• Transactions of the Korean hydrogen and new energy society
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• v.31 no.1
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• pp.33-40
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• 2020

As hydrogen utilization becomes more active recently, a large amount of hydrogen should be supplied safely. Among the three supply methods, liquefied hydrogen, which is an optimal method of storage and transportation convenience and high safety, has a low temperature of -253℃, which is complicated by the liquefaction process and consumes a lot of electricity, resulting in high operating costs. In order to reduce the electrical energy required for liquefaction and to raise the efficiency, hydrogen is cooled by using a mixed refrigerant in a precooling step. The electricity required for the precooling process of the mixed refrigerant can be reduced by using the cold energy of LNG. Actually, LNG cold energy is used in refrigeration warehouse and air liquefaction separation process, and a lot of power reduction is achieved. The purpose of this study is to replace the electric power by using LNG cold energy instead of the electric air-cooler to lower the temperature of the hydrogen and refrigerant that are increased due to the compression in the hydrogen liquefaction process. The required energy was obtained by simulating mixed refrigerant (MR) hydrogen liquefaction system with LNG cold heat and electric system. In addition, the power replacement rate of the electric process were obtained with the pressure, the temperature of LNG, the rate of latent heat utilization, and the hydrogen liquefaction capacity, Therefore, optimization of the hydrogen liquefaction system using LNG cold energy was carried out.

• Korean Chemical Engineering Research
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• v.59 no.2
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• pp.200-208
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• 2021

Compare to the gaseous hydrogen, liquid hydrogen has various advantages: easy to transport, high energy density, and low risk of explosion. However, the hydrogen liquefaction process is highly energy intensive because it requires lots of energy for refrigeration. On the other hand, the cold energy of the liquefied natural gas (LNG) is wasted during the regasification. It means there are opportunities to improve the energy efficiency of the hydrogen liquefaction process by recovering wasted LNG cold energy. In addition, hydrogen production by natural gas reforming is one of the most economical ways, thus LNG can be used as a raw material for hydrogen production. In this study, a novel hydrogen production and liquefaction process is proposed by using LNG as a raw material as well as a cold source. To develop this process, the hydrogen liquefaction process using hydrocarbon mixed refrigerant and the helium-neon refrigerant is selected as a base case design. The proposed design is developed by applying LNG as a cold source for the hydrogen precooling. The performance of the proposed process is analyzed in terms of energy consumption and exergy efficiency, and it is compared with the base case design. As the result, the proposed design shows 17.9% of energy reduction and 11.2% of exergy efficiency improvement compare to the base case design.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.4
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• pp.401-406
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• 2017

When Liquified Natural Gas (LNG) is vaporized into NG for industrial and household usage, tremendous cold energy was transferred from LNG to seawater during phase-changing process. This heat exchanger loop is not only a waste of huge cold energy, but will cause thermal pollution to the coastal fishery area also when cold water was re-injected into the sea. In this study, an innovation design has been performed to reclaim the cold energy for -35 to $62^{\circ}C$ refrigerated warehouse. Conventionally, this was done by installing mechanical refrigeration systems, necessitating tremendous electrical power to drive temperature. A closed loop LNG heat exchangers in series was designed to replace the mechanical or vapor-compression refrigeration cycle by process simulator. The process simulation software of PRO II with provision has been used to simulate this process for various conditions, what to effect on cold energy and used energy for re-liquefaction and evaporation process. In addition, through analysis the effect of the change of LNG supply pressure on sensible and latent heat, optimum operational conditions was suggested for LNG cold energy warehouse.

• Transactions of the Korean hydrogen and new energy society
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• v.30 no.3
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• pp.282-288
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• 2019

When liquefied natural gas (LNG) is vaporized to form natural gas for industrial and household consumption, a tremendous amount of cold energy is transferred from LNG to seawater as a part of the phase-change process. This heat exchange loop is not only a waste of cold energy, but causes thermal pollution to coastal fishery areas by dumping the cold energy into the sea. This project describes an innovative new design for reclaiming cold energy for use by cold storage warehouses (operating in the 35 to $62^{\circ}C$ range). Conventionally, warehouse cooling is done by mechanical refrigeration systems that consume large amounts of electricity for the maintenance of low temperatures. Here, a closed loop LNG heat exchange system was designed (by simulator) to replace mechanical or vapor-compression refrigeration systems. The software PRO II with PROVISION V9.4 was used to simulate LNG cold energy, gas re-liquefaction, and the vaporized process under various conditions. The effects on sensible and latent heats from changes to the array type of heat exchangers have been investigated, as well as an examination of the optimum.

