• Title/Summary/Keyword: 다공성 모델

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Theoretical Investigation on the Stress-Strain Relationship for the Porous Shape Memory Alloy (기공을 갖는 형상기억합금의 응력 및 변형률 관계에 대한 이론적 고찰)

  • Lee Jae-Kon;Yum Young-Jin;Choi Sung-Bae
    • Composites Research
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    • v.17 no.6
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    • pp.8-13
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    • 2004
  • A new three-dimensional model fur stress-strain relation of a porous shape memory alloy has been proposed, where Eshelby's equivalent inclusion method with Mori-Tanaka's mean field theory is used. The predicted stress-strain relations by the present model are compared and show good agreements with the experimental results for the Ni-Ti shape memory alloy with porosity of 12%. Unlike linear stress-strain relations during phase transformations by other models from the literature, the present model shows nonlinear stress-strain relation in the vicinity of martensite finish region.

Numerical Study About Compression Effect of Porous Electrodes on the Performance of Redox Flow Batteries (다공성 전극의 압축률이 레독스흐름전지의 성능에 미치는 영향에 대한 수치해석적 연구)

  • Jeong, Daein;Jung, Seunghun
    • Journal of ILASS-Korea
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    • v.22 no.2
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    • pp.69-79
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    • 2017
  • When designing a redox flow battery system, compression of battery stack is required to prevent leakage of electrolyte and to reduce contact resistance between cell components. In addition, stack compression leads to deformation of the porous carbon electrode, which results in lower porosity and smaller cross-sectional area for electrolyte flow. In this paper, we investigate the effects of electrode compression on the cell performance by applying multi-dimensional, transient model of all-vanadium redox flow battery (VRFB). Simulation result reveals that large compression leads to greater pressure drop throughout the electrodes, which requires large pumping power to circulate electrolyte while lowered ohmic resistance results in better power capability of the battery. Also, cell compression results in imbalance between anolyte and catholyte and convective crossover of vanadium ions through the separator due to large pressure difference between negative and positive electrodes. Although it is predicted that the battery power is quickly improved due to the reduced ohmic resistance, the capacity decay of the battery is accelerated in the long term operation when the battery cell is compressed. Therefore, it is important to optimize the battery performance by taking trade-off between power and capacity when designing VRFB system.

A Theoretical Approach on the Migration of a Chelating Radionuclide in Porous Medium (다공성 매질에서의 착화하는 방사성핵종의 이동에 대한 이론적 접근)

  • Baik, Min-Hoon;Lee, Kun-Jai
    • Journal of Radiation Protection and Research
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    • v.17 no.2
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    • pp.49-59
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    • 1992
  • A new model was developed in order to investigate the effects of chelating agents on the migration of a radionuclide in the form of ion or chelate. The migration behavior of the chelated radionuclide was analyzed by formulating a convective-dispersion transport equation which included a degradation of chelating agent and chelated radionuclide. The mathematical model was analytically solved and checked with the existing retardation factor. The results show that the migration velocity of the chelated radionuclide was much faster than the ionic one due to the decreased retardation. Therefore, it was concluded that a new remedial action should be developed to reduce the generation and release of chelating agents from the nuclear power plant into the environment.

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Development of efficient model order reduction for frequency dependent system (가진 주파수에 종속적인 시스템을 위한 효율적인 모델축소법 개발)

  • Yoon, Gil-Ho
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2011.04a
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    • pp.685-688
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    • 2011
  • 본 논문에서는 다양한 음향 가진에 따른 음향 응답을 유한 요소법을 통하여 효과적으로 계산하기 위한 새로운 모델 축소법을 제안한다. 일반적인 유한 요소법을 통한 기계구조물의 응답을 구하기 위해서는 음향 방정식의 강성 및 행렬을 구한 뒤 이들의 조합을 통한 동적 강성행렬을 구한 뒤 역행렬을 구하여 다양한 주파수 응답을 구하게 된다. 현재 컴퓨터 하드웨어의 발전과 소프트 웨어의 발전에 의하여 더 많은 유한 요소를 사용할 수 있게 되었고 이로 인하여 더욱 정확하고 넓은 대역의 음향 응답을 구할 수 있게 되었다. 그러나, 아직까지도 아주 복잡한 구조물의 음향 응답을 구하기 위하여 유한 요소를 무한정으로 증가할 수 없는 경우가 많다. 이를 해결하기 위하여 일반적으로 모델 축소법(Model order reduction) 기법을 사용한다. 이 모델 축소법은 기본적으로 전체 행렬을 아주 작지만 효율적인 작은 행렬로 바꾸어 응답을 예측하는 기법으로 mode superposition method, ritz vector method, quasi-static ritz vector method등이 있다. 기존의 모델 축소법은 기본적으로 질량 및 강성행렬이 가진 주파수에 영향을 받지 않는 행렬이라 가정한다. 그렇기 때문에 경계조건이나 다공성 재료를 모델링할 경우 가진 주파수에 영향을 받는 강성행렬과 질량행렬이 만들어지게 되어 기존의 모델 축소법은 효과적이지 못하게 된다. 이런 문제점을 해결하기 위하여 이 논문에서는 Quasi-static ritz vector method의 기본적인 개념을 확장하여 여러 개의 중심 주파수(Center frequency)에서 기저를 계산하고 이를 동시에 이용하는 Multi-frequency quasi-static ritz vector method를 제안한다.

