• Title/Summary/Keyword: 나노 제어

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Change of Calcium Carbonate Crystal Size at steady state in CMSMPR(Continuous Mixed Suspension Mixed Produce Removal) Crystallizer (연속식결정화기 정상상태에서 탄산칼슘 결정크기 변화)

  • Han, Hyun Kak
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.7
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    • pp.714-719
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    • 2017
  • The controlled synthesis of inorganic materials with a specific size and morphology is an important factor in the development of new materials in many fields, such as nanoparticles, medicine, electronics, semiconductors, pharmaceutical sand cosmetics. Solution crystallization is one of the most widely used separation processes in the chemical and pharmaceutical industries. Calcium carbonate has attracted a great deal of attention in industry because of its numerous applications. The mean crystal size, crystal size distribution and morphology are important factors in the continuous crystallization process. In this study, the continuous crystallization of calcium carbonate by the calcium chloride process was investigated. The mean crystal size and crystal size distribution data were obtained by a particle size analyzer. The morphological imaging of the crystalswasper formed by SEM. Under steady state operation, the mean crystal size change was small, but increasing the input concentration and mixing rate increased the crystal size. In this operation, some aragonite was found, but the main crystal phase was calcite.

Controlling Structural and Electrical Properties of Pt Nanopowder-Dispersed SiO2 Film (Pt 나노분말이 분산된 SiO2 박막의 구조 및 전기적 특성 제어)

  • Lee, Jae Ho;Shin, In Joo;Lee, Sung Woo;Kim, Hyeong Cheol;Choi, Byung Joon
    • Journal of Powder Materials
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    • v.21 no.5
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    • pp.355-359
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    • 2014
  • Pt nanopowder-dispersed $SiO_2$ (SOP) films were prepared by RF co-sputtering method using Pt and $SiO_2$ targets in Ar atmosphere. The growth rate and Pt content in the film were controlled by means of manipulating the RF power of Pt target while that of $SiO_2$ was fixed. The roughness of the film was increased with increasing the power of Pt target, which was mainly due to the increment of the size and planar density of Pt nanopowder. It was revealed that SOP film formed at 10, 15, 20 W of Pt power contained 2.3, 2.7, and 3.0 nm of spherical Pt nanopowder, respectively. Electrical conductivity of SOP films was exponentially increased with increasing Pt power as one can expect. Interestingly, conductivity of SOP films from Hall effect measurement was greater than that from DC I-V measurement, which was explained by the significant increase of electron density.

Design of Extendable BCD-EXCESS 3 Code Convertor Using Quantum-Dot Cellular Automata (확장성을 고려한 QCA BCD-3초과 코드 변환기 설계)

  • You, Young-won;Jeon, Jun-cheol
    • Journal of Advanced Navigation Technology
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    • v.20 no.1
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    • pp.65-71
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    • 2016
  • Quantum-dot cellular automata (QCA) consists of nano-scale cells and demands very low power consumption so that it is one of the alternative technologies that can overcome the limits of scaling CMOS technologies. Typical BCD-EXCESS 3 code converters using QCA have not considered the scalability so that the architectures are not suitable for a large scale circuit design. Thus, we design a BCD-EXCESS 3 code converter with scalability using QCADesigner and verify the effectiveness by simulation. Our structure have reduced 32 gates and 7% of garbage space rate compare with typical URG BCD-EXCESS 3 code converter. Also, 1 clock is only needed for circuit expansion of our structure though typical QCA BCD-EXCESS 3 code converter demands 7 clocks.

Application and therapeutic effects of sickle red blood cells for targeted cancer therapy (표적항암치료를 위한 겸형적혈구의 응용 및 치료 효과)

  • Choe, Se-woon
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.20 no.12
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    • pp.2395-2400
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    • 2016
  • Conventional drug carriers such as liposomes, nanoparticles, polymer micelles, polymeric conjugate and lipid microemulsion for cancer chemotherapy shield normal tissues from toxic drugs to treat cancer cells in tumors. However, inaccurate tumor targeting uncontrolled drug release from the carriers and unwanted accumulation in healthy sites can limit treatment efficacy with current conventional drug carriers with insufficient concentrations of drugs in the tumors and unexpected side effects as a result. Sickle red blood cells show natural tumor preferential accumulation without any manipulation due to the adhesive interaction between molecular receptors on the membrane surface and counter-receptor on endothelial cells. In addition, structural changes of microvascular in tumor sites enhances polymerization of sickle red blood cells. In this research, we examined the use of sickle red blood cells as a new drug carrier with novel tumor targeting and controlled release properties to quantify its therapeutic effects.

