• The Korean Journal of Pesticide Science
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• v.6 no.1
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• pp.16-24
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• 2002

Research trends in the measurement of foliar uptake of pesticides and the recently proposed action mechanism of the surfactant-induced uptake of pesticides were reviewed with the related reports and studies. Major techniques used in those fields are bioassay, radiotracer techniques with leaves or cuticular membrane. Recently, a new method using Congo Red as a tracer was proposed. The limiting factor in the pesticides uptake into leaves is the waxy layer which consists of the epicuticular and cuticular wax. Physico-chemical parameters such as molar volume, water solubility and partition coefficient of pesticides have limited influences on the pesticide uptake into leaves. Polydisperse ethoxylated fatty alcohol surfactants are well known as the good activator for many pesticides. It is now generally agreed that uptake activation is not related to the intrinsic surface active properties of surfactants such as surface activity, solvent property, humectancy and critical micelle concentration. Recent studies using ESR-spectroscopy revealed that the surfactants have an unspecific plasticising effect on the molecular structure of the wax and cuticular matrix, leading to increased mobilities of pesticides. Penetration of surfactants into waxy layer altered the pesticide mobility in wax and the partition coefficient of pesticide, and then the pesticides penetration into leaves was enhanced temporally. The enhancing effect of surfactant could be significantly different depending on the carbon number of aliphatic moiety and the number of ethoxy group in polyoxyethylene chain of surfactants. It is suggested that the rate of penetration of surfactants should have a significant relationship with the rate of penetration of pesticides.

• Journal of Life Science
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• v.32 no.6
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• pp.438-446
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• 2022

Some flowers have a high sensual appeal owing to their unique shape, color, smell, and taste and have been used as functional food and oriental medicine. Recently, edible dry flowers (EDFs) have attracted social attention as noble sources of functional teas. In this study, for the risk assessment of EDFs, pathogenic bacteria, heavy metals, and pesticide residues were monitored in 23 types of commercial EDF. No Enterobacteria spp. and Listeria spp. were found in all EDF products. However, common aerobic bacteria (3.24~3.85 Log CFU/g) were found in EDF, namely, Pueraria lobata, Chamaemelum nobile, Acacia decurrens, Rhododendron mucronulatum Turcz, Oenothera lamarckiana, Brassica napus, and Prunus serrulata. Staphylococcus aureus was found in 11 and Salmonella sp. was found in 8 of the 23 EDFs. Considering the cold extraction of EDF for tea and beverages, the regulation of pathogenic bacteria in EDFs is necessary. No heavy metals such as Pb, Cd, Co, Cr, Cu, Ni, and As were found in all EDFs, except the dry flower of Hemerocallis fulva, which contained Pb at 0.08 ppm. Different pesticides and fungicides were found in EDFs, but their concentrations were very low (0.01~0.08 ppm) and below the maximal residue level. Only the dry flower of Chrysanthemum morifolium had a high content of chlorpyrifos (0.215 ppm), which is long-lasting pesticide. Our results suggest that the establishment of EDF regulations for pesticide residue, culture separation between edible and garden flowers, and guidelines for preventing pathogenic microbial contamination are necessary.

• The Korean Journal of Pesticide Science
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• v.18 no.4
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• pp.236-246
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• 2014

Pesticide is used to protect the crops, but also become a cause of polluting the environment. Perform a risk assessment using physical and chemical properties, environmental fate and toxicity data in order to determine the pesticide registration. The aquatic model estimates pesticide concentrations in water bodies that result from pesticide applications to rice paddies and apple orchard. The used models are the PRZM, EXAMS and AGRO shell (PA5), Rice Water Quality Model (RICEWQ) and Screening Concentration In GROund Water (SCI-GROW). The residual concentration of water body was estimated using meteorological data, crop calendar and soil series of Korea. The chosen pesticides were butachlor, carbofuran, iprobenfos and tebuconazole. It has shown the potential that the RICEWQ is possible to predict residue level in water of butachlor and iprobenfos, because the maximum value in water monitoring data is lower than the peak concentration of the model, and the minimum value is lower than the average annual concentration of the model. But RICEWQ was insufficient to predict exposure concentrations in ground water. The estimated exposure concentrations of carbofuran in ground water is very higher than in surface water because of its low soil adsorption coefficient. Although tebuconazole were not detected in the water monitoring that means very low concentration, it is possible that the PA5 can be used to predict residue level in water.

