• Korean Journal of Plant Resources
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• v.25 no.5
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• pp.652-655
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• 2012

'Blue Edge' (Hosta minor) was induced by ethyle methane sulfonate (EMS) to obtain mutants. Among induced leaf variegated hosta plants, some with deep-green color pattern on the edge of the leaves was selected. They were cultivated via vegetative propagation. Assessment of botanical characteristics was conducted for three years since 2003. The major characteristic of these cultivars is that they maintain their deep-green color on the edge of the leaves all year round. These cultivars are useful as materials for pot plant or as ground cover plant.

• Applied Chemistry for Engineering
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• v.22 no.6
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• pp.594-598
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• 2011

We study on the preparation of green emitting materials for organic light emitting device. 3-chromonealdehyde derivatives possessing a conjugated structure, which were composed of electron acceptor of 3-chromonealdehydes and electron donor of diamines, were synthesized by dehydration-condensation process. The structural properties of reaction products were analyzed FT-IR and $^1H-NMR$ spectroscopy. The thermal stabilities and reactivities were measured by melting points and yields. The UV-visibles and PL properties can be determined by excitation spectra and emission spectra, respectively.

• Journal of the Korea Organic Resources Recycling Association
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• v.19 no.1
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• pp.123-130
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• 2011

Objectives of this study were to compare the environmental effects of digestates produced in bioenergy village on the rice paddy field for recycling. Digestates were applied to the soils and the soil properties and the crop responses were analyzed according to the standard methods of soil evaluation. Plant height and the number of tiller showed similar results in both the conventional and digestate treated field, and the yield of rough rice was higher in the field treated with digestates than that with chemical fertilizer. The amounts of nitrogen absorbed in straw and grain were larger in the digestates-treated field than chemical fertilizer-treated one, and efficiency of nitrogen applied was shown to be the highest in 100% treated digestate of the pig manure. Exchangeable cation and pH increased in the soil treated with digestate after harvesting, but salt was not accumulated. With these results, it was concluded that resource recycling in green town can be facilitated through the securement of arable lands for the application of digestates and the proper use of these fertilizers. Long-term effects of digestate application on the soil environment should be sustainingly studied.

• Conservation Science in Museum
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• v.30
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• pp.71-88
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• 2023

This paper examined the visible characteristics and chemical composition of glass beads from the Joseon Dynasty as well as the associations thereof. It also explored the characteristics and uses of glass beads by region. This study covered a total of 1,819 pieces excavated from 25 locations in the Gyeonggi, Chungcheong, and Gyeongsang regions, of which 537 pieces were analyzed for their chemical composition. Glass beads of the Joseon Dynasty take a variety of shapes such as a Round, Coil, Floral, Segmented, Flat, Oval, and Calabash. Colors vary from shades of brown (brown, lemon yellow) and shades of blue (Bluish-Green, greenish-Blue, Purple-Blue) to shades of white (colorless, white) and shades of green (Green, Greenish-Blue, Greenish-Brown). Brown accounts for the largest percentage, followed by Bluish-Green, greenish-Blue. It was identified that Drawing technique was the most common glass bead production technique of the Joseon Dynasty. Potassium oxide (K₂O) was the most common flux agent for glass beads, while the potash glass and mixed alkali glass groups account for the largest quantity. The choice of stabilizers depended on the type of flux agents used, but the most common were calcium oxide (CaO) and aluminum oxide (Al₂O₃). The potash glass and potash lead glass groups are high in CaO and low in Al₂O₃, the mixed alkali glass group is high in CaO, and the lead glass group is low in CaO. In terms of the association between color and shape, most of the beads with shade of brown and blue have round shapes of brown and blue have spherical shapes, while the coil shape is prominent in blue beads. A high percentage of green and colorless beads also take the shape of a coil, while white beads in general have a floral shape. In terms of the association between shape and chemical composition, round, floral and segmented shapes account for a high percentage of the potash glass group, while coil and flat shapes are common in the mixed alkali glass group. This paper also analyzed the colorants for each color based on the association between color and chemical composition. Iron (Fe) was used as the colorant for brown and white, and titanium (Ti) and iron were used for light yellow. Purple-Blue was produced by by cobalt (Co), and greenish-Blue, Bluish-Green, green, Greenish-Blue were produced by iron and copper (Cu). Colorless beads had a generally low colorant content.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.202.1-202.1
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• 2015

