• Title/Summary/Keyword: 단계선택법

Search Result 292, Processing Time 0.026 seconds

Recovery of the Vanadium and Tungsten from Spent SCR Catalyst Leach Solutions by Hydrometallurgical Methods (SCR 폐촉매 침출액으로부터 습식제련법에 의한 바나듐, 텅스텐의 회수)

  • Choi, In-Hyeok;Moon, Gyeonghye;Jeon, Jong-Hyuk;Lee, Jin-Young;Jyothi, Rajesh Kumar
    • Resources Recycling
    • /
    • v.29 no.2
    • /
    • pp.62-68
    • /
    • 2020
  • In new millennium, wide-reaching demands for selective catalytic reduction (SCR) catalyst have been increased gradually in new millennium. SCR catalyst can prevent the NOx emission to protect the environment. In SCR catalyst the main composition of the catalyst is typically TiO2 (70~80%), WO3 (7~10%), V2O5 (~1%) and others. When the SCR catalysts are used up and disposed to landfills, it is problematic that those should exist in the landfill site permanently due to their extremely low degradability. A new advanced technology needs to be developed primarily to protect environment and then recover the valuable metals. Hydrometallurgical techniques such as leaching and liquid-liquid extraction was designed and developed for the spent SCR catalyst processing. In a first stage, V and W selectively leached from spent SCR catalyst, then both the metals were processed by liquid-liquid extraction process. Various commercial extractants such as D2EHPA, PC 88A, TBP, Cyanex 272, Aliquat 336 were tested for selective extraction of title metals. Scrubbing and stripping studies were tested and optimized for vanadium and tungsten extraction and possible separation. 3rd phase studies were optimized by using iso-decanol reagent.

Efficient Stereoselective Synthesis of (2S,3S,4S)-3,4-Dihydroxyglutamic Acid ((2S,3S,4S)-3,4-다이하이드록시글루타믹산의 효율적인 입체선택적 합성)

  • Jeon, Jongho;Shin, Nara;Lee, Jong Hyup;Kim, Young Gyu
    • Applied Chemistry for Engineering
    • /
    • v.25 no.4
    • /
    • pp.392-395
    • /
    • 2014
  • (2S,3S,4S)-3,4-Dihydroxyglutamic acid (DHGA), a biologically active ${\alpha},{\beta}$-dihydroxy-${\gamma}$-amino acid, was efficiently synthesized from a readily available D-serine derivative in 30% overall yield over 11 steps. The key stereoselective $OsO_4$-catalyzed dihydroxylation reaction controlled by an N-diphenylmethylene group on the amino group of ${\gamma}$-amino-${\alpha},{\beta}$-unsaturated (Z)-ester successfully introduced the diol moiety of the intermediate 5a in 86% with more than 10 : 1 diastereomeric ration. Then it was in turn successfully converted to the desired target compound, (2S,3S,4S)-3,4-DHGA, via simple oxidation and hydrolysis in a highly stereoselective manner and a higher yield than the previous syntheses. This result strongly supports that our synthetic methodology of stereoselective $OsO_4$-catalyzed dihydroxylation should be useful in stereoselctive synthesis of various bioactive compounds with an amino diol moiety.

An Exploratory Study on the Buying Decision-making Process of Automobile Books (자동차전문서적 구매의사 결정과정에 관한 탐색적 연구)

  • Kim, Kil-Hyun;Ha, Kyu-Soo
    • Asia-Pacific Journal of Business Venturing and Entrepreneurship
    • /
    • v.6 no.3
    • /
    • pp.1-18
    • /
    • 2011
  • Publication Industry of scientific technology is showing tendency of decreasing in sales, which clearly draws down curve since 2000. The printing culture is declining whether it is because of trend avoiding pure science or technological science and engineering, advancement of mass media or increasing frequency of using internet. Nevertheless, researcher considered car industry in publication industry as a life-long purpose for study. For this reason, the researcher tried to find the variables of the marketing which give impact on the customers such as student group and consumer who buys cars, when buying professional books. The found variables are expected to have a huge impact on the publication industry of professional books. As a result of research, in the area of the vision and motive, most said that they have "chosen a major in car because they liked car in usual base." In the stage of recognizing the problem, they buy the books when it is inevitably necessary. In the stage of searching for the information, they get information from advertisements, friends, professors, internet or sales clerk in book stores. In the stage of evaluation, they look for the title and the publication date of the books. In addition, in the stage of deciding purchase, "buy immediately" was the most frequent answer while impulsive purchase is the least frequent answer. In the stage of evaluating after purchase, many of them mostly are satisfied with their purchase.

