CO_2$ and $H_2O$ via FIR and FGR were analyzed through comparing flame characteristics and NO behaviors from real species($CO_2$ and $H_2O$) with those from their artificial species($XCO_2$ and $XH_2O$) which have the same thermochemical, radiative, and transport properties to those for the real species. The results showed that flame temperature and NO emission with FIR varied much more sensitively than that with FGR. Those varied little irrespective of adding $CO_2$, $H_2O$, and their artificial species to the fuel stream via FIR. However, Those were varied complicatedly by chemical effects of added $CO_2$ and $H_2O$ via FGR. Detailed analyses for them were made and discussed.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.29 no.3 s.234
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• pp.390-401
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• 2005

In this study, extinction limit extension of unsteady $(CH_{4}+N_{2})$/air diffusion flames was investigated experimentally. A spatially locked flame in an opposing jet burner was perturbed by linear velocity variation, and time-dependent flame luminosity, transient maximum flame temperature and OH radical were measured over time with the high speed camera, Rayleigh scattering method and OH laser-induced fluorescence, respectively. Unsteady flames survive at strain rates that are much higher than the extinction limit of steady flames, and unsteady extinction limits extend as the slope of the strain rate increases or the initial strain rate decreases. We verified the validity of the equivalent strain rate concept by comparing the course of unsteady extinction process and steady extinction process, and it was found that the equivalent strain rate concept represents well the unsteady effect of a convective-diffusive zone. To investigate the reason of the unsteady extinction limit extension, we subtracted the time lag of the convective-diffusive zone by using the equivalent strain concept. Then the modified unsteady extinction limits become smaller than the original unsteady extinction limits, however, the modified unsteady extinction limits are still larger than the steady extinction limits. These results suggest that there exist the unsteady behavior of a diffusive-reactive zone near the extinction limit due to the chemical non-equilibrium states associated with unsteady flames.

• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.93-101
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• 2003

The extinction of unsteady diffusion flame was experimentally studied in an opposing jet counterflow burner using diluted methane. The stabilized flame was perturbed by linearly varying velocity change that was generated by pistons installed on both sides of the air and fuel stream. As the results, the extinction of unsteady flame is dependent not only on the history of unsteadiness, but also on the initial condition. We found that there are several unsteady effects on the flame extinction. First, the extinction strain rates of unsteady cases are extended well beyond steady state extinction limits. Second, as the slope of the strain rate change increases, the unsteady extinction strain rate becomes larger. Third, the extension of unsteady extinction strain rate becomes smaller as the initial strain rate increases. We also found that the extension of the extinction limit mainly results from the unsteady response of the reaction zone because there is no retardation effect of a mixing layer for our experimental condition.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.4
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• pp.371-381
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• 2004

Numerical simulation of $CO_2$ addition effects to fuel and oxidizer streams on flame structure has been conducted with detailed chemistry in H$_2$-O$_2$ diffusion flames of a counterflow configuration. An artificial species, which displaces added $CO_2$ in the fuel- and oxidizer-sides and has the same thermochemical, transport, and radiation properties to that of added $CO_2$, is introduced to extract pure chemical effects in flame structure. Chemical effects due to thermal dissociation of added $CO_2$ causes the reduction flame temperature in addition to some thermal effects. The reason why flame temperature due to chemical effects is larger in cases of $CO_2$ addition to oxidizer stream is well explained though a defined characteristic strain rate. The produced CO is responsible for the reaction, $CO_2$＋H=CO＋OH and takes its origin from chemical effects due to thermal dissociation. It is also found that the behavior of produced CO mole fraction is closely related to added $CO_2$ mole fraction, maximum H mole fraction and its position, and maximum flame temperature and its position.