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Controlled Release of Nifedipine from Osmotic Pellet Based on Porous Membrane (니페디핀을 포함한 삼투성펠렛의 제조와 다공성막을 통한 약물방출제어)

  • Youn, Ju-Yong;Ku, Jeong;Kim, Byung-Soo;Kim, Moon-Suk;Lee, Bong;Khang, Gil-Son;Lee, Hai-Bang
    • Polymer(Korea)
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    • v.32 no.4
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    • pp.328-333
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    • 2008
  • The osmotic delivery systems are based on osmosis. The transverse diffusion of water through a porous membrane from a medium with a low osmotic pressure to a medium with a high osmotic pressure. Nifedipine tablet dosage forms of Procardia $XL^{(R)}$(Pfizer) and $Adalat^{(R)}$(Bayer) are commercialized systems of this type that push-pull osmotic tablet operates successfully in delivering water-insoluble drugs. We prepared osmotic pellet system by fluidized bed coating method, and model-drug used nifedipine. The osmotic pellet system was composed of the core material. the swelling and osmotic pressure layer, the drug coating layer, and the porous membrane. This work is performed to investigate the effect of different factors, such as composition and thickness of membrane. The osmotic pellet has been successfully prepared by fluidized bed coating technology. The drug release behavior depended on the increase of CA ratio and thickness in porous membrane. The morphology of the osmotic pellet before and after the dissolution test were observed by SEM. In conclusion, we found that the drug release of osmotic pellet depended on the composition and coating thickness of porous membrane.

Characterization of Elastic Modulus of Kelvin Foam Using Elastic Structural Model and Ultrasound (초음파와 탄성 구조 모델을 이용한 캘빈 폼 재료의 탄성계수 평가)

  • Kim, Woochan Ethan;Kim, Nohyu
    • Journal of the Korean Society for Nondestructive Testing
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    • v.36 no.6
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    • pp.474-482
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    • 2016
  • A Kelvin foam plate - widely used in the energy and transport industries as a lightweight structural material - was examined to estimate its Young's modulus using ultrasound. An isotropic tetrakaidecahedron foam structure was designed in SolidWorks and printed using 3D printer with an ABS plastic material. The 3D printed foam structure was used to build a foam plate with a 14 mm thickness ($50mm{\times}100mm$ in size) for the ultrasonic test. The Kelvin foam plate, a significantly porous medium, was completely filled with paraffin wax to enable the ultrasound to penetrate through the porous medium. The acoustic wave velocity of the wax-filled Kelvin foam was measured using the time of flight (TOF) method. Furthermore, the elastic modulus of the Kelvin foam was estimated based on an elastic structural model developed in this study. The Young's modulus of the produced Kelvin foam was observed to be approximately 3.4% of the bulk value of the constituent material (ABS plastic). This finding is consistent with experimental and theoretical results reported by previous studies.

A Study on the Groundwater Flow in Fractured-Porous Media by Flow Resistance Theory (단열-다공암반에서 유동저항 이론을 이용한 지하수 유동 평가에 관한 연구)

  • Han Ji-Woong;Hwang Yong-Soo;Kang Chul-Hyung
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.231-238
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    • 2005
  • On the basis of flow resistance theory the conceptual model and related mathematical descriptions is proposed for resistance modeling of groundwater flow in CPM(continuum Porous medium), DFN(discrete fracture network) and fractured-porous medium. The proposed model is developed on the basis of finite volume method assuming steady-state, constant density groundwater flow. The basic approach of the method is to evaluate inter-block flow resistance values for a staggered grid arrangement, i.e. fluxes are stored at cell walls and scalars at cell centers. The balance of forces, i.e. the Darcy law, is utilized for each control volume centered around the point where the velocity component is stored. The transmissivity (or permeability) at the interface is assumed to be the harmonic average of neighboring blocks. Flow resistance theory was utilized to relate the fluxes between the grid blocks with residual pressures. The flow within porous medium is described by three dimensional equations and that within an individual fracture is described by a two dimensional equivalent of the flow equations for a porous medium. Newly proposed models would contribute to develop flow simulation techniques with various matrix characteristics.

