• Title/Summary/Keyword: 농축지수

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몰비지수에 의한 증기발생기 틈새수화학 특성평가

  • 나정원;성기운;조영현;김우철
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05a
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    • pp.369-373
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    • 1998
  • 증기발생기에서 부식에 의한 전열관 손상은 전열관과 관판사이의 틈새에서 대부분 발생되고 이 틈새에서의 수질환경에 좌우된다. 틈새에서는 과열도가 높아 미량의 불순물이 농축되면서 틈새수화학 (crevice chemistry)은 증기발생기 내부수 수화학과는 달라진다. 전열관 손상을 억제하기 위해서는 틈새수질을 적절히 제어하여야 하는데 이는 틈새수화학을 정확히 분석평가할 수 있는 기술을 기반으로 하여야 한다. .기존의 틈새수질을 계산하는 방법으로는 증기발생기 내부수에 비해 틈새에서 화학종들이 얼마나 농축되는지를 가정하는 농축도 (concentration factor) 방법이 있으나 가정에 의한 불확실성으로 인해 틈새수질을 정확히 해석할 수 없었다. 그러나 원전 증기발생기의 잠복불순물 방출시험 자료로부터 틈새수질을 보다 정확히 평가할 수 있는 새로운 개념의 몰비지수(molar ratio index) 방법이 최근 EPRI에서 제시되었고 EPRI 산하의 많은 발전소에서 적용중이다. 본 연구에서는 PWR 원전 증기발생기의 틈새수화학을 평가할 수 있는 기술을 개발하기 위해 잠복불순물 방출시험 자료로부터 틈새에서의 몰비지수를 계산할 수 있는 CRAP (CRevice-chemistry Analysis Program) 전산프로그램을 작성하였다 CRAP를 국내원전에 적용하여 증기발생기 및 그 틈새에서의 수화학을 평가하였다.

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Rheological Properties of Pear Juice Concentrates (배주스 농축액의 리올로지 특성)

  • Choi, Hee-Don;Kim, Kyung-Tack;Hong, Hee-Do;Lee, Boo-Yong;Kim, Sung-Su
    • Korean Journal of Food Science and Technology
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    • v.27 no.6
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    • pp.845-851
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    • 1995
  • To improve the utilization of pear in its processing, the cloudy and clear juice concentrates were prepared and their rheological properties were investigated in the range of temperatures($5{\sim}60^{\circ}C$) and concentrations($15{\sim}60^{\circ}Brix$). Pear juice concentrates showed flow behavior close to Newtonian fluids. Their flow behavior was also explained by applying Power law model and Herschel-Bulkley model. Flow behavior index did not have good correlation with concentration, but decreased with the increase of temperature, showing pseudoplastic properties. Consistency index increased with the increase of concentration and with the decrease of temperature. The effect of temperature and concentration on the apparent viscosity at 1500 1/s shear rate was examined by applying Arrhenius equation. The activation energy for flow of the cloudy and clear pear juice concentrates increased from $1.5140{\times}10^4\;to\;3.4141{\times}10^4\;J/kg{\cdot}mol$, and from $1.4762{\times}10^4\;to\;3.4963{\times}10^4\;J/kg{\cdot}mol$ with the increase of concentration, respectively. The influence of temperature on the apparent viscosity was more pronounced at higher concentration. And the concentration-dependent constant A decreased from $0.0789\;to\;0.0484^{\circ}Brix^{-1}$, and from $0.0786\;to\;0.0476^{\circ}Brix^1$ with the increase of temperature, respectively.

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Rheological Properties of Garlic Juice and its Concentrate (마늘 착즙 및 농축액의 Rheological Properties)

  • Kim, Byeong-Sam;Park, Noh-Hyun;Park, Moo-Hyun;Han, Bong-Ho;Bae, Tae-Jin
    • Korean Journal of Food Science and Technology
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    • v.22 no.6
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    • pp.646-650
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    • 1990
  • To develop a new form of spice material by concentration of garlic juice, its rheological properties were investigated. In the temperature range of $15\;to\;65^{\circ}C$, the garlic juice with the solid content of $32\;to\;60^{\circ}Brix$ was considered as a pseudoplastic fluid. Flow and consistency indices of the juice interpreted by power-law equation varied from $0.9937\;to\;0.6130\;and\;0.0041\;to\;3.1886Pa{\;s^n$, respectively. Apparent viscosity was lineally decreased as shear rate was increased. Activation energy for the flow of the garlic juice changed in the range of 11,216 to 23,195 kJ/kg mol.

