• Title/Summary/Keyword: 내오존

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Ozone kinetics and Diesel decomposition by Ozonation in Groundwater

  • Kwon, Choong-Il;Kong, Sung-Ho;Kim, Moo-Hoon
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.05a
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    • pp.153-156
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    • 2000
  • 본 연구에서는 지하수내에서의 오존의 거동과 오존산화공정에 의한 디젤의 분해를 조사하였다. 오존의 초순수와 지하수내에서의 반응은 모두 2차 분해반응속도식을 나타냈고, 초순수와 지하수내에서의 반감기는 각각 평균 37.5분, 14.7분으로 계산되었다. 지하수내에서 오존의 자가분해반응속도가 더 빠른 것으로 나타났는데 이는 오존이 지하수내에 존재하는 각종 유기·무기물질들과의 빠른 반응때문이라고 생각된다. 오존의 TCE, PCE 그리고 디젤의 빠른 제거효율을 통하여 디젤로 오염된 지하수를 처리하는데 있어서 오존산화공정은 효과적으로 적용될 수 있을 것이라 판단된다.

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Effect of Gas Composition on Ozone Production in Dielectric Barrier Discharge Process (무성방전내에서 오존 발생에 미치는 가스 조성의 영향)

  • 조백근;이현돈;이석부;전현정;박정호;전기일;정재우
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.381-382
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    • 2003
  • 오존은 여러 가지 산업적 응용분야를 가지고 있으며 특히, 광범위한 환경공학적 응용분야를 가지고 있다. 오존생성을 위해 개발된 무성방전 공정이 비교적 최근부터 악취 및 VOC를 포함한 대기오염 물질의 제거를 위해 활용되어오고 있으며 이러한 공정내에서 오존의 발생은 공정내의 오염물질 제거에 중요한 역할을 하게 된다. 따라서, 본 연구에서는 무성방전 공정에서 유입기체의 조성이 오존발생에 미치는 영향에 관해 알아보고자 하였다 (중략)

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Variation of Indoor Average Ozone Concentration within the Radiation Therapy Room by High Energy Radiation (고 에너지 방사선에 기인된 방사선치료실 내 평균 오존 농도의 변화)

  • Lee, Jin-kook;Lee, Hyo-Yeong;Im, In-Chul;Yu, Yun-Sik
    • Journal of the Korean Society of Radiology
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    • v.10 no.3
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    • pp.171-180
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    • 2016
  • This study was to evaluate the change in characteristics of concentration of ozone after exposure to high energy radiation in linac room. Background ozone concentration of linac room was measured and compared to ozone concentration around linac room. Background ozone concentration of linac room was mean $17.4{\pm}7.9ppb$. It was 50% of the ozone concentration($36.8{\pm}22.3ppb$) around linac room(p<0.05). The concentration of ozone after exposure to high energy radiation in linac room was elevated to double of background ozone level, intensity after exposure. with exposure time concentration of ozone increased proportionally. It showed maximum level at 130~180seconds and slowed a tendency to saturate. It required more than 10 minutes for ozone concentration in linac room to drop to ozone concentration around linac room. The concentration of ozone after exposure to high energy radiation is high enough to cause specific physical symptoms, such as acute dyspnea or chest pain due to dry cough. Exposure to high concentration of ozone in sealed linac room can aggravate pulmonary disease, so special attention is needed.

Experimental Study on Evaluation of Bond Strength after Ozone Treatment and Ozone Resistance of Concrete Metal Spray Coating for Advanced Water Treatment (고도정수처리용 콘크리트 금속용사 피막의 내오존성 및 오존처리 후 부착강도 평가에 관한 실험적 연구)

  • Park, Jin-Ho;Jang, Hyun-O;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.4
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    • pp.68-75
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    • 2018
  • The introduction of advanced water treatment facilities has increased as the conventional purification method cannot remove the substance clearly. However, the internal waterproofing and Anticorrosion materials of the advanced water treatment facility using ozone deteriorate due to the oxidation power of ozone and affects the concrete, which causes a decrease in durability. This study is to evaluate the ozone resistance according to the type of spray metal and the surface treatment method of the coating, and the bond strength after ozone treatment in order to develope a finishing method to prevent deterioration of concrete structure of water treatment facility using metal spraying method as a way to construct metal panel with excellent ozone resistance and chemical resistance by an easier way than the previous. The Experimental results show that spray metal Ti has superior ozone resistance even after spraying. It is considered to be the most suitable method for ozone resistance and bond performance by finishing using Teflon sealing as surface treatment method.

