• Analytical Science and Technology
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• v.7 no.1
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• pp.33-39
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• 1994

The purpose on this study was to develop a new improved chromatographic method for determination of trace phenols from environmental waste water. The research was carried out with selected 8 phenols, and solid-phase extraction was employed as sample pretreatment method. The coupling of XAD-4 and Dowex $1{\times}8$ resin as preconcentration column increased the selectivities toward interferences coexisted in matrix. Automation was accomplished with on-line process of pretreatment and HPLC system. After elution of sample through XAD-4 column, phenols were adsorbed by dispersion force, then displaced from it by ACN basified, simultaneously and selectively readsorbed via anion exchange on Dowex $1{\times}8$. Dowex $1{\times}8$ column was washed by water. Phenols readsorbed were removed from Dowex $1{\times}8$ column by a minimum volumn of methanol containing HCl. Each pretreatment step was connected by switching valves and the eluate was directly on-line injected to obtain fast and reliable results into the HPLC. Recovery of phenols was greater than 90%. To examine utility of this method, analysis of phenols from laboratory waste water sample which was added some organic pollutants to find with phenols on environmental waste water were also accomplished without their interference effects.

• Journal of Korean Society of Forest Science
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• v.86 no.1
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• pp.17-24
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• 1997

As the first step to estimate the potential natural vegetation distribution of the globe, the best spherical interpolation method was developed to the temperature and precipitation which have close relation to the distribution pattern of world natural vegetation. For developing the interpolation method, a named Light Climatic Dataset composed of 1,060 stations around the globe was randomly divided into halves of feeding side and target side. The discrepancy between the observed and estimated values at the target stations was compared with combinations of parameters and methods. The estimated values were calculated to each combination which is all-out, constant radius and constant station methods in the selection of the feeding stations, n square reciprocal and negative exponential functions in weighting function of distance between feeding stations and each target, and oval weighting in direction of the feeding stations from each target. As a result, it turned out that the spherical interpolation with negative exponential weighting function fed from the constant radius stations ovally weighed yields the best estimates both for temperature and for precipitation. The parameters for temperature are $30^{\circ}$ in constant radius, 0.78 in negative exponential function and 0.4 in oval weighting, and for precipitation are $30^{\circ}$, 0.53 and 0.4, respectively.

• The Journal of the Korea Contents Association
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• v.15 no.7
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• pp.21-29
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• 2015

This paper proposes a novel two-tier optimization approach for decision making in many-objective problems. Because the Pareto-optimal solution ratio increases exponentially with an increasing number of objectives, simply finding the Pareto-optimal solutions is not sufficient for decision making in many-objective problems. In other words, it is necessary to discriminate the more preferable solutions from the other solutions. In the proposed approach, user preference-oriented as well as diverse Pareto-optimal solutions can be obtained as candidate solutions by introducing an additional tier of optimization. The second tier of optimization employs the corresponding secondary objectives, global evaluation and crowding distance, which were proposed in previous works, to represent the users preference to a solution and the crowdedness around a solution, respectively. To demonstrate the effectiveness of the proposed approach, decision making for some benchmark functions is conducted, and the outcomes with and without the proposed approach are compared. The experimental results demonstrate that the decisions are successfully made with consideration of the users preference through the proposed approach.

• Journal of the Korean Society of Hazard Mitigation
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• v.10 no.1
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• pp.23-28
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• 2010

Reliable dynamic analysis is essential in order to properly maintain structures so that structural hazards may be minimized. The finite element method (FEM) is proven to be an affective approximate method of structural analysis if proper element types and meshes are chosen. When the method is applied to dynamics analyzed in time domain, the meshes may need to be modified at each time step. As many meshes need to be generated, adaptive mesh generation schemes have become an important part in complex time domain dynamic finite element analyses of structures. In this paper, an adaptive mesh generation scheme for dynamic finite element analyses of structures is described. The concept of representative strain value is used for error estimates and the refinements of meshes use combinations of the h-method (node movement) and the r-method (element division). The validity of the scheme is shown through a cantilever beam example under a concentrated load with varying values. The example shows reasonable accuracy and efficient computing time. Furthermore, the study shows the potential for the scheme's effective use in complex structural dynamic problems such as those under seismic or erratic wind loads.