• Transactions of the Korean hydrogen and new energy society
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• v.25 no.2
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• pp.200-208
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• 2014

This paper presents thermodynamic performance analysis of organic Rankine cycle (ORC) using low temperature heat source in the form of sensible energy and using liquefied natural gas (LNG) as heat sink to recover the cryogenic energy of LNG. LNG is able to condense the working fluid at a very low condensing temperature in a heat exchanger, which leads to an increased power output. Based on the mathematical model, a parametric analysis is conducted to examine the effects of eight different working fluids, the turbine inlet pressure and the condensation temperature on the system performance. The results indicate that the thermodynamic performance of ORC such as net work production or thermal efficiency can be significantly improved by the LNG cold energy.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.6
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• pp.510-517
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• 2013

The ammonia-water based power generation cycle utilizing liquefied natural gas (LNG) as its heat sink has attracted much attention, since the ammonia-water cycle has many thermodynamic advantages in conversion of low-grade heat source in the form of sensible energy and LNG has a great cold energy. In this paper, we carry out thermodynamic performance analysis of a combined power generation cycle which is consisted of an ammonia-water regenerative Rankine cycle and LNG power generation cycle. LNG is able to condense the ammonia-water mixture at a very low condensing temperature in a heat exchanger, which leads to an increased power output. Based on the thermodynamic models, the effects of the key parameters such as source temperature, ammonia concentration and turbine inlet pressure on the characteristics of system are throughly investigated. The results show that the thermodynamic performance of the ammonia-water power generation cycle can be improved by the LNG cold energy and there exist an optimum ammonia concentration to reach the maximum system net work production.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.3
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• pp.295-299
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• 2017

In this study, computer simulation and optimization works have been performed for an open-loop Rankine cycle to generate power using five cases of liquefied natural gas compositions. PRO/II with PROVISION V9.4 from Schneider electric company was used, and the Soave-Redlich-Kwong equation of the state model was utilized for the design of the power generation cycle. It was concluded that more power was obtained from less molecular weight liquefied natural gas since there was more volumetric flow rate with less molecular weight.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.2
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• pp.234-241
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• 2020

This paper presents a thermodynamic performance analysis of a combined cycle consisting of regenerative organic Rankine cycle (ORC) and liquefied natural gas (LNG) Rankine cycle to recover low-grade heat source and the cold energy of LNG. The mathematical models are developed and the system performances are analyzed in the aspect of thermodynamics. The effects of the turbine inlet pressure and the working fluid on the system performance such as the mass flow rates, heat transfers at heat exchangers, power productions at turbines, and thermal efficiency are systematically investigated. The results show that the thermodynamic performance of ORC such as net power production and thermal efficiency can be significantly improved by the regenerative ORC and the LNG cold energy.

• Transactions of the Korean hydrogen and new energy society
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• v.35 no.1
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• pp.90-96
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• 2024

In this paper, a new technology to obtain electronic grade, highly pure carbon dioxide by using membrane and liquefied natural gas (LNG) cold heat assisted cryogenic distillation has been proposed. PRO/II with PROVISION release 2023.1 from AVEVA company was used, and Peng-Robinson equation of the state model with Twu's alpha function to predict pure component vapor pressure versus temperature more accurately was selected for the modeling of the membrane and cryogenic distillation process. Advantage of using membrane separation instead of selecting absorber-stripper configuration for the concentration of carbon dioxide was the reduction of carbon dioxide capture cost.

• The Journal of Korean Institute for Practical Engineering Education
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• v.3 no.1
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• pp.9-14
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• 2011

The expansion work that is wasted through the irreversible expansion through the PC valve of decompression process of the natural gas governor station can be recovered by replacing the process by an isentropic expansion. The energy and exergy analyses for the two decompression process models of power producing and current decompression process model are presented. Analysis results showed that the exergy by gas supply is 56.29%, the exergy by producing power is 32.12 % in case of preheating system and 22.52% in case of non-preheating system. The dead exergy at the PCV is generated much more network. As these results, the usefulness of exergy analysis is verified.