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http://dx.doi.org/10.5338/KJEA.2019.38.3.21

Monitoring of Pesticide Residues Concerned in Stream Water  

Hwang, In-Seong (Chemical Safety Division, Department of Agro-Food Safety and Crop Protection, National Institute of Agricultural Sciences, Rural Development Administration)
Oh, Yee-Jin (Chemical Safety Division, Department of Agro-Food Safety and Crop Protection, National Institute of Agricultural Sciences, Rural Development Administration)
Kwon, Hye-Young (Planing and Coordination Bureau, Rural Development Administration)
Ro, Jin-Ho (Chemical Safety Division, Department of Agro-Food Safety and Crop Protection, National Institute of Agricultural Sciences, Rural Development Administration)
Kim, Dan-Bi (Chemical Safety Division, Department of Agro-Food Safety and Crop Protection, National Institute of Agricultural Sciences, Rural Development Administration)
Moon, Byeong-Chul (Chemical Safety Division, Department of Agro-Food Safety and Crop Protection, National Institute of Agricultural Sciences, Rural Development Administration)
Oh, Min-Seok (Chemical Safety Division, Department of Agro-Food Safety and Crop Protection, National Institute of Agricultural Sciences, Rural Development Administration)
Noh, Hyun-Ho (Chemical Safety Division, Department of Agro-Food Safety and Crop Protection, National Institute of Agricultural Sciences, Rural Development Administration)
Park, Sang-Won (Chemical Safety Division, Department of Agro-Food Safety and Crop Protection, National Institute of Agricultural Sciences, Rural Development Administration)
Choi, Geun-Hyoung (Chemical Safety Division, Department of Agro-Food Safety and Crop Protection, National Institute of Agricultural Sciences, Rural Development Administration)
Ryu, Song-Hee (Chemical Safety Division, Department of Agro-Food Safety and Crop Protection, National Institute of Agricultural Sciences, Rural Development Administration)
Kim, Byung-Seok (Chemical Safety Division, Department of Agro-Food Safety and Crop Protection, National Institute of Agricultural Sciences, Rural Development Administration)
Oh, Kyeong-Seok (Chemical Safety Division, Department of Agro-Food Safety and Crop Protection, National Institute of Agricultural Sciences, Rural Development Administration)
Lim, Chi-Hwan (Department of Bio-Environmental Chemistry, College of Agriculture and Life Sciences, Chungnam National University)
Lee, Hyo-Sub (Chemical Safety Division, Department of Agro-Food Safety and Crop Protection, National Institute of Agricultural Sciences, Rural Development Administration)
Publication Information
Korean Journal of Environmental Agriculture / v.38, no.3, 2019 , pp. 173-184 More about this Journal
Abstract
BACKGROUND: This study was carried out to investigate pesticide residues from fifty streams in Korea. Water samples were collected at two times. Thee first sampling was performed from april to may, which was the season for start of pesticide application and the second sampling event was from august to september, which was a period for spraying pesticides multiple times. METHODS AND RESULTS: The 136 pesticide residues were analyzed by LC-MS/MS and GC/ECD. As a result, eleven of the pesticide residues were detected at the first sampling. Twenty eight of the pesticide residues were detected at the second sampling. Seven pesticides were frequently detected from more than 10 water samples. Ecological risk assessment (ERA) was carried out by using residual and toxicological data. Four scenarios were applied for the ERA. Scenario 1 and 2 were performed using LC50 values and mean and maximum concentrations. Scenarios 3 and 4 were conducted by NOEC values and mean and maximum concentrations. CONCLUSION: Frequently detected pesticide residues tended to coincide with the period of preventing pathogen and pest at paddy rice. As a result of ERA, five pesticides (butachlor, carbendazim, carbofuran, chlorantranilprole, and oxadiazon) were assessed to be risks at scenario 4. However, only oxadiazon was assessed to be a risk at scenario 3 for the first sampling. Oxadiazon was not assessed to be a risk at the second sampling. It seems to be temporary phenomenon at the first sampling, because usage of herbicides such as oxadiazon increased from April to march for preventing weeds at paddy fields. However, this study suggested that five pesticides which were assessed to be risks need to be monitored continuously for the residues.
Keywords
Agricultural water; Monitoring; Pesticide residue; Stream;
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Times Cited By KSCI : 1  (Citation Analysis)
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1 Albanis, T. A., Hela, D. G., Sakellarides, T. M., & Konstantinou, I. K. (1998). Monitoring of pesticide residues and their metabolites in surface and underground waters of Imathia (N. Greece) by means of solid-phase extraction disks and gas chromatography. Journal of Chromatography A, 823(1-2), 59-71.   DOI
2 Ccanccapa, A., Masia, A., Navarro-Ortega, A., Pico, Y., & barcelo, D. (2016). Pesticides in the Ebro stream basin: Occurrence and risk assessment. Environmental Pollution, 211, 414-424.   DOI
3 Chau, N. D. G., Sebesvari, Z., Amelung, W., & Renaud, F. G. (2015). Pesticide pollution of multiple drinking water sources in the Mekong Delta, Vietnam: evidence from two provinces. Environmental Science and Pollution Research, 22(12), 9042-9058.   DOI
4 Griffini, O., Bao, M. L., Barbieri, C., Burrini, D., & Pantani, F. (1997). Occurrence of pesticides in the Arno river and in potable water-a survey of the period 1992-1995. Bulletin of Environmental Contamination and Toxicology, 59(2), 202-209.   DOI
5 Kim, C. S., Lee, H. D., Ihm, Y. B., & Son, K. A. (2017). Temporal Patterns of Pesticide Residues in the Keum, Mangyung and Dongjin streams in 2002. Korean Journal of Environmental Agriculture, 36(4), 230-240.   DOI
6 Kim, J. G., Park S. S., & Kim H. G. (1996). Distribution and Bioaccumulation of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans in Water Environment. Journal of Korean Society of Environmental Engineers, 18(11), 1417-1428.
