• Title/Summary/Keyword: 대기 환경

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Generation of calibration standard gases using capillary gas divider: uncertainty measurement and method validation (다중 모세관을 이용한 교정용 표준가스의 제조: 불확도와 유효성 평가)

  • Lee, Sangyun;Hwang, Eun-Jin;Jung, Hye-Ja;Lee, Kwang-Woo;Chun, Ki-Joon
    • Analytical Science and Technology
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    • v.19 no.5
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    • pp.369-375
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    • 2006
  • Calibration gas mixtures were prepared using dynamic volumetric method according to ISO 6145-5 and the uncertainty was evaluated. Ten identical capillaries with 0.25 mm in inner diameter and 50 cm in length were applied in this system. Dilution ratio of parent gas was determined by the number of capillaries that passes parent gas and that passes balance gas through. Capillaries were made of Teflon which had good chemical stability against adsorption of gaseous substances. Mechanical valves were introduced in this system in order to minimize the thermal effect of solenoid valves. Concentration of prepared gases were compared with master grade standard gases in cylinders made by RiGAS Co. and calibration of the instrument were completed using comparison method according to ISO 6143. Experimental results showed that the coefficient of variance of diluted oxygen standard gases showed less then 0.2% in most dilution range, that of diluted hydrogen sulfide standard gases showed less then 1.0%. Therefore, it is proven that the standard gases prepared by this system are appropriate to be used as a calibration standards in ambient monitoring, etc.

Assessments of Nitrate Budget by Currents and Biogeochemical Process in the Korea Strait based on a 3D Physical-Biogeochemical Coupled Model (3차원 물리-생지화학 결합 모델을 이용한 대한해협 주변의 해류와 생지화학적 요인에 의한 질산염 유출입 평가)

  • TAK, YONG JIN;CHO, YANG KI
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.27 no.1
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    • pp.1-16
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    • 2022
  • Nitrate (NO3-) plays an important role in aquaculture and ecosystems in the Korea Strait. Observational data propose that ocean currents are crucial to NO3- budget in the Korea Strait. However, assessment of budget by currents and biogeochemical processes has not yet been investigated. This study examines seasonal and spatial variations in NO3- budget by currents and biological processes in the Korea Strait from 2011 to 2019 using a physical-biogeochemical coupled model. Model results suggest that current-driven net supply of NO3- is consumed by uptake of phytoplankton in the Korea Strait. Advective influx is driven by the Tsushima warm current and the influx by the Jeju warm current is approximately one third of it. All of the influxes are transported out to the East Sea through the Korea Strait, of which two third passes through the western channel and the rest through the eastern channel. Annual mean NO3- net transport show that currents supply NO3- year round except for January, but the budget by biogeochemical processes consumes it every season except for winter.

Establishment about Service Level and Evaluation Model of Bus Stop (버스 정류장의 서비스 수준 및 평가모델 구축에 관한 연구)

  • Lee, Won Gyu;Jung, Hun Young
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.2D
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    • pp.217-225
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    • 2008
  • Bus stop is necessary to improve user-focused environment to offer convenient service because of the large number of passengers. This study is to analyze user's evaluation and establishment model of the service levels at bus stop using GAP analysis, IPA and Structural equation model and suggests improvement direction of bus stop. In the GAP analysis, on thirty-one service items of bus stop, the difference appeared highly from the items such as obstacle's facility and the information related to the using bus. In the current IPA service bus operation information, cadence facility and obstacle support facility need to be improved. And in service expectation bus operation information and th exchange facility, the obstacle support facility need to be improved continuously. The evaluation model of bus stop service due to a structure equation's was fitted well by structure equation. In overall satisfaction on bus stop, the waiting satisfaction is more affect the satisfaction of bus use facility. Satisfaction in bus use facility, the related information of bus operation, cadence facility, bus operation information and trans facility, obstacle support facility is more affect compare to other items. The lower overall satisfaction in bus stop is the higher the expectation of overall satisfaction is. Therefore, the information of bus operation and the support facility for the handicapped needs an active improvement plan than ever.

A Study on Moisture Transport of Artificial Lightweight Concrete (인공경량골재 콘크리트의 수분이동 특성에 관한 연구)

  • Lee, Chang Soo;Choi, Sang Hyun;Park, Jong Hyok;Kim, Young Ook
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.4A
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    • pp.373-384
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    • 2009
  • For the first step on the quantitative evaluation of shrinkage reduction and differential shrinkage analysis of lightweight aggregate concrete, this study sets the moisture transport model of concrete by pre-absorbed water of porous lightweight aggregates and measured effective moisture diffusion coefficient, moisture capacity, degree of humidity supply and degree of humidity consumption by water binder ratio and aggregate type. The effective moisture diffusion coefficient in steady state caused by humidity difference between inside and outside of concrete had low value as low water-binder ratio. And in case of same water-binder ratio, effective moisture diffusion of mixtures used normal aggregates were lower than those used lightweight aggregates. To determine moisture store capability of concrete - moisture capacity, moisture contents were measured in 9 humidity conditions. As a result moisture contents of mixtures used lightweight aggregates was higher than mixtures used normal aggregates in all humidity conditions. This study measured lightweight aggregates' degree of humidity supply that applicable to normal atmospheric environment (above RH 50%) and made it quantitatively. Also amount of moisture release was set as a exponential function that represents a clear trend proportion to time and inverse proportion to humidity of the surroundings. As the result of measurement about degree of moisture consumption inside concrete following the internal consumption caused by cement hydration self-drying, it was showed that rapid decrease of humidity, around 10%, at early ages (7~10 days) when water-binder ratio is 0.3 and slow decrease around 5% and 1% when water-binder ratio is 0.4 and 0.5.

