• Journal of the Korea Concrete Institute
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• v.26 no.4
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• pp.457-463
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• 2014

The permitted limit, ${\pm}12%$, of the change in solid contents based on ASTM C 494 as an interim standard in Korea Expressway Corporation, can not reflect the kind of chemical admixture and the characteristics of solid content so that it differed depending on the admixture types. In this study, effect of cement concrete quality was investigated by solid changes which can be used chemical admixtures acceptance criteria. As a result of an evaluation of a change in the quality of concrete due to solid content, since Ligno-sulfonate based (LG) had a low water reducing ratio, the range of the change in solid content was great while Naphthalene sulfonated based (PNS) and Poly-carboxylate based (PC) High Range Water-reducing Admixtures (HRWR) had a high water reducing ratio, the permitted limit of the difference in solid content currently used as the acceptance criterion should be readjusted. As a result, it is found that the acceptable range must be managed within 10% and 5% when the solid contents less than 25% and more than 25%, respectively.

• Journal of the Korean Chemical Society
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• v.34 no.4
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• pp.325-330
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• 1990

The solubilities of caffeine in supercritical ammonia were measured at various temperatures and pressures to represent the relationship between the solubility and the density of ammonia at desired temperature and pressure by means of a simple equation. Using the equation, the interaction virial coefficient between ammonia and caffeine has been determined to give the parameters of Lennard-Jones potential function for the system. Furthermore, there are comparisons and discussions of the interaction virial coefficients and Lennard-Jones potential functions determined by the same techniques from the solubility data of naphthalene in supercritical ammonia and of caffeine and naphthalene in supercritical carbon dioxide from existing data sources others.

• Applied Chemistry for Engineering
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• v.21 no.4
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• pp.457-462
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• 2010

In this research, the effects of the concrete superplastizers on the wettability of cement particle and concrete strength were studied. The wettability of the cement particles strongly depended on the type of the superplastizer. When the superplastizer had a higher wettability with the cement particles, it revealed a good fluidity of the concrete mortar and a higher concrete strength. Non-ionic superplastizers (polycarboxylic type) had a relatively good performance on the mortar fluidity and concrete strength properties compared to anionic superplastizers (lignosulfate, sulfonated naphthalene formaldehyde, sulfonated melamin formaldehyde). It was observed that the blending of the polycarboxylic and the lignosulfate type concrete superplastizers resulted in synergistic effects on the concrete mortar fluidity and concrete strength properties.

• Proceedings of the Membrane Society of Korea Conference
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• 2003.05a
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• pp.88-90
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• 2003

• Membrane Journal
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• v.13 no.2
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• pp.110-117
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• 2003

Sulfonated polyimides had been utilized and studied widely as available materials in chloro-alkali electrolysis, cationic exchange resins, and so on. However, a slow decrease in performance during experiments had been reported, which could be attributed to a loss of ionic conductivity related to either a continuous dehydration or polymer degradation. One of main reasons to account for the degradation of sulfonated polymers is the hydrolysis leading to polymer chain scission and decrement of molecular weight. Therefore, the objective of our study was to investigate possible imide cycle and additional ester bond cleavage connected with $SO_3$H presence under hydrated condition. In order to confirm and obtain as clear information as possible about breakages of bonds via $^1H\; and \;^{13}C$ NMR and IR spectroscopic analyses, our study was performed by model compound. Consequently, model compounds with both phthalic and naphthalenic imide ring and ester bonds were synthesized to evaluate the hydrolysis stability of sulfonated polyimide. The experiments were performed for prepared model compounds before and after aging in deionized water at $80^{\circ}C$ and were terminated by lyophilization technique. The aging products were finally analyzed by NMR and IR spectroscopy.

