• Title/Summary/Keyword: 단일 벽 탄소나노튜브

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Surface Conductance Modulation of Single-Walled Carbon Nanotubes and Effects on Dielectrophoresis (단일벽 탄소나노튜브의 표면 전도도 조절 및 유전영동에 대한 영향)

  • Hong Seung-hyun;Jung Se-hun;Kim Young-jin;Choi Jae-bong;Baik Seunghyun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.2 s.245
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    • pp.179-186
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    • 2006
  • Dielectrophoresis has received considerable attention for separating nanotubes according to electronic types. Here we examine the effects of surface conductivity of semiconducting single-walled carbon nanotubes (SWNT), induced by ionic surfactants, on the sign of dielectrophoretic force. The crossover frequency of semiconducting SWNT increases rapidly as the conductivity ratio between the particle and medium increases, leading to an incomplete separation of ionic surfactant suspended SWNT at an electric field frequency of 10 MHz. The surface charge of SWNT is neutralized by an equimolar mixture of anionic surfactant sodium dodecyl sulfate (SDS) and cationic surfactant cetyltrimenthylammonium bromide (CTAB), resulting in negative dielectrophoresis of semiconducting species at 10 MHz. A comparative Raman spectroscopy study shows a nearly complete separation of metallic SWNT.

The Quantitative Characterization of the Dispersion State of Single-Walled Carbon Nanotubes (단일벽 탄소나노튜브의 분산도 정량적 평가)

  • Yoon, Do-Kyung;Choi, Jae-Boong;Kim, Young-Jin;Baik, Seung-Hyun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.31 no.4
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    • pp.483-489
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    • 2007
  • We have investigated quantitative measurement techniques of the degree of dispersion of single-walled carbon nanotubes (SWNTs). SWNTs were suspended in aqueous media using a sodium dodecyl sulfate (SDS) surfactant. SWNTs with different dispersion states were prepared by controlling the intensity and time of sonication and centrifugation. The laser spectroscopic techniques were employed to characterize the dispersion state; i.e., raman fluorescence and absorption spectroscopic techniques. Raman spectroscopy has been used to probe the dispersion and aggregation state of SWNTs in solution. Individually suspended SWNTs show increased fluorescence peaks and decreased roping peaks at a raman shift 267 $cm^{-1}$ compared with the samples containing bundles of SWNTs. The ultraviolet-visible-near infrared (UV-vis-NIR) absorption spectrum of decanted supernatant samples show sharp van Hove singularity peaks

Development of Epoxy Composites with SWCNT for Highly Thermal Conductivity (고방열 재료 개발을 위한 에폭시/단일벽 탄소나노튜브 복합체 개발)

  • Kim, Hyeonil;Ko, Heung Cho;You, Nam-Ho
    • Composites Research
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    • v.33 no.1
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    • pp.7-12
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    • 2020
  • Over the past decade, liquid crystalline epoxy (LCER) has attracted much attention as a promising matrix for the development of efficient heat dissipation materials. This study presents a comprehensive study including synthesis, preparation and chacterization of polymer/inorganic composites using typical 4,4-diglycidyloxybiphenyl (DP) epoxy among LECR. To confirm the thermal conductivity of composite materials, we have prepared composite samples composed of epoxy resin and single-wall carbon nanotube (SWCNT) as a filler. In particular, DP composites exhibit higher thermal conductivity than commercial epoxy composites that use the same type of filler due to the highly ordered microstructure of the LCER. In addition, the thermal conductivity of the DP composite can be controlled by controlling the amount of filler. In particular, the DP composite containing a SWCNT content of 50 wt% has the highest thermal conductivity of 2.008 W/mK.

Actuaots based on Single Walled Carbon Nanotube (단일벽 탄소 나노튜브의 엑츄에이터 응용)

  • Oh, Young-Seok;Cao, Cheng-Fan;Choi, Jae-Boong;Kim, Young-Jin;Baik, Seung-Hyun
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2006.05a
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    • pp.1387-1390
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    • 2006
  • Several actuation mechanism for carton nanotubes has teen reported recently, including actuation by double-layer charge injection and ac voltages applyied to multiple electrodes. Carbon nanotube actuator based on double layer charge injection work well in electrolyte at low voltage. AC dielectrophoresis based on four electrode geometry demonstrated carton nanotubes in solution phase can be oriently manipulated by dielectrophoresis. From this point of view, and in regard to their performance, bucky paper actuator may alternate natural muscle. also, applied AC signal with appropriate magnitude and frequency together with four electrode arrangement has potential to realize nanotube electrokinetics.

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Measurement of Thermal Diffusivity and the Optical Properties of a Carbon Nanotube Dispersion by Using the Thermal Lens Effect (열렌즈 효과를 이용한 탄소 나노 튜브 분산액의 열확산도와 광학적 특성 측정)

  • Park, Hyunwoo;Kim, Hyunki;Kim, Sok Won;Lee, Joohyun
    • New Physics: Sae Mulli
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    • v.68 no.11
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    • pp.1167-1172
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    • 2018
  • Carbon nanotubes (CNTs) are structures of carbon atoms bonded together in hexagonal honeycomb shapes, with multi-walled CNTs having a very high thermal conductivity of $3000W/m{\cdot}K$ and single-walled CNTs having a conductivity of $6000W/m{\cdot}K$. In this work, the transmittance and the thermal diffusivity of a multi-walled carbon nanotube dispersion with a concentration of 1.5 M were measured using a single beam method, a dual beam method, and the thermal lens effect. The nonlinear optical coefficients were obtained by using the z-scan method, which moved the sample in the direction of propagation of the single laser beam, propagation and the thermal diffusivity was measured using a double laser beam. As a pump beam, a diode-pumped solid state (DPSS) laser with a wavelength of 532 nm and an intensity of 100 mW was used. As the probe beam, a He-Ne laser having a wavelength of 633 nm and an intensity of 5 mW was used. The experimental result shows that when the concentrations of the sample were 9.99, 11.10, 16.65, and 19.98 mM, the nonlinear absorption coefficients were 0.046, 0.051, 0.136 and 0.169 m/W, respectively. Also, the nonlinear refractive indices were 0.20, 0.51, 1.25 and $1.32{\times}10^{-11}m^2/W$, respectively, and the average thermal diffusivity was $1.33{\times}10^{-6}m^2/s$.