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Numerical Experiments on the Evaluation of Effective Permeability and Tunnel Excavation in the Three Dimensional Fracture Network Model (3차원 균열연결망 모델에서의 유효투수계수 평가 및 터널굴착 지하수 유동해석에 대한 수치실험)

  • 장근무
    • Tunnel and Underground Space
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    • v.8 no.4
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    • pp.275-286
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    • 1998
  • The effective permeability and the representative element volume(REV) of fracture network model were evaluated based on the parameters such as permeability tensor, principal permeability and the direction of principal permeability. The effective permeability ranges between the harmonic mean and the arithmetic mean of the local permeabilities of subdivided blocks. From the numerical experiments, which were for investigating the influence of model volume on the variation of flux for the cubic models, it was found that the variation of flux became reduced as the model volume approached REV. The variation of groundwater flux into the tunnel in the fracture network model was mainly dependent on the ratio of the tunnel length to model size rather than REV. And it was found that groundwater flux into the tunnel was not completely consistent between the fracture network model and the equivalent porous media model, especially when the ratio of the tunnel length to model size is small.

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A Smooth Elasto-Plastic Cap Model(I): Rate Formulation, Yield Surface Determination (연속 탄소성 캡 모델(I): 구성모델 및 항복면의 결정)

  • 서영교
    • Journal of the Korean Geotechnical Society
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    • v.17 no.3
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    • pp.15-23
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    • 2001
  • 탄소성 캡 모델의 중요한 장점은 여러 가지 다공체의 전체적인 축차 및 체적의 비선형 상호거동을 동시에 다룰 수 있음에 있다. 그러나 대부분의 캡 모델이 가진 문제점중의 하나는 세 개의 독립적인 항복면이 불연속으로 연결되어 있음으로부터 기인된다. 본 연구에서는 이러한 항복면 사이의 연결점에서의 탄소성 접선 계수는 특이점이 되고 수치해석상 잠재적인 어려움을 내재하고 있음을 나타내고 이러한 문제의 해결방안의 하나로 세 개의 항복면이 연속적으로 만나는 새로운 탄소성 캡 모델을 제시하였다. 본 논문에서는 모델의 증분형태의 구성식 및 새로운 응력을 구하기 위한 활동 항복면의 결정을 판단하는 알고리즘이 제시되었다. 동반 논문에서는 내재적인 응력적분 및 일관적인 접선계수를 유도하였고 예제계산들을 수행하였다.

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Study of Separation of carbon dioxide through hollow fiber membrane contactor (중공사막 접촉장치를 통한 이산화탄소 분리에 관한 연구)

  • 염봉열;김민수;이용택;박유인;이규호
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.61-64
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    • 1997
  • 1. 서론 : 적절한 이산화탄소의 분리는 지구온난화의 가속현상을 늦출 수 있을 뿐만 아니라 각종 탄화수소가스의 원료로 분리 정제된 이산화탄소를 재이용할 수 있으므로 경제적으로 매우 중요하다. 이산화탄소 분리에 사용되던 기존 공정들의 단점을 보완할 수 있는 대체방안으로 최근에 개발되기 시작한 것이 소수성의 다공성 고분자 분리막(hydrophobic porous ploymeric membrane) 방법인데, 이는 모듈의 유효 막 표면적이 상대적으로 크고 기체와 액체의 흐름을 독립적으로 제어할 수 있으므로 범람 등의 현상이 없으나 막 자체의 저항이 비교적 큰 단점을 가지고 있다. Qi와 Cussler는 이러한 특성을 가지는 중공사막 모듈에서의 기-액 흐름에 대한 물질전달 상관관계식을 얻었으며[1], Karoor 등은 여러 가지 중공사막 모듈을 사용하여 순수물과 diethanolamine(DEA) 등의 흡수제에 대한 이산화탄소의 물질전달 거동을 수치모델과 실험을 통하여 고찰하였다[3]. 또한 중공사막 접촉기의 실제적 응용에 대하여 Matsumoto 등은 화력발전소에서 발생하는 연소가스 내의 이산화탄소 흠수에 대한 연구를 수행하였다[4]. 본 연구에서는 중공사막 접촉장치를 사용하여 흡수제를 순수물과 탄산칼륨($K_2CO_3$)을 사용했을 경우의 이산화탄소의 분리 거동을 수치모델과 실험을 통하여 고찰하였다. 수치모델의 경우 이전까지의 연구가 반응이 없는 경우나 반응식을 간략화시킨 경우에 한정되었는데 비하여, 반으이 있는 경우 각각의 반응물질들의 거동을 고려한 반응식을 유도하여 해를 구하고자 하녔다.

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