Data Assimilation of Radar Non-precipitation Information for Quantitative Precipitation Forecasting (정량적 강수 예측을 위한 레이더 비강수 정보의 자료동화)

  • Yu-Shin Kim;Ki-Hong Min
    • Journal of the Korean earth science society
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    • v.44 no.6
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    • pp.557-577
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    • 2023
  • This study defines non-precipitation information as areas with weak precipitation or cloud particles that radar cannot detect due to weak returned signals, and suggests methods for its utilization in data assimilation. Previous studies have demonstrated that assimilating radar data from precipitation echoes can produce precipitation in model analysis and improve subsequent precipitation forecast. However, this study also recognizes the non-precipitation information as valuable observation and seeks to assimilate it to suppress spurious precipitation in the model analysis and forecast. To incorporate non-precipitation information into data assimilation, we propose observation operators that convert radar non-precipitation information into hydrometeor mixing ratios and relative humidity for the Weather Research and Forecasting Data Assimilation system (WRFDA). We also suggest a preprocessing method for radar non-precipitation information. A single-observation experiment indicates that assimilating non-precipitation information fosters an environment conducive to inhibiting convection by lowering temperature and humidity. Subsequently, we investigate the impact of assimilating non-precipitation information to a real case on July 23, 2013, by performing a subsequent 9-hour forecast. The experiment that assimilates radar non-precipitation information improves the model's precipitation forecasts by showing an increase in the Fractional Skill Score (FSS) and a decrease in the False Alarm Ratio (FAR) compared to experiments in which do not assimilate non-precipitation information.

Enhancing Electrical Properties of Sol-Gel Processed IGZO Thin-Film Transistors through Nitrogen Atmosphere Electron Beam Irradiation (질소분위기 전자빔 조사에 의한 졸-겔 IGZO 박막 트랜지스터의 전기적 특성 향상)

  • Jeeho Park;Young-Seok Song;Sukang Bae;Tae-Wook Kim
    • Journal of the Microelectronics and Packaging Society
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    • v.30 no.3
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    • pp.56-63
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    • 2023
  • In this paper, we studied the effect of electron beam irradiation on sol-gel indium-gallium-zinc oxide (IGZO) thin films under air and nitrogen atmosphere and carried out the electrical characterization of the s ol-gel IGZO thin film transistors (TFTs). To investigate the optical properties, crystalline structure and chemical state of the sol-gel IGZO thin films after electron beam irradiation, UV-Visible spectroscopy, X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) were carried out. The sol-gel IGZO thin films exhibited over 80% transmittance in the visible range. The XRD analysis confirmed the amorphous nature of the sol-gel IGZO films regardless of electron beam irradiation. When electron beam irradiation was conducted in a nitrogen (N2) atmosphere, we observed an increased proportion of peaks related to M-O bonding contributed to the improved quality of the thin films. Sol-gel IGZO TFTs subjected to electron beam exposure in a nitrogen atmosphere exhibited enhanced electrical characteristics in terms of on/off ratio and electron mobility. In addition, the electrical parameters of the transistor (on/off ratio, threshold voltage, electron mobility, subthreshold swing) remained relatively stable over time, indicating that the electron beam exposure process in a nitrogen atmosphere could enhance the reliability of IGZO-based thin-film transistors in the fabrication of sol-gel processed TFTs.

The Effect of Workplace Flexibility on Employees' Organizational Commitment (직장 유연성이 종업원의 조직몰입에 미치는 영향)

  • Chang, Ouk-jin;Lee, Sang-jik
    • Journal of Venture Innovation
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    • v.6 no.3
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    • pp.185-202
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    • 2023
  • The COVID-19 pandemic catalyzed major changes in our work environment, underscoring the critical role of workplace flexibility. While a wealth of research exists on specific flexible work strategies and schedules, a broader understanding of workplace flexibility has been somewhat overlooked. This study aimed to bridge this gap by examining the correlation between workplace flexibility and organizational commitment. Our sample consisted of 300 employees from foreign businesses in the ICT(information and communications technology) service sector and the manufacturing industry, along with those from the top 50 leading Korean enterprises. We bifurcated workplace flexibility into two distinct categories for this study: quantitative and qualitative. Our results revealed that within the quantitative category, the flexibility of continuity of work and flexible place significantly enhanced organizational commitment. Interestingly, the flexibility of work schedules didn't have a marked impact on commitment levels. On the qualitative side, job autonomy and teamwork emerged as significant drivers of organizational commitment. It's worth noting that qualitative aspects of workplace flexibility had a more pronounced effect on organizational commitment than the quantitative elements. These findings highlight the necessity of approaching workplace flexibility from a comprehensive perspective, embracing both its quantitative and qualitative dimensions. For businesses aiming to maximize the benefits of flexibility, it's essential to cultivate a culture of open communication, champion collaboration, and prioritize job autonomy and teamwork. Establishing a work environment that actively supports feedback-oriented communication stands as a key component in this endeavor.