The Study on the Graded Index Antireflection(AR) Coating (구배형 굴절률 반사방지막 연구)

  • Kim, Chang-Bong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.5
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    • pp.565-570
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    • 2017
  • The various techniques proposed previously to obtain a good antireflection(AR) coating induce a scattering of incident light by nanoparticles or control the refractive index by using different materials. This paper compares a suggested graded index profile with the quintic index profile previously suggested for producing an index profile that gives good performance from an AR coating. We assume the structure of the AR coating has three, six, and nine layers with 180 nm total thickness. The wavelength of incident light ranges from 300 nm to 1100 nm. We use the transfer matrix theory for a single layer to obtain the reflectivity of three, six, and nine layers. The reflectivity of two different index profiles with three, six, and nine layers is compared. As a result, the suggested graded index profile shows lower reflectivity than the quintic index profile with three layers, especially in the wavelength range from about 600 nm to 1100 nm. Therefore, we expect that these results can be applied to optical devices and filters in the range from visible(red) to near infrared.

Hierarchical Porous 3D gel of the Co3O4/graphene with Enhanced Catalytic Performance for Green Catalysis (녹색 촉매반응을 위한 코발트 옥사이드/그래핀의 계층적 다공성 3D 젤)

  • Jeong, Jae-Min;Jang, Sukhyeun;Kim, Yunsu;Kim, Hyun Bin;Kim, Do Hyun
    • Korean Chemical Engineering Research
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    • v.56 no.3
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    • pp.404-409
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    • 2018
  • The integration of organic and inorganic building blocks into hierarchical porous architectures makes potentially desirable catalytic material in many catalytic applications due to their combination of dissimilar components and well-constructed reactant transport path. In this study, we prepared the hierarchical porous $Co_3O_4@graphene$ 3D gel by hydrothermal method to achieve high catalytic performance in PET glycolysis reaction. Obtained $Co_3O_4@graphene$ 3D gel consisted of interconnected networks of $Co_3O_4$ and graphene sheets, providing large number of accessible active sites for efficient catalytic reaction. These structural merits from synergistic effect of $Co_3O_4$ and graphene gave a high performance in the PET degradation reaction giving high conversion yield of BHET, fast degradation rate of PET, and remarkable stability.

Design and Analysis of a Receiver-Transmitter Optical System for a Displacement-Measuring Laser Interferometer (위치변위 레이저 간섭계용 송수신 광학계의 설계 및 분석)

  • Yun, Seok-Jae;Rim, Cheon-Seog
    • Korean Journal of Optics and Photonics
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    • v.28 no.2
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    • pp.75-82
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    • 2017
  • We present a new type of receiver-transmitter optical system that can be adapted to the sensor head of a displacement-measuring interferometer. The interferometer is utilized to control positioning error and repetition accuracy of a wafer, down to the order of 1 nm, in a semiconductor manufacturing process. Currently, according to the tendency of scale-up of wafers, an interferometer is demanded to measure a wider range of displacement. To solve this technical problem, we suggest a new type of receiver-transmitter optical system consisting of a GRIN lens-Collimating lens-Afocal lens system, compared to conventional receiver-transmitter using a single collimating lens. By adapting this new technological optical structure, we can improve coupling efficiency up to about 100 times that of a single conventional collimating lens.

Dispersion and Shape Control on Nanoparticles of Gd2O3:Eu3+ Red Phosphor Prepared by Template Method (주형법으로 제조된 Gd2O3:Eu3+ 적색 형광체의 나노입자 분산 및 형상제어)

  • Park, Jeong Min;Ban, Se Min;Jung, Kyeong-Youl;Choi, Byung-Ki;Kang, Kwang-Jung;Kim, Dae-Sung
    • Korean Journal of Materials Research
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    • v.27 no.10
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    • pp.534-543
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    • 2017
  • $Gd_2O_3:Eu^{3+}$ red phosphors were prepared by template method from crystalline cellulose impregnated by metal salt. The crystallite size and photoluminescence(PL) property of $Gd_2O_3:Eu^{3+}$ red phosphors were controlled by varying the calcination temperature and $Eu^{3+}$ mol ratio. The nano dispersion of $Gd_2O_3:Eu^{3+}$ was also conducted with a bead mill wet process. Dependent on the time of bead milling, $Gd_2O_3:Eu^{3+}$ nanosol of around 100 nm (median particle size : $D_{50}$) was produced. As the bead milling process proceeded, the luminescent efficiency decreased due to the low crystallinity of the $Gd_2O_3:Eu^{3+}$ nanoparticles. In spite of the low PL property of $Gd_2O_3:Eu^{3+}$ nanosol, it was observed that the photoluminescent property was recovered after re-calcination. In addition, in the dispersed nanosol treated at $85^{\circ}C$, a self assembly phenomenon between particles appeared, and the particles changed from spherical to rod-shaped. These results indicate that particle growth occurs due to mutual assembly of $Gd(OH)_3$ particles, which is the hydration of $Gd_2O_3$ particles, in aqueous solvent at $85^{\circ}C$.

