• Title/Summary/Keyword: 다양한 치환율

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Study on TCO Coatings for Flexible Display Devices (Flexible 디스플레이용 TCO 코팅 연구)

  • Lee, Geon-Hwan;Kim, Do-Geun;Park, Mi-Rang;Lee, Seong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.11a
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    • pp.55-56
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    • 2007
  • 디스플레이용 전극 소재로 사용되는 투명 전도막은 높은 가시광 투과율 (89%이상)과 우수한 전기전도성(비저항 10$^{-4}{\Omega}cm$ 이하)을 동시에 가지므로 LCD, PDP, OLED 소자의 핵심소재로 인식되고 있다. 투명 전도막은 광학적 밴드갭이 3.5eV 이상인 wide-gap 반도체로서, 산화인듐($In_2O_3$)에 주석(Sn), 아연(Zn) 등을 치환고용 시킨 ITO, IZO, 산화아연(ZnO)에 Al 혹은 Ga을 치환고용 시킨 AZO, GZO 등 다양한 재료에 대한 연구가 활발하게 진행되고 있다. 본 연구에서는 플라즈마 정밀 제어 기술을 이용하여 80$^{\circ}C$이하의 저온 코팅 공정 조건에서 우수한 비저항( $2{\times}10^{-4}$ ${\Omega} cm $)을 나타낼 수 있는 TCO 코팅 공정 기술을 개발하였으며 이러한 연구결과는 차세대 디스플레이 소자로 예측되고 있는 Flexible 디스플레이 소자의 전극 재료로 활용될 수 있을 것으로 기대된다.

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PCR and RFLP variation of conserved region of small subunit ribosomal DNA among Acanthamoeba isolates assigned to either A. castellanii or A. polyphaga (카스텔라니가시아메바 혹은 대식가시아메바로 분류된 분리주간의 ribosomaIDNA conserved region의 PCR-RFLP의 다양성)

  • 공현희;정동일
    • Parasites, Hosts and Diseases
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    • v.34 no.2
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    • pp.127-134
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    • 1996
  • Twelve isolates of Accnthamoebc app. assigned to either A. castellanii or A. poIMphoSa, and type strains of A. culbefsoni, A. henIWi, A. pqkestinefiE, and A. astronyxi,s were examined by restriction fragment length polymorphism (RFLP) of a conserved region of small subunit ribosomal RMh gene (ssu rDNA) amplified by polymerase chain reaction (PCR). The PCR products of the isolates measured approximately 910-930 bp, except for that of A. astronyxis which was extraordinarily long, approximately 1,170 bp. Average of estimated sequence divergence of the amplified DNA among the isolates assigned to A. castellanii was 9.8% whereas that among the isolates assigned to A. polvphusn 9.6%. The maximum intraspecific sequence divergence among the isolates assigned to A. costellanii was observed between the Chang and Ma strains (17.3%) while that among the isolates assigned to A. poIWphosa was observed between KA/S3 and KA/S7 strains (16.1%). The both maximum sequence divergences were much greater than the minimum interspecific sequence divergence between A. cnstellnnii and A. polwphasa (2.6%) which appeared between the Castellani (or CCAP 1501/12 g) and KA/S3 strains. The PCR-RFLP patterns of A. culbertsoni, A. healyi, A. palestinensis, and A. ostronvxis were quite diverse from one another and from those of isolates assigned to either A. castellanii or A. polyphoga. It is suggested that taxonomic validity of the isolates assigned to either A. castellnnii or A. polyphoga should be reevaluated.

