• 제목/요약/키워드: 나일론66

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나일론66에서 유리섬유의 종류 및 애향에 따른 기계적 물성 연구 (A study on the mechanical properties of reinforced Nylon66 for glass fiber type and its orientation)

  • 유종범;류민영
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2009년도 춘계학술대회 논문집
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    • pp.374-377
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    • 2009
  • Glass fiber reinforced nylon has been used in many plastic industries. Mechanical properties of reinforced plastics depend upon types of glass fiber as well as loading of glass fiber. Tensile properties of glass fiber reinforced nylon66 have been studied for different glass fiber types and sizes. Types of glass fibers were circular and flat, and diameters were 7, 10, and 13 micrometers. Orientations of glass fibers in the matrix of nylon66 have been analyzed through X-ray CT. Tensile specimens were prepared by cutting out of square plates of $100{\times}100{\times}3mm$ with different angles such as 0, 45, and $90^{\circ}$ to the flow direction. As the loading of glass fiber increases to 45 wt% tensile strength increases up 2.5 times compare with neat nylon66. Anisotropic tensile strength has been observed and minimum tensile strength was measured in the specimen cut from perpendicular to the flow direction.

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마이크로웨이브를 이용한 효율적인 탈산소탈수(DODH) 반응: 갈락토스 유래 아디픽산의 합성 (Efficient Microwave-assisted Deoxydehydration (DODH) Reactions: Synthesis of Adipic Acid from Galactose)

  • 신나라;권소현;김영규
    • 공업화학
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    • 제28권2호
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    • pp.165-170
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    • 2017
  • 나일론의 단량체인 아디픽산을 바이오매스인 갈락토스로부터 얻기 위한 효율적인 합성법을 개발하였다. 백금촉매를 이용한 갈락토스의 산화반응을 통해 얻어진 갈락타릭산으로부터 마이크로웨이브를 이용한 탈산소탈수(DODH)반응을 통하여 30 min의 매우 짧은 반응 시간 안에 97%의 높은 수율로 아디픽산의 주요 중간체인 뮤코네이트를 합성하였다. 생성된 뮤코네이트는 팔라듐 촉매를 이용한 수소화 반응 및 가수분해 반응을 통하여 성공적으로 나일론의 단량체인 고순도의 아디픽산으로 전환되었다.

셀룰로오스와 나일론 직물의 쑥 추출물에 대한 염색성과 항균성 (Dyeing and Antimicrobial Properties of Cellulose and Nylon Fabrics Treated with Artemisia Extracts)

  • 신승엽;정혜원
    • 한국의류학회지
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    • 제37권8호
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    • pp.1130-1138
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    • 2013
  • We examined dyeing properties using cotton, Tencel, general nylon 66 and hollow nylon 66 treated with aqueous and ethanol extracts without mordant. The antimicrobial properties of fabrics treated with Artemisia extracts against gram positive Staphylococcus aureus (S. aureus) and gram negative Klebsiella pneumonia (K. pneumonia) were also examined. The dying solution concentrations were determined from a calibration curve of the concentration and absorbance of Artemisia extracts. FTIR spectra confirmed that antimicrobial components and colorants (such as 1,8-cineol, thujone, caffeoylquinic acid and chlorophyll) were more present in ethanol extract than in aqueous extract. Nylons had higher $a^*$ and $b^*$, and lower $L^*$ values than cellulose fabrics dyed with aqueous solutions of Artemisia extracts; however, the dyed nylon fabrics were brown. Fabrics dyed with ethanol-extract added solutions were greener and had higher antimicrobial properties than those dyed with aqueous solutions; however, they faded and lost their antimicrobial properties after laundering. Fabrics regained their antimicrobial properties (especially against S. aureus) by the spraying of Artemisia ethanol extract; therefore, the application of Artemisia ethanol extract onto underwear is expected to relieve atopic dermatitis.