  • PDF

불공정거래행위 규제에 대한 발전적 입법론에 대하여

  • An, Byeong-Han
    • Journal of Korea Fair Competition Federation
    • /
    • no.150
    • /
    • pp.14-29
    • /
    • 2010
  • 비록 부정경쟁방지법의 제정 목적이 부정경쟁행위 등의 방지를 통하여 건전한 거래질서를 유지한다는 의미의 경쟁체제 확립에 있기는 하지만, 우리나라의 경우는 법 제정 당시와는 달리 사실상 산업스파이에 대한 영업비밀의 보호나 주지의 상표 영업표지의 보호와 같은 지적재산권의 보호 법률로서의 역할로 점차 변화하고 있고, 특히 부정경쟁방지법이 주지의 상표에 대한 출처의 혼동에 대한 규제뿐만이 아니라 별도로 저명상표의 희석화(稀釋化) 방지라는 법익, 이에 더 나아가 도메인 네임(Domain Name)의 선점과 원산지 및 품질의 오인(誤認) 야기행위, 주지 저명한 타인의 디자인(Design), 캐릭터(Character)와 같은 상품의 표지에 이르기까지 지적재산권과 관련된 보다 넓은 법익의 보호까지 수행하게 되면서 그 기능은 날로 강화되고 있는 상태이다. 이에 반하여 부정경쟁방지법상의 부정경쟁행위 자체에 대한 규제는 사실상 주지 저명한 타인의 상표나 상품표지의 식별력이나 출처표시기능 등의 보호라는 의미의 분쟁수준을 넘지 못하고 있어, '경쟁법'으로서의 역할은 상대적으로 미약해지고 있는 것 또한 현실이다. 또한, 공정거래법 제23조 제1항 제8호를 비롯하여 현행 공정거래법상의 불공정거래행위에 대한 규정체제를 살펴보면, 해석 여하에 따라서는 부정경쟁방지법상의 부정경쟁행위가 대부분 공정거래법상의 불공정거래행위의 범위 내로 포섭될 수도 있는 상황이기도 하다. 이에 양 법률의 성격과 역할, 앞으로 나아가야 할 방향을 고민하지 않을 수 없고, 이와 같은 논의는 발전적 입법론으로서의 가치를 갖는다. 물론 불공정거래행위(부정경쟁행위)에 대한 규제에 있어서 반드시 독일법체계에 따를 것인지 아니면 미국의 경우를 따를 것인지에 대한 선택 자체가 논리적으로 양립 불가능한 것은 아닐 것이지만 우리나라의 경우는 1980년 "독점규제 및 공정거래에 관한 법률"이 제정되는 과정에서 당시 부정경쟁방지법에 담겨 있던 기존의 부정경쟁행위에 대한 규정과 공정거래법상의 불공정거래행위와의 경합이나 중복문제는 마땅히 검토되었어야 했음에도 불구하고 공정 거래법의 제정과정에서 사실상 부정경쟁방지법의 존재 자체가 간과되어 오늘에 이르고 있다. 그동안 양 법률상의 규정 중복이나 충돌을 정식으로 문제 삼았던 바는 없었지만 '발전적 입법론' 이라는 차원에서 살펴 보면 부정경쟁방지법상의 부정경쟁행위에 대한 규제는 앞으로 공정거래법체계 내의 불공정거래행위로 포섭할 필요가 있고 이를 통하여 경쟁정책의 전문 전담기구로서 불공정거래행위에 대한 규제의 중심에 서 있는 공정거래위원회를 중심으로 효율적이고 통일적인 경쟁정책을 확립을 기대하여 볼 수 있을 것이다. 이 과정에서 공정거래법의 변화 또한 뒤따라야 하는데, 부정경쟁방지법상의 부정경쟁행위의 편입에 따라 불공정거래행위에 대한 규정 일부를 알맞게 다시 수정하는 것에 그치지 않고, 기존 부정경쟁방지법이 인정하고 있었던 사인간(私人間) 금지 또는 예방청구권 또한 공정거래법으로 그대로 편입되는 방향으로의 입법 개선이 이루어질 필요가 있으며, 그동안 '부정경쟁방지법의 공정거래법으로의 편입문제'와는 전혀 무관하게 공정거래법의 사적 구제 및 사소(私訴)의 활성화 차원의 논의로서 공정거래법상 사인간 금지청구권의 도입 여부가 검토되어 왔지만, 앞으로 이 문제는 부정경쟁방지법상 부정경쟁행위의 공정거래법체계 내로의 편입문제와 함께 이를 포함한 더욱 큰 논의로서 다시 적극적으로 검토될 필요가 있다고 본다. 이를 통하여 앞으로 부정경쟁방지법은 특허청을 중심으로 산업스파이에 대한 규제나 영업비밀의 보호와 기타 지적재산권의 보호에 온 힘을 다하고, 공정거래법은 공정거래위원회를 중심으로 불공정거래행위 (부정경쟁행위에 대한 보다 포괄적이고 통일적인 규제를 담당하여 '선택과 집중' 이라는 차원의 각 법률체계의 한 차원 높은 발전 또한 기대해 볼 수 있을 것으로 확신한다. 이러한 합의점을 시작으로 미시적인 다음 단계의 논의에 해당하는 사인간 금지청구권의 허용범위나 허용요건, 남용을 방지하기 위한 제도적 장치, 단체소송 등의 허용 여부 등의 논의도 함께 하여야 할 것이고, 이 과정에서 미국의 클레이튼법(Clayton Act)이나 가까운 일본의 입법례를 참고하여 우리의 실정에 맞는 규제의 틀을 마련함이 타당할 것이고, 이를 통하여 궁극적으로 그동안 공정거래법의 사적 집행의 활성화를 통한 경쟁질서의 확립의 강화라는 이상에 더욱 가까워질 수 있는 좋은 입법적 변화의 모습을 볼 수 있을 것이라 생각한다.

