• Proceedings of the Membrane Society of Korea Conference
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• 1994.10a
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• pp.28-29
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• 1994

일반적으로 polyimide는 열적, 화학적으로 안정하며 좋은 기계적 성질을 갖고 있고 기체투과 특성이 뛰어나므로 훌륭한 막 소재로 알려져 있다. 그러나, 높은 선택도를 나타내면 투과도가 떨어지고 투과도가 높으면 선택도가 떨어지는 일반적인 고분자 막이 보이는 경향을 따르므로, 본 연구에서는 이례적으로 높은 산소 투과도를 보이는 6FDA-pTeMPD polyimide와 높은 선택도를 나타내는 6FDA-mPDA polyimide을 공중합 시킴으로써 각각의 homopolyimide로서는 얻을수 없는 개선된 기체 투과도와 선택도를 얻을 수 있으리라 예상하여 연구를 하였다. 조성과 자유용적, 조성과 Tg관계, 조성과 투과도 및 선택도를 조사하여 공중합 하였을때 고분자의 화학 구조와 미시적 구조간의 관계를 규명하여 분자 설계로 적절한 막 특성을 갖는 공중합 막을 합성할 수 있는 정보를 확립하였다.

• Membrane Journal
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• v.26 no.3
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• pp.212-219
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• 2016

The alumina hollow fiber membranes were prepared by spinning and sintering a polymer solution containing suspended alumina powders. For determine pore structure of hollow fiber membranes formed by different solvent-nonsolvent interaction rate, dimethylsulfoxide (DMSO), dimethylacetamide (DMAc), triethylphosphite (TEP) were prepared in dope solution by solvent, polyethersulfone (PESf) and polyvinylpyrrolidone (PVP) were used as a polymer binder and additive. The pore structure of hollow fiber membranes was characterized using scanning electron microscope (SEM). The alumina hollow fiber membranes prepared by DMSO, DMAc were had the asymmetric structure mixed sponge-like and finger-like morphology, while TEP solvent were had single sponge-like structure. The prepared hollow fiber membranes were analyzed gas permeation and mechanical strength experiment also. The hollow fiber membrane having single sponge-like structure was had high gas permeation performance. On the contrary to this, more finger-like morphology was less gas permeation performance.

• Membrane Journal
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• v.24 no.5
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• pp.341-349
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• 2014

Molecular dynamics (MD) computer simulation is a very useful tool to calculate the trajectory and velocity of particles (generally, atoms), and thus to analyze the various structures and kinetic properties of atoms and molecules. For gas separation membranes, MD has been widely used for structure analysis of polymers such as free volume analysis and conformation search, and for the study of gas transport behavior such as permeability and diffusivity. In this paper, general methodology how to apply MD on gas separation membranes will be described and various related researches will be introduced.

• Journal of the Korean Society for Aviation and Aeronautics
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• v.25 no.3
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• pp.35-43
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• 2017

Research for solar-powered high altitude long endurance(HALE) UAV was conducted by Korea Aerospace Research Institute(KARI), and the EAV-3 with 19.5m wing span was developed. For HALE flight, aircraft should be lightly designed. Especially, airframe structure that accounts for a large portion of the total weight of aircraft should be lightweight. In this paper, development process of airframe structure for solar-powered HALE UAV, EAV-3, is described briefly. Domestic developed T-800 grade CFRP(Carbon Fiber Reinforced Plastic) composite material with high modulus and strength was used to design main load carrying structures. Flightloads analysis that takes into account large structural deformation was carried out. Stress and flutter analyses for airframe structure sizing were conducted. Static strength test for main wing and aircraft ground vibration test were conducted successfully and structural integrity was secured.

• Journal of the Korean Society of Propulsion Engineers
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• v.23 no.4
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• pp.70-80
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• 2019

Combustion tests using six bi-swirl coaxial injectors with different shapes and recess lengths were performed in a model combustion chamber capable of flame visualization. By utilizing gaseous methane and gaseous oxygen instead of actual propellants, the effects of injector design and experimental conditions on the flame structure and combustion stability were analyzed. It was found that not only the experimental conditions but also the injector geometry such as the recess length and orifice diameter had a considerable influence on the combustion stability. In addition, it was confirmed that the heat release pattern changed with the occurrence of combustion instability.