• THE HEALTH and ORGANIC FARMING
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• no.221
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• pp.1-12
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• 2005

제27회 한국유기농업대회 성황리 개최/농림부장관 격려사/우리의 산야초/겨울철 토양의 영양관리는 이동성이 어려운 칼슘과 고토 그리고 붕소를/제27회 한국유기농업대회 이모저모/'자원순환형농업 활성화 방안'/"우수 농축산물 합리적 생산이력 관리 방안"세미나/"농업,환경 문제와 연계 필요"/"충북,근교농업 준비 갖춰야"/전남,친환경농업기금 500억조성/농어업특위,'도시민을 농어촌으로'/태안군,웰빙 6쪽마늘 생산단지 조성/우리조상들이 연구한 물이야기/착각하고 있는 잘못된 웰빙/토양다발성 병해 예방/바이러스병 어떻게 전파되며, 어떻게 막아낼것인가?/시설채소의 병해방제/협회저농약9호/"금수강산"가격인상 안내/우수농산물코너/본 협회 인증위원회 개최/12월중 협회 일정 안내/배추 무사마귀병은 무와 윤작으로/미.영,급식등 '어린이영양'법제화/11월중 새식구 명단/협회소식/약이되는 웃음,약이 되는 웃음 운동/다층식 지렁이 사육시스템 개발/친환경 먹거리 대체의학센터 충주에 건립/미국?, 화학원료 넣어도 유기농산물?/멕시코도 유기농 제품 바람/과일껍질 이용한 아이디어 살림법/서식환경의 파괴

• The Optical Journal
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• s.158
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• pp.58-60
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• 2015

드론이 인기다. 드론이 뜨고 있다. 드론은 왜 인기인가? 왜 드론이 인기인지를 인식해보아야 한다. 결론부터 이야기하면 드론이 인기인 이유는 드론이 MMM이기 때문이다. MMM은 필자가 2년 전 쯤에 만든 신조어로 Multipurpose Mobile Machine의 약자다. 다목적 이동 기계라는 말이다. 우리말로 줄이면 다이기(多移機)쯤 된다. 드론은 다목적 이동 기계, 즉 다이기이다. 인터넷이 군용으로 사용되다가 민간이 사용하게 된 것처럼 드론 역시 정찰, 감시, 폭격 등의 군사용으로 출발했지만, 민간이 사용하는 드론의 용도는 무척 다양하다. 사진 촬영, 영화 제작, 드라마 촬영, 음식 배달, 씨앗의 파종과 농약의 살포, 현장 탐사, 경계 근무 등 정말 다용도에 사용되고 있다. 중요한 것은 드론 각각이 다목적으로 사용될 수 있다는 것이다. 이는 드론이 단지 물리적 기계인 것이 아니라 스마트 기계로, 스마트폰과 같은 SW중심 기기와 드론에 내장된 OS와 SW에 의한 제어를 통해 비로소 실현된다. 즉, 드론은 MMM이기도 하지만, 정확히 SMM(Smart Mobile Machine)이기 때문에 그 잠재성이 인정받고 있는 것이다. 지금까지 스마트 폰, 스마트 워치, 스마트 TV 등은 모두 스마트 기기이기는 하지만 스마트 이동 기기는 아니다. 한편, 로봇 청소기 등 기존의 가정용 로봇이나 산업용 로봇은 대부분 단일목적 이동기기이거나 다목적 고정 기계이므로, 로봇이라 부르기가 민망한 기계들이었다. 필자는 드론이 이렇듯 새로운 스마트 기기 산업과 기존의 로봇 산업이 갈 길 또는 가고 있는 길을 보여주고 있다는 점에서 관심을 갖는다. 스마트 기기 산업의 관점에서는 이제 비로소 고정형(스마트TV), 부착형(스마트 워치), 휴대형(스마트 폰) 스마트 기기 산업에서 다목적 스마트 이동 기계라는 새로운 블루 오션 창출 산업이기에 의미가 있다.