  • PDF

Documentation of Printed Hangul Images of the Selected Area by Finger Movement (손가락 이동에 의해 선택된 영역의 인쇄체 한글 영상 문서화)

  • Beak, Seung-Bok
    • Journal of the Korean Institute of Intelligent Systems
    • /
    • v.12 no.4
    • /
    • pp.306-310
    • /
    • 2002
  • In this paper, we realized a system that converts the Korean alphabet (Hangul) images, which are in any domain that is formed by the finger movement on the Hangul document, to the editable characters and then outputs them to the word editor. The domain of hand is separated from the sphere of document in the pre-process step of image. The centroid point of hand is drawn by the maximum circular movement method. After the system recognizes the hand with the circular pattern vector algorithm, finds out the position of finger by the distance spectrum and then draws out the sphere of selected character image by the finger movement to divide the characters into character units by applying the histogram between the Hangul characters. We standardized the characters of various sizes. We used the circular pattern vector algorithm that grafts on the fuzzy inference to divert the character images of the domain, which user wants, to the editable characters by comparing the characteristic vectors between the standard pattern character and the inputted character and by recognizing the character.

Factors Influencing on Continuous Usage Intention of Smartphone Based on the TAM (Technology Acceptance Model) (기술수용모델 기반 스마트폰 지속사용의도에 미치는 영향)

  • Nam, Soo-Tai;Jin, Chan-Yong
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.21 no.11
    • /
    • pp.2076-2082
    • /
    • 2017
  • Users of Smartphone in Korea are using the majority of the economically active population over 99% and experts have seen that they have reached saturation after the initial formation stages. The purpose of this study is to investigate the influencing factors of dominant design attributes on the intention of continuous use of Smartphone users. Predictor factors were selected perceived usefulness and perceived ease of use suggested on extended the technology acceptance model. The concept model was completed by selecting the dominant design attribute as a mediator. Participants of this study were 135 Smartphone users in Busan Gyeongnam and Iksan Jeonbuk province in accordance with convenience sampling. IBM SPSS Statistics 19 were employed for descriptive statistics, Smart PLS (partial least squares) was employed for confirmatory factor analysis and path analysis of casual relationship among variables. Therefore, when moderating mediated factor of dominant design and attitude, factor of continuous usage intention showed 76% explanatory power.