• Elastomers and Composites
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• v.43 no.3
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• pp.157-165
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• 2008

Suspension polymerization was carried out to synthesize poly(butyl methacrylate) (PBMA) composite particles containing carbon black. Water was selected as a reaction medium, hydrophobic silica as a stabilizer and azobisisobutyronitrile as an initiator. Concentration of stabilizer was varied from 0.67 to 2.55 weight% with respect to the water, and that of initiator was varied from 0.25 to 3.00 weight% with respect to the butyl methacrylate (BMA) monomer. All polymerization reactions were conducted at 75$^{\circ}C$. It is found that stabilizer concentration has no impact on reaction kinetics, while an increase in initiator concentration enhances polymerization reaction rate. Increase of carbon black concentration from 1 to 3 to 5 wt% into PBMA displayed progressive decrease in reaction conversion. The particle diameter of PBMA composite particles containing carbon black was found to be between 5 and 30 ${\mu}m$. Glass transition was determined to range from 23.8 to 24.7$^{\circ}C$, irrespective of variation in the concentration of stabilizer, initiator or carbon black.

• Resources Recycling
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• v.29 no.6
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• pp.114-124
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• 2020

In the cement industry, NOx emission is recognized as an important problem, and NOx reduction technologies can be divided into process change, staged combustion, low NOx burner, selective non-catalytic reduction and selective catalytic reduction method. The operation of the selective non-catalytic reduction method, which is the most used in the cement industry, is expected to make it difficult to meet the emission standards to be strengthened in the future, and it is necessary to improve equipment such as SCR and secure technologies. Recently, we are developing technologies for simultaneous application of SNCR and SCR, dust and denitrification filter technology, and removal technology using NO oxidation.

• Computational Structural Engineering
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• v.6 no.4
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• pp.83-88
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• 1993

A time-discontinuous Galerkin method based upon using a finite element formulation in time has evolved. This method, working from the differential equation viewpoint, is different from those which have been generally used. They admit discontinuities with respect to the time variable at each time step. In particular, the elements can be chosen arbitrarily at each time step with no connection with the elements corresponding to the previous step. Interpolation functions and weighting functions are taken to be discontinuous across inter-element boundaries. These methods lead to a unconditional stable higher-order accurate ordinary differential equation solver.

• Microbiology and Biotechnology Letters
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• v.28 no.4
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• pp.223-227
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• 2000

A novel two-step acetone treatment method was developed to enhance the enantioselectivity of Candida rugosa lipase (CRL) toward the hydrolysis of racemic naproxen methyl ester. The acetone-teated CRL was considerably more enantioselective than the crude CRL, yielding an enantiomeric excess of 98~100%. The crude and acetone-treated CRLs were subjected to anion exchange chromatography, and their chromatography profiles were compared. In consequence, both chromatography profiles were found to be almost identical, resulting in two separate lipase peaks (lipase A and B). The lipase B, which is known to be less enantioselective, was treated with acetone using a two-step treatment method. The enantioselectivity of acetone-treated lipase B was dramatically increased, yielding an enantiomeric excess of 99%.

• Electrical & Electronic Materials
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• v.8 no.4
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• pp.464-471
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• 1995

메그네트론 스퍼터링으로 제작한 고밀도 다층박막($Co_75{{Pt_12}{Cr_13}}$합금) 디스크를 투과전자현미경을 이용해 단면 및 평면의 미세조직의 조사 혹은 미소부위 성분분석을 할 경우, 선행되어야하는 시편준비 경로와 각 단계별 구체적방법 및 그 효과를 연구하였다. Ion밀링시간이 증가함에 따라 시료가 얇게 되는과정에서 스퍼터링된 물질이 관찰될 시편부위의 다른 표면에 증착되므로써 미세조직의 선명도를 해칠 수 있고, 이로인한 해석상의 오류가능성이 시사되었다. 또한, 자기박막 디스크와 같이 다층으로 구성된 단면분석용 시료에서는 서로 맞붙인 실리콘 단결정 접착면을 따라 밀링속도가 선택적으로 커서 우선축이 생김으로써 양질의 시편을 얻기 어려운 문제점이 제기되었다. 이같은 문제를 포함한 전자현미경 시료준비과정에서 생길 수 있는 문제를 해결할 수 있는 실마리와 이를 이용해 수행한 전자현미경 분석결과 및 효과적인 시편준비방법이 본 논문에서 언급되었다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1997.04a
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• pp.141-145
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• 1997

스퍼터링법으로 제조한 CoNbZr/Cu/CoNbZr 다층막에 대해 습식 식각법으로 패턴을 형성하기 위해 새로운 식각 용액을 제조하여 이 용액의 최적의 식각 조건에 대해 연구하였다. 염기성 수용액은 농도에 관계없이 Cu만을 선택적으로 식각하며 CoNbZr 비정질 박막은 식각하지 않았다. 그러나, 본 연구에서 제조 한 17.5 mol%의 염기성 수용액에 HF를 20 mol% 혼합한 식각 용액으로 CoNbZr/Cu/CoNbZr 다층막을 동시에 식각할 수 있었다. 또한 이 식각 용액은 CoNbZr/Cu/CoNbZr 다층막을 3단계로 식각하고 식각된 단면은 이방성 구조를 가지며, 매우 우수한 식각 특성을 나타내었다.