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Antioxidant Activities of Beverage Concentrates and Purees (음료 농축액 및 퓨레의 항산화 활성)

  • Kim, Dan Bi;Shin, Gi Hae;Cho, Ju Hyun;Baik, Soon Ok;Lee, Ok-Hawn
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.42 no.7
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    • pp.997-1002
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    • 2013
  • This study investigated the physicochemical properties (pH, Brix), total phenol content, antioxidant activities (DPPH radical scavenging activity and oxygen radical absorbance capacity (ORAC)), and nitrite scavenging activity of beverage concentrates and purees. All concentrates and purees were produced from natural materials and have been used as the main ingredients in health-related beverages. Our results show that the pH values and Brix of all concentrates and purees ranged from 2.81 to 5.12 and 1.70 to 70.30 Brix, respectively. The highest total phenol content (182.71 mg GAE/mL), DPPH radical scavenging activity (69.88%) and nitrite scavenging activity (28.19%) were obtained from acai berry puree. The concentrate from wild blueberry had the highest ORAC value ($27,514{\mu}M$ TE/mL). Among the correlation coefficient data, the total phenol content exhibited a high correlation coefficient (r=0.9099) and DPPH radical scavenging activity. These results suggest that concentrates and purees from natural materials contribute to antioxidant activities in healthy beverages.

Geochemical Contamination Assessment and Distribution Property Investigation of Heavy Metals, Arsenic, and Antimony Vicinity of Abandoned Mine (폐광산 인근지역에서 중금속, 비소, 안티모니의 지구화학적 오염도 평가 및 분산 특성 조사)

  • Han-Gyum Kim;Bum-Jun Kim;Myoung-Soo Ko
    • Economic and Environmental Geology
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    • v.55 no.6
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    • pp.717-726
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    • 2022
  • This study was conducted to assess the geochemical contamination degree of As, Cd, Cu, Pb, Sb, and Zn in the soil and water samples from an abandoned gold mine. Enrichment Factor (EF), Geoaccumulation Index (Igeo), and Pollution Load Index (PLI) were carried out to assess the geochemical contamination degree of the soil samples. Variations of sulfate and heavy metals concentration in water samples were determined to identify the geochemical distribution with respect to the distance from the mine tailing dam. Geochemical pollution indices indicated significant contaminated with As, Cd, Pb, and Zn in the soil samples that areas close to the mine tailing dam, while, Sb showed similar indices in all soil samples. These results indicated that the As, Cd, Pb, and Zn dispersion has occurred via anthropogenic sources, such as mining activities. In terms of water samples, anomalies in the concentrations of As, Cd, Zn, and SO42- was determined at specific area, in addition, the concentrations of the elements gradually decreased with distance. This result implies the heavy metals distribution in water has carried out by the weathering of sulfide minerals in the mine tailing and soil. The study area has been conducted the remediation of contaminated soil in the past, however, the geochemical dispersion of heavy metals was supposed to be occurred from the potential contamination source. Therefore, continuous monitoring of the soil and water is necessary after the completion of remediation.

Properties of Purple-Fleshed Sweet Potato Antocyanin Pigment Solutions (자색고구마 Antocyanin 색소 추출액의 유동특성)

  • 이정주;임종환
    • Food Science and Preservation
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    • v.8 no.1
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    • pp.102-108
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    • 2001
  • Flow properties of the concentrated pigment solutions extracted from purple-fleshed sweet potatoes were determined using a cone and plate rotational viscometer for soluble solids concentration range of 25 to 65% at temperature range of 20 to 60 $^{\circ}C$. The purple-fleshed sweet potato pigment solutions exhibited Newtonian behavior. Temperature dependency for the viscosity of the solution followed the Arhenius relationship with activation energy values between 14.23 and 43.00 kJ/mol, which increased linearly with soluble solids concentration. A relationship between viscosity, temperature and soluble solids concentration was investigated. At the same temperature, the viscosity of the concentrated pigment solutions increased exponentially as the concentration increased with higher degree of such phenomena at lower temperatures.

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Geochemical Characteristics and Heavy Metal Pollutions in the Surface Sediments of Gwangyang and Yeosu Bay, south coast of Korea (광양만 및 여수해만 표층퇴적물의 지화학적 특성과 중금속 오염)

  • 현상민;이태희;최진성;최동림;우한준
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.8 no.4
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    • pp.380-391
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    • 2003
  • Surface sediments were collected from Gwangyang and Yeosu Bays to evaluate their sedimentological characteristics and geochemical aspects of both the benthic environment and heavy metal pollution. The grain size distribution includes both sandy and muddy sediments. Sand-rich sediments occur mainly near the POSCO and the channel between Namhedo and Yeosu Bando, while elsewhere mud-dominated sediments are present. TOC content ranges from 0.2 to 2.1 % and C/N ratios indicate that the range arises from the mix of organic matter. The C/S ratios of this organic matter show that parts of the study area are anoxic or have sub-anoxic bottom conditions. The hydrogen sulfide content of the sediment has a range of 0.7 to 301 ppm, with a high content occurring inshore of Myodo Island, where it indicates a polluted environment. The enrichment factor (Ef) and index of accumulation rate (Igeo) of ten heavy metals (Co, Ni, Cu, Cd, Pb, Li, Zn, V, Cr, Ba) show that parts of the study area contain from one to seven times more Pb and Ba, and from 0.8 to 3.5 times more of the other elements than the mean sediment value. The Igeo values of V and Cd show that different parts of the area can be classified as heavily polluted, heavily to moderately polluted, or more or less unpolluted. Those areas that have both high levels of enrichment and high accumulation rates of heavy metals contain predominantly fine sediments with a high organic matter and hydrogen sulfide content.