Effect of Experimental Factors on Reduction of Nitrogen Compounds Contained in Crude Methylnaphthalene Oil by Formamide Extraction (포름아미드 추출에 의한 조제 메틸나프탈렌유에 함유된 질소화합물의 저감에 관한 실험인자의 영향)

  • Su Jin Kim
    • Applied Chemistry for Engineering
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    • v.34 no.6
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    • pp.665-669
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    • 2023
  • The crude methylnaphthalene oil (CMNO) contains nitrogen compounds (NCs) such as quinoline (QU), isoquinoline (IQU), and indole (IN). These NCs in the CMNO are treated as impurities contained in the CMNO due to contamination of the atmospheric environment and unpleasant odors. In order to improve the quality of CMNO, this study examined the effect of extraction experimental factors on the reduction of NCs contained in CMNO using CMNO as a raw material and an aqueous formamide solution as a solvent, respectively. The increase in the volume ratio of solvent to feed in initial (S/F)0 in initial increased the distribution coefficient of NCs and the selectivity of NCs in reference to 2-methylnaphthalene (2MNA). Additionally, an increase in operating temperature (T) increased the distribution coefficient of NCs but conversely decreased selectivity. The compositions of QU, IQU, and IN in the raffinate oil recovered through equilibrium extraction under a constant condition (volume fraction of water to solvent in initial (yw,0) = 0.1, (S/F)0 = 9, T = 303 K, liquid-liquid contacting time = 72 h) were reduced by about 58.5 wt%, 61.9 wt%, and 73.4 wt%, respectively, compared to those of CMNO. The formamide extraction method in this study was expected to be an effective reduction method for NCs contained in CMNO.

A global-scale assessment of agricultural droughts and their relation to global crop prices (전 지구 농업가뭄 발생특성 및 곡물가격과의 상관성 분석)

  • Kim, Daeha;Lee, Hyun-Ju
    • Journal of Korea Water Resources Association
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    • v.56 no.12
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    • pp.883-893
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    • 2023
  • While South Korea's dependence on imported grains is very high, droughts impacts from exporting countries have been overlooked. Using the Evaporative Stress Index (ESI), this study globally analyzed frequency, extent, and long-term trends of agricultural droughts and their relation to natural oscillations and global crop prices. Results showed that global-scale correlations were found between ESI and soil moisture anomalies, and they were particularly strong in crop cultivation areas. The high correlations in crop cultivation areas imply a strong land-atmosphere coupling, which can lead to relatively large yield losses with a minor soil moisture deficits. ESI showed a clear decreasing trend in crop cultivation areas from 1991 to 2022, and this trend may continue due to global warming. The sharp increases in the grain prices in 2012 and 2022 were likely related to increased drought areas in major grain-exporting countries, and they seemed to elevate South Korea's producer price index. This study suggests the need for drought risk management for grain-exporting countries to reduce socioeconomic impacts in South Korea.

A Study on Applying the Nonlinear Regression Schemes to the Low-GloSea6 Weather Prediction Model (Low-GloSea6 기상 예측 모델 기반의 비선형 회귀 기법 적용 연구)

  • Hye-Sung Park;Ye-Rin Cho;Dae-Yeong Shin;Eun-Ok Yun;Sung-Wook Chung
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.16 no.6
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    • pp.489-498
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    • 2023
  • Advancements in hardware performance and computing technology have facilitated the progress of climate prediction models to address climate change. The Korea Meteorological Administration employs the GloSea6 model with supercomputer technology for operational use. Various universities and research institutions utilize the Low-GloSea6 model, a low-resolution coupled model, on small to medium-scale servers for weather research. This paper presents an analysis using Intel VTune Profiler on Low-GloSea6 to facilitate smooth weather research on small to medium-scale servers. The tri_sor_dp_dp function of the atmospheric model, taking 1125.987 seconds of CPU time, is identified as a hotspot. Nonlinear regression models, a machine learning technique, are applied and compared to existing functions conducting numerical operations. The K-Nearest Neighbors regression model exhibits superior performance with MAE of 1.3637e-08 and SMAPE of 123.2707%. Additionally, the Light Gradient Boosting Machine regression model demonstrates the best performance with an RMSE of 2.8453e-08. Therefore, it is confirmed that applying a nonlinear regression model to the tri_sor_dp_dp function during the execution of Low-GloSea6 could be a viable alternative.