LPG 용기용 밸브패킹의 누설안전에 관한 수치적 연구 (Numerical Study on the Sealing Safety of a Valve Packing in a LPG Cylinder)

  • 김청균;김태환
    • 한국가스학회지
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    • 제11권1호
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    • pp.34-39
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    • 2007
  • 본 본문에서는 LPG 용기용 밸브의 개폐과정에서 발생하는 밸브패킹과 밸브시트의 상대접촉 마찰작용에 따른 밀봉성에 대한 FEM 해석결과를 제시하고 있다. 개폐용 밸브의 밀봉작용은 나일론-66으로 제조한 디스크 형상의 밸브패킹이 원형 파이프의 밸브시트 단면을 막아 LP 가스의 외부 송출을 차단하면서 완료된다. 밸브패킹은 밸브시트에 대하여 평면으로 접촉밀봉을 하는 경우와 원형홈의 둥근접촉 형상에 대한 밀봉 압착력을 확보하는 두 가지가 있다. FEM 해석 및 실험적 연구결과에 의하면, 밸브패킹을 사용하기 이전의 평면접촉 밀봉 작용력은 4.9 MPa로 높지만, 밸브를 사용한 이후의 원형홈 접촉 밀봉력은 4.4 MPa로 약간 낮게 나타났다. 그러나 이들 최대응력은 나일론 소재의 항복응력 83 MPa에 비하여 대단히 낮은 값이기 때문에 현재의 개폐밸브용 패킹은 과도하게 설계되었다 할 수 있다.

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나노 섬유를 혼합한 시멘트 페이스트의 미세구조와 강도에 대한 연구 (A Study about the Strength and Microstructure of Hardened Cement Pastes Including Nanofibers)

  • 응유옌 트리;김정중
    • 대한토목학회논문집
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    • 제40권2호
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    • pp.177-182
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    • 2020
  • 본 연구에서는 시멘트 페이스트에 혼합된 나노 섬유가 경화된 시멘트페이스트의 압축강도와 인장강도에 미치는 영향을 연구하였다. 2종류의 나노 섬유를 사용하였다. 나일론 66 나노 섬유와 카본 나노 튜브로 보강된 나일론 66 나노 섬유를 전기방사로 제작하여 시멘트 파우더에 각각 혼합하였다. 물-시멘트비 0.5의 시멘트 페이스트 시편을 제작하고 28일간 양생하였다. 실험 결과, 나노섬유의 혼합이 시멘트 페이스트 시편의 압축강도와 인장강도를 증가시킴을 확인하였다. 나노 섬유의 보강 매카니즘을 확인하기 위해 주사전자현미경(SEM) 분석, 전계방사 투과전자 현미경(FE-TEM) 분석 및 열 중량 분석(TGA)을 수행하여 나노섬유를 포함한 시멘트 페이스트의 미세 구조를 분석하였다.

전기방사된 나일론66 나노웹의 열적·기계적 특성에 전자선 조사가 미치는 영향 (The Effects of Electron Beam Irradiation on Thermal and Mechanical Properties of Electrospun Nylon 66 Nano-web)

  • 전준표;강효경;강필현
    • 방사선산업학회지
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    • 제5권1호
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    • pp.69-73
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    • 2011
  • Polyamide 66 (PA66) nanofibers with Triallyl cyanurate (TAC) were obtained by electrospinning of formic acid and chloroform solution. Electron beam irradiation of PA66 nanofiber with and without TAC was carried out over a range of absorbed doses (20~100 kGy) in nitrogen. The characterization of the irradiated PA66 nanofibers and PA66 nanofibers with TAC was done by scanning electron microscopy (SEM), nuclear magnetic resonance (NMR), thermogravimetric analysis (TGA) and universal testing machine (UTM). The results of the SEM image analysis confirmed that the morphology of PA66 nanofibers was not altered by electron beam. The amount of TAC in PA66 nanofiber with TAC was identified by $^1H-NMR$ analysis. The degradation temperature of PA66 nanofibers with TAC at an absorbed dose of 20~100 kGy was higher than the irradiated PA66 nanofiber without TAC. On the other hand, the decreasing rate of modulus of irradiated PA66 nanofibers with TAC was less than PA66 nanofibers.