Development of 80kW Bi-directional Hybrid-SiC Boost-Buck Converter using Droop Control in DC Nano-grid (DC 나노그리드에서 Droop제어를 적용한 80kW급 양방향 하이브리드-SiC 부스트-벅 컨버터 개발)

  • Kim, Yeon-Woo;Kwon, Min-Ho;Park, Sung-Youl;Kim, Min-Kook;Yang, Dae-Ki;Choi, Se-Wan;Oh, Seong-Jin
    • The Transactions of the Korean Institute of Power Electronics
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    • v.22 no.4
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    • pp.360-368
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    • 2017
  • This paper proposes the 80-kW high-efficiency bidirectional hybrid SiC boost/buck converter using droop control for DC nano-grid. The proposed converter consists of four 20-kW modules to achieve fault tolerance, ease of thermal management, and reduced component stress. Each module is constructed as a cascaded structure of the two basic bi-directional converters, namely, interleaved boost and buck converters. A six-pack hybrid SiC intelligent power module (IPM) suitable for the proposed cascaded structure is adopted for high-efficiency and compactness. The proposed converter with hybrid switching method reduces the switching loss by minimizing switching of insulated gate bipolar transistor (IGBT). Each module control achieves smooth transfer from buck to boost operation and vice versa, since current controller switchover is not necessary. Furthermore, the proposed parallel control using DC droop with secondary control, enhances the current sharing accuracy while well regulating the DC bus voltage. A 20-kW prototype of the proposed converter has been developed and verified with experiments and indicates a 99.3% maximum efficiency and 98.8% rated efficiency.

Surface Modification of Materials in KOMAC by Accelerator Technology (가속기 기술을 이용한 재료에의 표면처리기술 응용)

  • Lee, Jae-Sang
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.89-89
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    • 2017
  • 가속기 기술을 이용한 재료에의 표면처리기술은 일정에너지를 가지는 이온이 재료표면에 충돌함으로서, 스퍼터링, 이온주입, 미세구조 변화 등의 현상을 이용하여 재료표면의 특성을 변화시켜 기계적, 화학적, 광학적, 전기적 특성 등을 변화시키는 표면개질기술에 활용되어져 왔다. 이러한 이온빔 표면처리기술은 이온의 종류나 시편의 제한 없이 치밀한 원자혼합물을 형성하고, 계면형성이 없고, 또한 저온공정이 가능하므로, 정밀도가 요구되는 부품의 내마모성과 내부식성 등을 포함한 기본적인 표면특성 뿐만 아니라 전기전도도, 친소수특성, 내광성 등 표면에 관계된 특성을 개선시키는 역할을 하며, 이온빔 믹싱, 이온빔 스퍼터링, 이온빔 전처리 후 코팅 등의 복합공정을 통해 보다 개선된 표면특성을 가지는 박막제조공정에 적용될 수 있다. 본 발표에서는 지난 10년간 가속기기술을 응용한 이온빔 장치기술 개발현황을 발표하고, 이러한 장치를 활용하여 이온빔 표면처리기술 사례인 내광성/내스크래치성 향상 고분자, 정전기방지, 초친수 표면처리, 기체투과도제어, 자외선차단 필름, 고속에칭기술 등의 기술개발 현황을 발표하고자 한다. 한국원자력연구원 양성자가속기연구센터에서는 수백 keV급의 이온빔 표면처리 장치 이외에도 100MeV 선형 양성자가속기를 이용하여 2013년부터 다양한 분야의 양성자빔/이온빔 이용자들에게 이온빔 장치와 20MeV와 100MeV 이용시설에서 양성자빔/이온빔 서비스를 제공하고 있다. 2016년 기준 이용자수는 양성자가속기 392명, 이온빔장치 279명이며, 이용자 수행과제는 양성자가속기, 이온빔장치 각각 130여개 과제가 수행되었다. 이러한 이용자들의 빔이용연구를 통해 20여편의 논문투고, 10여편의 특허출원의 성과를 얻었으며, 나노분야, 생명공학분야 등의 다양한 분야에서의 빔이용기술을 통해 활발한 연구가 이루어질 것으로 예상된다.

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