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Finite Element Analysis for Investigating the Behavior of Gravel Compaction Pile Composite Ground (GCP 복합지반의 거동분석을 위한 유한요소해석)

  • Kim, Gyeong-eop;Park, Kyung-Ho;Kim, Ho-Yeon;Kim, Daehyeon
    • Journal of the Korean Geosynthetics Society
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    • v.17 no.3
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    • pp.19-32
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    • 2018
  • Gravel Compaction Pile (GCP) method is currently being designed and constructed by empirical method because quantitative design method has not been developed, leading to various types of and frequent destruction such as expansion failure and shear failure and difficulties in establishing clear cause and developing measure to prevent destruction. In addition, despite the difference with domestic construction equipment and material characteristics, the methods applied to the overseas ground is applied to the domestic as it is, leading to remarkable difference between applied values and measured values in variables such as bearing capacity and the settlement amount. The purpose of this study was, therefore, to propose a reasonable and safe design method of GCP method by analyzing the settlement and stress behavior characteristics according to ground strength change under GCP method applied to domestic clay ground. For the purpose, settlement amount of composite ground, stress concentration ratio, and maximum horizontal displacement and expected location of GCP were analyzed using ABAQUS. The results of analysis showed that the settlement and Settlement reduction rate of composite ground decreased by more than 60% under replacement ratio of 30% or more, that the maximum horizontal displacement of GCP occurred at the depth 2.6 times pile diameter, and that the difference in horizontal displacement is slight under replacement ratio of 30%.

Synthesis of 2,3-Dihydrobenzofuran Derivatives over HMCM-41 Catalysts (HMCM-41 촉매에서 2,3-Dihydrobenzofuran 유도체의 합성)

  • Kim, Hyung Jin;Seo, Gon;Kim, Jung-Nyun;Choi, Kyung Ho
    • Korean Chemical Engineering Research
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    • v.43 no.6
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    • pp.662-667
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    • 2005
  • 2,3-Dihydrobenzofuran derivatives, important intermediates of medicines and agricultural chemicals, were prepared from aryl methallyl ethers over MCM-41 mesoporous material catalysts. Two mesoporous materials with Si/Al mole ratios of 40 and 50 were prepared to investigate the effect of acid site concentration on their catalytic activities. Aryl methallyl ethers with various substituents on their benzene rings were used to investigate the effect of electron density on benzene ring on the conversion of the ethers and the yield of 2,3-dihydorbenzofuran derivatives. The catalyst with a high acid site concentration showed high conversions, but it is difficult to correlate the yield of the derivatives with the acid site concentration. The increase in the electron density of the benzene ring by introducing electron-donating groups accelerated Claisen rearrangement reaction, resulting in the enhanced yield of the derivatives. On the other hand, the decrease in the electron density by introducing electron-attracting groups accelerated the cracking reaction of aryl methallyl ether by acid catalysts, producing phenol derivatives rather than 2,3-dihydrobenzofuran derivatives.

Clinical Study of Composite Valve Graft Replacement of the Aortic Root (대동맥 근부 복합 인공 판막 도관 치환술에 관한 임상적 고찰)

  • Park, Kwon-Jae;Woo, Jong-Soo;Cho, Gwang-Jo;Bang, Jung-Hee;Jeong, Sang-Seok
    • Journal of Chest Surgery
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    • v.43 no.3
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    • pp.260-265
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    • 2010
  • Background: A composite valve graft replacement has been used for a variety of aortic root diseases. The aim of this study was to evaluate the mid-term results of this technique. Material and Method: We conducted a retrospective analysis of aortic root composite valve graft replacements in 39 patients and these procedures were done at our institution between 1992 and 2009. The mean age of the patients was $49.2{\pm}16.4$ years. The mean follow-up was $64.2{\pm}53.4$ months (maximum: 176 months). Result: There were 4 hospital deaths (8.6%) due to emergency aortic dissection and 4 late deaths owing to several causes. The causes of late death were 2 ruptures of a remnant aneurysm, 1 subdural hemorrhage and 1 paravalvular leakage. The calculated survival rate was 93.5%, 85.0% and 85.0% at 1, 5 and 10 years, respectively. There were 3 cerebrovascular accidents during the follow up period. The rate of freedom from cerebrovascular accidents was 97.0%, 92.0% and 80.0% at 1, 5 and 10 years, respectively. All of these brain accidents were hemorrhage-related complications. Conclusion: A composite valve graft replacement of the aortic root was associated with favorable results. So, this technique seems to be a good method to treat various aortic root diseases.