탄소의 $sp^2$ 혼성으로 이루어진 2차원 단일시트(two-dimensional single sheet)인 그래핀은 기계적, 열역학적, 전기적 특성이 매우 우수하며 특히 고유연성과 투명성을 가진다는 장점 때문에 오랜 기간 주목 받으며 다양한 분야에서 연구되어 왔다. 이러한 그래핀을 만드는 방법에는 화학적 증기 증착법 및 흑연으로부터의 물리적, 화학적 박리 방법이 있다. 양질의 그래핀을 대면적에서 획득 할 수 있는 화학적 증기 증착법의 경우 높은 공정 비용과 함께 수반되어야 하는 전사과정의 어려움으로 인하여 실제 상용화에 어려움이 있다. 이러한 단점의 극복을 위해 대량의 그래핀을 저렴하게 확보 할 수 있는 화학적 박리 방법이 주목을 받고 있다. 화학적 박리 방법의 경우 박리 과정에서 수반되는 산화 그래핀의 환원과정이 필요하였으며, 이를 위해 강력한 환원제를 이용한 화학적 환원 방법, 고온에서의 열처리를 이용한 열역학적 환원 방법, 및 빛을 노광시켜 산화 그래핀을 환원시키는 광학적 방법이 시도되었다. 화학적 및 열역학적 환원방법의 경우 고품질의 환원된 산화 그래핀을 획득 할 수 있으나, 강한 환원제 및 높은 열처리 온도로 인하여 유연 기판의 사용이 제한되는 단점이 있다. 이러한 단점을 극복하기 위해 빛을 이용한 광학적 방법이 제시되었으나, 환원과정에 사용되는 단파장의 자외선 광원의 높은 가격으로 인하여 경제성의 확보가 제한된다. 본 논문에서는 우수한 광학적 특성을 보이는 란타넘족 이온을 사용하여 선택적 파장 대에서 높은 광흡수도를 가지는 산화 그래핀-란타넘 이온 혼합용액을 만들었으며, 가시광선대역의 파장을 가지는 레이저를 사용하여 우수한 품질을 가지는 환원된 산화 그래핀을 제작하였다. 구체적으로 산화 그래핀은 modified hummer's method를 이용하여 만들어졌으며, 자외선 대역을 흡수하는 $Gd_{3+}$, 녹색 레이저를 흡수하는 $Tb_{3+}$, 적색 레이저를 흡수하는 $Eu^{3+}$를 1 mM 섞어주었다. 그 후, 300~800 nm의 파장을 가지는 레이저를 $1mW/cm^2$를 노광시켜 산화 그래핀을 환원시켰다. 환원된 산화 그래핀의 특성은 FT-IR, UV-Vis, 저온 PL, SEM, XPS 및 전기측정을 이용해 측정하여 재현성 및 반복성을 확인하였다.

• Prospectives of Industrial Chemistry
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• v.14 no.4
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• pp.29-40
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• 2011

앞으로 글로벌 시장에 진입할 수 있는 작물보호 신물질 개발을 위해서는 기술 난이도가 크면서 파급성 및 경제성을 갖는 친환경 신규작용점 탐색과 독창적 Scaffold를 갖는 후보물질 또는 천연물소재 발굴에 주력해야 하며, 이를 지원하는 HTS, 화합물은행 및 천연물은행 활용 분자설계 및 최적화 합성기술 등 후보물질 발굴 핵심 기술개발에 국가적인 지원이 지속적이고 장기간에 걸쳐 이루어져야 한다. 고품질의 식량생산 관리기술은 물론 석유대체 에너지 확보를 위한 농작물 바이오매스(작물, 사료, 바이오연료 등) 생산관리기술로서, 그린바이오기반(Target 효소, 천연물소 재탐색응용) 저탄소 녹색성장을 실현시키기 위한 친환경적인 생화학 작물보호제 개발이 필요하다. 또한 인구 증가와 유가상승 등 전 세계적인 경제위기 극복과 이산화탄소 증가에 따른 온난화 등 지구환경보존의 중요성이 크게 증가되면서 안전한 먹거리 생산과 환경오염을 최소화하는 지속적 생산체제를 갖추기 위하여 LOHAS (Lifestyle Of Health And Sustainability) 트랜드가 최근 농업의 화두로 떠오르고 있다. 이를 만족시키기 위하여 OECD를 중심으로 하는 선진 국가들은 기존 작물보호제의 사용을 5년 이내에 현재 사용량의 절반 이하로 감소시키고자 하고 있는데, 특히 지속적 재배와 국민건강 보호를 위한 LOHAS 농작물의 생산이 매년 50-100억불로 성장하고 있다. 이러한 추세는 2017년까지 그 성장세가 계속 지속될 것으로 예상되고 있어 미생물/생화학 중심의 바이오작물보호제의 개발은 LOHAS 트랜드를 충족시킬 수 있는 유력한 수단으로 인식되고 있다.

