• Journal of the Korean Applied Science and Technology
• /
• v.38 no.6
• /
• pp.1678-1686
• /
• 2021

In this study, we prepared phosphorous flame-retarding coating solutions by mixing triphosphate (3 phosphonate), phytic acid (6 phosphonate), or ammonium polyphosphate (10 phosphonate) with boric acid as a crosslinking agent and acryl resin binder. Prepared phosphorous flame-retarding coating solutions were coated onto non-woven fabrics, respectively, to obtain high flame-retarding effects. These prepared flame-retardant non-woven fabrics were evaluated using smoke density standard test (ASTM E662), limit oxygen index standard test (ISO E622), and vertical burning standard test (UL 94). Their flame-retarding effects were affected by the number of phosphonate groups. Regardless of natural or synthetic binder resins, their effects showed the following order: ammonium polyphosphate > phytic acid > triphosphate. Natural hydrocarbon compounds were also examined to determine the possible retardancy of binder resins. Results showed that natural hydrocarbon binder resins could be used for preparing fire-retardant nonwoven fabrics.

• Applied Chemistry for Engineering
• /
• v.17 no.2
• /
• pp.144-149
• /
• 2006

Non-halogen flame retardants have been the focus of extensive research because of environmental problems. Hexakisp-henoxycyclotriphosphazene was synthesized in order to use as the flame retardant of ABS resin. And using bisphenol A, the polymers containing a cyclotriphosphazene structure were synthesized in order to also use as the flame retardant of ABS resin. All of the synthesized polymers themselves had the excellent flame retardancy. And as their molecular weight and crosslinking density were increased, the thermal stability was increased. But when the synthesized compounds were used as the flame retardant for ABS resin, the lower molecular weight compound in these compounds showed the better flame retardancy and the better physical properties of ABS resin.

• Polymer(Korea)
• /
• v.27 no.6
• /
• pp.576-582
• /
• 2003

When the halogenated flame retardant, decabromodiphenyl oxide, was added to the polypropylene/nylon blend, and was compounded with montmorillonite and compatibilizer, maleic anhydride polypropylene, the improvement of flame retardancy and mechanical properties was investigated. The degree of dispersion between polymer resin and inorganic nanoparticles was investigated, and the flame retardancy and mechanical properties was measured quantitatively. XRD results showed that the montrnorillonite was com-pletely exfoliated after polypropylen/nylon nanocomposites was mixed above twice. By compounding with montmorillonite, polypropylene/nylon blend system was overcome the deterioration of flame retardancy. The tensile strength and impact strength were slightly increased, and by compounding with montmorillonite, the additional increase in mechanical properties was obtained. Therefore, the flame retardancy of polypropylene / nylon blend was decreased by adding nylon, but by compounding with inorganic nanoparticle, improvement of the flame retardancy and mechanical properties was obtained.

• Fire Science and Engineering
• /
• v.12 no.4
• /
• pp.41-49
• /
• 1998

In this study, the thermal improvement of an isophthalic acid polyester resin by the incorporation of flame retardants has been investigated. Aluminium hydroxide, antimony oxide and alumina powder were used to formulate the flame retardant systems. The improvement of an isophthalic resin by incorporating aluminium hydroxide is dramatic(burning rate and smoke emission are reduced), although the mechanical property is decreased significantly. The addition of small amount(2.5 phr) of antimony oxide produces high char yield(31%) which acts as a protective layer on the surface of the resin.

• Journal of Adhesion and Interface
• /
• v.11 no.4
• /
• pp.168-173
• /
• 2010

Flame retardant halogen containing compounds have been replaced as environmentally safe material which does not contain hazardous materials generating toxic gas. Self-extinguishing epoxy resin compositions have been studied in order to produce eco-friendly epoxy molding compound, which is used as insulating materials in semiconductor. We developed self-extinguishing epoxy resin compositions which do not contain halogen compounds with new epoxy resin (E3). The new epoxy molding compound (EMC-1) showed high flame resistance (UL-V0) and high thermal resistance ($451.9^{\circ}C$ at 5 wt% loss) enough to use as eco-friendly material.