Enhanced Expression and Substrate Specificity Changes of Barley $\alpha$-Amylase Isozyme 2 in E. coli by Substitution of the $42^{nd}$ Alanine Residue with Proline (42번째 alanine 잔기의 proline 치환에 의한 보리 $\alpha$-amylase isozyme 2의 대장균 내 발현 증가 및 기질특이성 변화)

  • Choi, Seung-Ho;Jang, Myoung-Uoon;Lee, Hong-Gyun;Svensson, Birte;Kim, Tae-Jip
    • Korean Journal of Food Science and Technology
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    • v.42 no.2
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    • pp.198-203
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    • 2010
  • Although barley $\alpha$-amylase isozyme 1 (AMY1) and 2 (AMY2) share up to 80% of amino acid sequence identity, their enzymatic properties differ remarkably. In this study, the 42nd alanine residue of AMY2 was replaced with another random amino acid via saturation mutagenesis. Eight out of 370 recombinant E. coli cells showing enhanced starch-hydrolyzing activity were characterized as possessing the same proline residue instead of alanine. Even though the specific activity of AMY2-A42P is reduced to 81% of wild-type, its expression level and purification yield were enhanced by approximately 2 and 4 times that of AMY2, respectively. Characterization of its enzymatic properties confirmed that AMY2-A42P is similar to that of wild-type. However, its specificity to starch substrates is likely to be intermediate between AMY1 and AMY2.

Characteristics of EVA-Polymer Modified Mortars Recycling Rapid-chilled Steel Slag Fine Aggregate (급냉 제강슬래그를 재활용한 EVA-폴리머 시멘트 모르타르의 특성)

  • Hwang, Eui-Hwan;Kim, Jin-Man
    • Applied Chemistry for Engineering
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    • v.19 no.6
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    • pp.652-660
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    • 2008
  • For the recycling of rapid-chilled steel slag, the mechanical strengths and physical properties of EVA-polymer modified mortars with the various replacement ratios of rapid-chilled steel slag were investigated. Twenty five specimens of polymer modified mortars were prepared with the five different amounts of EVA-polymer modifier (0, 5, 10, 15, 20 wt%) and rapid-chilled steel slag (0, 25, 50, 75, 100 wt%). For the investigation of the characteristics of polymer modified mortars, the measurements such as water-cement ratio, unit volume weight, air content for fresh mortar and compressive strength, flexural strength, water absorption, hot water resistance, porosity and SEM investigation for curing specimens were conducted. As a results, with an increase in the replacement ratio of rapid-chilled steel slag, water-cement ratios decreased but unit volume weight increased remarkably. With increasing EVA-polymer modifier and the replacement ratio of rapid-chilled steel slag, percent of water absorption decreased but compressive and flexural strengths increased remarkably. By the hot water resistance test, mechanical strengths decreased but total pore volume and porosity increased remarkably. In the SEM observation, the components of specimen were shown to stick to each other in the form of co-matrix phase before hot water resistance test, but polymer modifier of co-matrix phase was decomposed or deteriorated after hot water resistance test.