키토산 전처리(前處理)가 면(綿), 견(絹), 나일론, 폴리에스테르의 코치닐염색(染色)에 미치는 효과(效果) (The Effect of Chitosan-Pretreatment on the Cochineal Dyeing of Cotton, Silk, Nylon, and Polyester Fabrics)

  • 전동원;김종준;김선화
    • 패션비즈니스
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    • 제7권4호
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    • pp.57-66
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    • 2003
  • Cochineal dyeing was applied to natural fiber fabrics, cotton and silk fabrics, and synthetic fiber fabrics, nylon and polyester fabrics. Chitosan-pretreatment was applied to the fabrics in order to investigate the effect of chitosan treatment on the dyeing behavior. The effect of chitosan treatment on the mordanting was also investigated by incorporating Cu-mordant on the chitosan-treated or chitosan-untreated fabrics during the dyeing process.

전기방사 나일론 66 섬유웹의 특성화 (Characterization of Electrospun Nylon 66 Fiberwebs)

  • Lee, Young-Soo;Park, Sung-Shin;Lee, Chung-Jung;Joo, Chang-Whan
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 봄 학술발표회 논문집
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    • pp.165-168
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    • 2003
  • Nylon was the first commercialized synthetic fiber. It is a polyamide, derived from a diamine and dicarboxylic acid. The nylon fiber has outstanding durability and excellent physical properties such as stiffness, wear and abrasion resistance, friction coefficient and chemical resistance. Due to these properties of nylon 66, nano-sized fibers are produced by electrospinning method in this study. During the past years the nylon 66 fibers have been prepared by conventional melt spining. (omitted)

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전기방사된 나일론 66 부직포의 특성 (Characterization of Nylon 66 Non-woven via Electrospinning)

  • Kim, Chi-Hun;Jung, Yoon-Ho;Kim, Hak-Yong;Ryu, Young-Jun;Lee, Douk-Rae;Park, Soo-Jin
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 가을 학술발표회 논문집
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    • pp.265-266
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    • 2003
  • The first developed engineering plastic and synthetic fiber, Nylon has been widely used because of its excellent properties. Recently, electrospinning has been gradually spotlighted as a different method of producing fibers, in which fibers of submicron can be consistently produced [1,2]. In this work, we have prepared nanofiber non-woven from Nylon 66 of which properties were investigated. The morphological properties of Nylon 66 non-woven was observed by SEM. (omitted)

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카본/나일론 복합재료의 냉각속도에 따른 기계적 특성변화 (Effect of Cooling Rate on Mechanical Properties of Carbon/Nylon66 Composites)

  • 홍순곤;변준형;황병선;강범수
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2001년도 춘계학술발표대회 논문집
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    • pp.122-125
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    • 2001
  • The objective of this research is to develop hybridized yarns for thermoplastic composites, and to examine tile effect of cooling rate on mechanical properties of the composites. The co-braided yarn utilizing carbon fibers as reinforcements and Nylon 66 fibers as matrix materials has been fabricated. Thermoplastic composites have been manufactured by the hot-press forming process. For the processing conditions, cooling rates of $-2.5^{\circ}C$/min and $-60^{\circ}C$/min have been considered. Three-point bending test and losipescu shear test were performed to investigate the effect of the cooling rate and the surface treatment of carbon fibers. SEM photographs were used to investigate the fracture surfaces of the tested samples. The cooling rate of $-60^{\circ}C$/min resulted in the higher strength and elastic modulus for bending and shear tests. The composites of the epoxy-sized carbon fibers showed the lowest strength due to the degradation of the sizing material during the thermoforming process.

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