• Journal of Conservation Science
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• v.28 no.3
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• pp.205-216
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• 2012

65 samples of glass bead excavated from Mahan tombs of Asan Bakjimeure site consists of 13 of potash glass group and 52 of soda glass group and soda glass is superior in numbers. When classified according to color, purple blue glass bead is accompanied potash and soda glass group whereas purple glass bead is potash glass group and red, greenish blue, green and gold foil glass bead is soda glass group. Purple blue glass bead is classified as LCA type in which the content of the stabilizer is low. Of this, the soda glass categorized as LMK type with low content of MgO and $K_2O$ is determined that natron is used as the raw material. As to red glass, the homogeneous glass is LCA-B/HMK type and the heterogeneous glass is HCLA/LMK type. Thus, each of these two types are likely to be used plant ash and natron respectively. Greenish blue and green glass depends of the type that round glass is LCA-A/LMHK type and the segmented glass is LCA-B/HMK type. The gold foil glass bead is manufactured by the purity of 19.9~22.6K gold foil and the soda glass of HCLA/LMK type. In other words, the most of the glass bead of Asan Bakjimeure site is similar to the composition of the glass confirmed in other sites of the Baekche period. On the other hand, the greenish blue and green segmented bead and some red round bead is a different chemical composition is considered that the difference in raw materials. These characteristics is expected to be an important evidence for the understanding of the trade system of the ancient glass.

• Horticultural Science & Technology
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• v.30 no.5
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• pp.519-526
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• 2012

Anaerobic treated green teas were sealed with aluminum pack and stored for 12 months at three different temperatures such as 25, 4, or $-10^{\circ}C$. Anaerobic green teas were evaluated with respect to physiochemical properties and physiological functions. The longer anaerobic green teas were stored, their total nitrogen, tannins, or chlorophyll contents were reduced. Especially, the lower storage temperature of green tea resulted in less loss of physiochemical contents in green tea. Since green teas stored at $-10^{\circ}C$ exhibited less loss of physiochemical contents, compared to green teas stored at 25 or $4^{\circ}C$. The qualities of green teas stored at $-10^{\circ}C$ for 12 months were similar with those of teas stored at $4^{\circ}C$ for 8 months or stored at $25^{\circ}C$ for 4 months. Since 'a' value (green color) of green tea was considered as an important criteria to evaluate the tea quality. Anaerobic teas stored for 12 months were monitored their 'a' color values with -12.40 (fresh one), -10.54 ($-10^{\circ}C$), -9.77 ($4^{\circ}C$), and -9.06 ($25^{\circ}C$). Sensory evaluation results showed that anaerobic teas at $-10^{\circ}C$ were more favored than those at or 4 or $25^{\circ}C$. In conclusion, optimum storage temperature for anaerobic green teas should be $-10^{\circ}C$.

• Journal of the Korean Chemical Society
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• v.46 no.4
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• pp.336-345
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• 2002

In this study, we have screened $Eu^{3+}$- and $Tb^{3+}$-activated candidate phosphors for PDP in the sys-tems of CaO-Gd$_2$O$_3$-Al$_2$O$_3$ by combinatorial chemistry and investigated the synthetic temperature, optimum com-position and luminescent properties about the candidate phosphors. To construct the emission intensity library by VUV PL, we have synthesized 210 different compositional samples using a polymerized-complex method. Good luminescent samples were identified by X-ray diffraction method. $Ca_$\alpha$$G$d_{0.95-$\alpha$-$\beta$}Al_$\beta$O_$\delta$$ : Eu(0.02< $\alpha$+$\beta$ <0.04) phos-phors screened as a red phosphor have good color purity than commercial phosphor. In the candidate phosphors of CaGdAl$_3O_7$ : Tb, Ca$Al_{12}O_{19}$ : Tb, Gd$_4$Al$_2O_9$ : Tb, and Gd$_3Al_5O_{12}$ : Tb CaGdAl$_3O_7$ : Tb, and Ca$Al_{12}O_{19}$ : Tb have shorter decay time than commercial phosphor.

• Journal of the Mineralogical Society of Korea
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• v.31 no.2
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• pp.123-135
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• 2018

This study tried to find the clue to Seokrok province by comparing Seokrok used in painting culture properties with Seokrok ore from domestic occurrence and imported Seokrok ore. To this end, chemical and mineralogical characteristics of painting cultural properties were identified with portable X-ray Florescence (p-XRF), micro X-ray diffraction (micro XRD) and SEM/EDS Analysis. To obtain Pb isotopic ratio, the Pb contained in Seokrok has been analyzed with Thermal Ionization Mass Spectrometer. Atacamite (or botallackite) and small quantity of brochantite were identified from Seokrok in Dancheong, and malachite was also identified from Buddhist painting besides those two ingredients. Without distinction of type, most Seokrok used in painting cultural properties is atacamite composed of Cu and Cl. From Pb isotope analysis, it was found that Seokrok in painting cultural properties was closer to that of north Korea, north China and Japan than south Korea as in regional division for East North Asia suggested by Mabuchi. The Pb isotopic ratio of domestic green mineral belongs to the distribution of Seokrok inside the painting cultural properties but imported malachite showed considerably difference. Considering the fact that atacamite, the main mineral of Seokrok in painting cultural properties is rarely produced from southern mine of the Korean Peninsula and the result of Pb isotope analysis.