Mixture-Proportioning Model for Low-CO2 Concrete Considering the Type and Addition Level of Supplementary Cementitious Materials (혼화재 종류 및 치환율을 고려한 저탄소 콘크리트 배합설계 모델)

  • Jung, Yeon-Back;Yang, Keun-Hyeok
    • Journal of the Korea Concrete Institute
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    • v.27 no.4
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    • pp.427-434
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    • 2015
  • The objective of this study is to establish an rational mixture-proportioning procedure for low-$CO_2$ concrete using supplementary cementitious materials (SCMs) achieving the targeted $CO_2$ reduction ratio as well as the conventional requirements such as initial slump, air content, and 28-day compressive strength of concrete. To evaluate the effect of SCM level on the $CO_2$ emission and compressive strength of concrete, a total of 12537 data sets were compiled from the available literature and ready-mixed concrete plants. The amount of $CO_2$ emission of concrete was assessed under the system boundary from cradle to concrete production stage at a ready-mixed concrete plant. Based on regression analysis using the established database, simple equations were proposed to determine the mixture proportions of concrete such as the type and level of SCMs, water-to-binder ratio, and fine aggregate-to-total aggregate ratio. Furthermore, the $CO_2$ emissions for a given concrete mixture can be straightforwardly calculated using the proposed equations. Overall, the developed mixture-proportioning procedure is practically useful for determining the initial mixture proportions of low-$CO_2$ concrete in the ready-mixed concrete field.

Maturity-Based Model for Concrete Compressive Strength with Different Supplementary Cementitious Materials (혼화재 치환율을 고려한 성숙도 기반의 콘크리트 압축강도 평가 모델)

  • Mun, Jae-Sung;Yang, Keun-Hyeok;Jeon, Yong-Soo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.6
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    • pp.82-89
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    • 2014
  • The purpose of this study is to propose a simple model to evaluate the compressive strength development of concrete with various supplementary cementitious materials (SCMs) and cured under different temperatures. For the generalization of the model, the ACI 209 parabola equation was modified based on the maturity function and then experimental constants A and B and 28-day compressive strength were determined from the regression analysis using a total of 265 data-sets compiled from the available literature. To verify the proposed model, concrete specimens classified into 3 Groups were prepared according to the SCM level as a partial replacement of cement and curing temperature. The analysis of existing data clearly revealed that the 28-day compressive strength decreases when the curing temperature is higher and/or lower than the reference curing temperature ($20^{\circ}C$). Furthermore, test results showed that the compressive strength development of concrete cured under $20^{\circ}C$ until an early age of 3 days was marginally affected by the curing temperature afterward. The proposed model accurately predicts the compressive strength development of concrete tested, indicating that the mean and standard deviation of the ratios between predictions and experiments are 1.00 and 0.08, respectively.

Service Life Variation Considering Increasing Initial Chloride Content and Characteristics of Mix Proportions and Design Parameters (초기 염화물량의 증가와 배합 및 설계 변수 특성을 고려한 콘크리트 내구수명의 변동성)

  • Park, Sun-Kyung;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.3
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    • pp.236-245
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    • 2021
  • It is very important for structure designer to understand the service life variation since a wide range of service life is evaluated with changing exposure conditions and design parameters. Recently, for zero-carbon, waste plastic has been used for fuel for clinker production and this yields increase in chloride content in cement. This study is for evaluation of changing service life in the concrete with increasing initial chloride content due to usage of plastic-SRF(Solid Refuse Fuel) considering various exposure conditions and design parameters. For this, 4 levels of initial chloride content were assumed, and the service life was assessed using LIFE 365 program considering various environmental conditions including 3 levels of surface chloride content. As for analysis parameters, critical/initial chloride content, blast furnace slag powder replacement ratio, W/B(Water to Binder) ratio, cover depth, and unit mass for binder are adopted. Service life decreases with increasing initial chloride content and a significant reduction of service life is not evaluated permitting up to 1,000ppm of initial chloride content. With increasing slag replacement ratio, a longer service life can be secured since blast furnace slag powder has the effect of reducing the diffusion of external chloride ions and fixing the free chloride. It is thought that increasing initial chloride content up to European standard is helpful for enhancing sustainability and reducing carbon emission. Though the reduction in service life due to an increase in the initial chloride content is not significant in slag-concrete with low surface chloride content, careful consideration for mixing design should be paid for the exposure environment with high surface chloride content.