Incremental Techniques for Timing Analysis Considering Timing and Circuit Structure Changes (지연시간과 회로 구조 변화를 고려한 증가적 타이밍 분석)

  • O, Jang-Uk;Han, Chang-Ho
    • The Transactions of the Korea Information Processing Society
    • /
    • v.6 no.8
    • /
    • pp.2204-2212
    • /
    • 1999
  • In this paper, we present techniques which perform incremental timing analysis using Timed Boolean Algebra that solves the false path problem and extracts the timing information in combinational circuits. Our algorithm sets histories of internal inputs that are substituted for internal output and extracts maximal delays through checking sensitizability of primary outputs. Once finding the sum of primitive delay terms, then it applies modified delay with referencing histories of primary output and it can extract maximal delays of primary outputs fast and efficiently. When the structure of circuit is changed, there is no need to compute the whole circuit again. We can process partial timing analysis of computing on the gates that are need to compute again. These incremental timing analysis methods are considered both delay changes and structure of circuit, and can reduce the costs of a trial error in the circuit design.

  • PDF

Determination of Fermentation Specific Carcinogen, Ethyl Carbamate, in Kimchi (김치에서 발효 식품의 고유 발암원 Ethyl Carbamate 검출)

  • Koh, Eun-Mi;Kwon, Hoon-Jeong
    • Korean Journal of Food Science and Technology
    • /
    • v.28 no.3
    • /
    • pp.421-427
    • /
    • 1996
  • Ethyl carbamate is an animal carcinogen and a suspected human carcinogen found in fermented foods and beverages. For the determination of ethyl carbamate in typical Korean diet, an analytical method was established for the food as complex as Kimchi. Kimchi samples collected from various locations in the country were homogenized and extracted four times with ethyl acelate. Following concentration and reconstitution with water, the extract was loaded onto $C_{18}$ column. Fraction containing ethyl carbamate was eluted with methanol, while most of the red pigment of the sample was retained on the column. The eluent was further purified with alumina, followed by Florisil column. The final eluent was analyzed by gas chromatography mass spectrometry in the selected ion monitoring mode. None of the twenty Kimchi samples showed ethyl carbamate level higher than 4.6 ppb without correction for the recovery. The concentration of ethyl carbamate in Kimchi increased as pH decreased, suggesting fermentation dependent formation of ethyl carbamate.

  • PDF

Change of Ammonia Consumption with Gas Turbine Output in DeNOx System for a 580 MW Combined Cycle Power Plant (580 MW급 복합발전소 탈질설비에서 가스터빈 출력에 따른 암모니아 소모량 변화)

  • Jang, Yong-Woo;Yoo, Ho-Seon
    • Plant Journal
    • /
    • v.15 no.3
    • /
    • pp.23-28
    • /
    • 2019
  • In this study, ammonia consumption by gas turbine output was adjusted to find out the amount of ammonia consumption that complies with the enhanced Air Quality Preservation Act and internal regulation emission standards in SCR type DeNOx System for a 580 MW Sejong Combined Cycle Power Plant. For measurements, the gas turbine output was varied to 50, 99, 149, 198 MW and ammonia consumption was adjusted with the combustion gas and ammonia supply conditions fixed at each stage. When the emission limit were change from 10 ppm to 8 ppm, ammonia consumption was increased from 78, 93, 105, 133 kg/h to 89, 113, 132, 176 kg/h. The increase rate of ammonia consumption was 14, 22, 26, 32% per output category compared to the 10 ppm emission limit, which was shown to increase as output increased.

Linear interpolation and Machine Learning Methods for Gas Leakage Prediction Base on Multi-source Data Integration (다중소스 데이터 융합 기반의 가스 누출 예측을 위한 선형 보간 및 머신러닝 기법)

  • Dashdondov, Khongorzul;Jo, Kyuri;Kim, Mi-Hye
    • Journal of the Korea Convergence Society
    • /
    • v.13 no.3
    • /
    • pp.33-41
    • /
    • 2022
  • In this article, we proposed to predict natural gas (NG) leakage levels through feature selection based on a factor analysis (FA) of the integrating the Korean Meteorological Agency data and natural gas leakage data for considering complex factors. The paper has been divided into three modules. First, we filled missing data based on the linear interpolation method on the integrated data set, and selected essential features using FA with OrdinalEncoder (OE)-based normalization. The dataset is labeled by K-means clustering. The final module uses four algorithms, K-nearest neighbors (KNN), decision tree (DT), random forest (RF), Naive Bayes (NB), to predict gas leakage levels. The proposed method is evaluated by the accuracy, area under the ROC curve (AUC), and mean standard error (MSE). The test results indicate that the OrdinalEncoder-Factor analysis (OE-F)-based classification method has improved successfully. Moreover, OE-F-based KNN (OE-F-KNN) showed the best performance by giving 95.20% accuracy, an AUC of 96.13%, and an MSE of 0.031.