• Korean Journal of Environmental Agriculture
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• v.38 no.3
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• pp.173-184
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• 2019

BACKGROUND: This study was carried out to investigate pesticide residues from fifty streams in Korea. Water samples were collected at two times. Thee first sampling was performed from april to may, which was the season for start of pesticide application and the second sampling event was from august to september, which was a period for spraying pesticides multiple times. METHODS AND RESULTS: The 136 pesticide residues were analyzed by LC-MS/MS and GC/ECD. As a result, eleven of the pesticide residues were detected at the first sampling. Twenty eight of the pesticide residues were detected at the second sampling. Seven pesticides were frequently detected from more than 10 water samples. Ecological risk assessment (ERA) was carried out by using residual and toxicological data. Four scenarios were applied for the ERA. Scenario 1 and 2 were performed using LC50 values and mean and maximum concentrations. Scenarios 3 and 4 were conducted by NOEC values and mean and maximum concentrations. CONCLUSION: Frequently detected pesticide residues tended to coincide with the period of preventing pathogen and pest at paddy rice. As a result of ERA, five pesticides (butachlor, carbendazim, carbofuran, chlorantranilprole, and oxadiazon) were assessed to be risks at scenario 4. However, only oxadiazon was assessed to be a risk at scenario 3 for the first sampling. Oxadiazon was not assessed to be a risk at the second sampling. It seems to be temporary phenomenon at the first sampling, because usage of herbicides such as oxadiazon increased from April to march for preventing weeds at paddy fields. However, this study suggested that five pesticides which were assessed to be risks need to be monitored continuously for the residues.

• Korean Journal of Environmental Agriculture
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• v.24 no.2
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• pp.123-131
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• 2005

This study was focused on adsorption, leaching, photolysis, and hydrolysis of the fungicide procymidone in soils. Adsorption type of procymidone on three different soil were well fitted to Linear and Freundlich isotherm. Distribution coefficients (Kd) were ranged from 2.75 to 12.18 and Freundlich isotherm Kf value $1.99{\sim}9.98$, 1/n value $0.74{\sim}0.89$. Desorption rates were $20.1{\sim}34.0%$ (Namgye), $26.3{\sim}44.6%$ (Jigog) and $31.6{\sim}50.9%$ (Baegsan series) and desorption hysteresis were $0.65{\sim}0.79,\;0.55{\sim}0.73\;and\;0.49{\sim}0.68$. Procymidone seemed to be stable to photolysis in acidic and neutral solutions but hydrolyzed rapidly in alkaline solution. Considering leaching properties procymidone mobility low in soils.

• Analytical Science and Technology
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• v.5 no.2
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• pp.153-158
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• 1992

In this work, we developed supercritical fluid chromatographic methods for the samples which are difficult to analyze with conventional GC or HPLC. Long-chain Hydrocarbons, mink oils and soybean oils unsuitable for GC because of their low volatility or limited thermal stability were separated by SFC due to the high solvating properties of supercritical carbon dioxide fluids. In our research, a new method for the analysis of polar fatty acids and pesticides was developed. This method should be used to overcome problems with polar samples in SFC.

• Journal of Korea Soil Environment Society
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• v.5 no.3
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• pp.17-23
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• 2001

The adsorption and movement characteristics of herbicide pendimethalin was studied in three kinds of soil, sandy loam, silty clay and loam. The results of the batch test and columnexperimentweresummarizedasfollows. The shaking time reached to the adsorption equilibrium of pendimethalin in soils was 6 hours. The adsorption rates of pendimethalin for sandy loam, silty clay and loam were 59.6%, 77.3% and 64.0%, respectively. The adsorption isotherms with the Freundlich equation showed better consistency than that with the Langmuir one. The adsorption coefficients of pendimethalin for soils were 8.0. 16.1 and 9.5. respectively. When breakthrough point was 0.05Co, the breakthrough times reached for soils were 256 minutes, 810 minutes and 420 minutes. respectively.

• The Korean Journal of Pesticide Science
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• v.18 no.4
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• pp.228-235
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• 2014

The residue levels of flonicamid and its metabolites, 4-(trifluoromethyl)nicotinic acid (TFNA) and N-4-(trifluoromethyl)nicotinoyl glycine (TFNG) in sweer pepper were investigated to examine the residual characteristics of analytes for 87 days after pesticide application. The pesticide was applied once at recommended dosage and double dosage by foliar sprays and the samples of fruits and leaves of sweet pepper were collected for each treatment. The residues of flonicamid in all of fruits and leaves decreased gradually over time, while the residue levels of TFNG metabolite exhibited tendency that increased for long periods and thereafter decreased. Total flonicamid residual concentrations containing metabolites residues in fruit samples increased consistently until 30 days post-application and higher residue levels than residues at 1 day post-application were detected from 30 day to 87 day after treatment. The residue pattern observed in fruit could be explained by the movement of TFNG from leaves to fruits of plant. Such residual characteristic was similarly found in samples treated both recommended dosage and double dosage.