• Journal of Advanced Marine Engineering and Technology
• /
• v.38 no.9
• /
• pp.1150-1155
• /
• 2014

To prevent the flame spread in FRP vessel in fire, the engine-room of the vessel should be constructed additionally with laminated fire-retardant resin over 3 times or equivalent insulation materials to former according to the relevant standard for FRP vessel structure. It is surveyed that insulation materials called 'Gel coat' are widely used in FRP fishing vessel, however, test method and its criteria for Gel coat are not clearly establish and have not been evaluated yet, while test method and criteria for fire-retardant resin and fire-retardant polyurethane composite are described in test standard for type-approval. In this study, 3 fire-retardant resins, 4 gel coats, 1 flame-retardant paint and 1 polyurethane composite were selected based on the survey and were evaluated according to both IMO FTP Code part 5 and flame-retardant test. When comparing based on CFE values from flame-spread test, average value for 4 gel coats were lower than that of 3 fire-retardant resins. As for flame-retardant test, there were no significant differences between fire-retardant resin and gel coat, based on charred area.

• Polymer Science and Technology
• /
• v.20 no.1
• /
• pp.8-15
• /
• 2009

• Journal of the Korean Wood Science and Technology
• /
• v.43 no.6
• /
• pp.792-797
• /
• 2015

In this study, three softwood species were treated with water-soluble melamine resin by different concentration and treatment time under vacuum pressure for improving mechanical property, abrasion resistance, and incombustibility. After the treatment, a compreg was manufactured and then evaluated on physical properties. Additionally, incombustibility of compreg was determined by comparing with a wood that was treated by spraying a water-soluble fire retardant on surface. As concentration of resin increased, bending strength and Brinell hardness increased as well as abrasion resistance, but there was no correlation on treatment and mechanical properties by treatment time. The wood impregnated by water-soluble melamine resin under vacuum pressure showed better incombustibility than that of a water-soluble fire retardant sprayed wood. Therefore, this treatment could be used for improving incombustibility of wood.

• Polymer(Korea)
• /
• v.27 no.6
• /
• pp.569-575
• /
• 2003

The flame retardancy was investigated when the halogenated flame retardant, decabromodiphenyl oxide (DBDPO) and chlorinated paraffin wax (CPW), was added to the polypropylene (PP) / montmorillonite (MMT) nanocomposites. The flame retardancy of polymer resin could be improved not only by addition of flame retardant but also with nanoparticles compositions. The effect of the contents of flame retardant and nanoparticles on the flame retardancy of polypropylene/ montmorillonite nanocomposite systems was thoroughly examined in terms of limited oxygen index (LOI) and cone calorimetry. As a results of cone calorimetry, the heat release rate (HRR) was reduced by the flame retardant DBDPO and CPW, and CPW was a little better than DBDPO. The LOI increased from flammable region (LOI<19) to nonflammable region (LOI>20) for all the flame retardants used in this study. Especially, the improvement in flame retardancy by compounding with PP and MMT was better than that by adding flame retardant to polypropylene. So, the addition of flame retardant after compounding with montmorillonite was more efficient than simple addition of flame retardant.

• Clean Technology
• /
• v.23 no.4
• /
• pp.378-387
• /
• 2017

To obtain epoxy resin with permanently attached flame-retardant groups, phosphorus compound containing di-hydroxyl group [10-(2,5-dihydroxyphenyl)-9,10-dihydro-9-oxa-10-phospha phenanthrene-10-oxide, DOPO-HQ] and silicone compound containing di-hydroxyl group (polydimethylsiloxane, hydroxyl terminated, PDMS) were reacted with uncured epoxy prepolymer (diglycidyl ether of bisphenol A, DGEBA) and then cured using 4,4-diaminodiphenylmethane (DDM) as a crosslinking agent. The properties of the resulting epoxy materials were characterized using Fourier transform infrared (FTIR) spectrometer, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), limiting oxygen index (LOI) test/vertical burning test (UL 94-V test), tensile properties test and impact test. This study examined the effect of phosphorus/silicone compound contents on the thermal/mechanical properties and flame retardancy of cured epoxy resins containing phosphorus and silicone compounds. It was found that the thermal/mechanical properties of epoxy resins containing phosphorus and silicone components were higher than those of simple epoxy resin. The flame-retardancy (LOI: 29.9 ~ 31.8% and UL 94-V: V-0) of all samples containing phosphorus compound and phosphrous compound/silicone compound was found to be passed the flame-retardant requirements (LOI: > 30%, UL 94-V: V-0) of LOI and vertical burning tests. However, the flame-retardancy (LOI: 21.4% and UL 94-V: no rating) of simple epoxy resin was found to be failed the flame-retardant requirements.