Heavy Metals in Surface Sediments from Doam Bay, Southwestern Coast of Korea (한국 남서해안 도암만 표층퇴적물의 중금속 함량 및 분포 특성)

  • CHO, HYEONG-CHAN;CHO, YEONG-GIL
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.20 no.4
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    • pp.159-168
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    • 2015
  • Forty-four surface sediments from Doam Bay were analyzed for total organic carbon (TOC), total nitrogen (TN), total metal (Al, Fe, Mn, Cr, Cu, Ni, Pb, Zn) and further chemical partitioning of metals were carried out in some samples. The TOC (0.32~3.10%) and TN (0.03~0.26%) values of the samples were similar to those of other coastal area. The C/N ratios ranged from 7.9 to 11.9 with an average 9.3 which revealed that contribution of terrestrial organic matters was relatively rare. Contents of analysed metals showed a level lower than threshold effects level (TEL) in sediment quality guidelines. Based on the chemical speciation of metals, the lattice fractions were found in the order Cr > Cu > Ni > Zn > Pb > Mn, while Mn and Pb are the ratio of the non-lattice fractions accounted for more than 50%. The average baseline values were obtained relative cumulative frequency curves and linear regression analysis. The respective baseline concentrations for Cu, Ni, Pb, Zn, Cr and Mn were 11.8, 23.1, 26.8, 76.6, 56.7, 585 mg/kg, respectively. Based on geoaccumulation index ($I_{geo}$) with a baseline values of Mn showed that face the contamination phase from estuarine stations. However, in case of Zn and Pb, although there is no sign of contamination, it could be release from sediment when there is a change in the environment, which is caused from the high ratio of non-lattice fractions.

Uranium Enrichment Analysis with Gamma-ray Spectroscopy (FRAM을 이용한 우라늄 농축도 분석의 신뢰성 평가 연구)

  • Eom, Sung-Ho;Jeong, Hye-Kyun;Park, Jun-Sic;Park, Se-Hwan;Shin, Hee-Sung
    • Journal of Radiation Protection and Research
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    • v.36 no.1
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    • pp.16-23
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    • 2011
  • Accurate measurement of uranium enrichment is very important in nuclear material accountability. The analysis uncertainty of the uranium enrichment measurement with gamma-ray analysis was studied in the present work. FRAM (Fixed energy Response function Analysis with Multiple efficiencies) code was used to determine the uranium enrichment. If the shield materials were placed between the detector and the sample, the error was measured and analyzed. Measurement time was varied and the dependency of the analysis uncertainty on the measurement time was studied. Transmitted gamma-ray intensities and FWHMs of the peaks in the energy spectrum were measured as the shield thickness was varied. The transmitted gamma-ray intensity follows shape of the exponential function, and the FWHM was almost independent of the shield thickness. The uncertainty of FRAM analysis was studied when the thick shield material was placed between the detector and the sample. Our work could be helpful in analysis of the fissile material in uranium sample.

Improvement of the Environmental Impact Assessment and Post-environment Impact Survey Reports Using Marine Environment Assessment Indices (해양환경 평가지수를 활용한 환경영향평가서 및 사후환경영향조사결과 통보서 개선 방안 연구)

  • Lee, Eojin;Kim, Taeyun
    • Journal of Environmental Impact Assessment
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    • v.30 no.2
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    • pp.61-74
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    • 2021
  • In this study, we used marine environment assessment indices to evaluate impacts of various development projects on the marine environment. TheWaterQuality Index (WQI) was applied in the field of marine water quality and the Cleanup Index of Harmful Chemicals (CIHC), the Cleanup Index of Eutrophication (CIET), the Enrichment Factor(EF) were used in the field of marine sediment. In the field of marine benthic organisms, the Benthic Health Index (BHI) and the Benthic Pollution Index (BPI) were utilized. Each assessment index was calculated using the data observed in the development project, and its characteristics and usefulness were evaluated. The assessment method and criteria were clearly defined for WQI, CIHC, and BHI. Furthermore, through these indices, an integrated environment impact analysis was possible. Apart from the indices presented in this study, there are various indices that can be used for evaluating the marine environment. Therefore, it is important to utilize appropriate indices according to the characteristics of each project.