• Applied Chemistry for Engineering
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• v.33 no.4
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• pp.431-435
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• 2022

The reduction of nitrogen-containing compounds (NC) containing the model crude methylnaphthalene oil (CMNO) of 5 compounds system was experimentally studied by solvent extraction. The model CMNO consisting of 3 kinds of NC including quinolone (QU), iso-quinoline (IQU), indole(IN) and 2 kinds of bicyclic aromatic compounds such as 1-methylnaphthalene (1MNA), 2-methylnaphthalene (2MNA) as raw materials, as well as the aqueous solution of formamide as a solvent, were used. The increase in the volume fraction of water to the solvent at the initial state (y_w,0) sharply decreased, but the distribution coefficient and the yield of NC conversely increased the selectivity of NC based on 2MNA, and an increase in the volume fraction of solvent to feed (S/F) simultaneously increased the distribution coefficient, yield and selectivity of NC. The yields of QU, IQU and IN under constant conditions (y_w,0 = 0.1, S/F = 1, equilibrium temperature 303 K) were 30%, 31% and 10%, respectively, and selectivity was 15, 15 and 20, respectively. From the excellent yield and selectivity of NC, the formamide extraction method of this study was expected as a method for reducing the NC contained in the model CMNO.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.05a
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• pp.210-211
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• 2017

According to KS F 2560, water-reducing agents used when mixing concrete are to undergo quality evaluation testing slump, air contents, setting time, etc., when delivered from the admixture factory to the ready mixed concrete site. Yet in actual acceptance testing this could be substituted by the score report of the admixture company, in which a possibility of low reliability lies. Therefore this study sought to analyze whether by artificially changing the solid content rate of lignin- and naphthalene-based water-reducing agents and using a liquid densimeter evaluate the quality of the admixture. The results showed that the Type B liquid densimeter was most appropriate and 50cc the most appropriate capacity for the mass cylinder. Also, judging from the changes in density and pH according to the changes in solid content rate, it concludes that a rapid appraisal of the quality of lignin- and naphthalene-based water-reducing agents would be possible using a Type B liquid densimeter.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.7
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• pp.4644-4652
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• 2014

This study examined the effects of the cement type and sand to cement ratio on the properties of grout for offshore PSC structures. Types I and III cement were used and the sand to cement ratio was varied from 0.5 to 1.5. When type I cement was used, considerable bleeding occurred on the all S/C after 3 hours and 20 hours. When type III cement was used, bleeding was reduced but the flowability decreased. A comparison of a superplasticizer containing naphthalene with that containing polycarboxylate showed that the problem of flowability could be solved using polycarboxylate.

• Magazine of the Korea Concrete Institute
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• v.7 no.3
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• pp.156-163
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• 1995

In the previous study, styrene mdleic dnhydride copolymer(SMA) as synthesized flom styrene and rnale~c dnhydr~de and further redcted with sulfuric acid to obtam water soluble SMA. In thls study, the flow dnd strcngth tests of cement mortar rmxed wth copolymers wele carried out to evaluate the capability of copolymers as high range water reducer for the con crete. It was found from flow exper~ment that the fluidity of cenient mortar rmxed wth sulfonated SMA(SSMAj was larger thdn that mxed ulth amnophenol substituted SSMA (SmSMAj. The decreasing rate of the flow of cement mortar rmxed ulth SSMA and SmSMA was significantly lower than that mixed ulth naphthalene condensate(NSC) The compressslve strength of the hardened cement mortars containing 0.5% copolymers after 28 dys curing was exarmned. 'The compressive strength of hdrdened cement mortar containing SSMA and SmSMA was mcreased up to 31% and 13%, respectively, when omp pared to the plain. As the results, the copolyniers(SSMA and SrnSMA) used in thls study are greatly expected as a good high range water reducers for the concrete.

• Applied Chemistry for Engineering
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• v.16 no.6
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• pp.815-821
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• 2005

Three major commercially available organic chemical admixtures are modified lignosulfonates (LS), sulfonated naphthalene-formaldehyde resins (SNF) and sulfonated melamine-formaldehyde (SMF). In this study, various sulfonated melamine-formaldehyde (SMF) superplasticizers were synthesized via four synthetic steps including hydroxymethylation (Step 1), sulfonation (Step 2), polymerization (Step 3) and neutralization and stabilization (Step 4). In this synthesis, mole ratio of melamine to formaline and the amount of acid catalyst used were varied. The obtained SMF superplasticizers were applied to cement paste and mortar and their physical properties including workability, slump loss, compressive strength were investigated. Also their hydrate shapes were investigated by examining SEM images of the cured paste. It was found that the fluidity properties of cement were significantly influenced by the structure of SMF condensates.