A study on the Ozone oxidation of Diesel-contaminated Groundwater (디젤로 오염된 지하수의 오존산화처리에 대한 연구)

  • 권충일;공성호;김무훈
    • Journal of Korea Soil Environment Society
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    • v.5 no.3
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    • pp.3-15
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    • 2001
  • The ozone kinetics including ozone auto-decomposition. effect of pH, and solubility were investigated. Diesel decomposition process including TCE & PCE decomposition. effect of hydroxyl radical scavenger, effect of pH, and ozone/$H_2O$$_2$by ozonation process were also examined using deionized water, simulated groundwater. and actual groundwater. Reactions with deionized water and groundwater both stowed the second-order reaction rates, and the reaction rate was much higher in groundwater (half-life of 14.7 min) than in deionized water (hal(half-life of 37.5 min). The reaction rate was accelerated at high pH values in both waters. The use of ozone showed high oxidation rates of TCE. PCE and diesel. Though hydroxyl radical scavengers existing in groundwater were inhibitors for treating diesel, high pH condition and addition of hydrogen peroxide could accelerate to degrade diesel in groundwater, indicating ozone oxidation process could be applied to treating diesel contaminated-groundwater.

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Consideration about Ozone Generation in the Treatment Room While Treating a Patient (방사선 치료 시 치료실 내에서 발생하는 오존에 관한 고찰)

  • Kwak, Yong-Kuk;Yoon, Il-Kyu;Lee, Jae-Hee;Yoo, Suk-Hyun
    • The Journal of Korean Society for Radiation Therapy
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    • v.21 no.2
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    • pp.75-82
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    • 2009
  • Purpose: Measure the ozone level in the treatment room while treating a patient so want to know the degree of contamination caused by ozone occurrence. Materials and Methods: Use the linear accelerator (Clinac 21EX, Varian, USA) with the ozone meter (series-200, aeroQual, New Zealand) and water phantom (Wellhofer, IBA, Germany) is irradiated the radiation so that measured the ozone generation level according to MU, dose-rate, SSD, field size, energy, delay time and put the ozone meter in the treatment room actually while treating a patient so measured the daily ozone level variation. Results: While irradiating the radiation, degree of ozone contamination wasn't affected by the energy but mostly in case of electron beam, ozone level was higher than photon beam. The higher dose-rate (0.016~0.025 ppm/hr), the farther SSD (0.018~0.030 ppm/hr), the wider field sizes (0.016~0.025 ppm/hr), the more MU (0.018~0.046 ppm/hr), it occurred high ozone level. Ozone decrement according to delay time changed the background level (0.016 ppm/hr) after elapsed time of 10 minutes from irradiating radiation. And daily ozone occurrence level in the treatment room was below ozone standard level 0.1 ppm/hr (average:0.06 ppm/8 hr) but it could confirm that ozone generation level was included the level (max:0.038 ppm/hr) above 0.02 ppm/hr which patient could perceive. Conclusion: Through ozone level according to variation of certain conditions, actually in the treatment room ozone generation level didn't damaged to patients or workers. Commonly peoples think that ozone was harmful gas but it thought that small amount of ozone generation level while treating a patient was beneficial in the treatment room through air purge action of pathogenic germ or virus sterilization.