• Journal of the Korean Society of Propulsion Engineers
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• v.23 no.1
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• pp.1-8
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• 2019

To analyze the dynamic behavior and the structure of the gaseous methane-gaseous oxygen diffusion flame formed by a swirl/shear-coaxial injector, combustion experiments were carried out under different propellant injection conditions. As a result, the OH radical emission intensity of the diffusion flame visualized through chemiluminescence was observed to increase as the propellant mass flow and the momentum flux ratio increased. And flames with swirl showed a more high radical emission intensity than those without swirl.

• Journal of the Korean Society of Propulsion Engineers
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• v.23 no.6
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• pp.28-38
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• 2019

To investigate the relation between flame structure and combustion dynamic characteristics in bi-swirl coaxial injectors for a liquid rocket engine, combustion experiments were performed using gaseous methane and gaseous oxygen. CH* radicals and pressure fluctuations were simultaneously measured by changing the injector geometries such as recess length/orifice diameter and the flow conditions such as equivalence ratio/oxidizer mass flow rate. As the injector geometries affected the velocities and mixing of the propellants, the change in flame structures was observed. From a result of the frequency analysis, it was confirmed that combustion dynamic characteristics varied according to the injector geometry/flow condition and combustion instabilities could occur under specific recess length/flow conditions.

• Journal of the Korean Chemical Society
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• v.40 no.6
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• pp.401-408
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• 1996

In general, the high temperature superconductors have two-dimensional anisotropic structures. It is important to investigate the dependence of the critical temperature on the dimensions of the electron's motion. The equation of state for electron gas is deduced which describes the electron's motion in superconductors using the kinetic theory of gas. And the critical temperatures of three, two, and one dimensional gases were calculated. According to these equations, restricting the dimension of the electron's motion induces the increase of the critical temperatures. This implies the possibility that the multi-critical temperature of some superconductors is caused by the change of the dimension related to the pathways of the electron.

• 한국신재생에너지학회:학술대회논문집
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• 2006.11a
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• pp.403-406
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• 2006

본 연구에서는 양극의 two-phase simulation 모델을 확립하고 GDL 물성과 작동조건이 전지성능에 미치는 영향에 대해 시행하였다. 모델로는 Multi-phase $mixture(M^2)$ 모델을 사용하였는데 이 모델은 각 상의 balance식을 하나의 mixture-phase식으로 통합하여 수학적 계산이 용이할 뿐만 아니라 실제 전지 성능에 매우 근사하여 신뢰성성도 확보할 수 있었다. 최적의 GDL 구조와 작동조건을 규명하기 위해 기체투과도, 접촉각, 기공도, 기체 공급가스 차이에 따른 전지 성능 분석을 시행하였는데 그 결과 모든 파라미터들이 증가할수록 비례적으로 전지 성능이 증가하였다. 기체 공급가스>기공도>>접촉각>기체투과도 순으로 전지에 미치는 영향이 큰 것으로 나타났다.

• Proceedings of the Membrane Society of Korea Conference
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• 1992.10a
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• pp.5-6
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• 1992

무기막은 고분자 계통의 유기막과는 달리 200$\circ$C 이상의 고온에서도 높은 기체 투과도와 구조적 안정성을 보인다. 따라서 무기막을 고온의 촉매 반응에 이용하면 생성물 중 일부를 선택적으로 분리시키므로써 열역학적으로 예측할 수 있는 값 이상의 높은 전환율을 얻을 수 있으며, 또한 반응물 중 일부를 막을 통해 주입하면 반응의 정도를 조절함으로써 원하는 생성물의 수율을 높일 수 있게 된다. 그러나, 현재 실험실에서 많이 연구되고 있는 다공성 유리 또는 다공성 알루미나와 같은 무기막들은 기체 투과도는 높은 반면에 기체 분리가 Knudsen diffusion에 의해 이루어지기 때문에 분리선택도가 낮은 단점이 있다.