7 Konstantinou, I. K., Hela, D. G., & Albanis, T. A. (2006). The status of pesticide pollution in surface waters (rivers and lakes) of Greece. Part I. Review on occurrence and levels. Environmental Pollution, 141(3), 555-570.   DOI
8 Lee, J. H., Park, B. J., Kim J. K., Kim, W. I., Hong, S. M., Im, G. H., & Hong, M. G. (2011). Risk assessment for aquatic organisms of pesticides detected in water phase of six major rivers in Korea. The Korean Journal of Pesticide Science, 15(1), 48-54.
9 Lee, S. R., Kang, S. Y., Pack, C. K., Lee, J. H., & Rho, C. S. (1976). A survey on the residues of organochlorine pesticide in water, mud and clam samples from the Kwangyang bay, Korea. Applied Biological Chemistry, 19(2), 112-119.
10 Lee, W. S., & Kim J. E. (1998). Effects of orgnic matter and oxidoreductase on adsorption and desorption of herbicide oxadiazon in soils. The Korean Journal of Pesticide Science, 2(3), 78-78.
11 Lee, Y. H., Hwang, E. C., & Park, C. K. (1985). Evaluation of polychlorinated biphenyls (PCBs) and organochlorine insecticide residues in irrigation waters in the periphery of Suwon. Korean Journal of Environmental Agriculture, 4(2), 95-101.
12 Lee, Y. J., Choi, J. H., Kim, S. D., Jung, H. J., Lee, H. J., & Shim, J. H. (2015). Monitoring of Pesticides in the Yeongsan and Seomjin stream Basin. Korean Journal of Environmental Agriculture, 34(4), 274-281.   DOI
13 Lobson, C., Luong, K., Seburna, D., White, M., Hannd, B., Prosser, R. S., Wong, C. S., & Hansona, M. L. (2018). Fate of thiamethoxam in mesocosms and response of the zooplankton community. Science of the Total Environment, 637-638. 1150-1157.   DOI
14 Masia, A., Campo, J., Vazquez-Roig, P., Blasco, C., & Pico, Y. (2013). Screening of currently used pesticides in water, sediments and biota of the Guadalquivir stream Basin (Spain). Journal of Hazardous Materials, 263, 95-104.   DOI
15 Min, K. J., & Cha C. G. (1999). Determination of bioconcentration factor in some pesticides. Journal of Food Hygiene and Safety, 14(2), 146-152.
16 Park, B. J., Choi, J. H., Lee, B. M., Im, G. J., Kim C. S., & Park, K. H. (1998). Decomposition rate of iprobenfos, isoprothiolane,and diazinon by some environmental factors in aqueous systems. The Korean Journal of Pesticide Science, 2(2), 39-44.
17 Park, B. J., Lee, B. M., Kim, C. S., Park, K. H., Park, S. W., Kwon, H. Y., Kim, J. H., Choi, G. Y., & Lim, S. J. (2013). Long-term monitoring of pesticide residues in arable soils in Korea. The Korean Journal of Pesticide Science, 17(4), 283-292.   DOI
18 Park, K. H., Park, B. J., Lee, B. M., Choi, J. H., Kim C. S., Jeong, M. H., Kim, B. S., & Par J. H. (2007). Monitoring of pesticide residues in water and soil at the Bokpocheon watershed in Yangpyong. The Korean Journal of Pesticide Science, 11(4), 230-237.
19 Park, Y. K., Lee, C. H., Lee, S. H., & Kim, J. W. (1996). Characteristics of pesticide discharge in the Nakdong stream basin: Evaluation of pesticide discharge from farmland and golf links. Journal of Korean Society of Environmental Engineers, 18(5), 627-636.
20 Rice, C. P., Bialek, K., Hapeman, C. J., & McCarty, G. W. (2016). Role of riparian areas in atmospheric pesticide deposition and its potential effect on water quality. Journal of the American Water Resources Association, 52(5), 1109-1120.   DOI
21 Shin, J. J., Kim, S. W., Cho, H., & Kim S. J. (2012). Examination of bioconcentration of a new algicide, thiazolidinedione derivative (TD49) to marine organisms. Korean Society for Biotechnology and Bioengineering Journal, 27(2), 91-96.
22 Thurman, E. M., Goolsby, D. A., Ragozza, L., Bartoletti, C., Ioannilli, E., & Delre, A. A. M. (1991). Herbicides in surface waters of the midwestern United States: the effect of apring flush. Environmental Science & Technology, 25(10), 1794-1796   DOI
23 Vasickova, J., Hvezdova, M., Kosubova, P., Hofman, J. (2019). Ecological risk assessment of pesticide residues in arable soils of the Czech Republic. Chemosphere, 216, 479-487.   DOI
24 Yu, J., Yang, D. B., Kim, K. T., & Lee, K. W. (2002). Distribution of organophosphorus pesticides in Asan and Kyeonggi Bay, Korea. Journal of the Korean Society for Marine Environment & Energy, 5(1), 38-50.