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상하수도 오존 고도처리시스템의 기술동향

  • 대한전기협회
    • JOURNAL OF ELECTRICAL WORLD
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    • s.254
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    • pp.53-61
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    • 1998
  • 오존은, 그 강력한 산화력에 의하여 살균, 탈취, 탈색과 유기물 제거 등의 효과를 복합적으로 얻을 수 있고 또한 신속하게 산소로 분해되어 잔류하지 않기 때문에 환경개선에 사용하기에 이상적인 물질이다. 미쓰비시전기에서는 이러한 오존의 이점에 착안하여 1970년부터 오존발생기와 오존처리설비의 개발, 제품화를 추진하여 왔다. 오존에 의한 고도처리가 널리 일반에게 인정되어 그 수요가 높아지고 있는 오늘날에 있어서도 보다 많은 오존설비의 보급을 위하여 오존기술의 개발에 힘쓰고있다. 본고에서는 상하수도 오존고도처리의 기술동향의 일부로 시도되고 있는 다음의 세 가지 내용을 소개한다. (1)오존처리시스템의 자에너지, 고효율화 기술 방전갭의 단축화, 관분내압력의 고압화로 고농도$\cdot$고효율의 오존발생을 실현하여 자전력화를 가능케 한 신형오조나이저를 개발 제품화하였다. (2)오존 반응조 내에서의 산기장치특성의 파악 모델화가 곤란한 신기장치에 대하여 실설비규모의 실험설비를 사용하여 그 산기특성을 분명히 하였다. (3)과산화수소첨가 오존처리법에 의한 하수처리수의 재생이용 과산화수소첨가 오존처리법에 의하여 장기간에 걸쳐 하수처리수를 전유기탄소(TOC)3mg/$\ell$이하로까지의 처리를 달성하여 하수처리수를 수도수레벨로까지 고도로 정화할 수 있음을 실증하였다.

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Influence of LNAPL and Soil Water on Migration of Gaseous Ozone in Unsaturated Soils (불포화 토양내에서 가스상 오존 이동특성에 대한 LNAPL과 토양수분의 영향)

  • Jung, Hae-Ryong;Choi, Hee-Chul
    • Journal of Soil and Groundwater Environment
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    • v.10 no.6
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    • pp.63-67
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    • 2005
  • Laboratory scale experiments were carried out to delineate the effects of liquid phases, such as soil water and light nonaqeous phase liquid (LNAPL) on the transport of gaseous ozone in unsaturated soil. Soil water enhanced the transport of ozone due to water film effect, which prevents direct reaction between soil particles and gaseous ozone, and increased water content reduced the breakthrough time of ozone because of increased average linear velocity and decreased air-water interface area. Diesel fuel as LNAPL also played a similar role with water film, so the breakthrough time of ozone in diesel-contaminated soil was significantly reduced compared with uncontaminated soil. Ozone breakthrough time was retarded with increased diesel concentration, however, because of high reactivity of diesel fuel with ozone. In unsaturated soil containing two liquids of soil water and LNAPL, the transport of ozone was mainly influenced by nonwetting fluid, diesel fuel in this study.

Preparation and Characterization of Hybrid Ozone Resistance Coating Film Using Carbon Nanotube (탄소나노튜브를 이용한 하이브리드 내오존성 코팅 막의 제조 및 특성)

  • Kim, Sung Rae;Lee, Sang Goo;Yang, Jeong Min;Lee, Jong Dae
    • Polymer(Korea)
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    • v.38 no.5
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    • pp.573-579
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    • 2014
  • The effect of synthesis conditions such as carbon nanotube (CNT), 2,2,2-trifluoroethylmethacrylate (3FMA), and composition of organic-inorganic material in ozone resistance and surface characteristics of ultraviolet cured organic-inorganic hybrid coating film has been investigated. Coating solution was prepared using tetraethoxysilane (TEOS), silane coupling agent methacryloyloxypropyltrimethoxysilane (MPTMS), 3FMA, various organic materials with acrylate group, and CNT, then bar-coated on substrates using applicator, and densified by UV-curing. It was found that ozone resistance and adhesion of the coating film were strongly dependent upon contents of TEOS, 3FMA, and CNT. Especially, ozone resistance, adhesion, and surface hardness of coating film with CNT were improved, relatively. Ozone resistance of coating film with a high TEOS content was increased, but adhesion was decreased. In addition, it was also found that ozone resistance of coating film was increased with contents of 3FMA. On the other hand, surface hardness was decreased with increase of 3FMA.

오존의 살균 및 탈취와 오존발생기의 발생농도 변화

  • Yun, Yeong-Mi;Go, Myeong-Seok;Kim, Hyeon-Jong;Lee, Eun-Mi;Jeong, Bong-U;Lee, Hyeon-Cheol
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.473-474
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    • 2000
  • Ozone has a potency for disinfection, deodorization, decolorization and decomposition of organic materials by strong oxidation. therefore we used the ozonizer to disinfection and deoderization of a piggery. CFU of the ozonated piggery was lower than the others. And the of ozonizer was redesigned from open-type to close-type to obtain high ozone concentration. We was also investigated the effect of air velocity to ozone concentration.

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