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Effect of DC bias on structure of hydrogenated amorphous silicon and microcrystalline silicon

  • 이윤정;주성재;임승현;윤의준
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.84-84
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    • 2000
  • 수소화된 비정질 실리콘(a-Si:H)과 미세결정질 실리콘 ($\mu$c-Si:H)은 저온.건식 공정인 PECVD로 값싼 유리 기판을 사용하여 넓은 면적에 증착이 가능하다는 큰 장점으로 인해 광전소자(photovoltaic device)와 박막 트랜지스터(TFTs)등에 폭넓게 응용되어 왔으며 최근에는 nm 크기의 실리콘 결정(nc-Si)에서 가시광선 영역의 발광 현상이 발견됨에 따라 광소자로서의 특성을 제어하기 위해서는 성장 조건과 공정 변수에 따른 구조 변화에 대한 연구가 선행되어야 한다. 본 연구에서는 UHV-ECR-PECVD 법을 이용하여 H2로 희석된 SiH4로부터 a-Si:H과 $\mu$c-Si:H를 증착하였다. 그림 1은 SiH4 20sccm/H2 50sccm/25$0^{\circ}C$에서 기판의 DC bias를 변화시키면서 박막을 증착시킬 때 나타나는 박막의 구조 변화를 raman spectrum의 To phonon peak의 위치와 반가폭의 변화로 나타낸 것이다. 비정질 실리콘 박막은 DC bias를 증가시킴에 따라 무질서도가 증가하다가 어떤 critical DC bias에서 최대치를 이룬후 다시 질서도가 증가한다. 이온의 충격력에 의해 박막내에 응력이 축적되면 박막의 에너지 상태가 높아지고 이 축적된 응력이 ordering에 대한 에너지 장벽을 넘을 수 있을 만큼 커지게 되면 응력이 풀리면서 ordering이 가능해지는 것으로 생각된다. 그림 2는 수소 결합 형태의 변화이다. 박막의 무질서도가 증가할 경우 알려진 바와 같이 2000cm-1근처의 peak은 감소하고 2100cm-1 부근이 peak이 증가하는 현상을 보였다. 본 논문에서는 여러 공정 변수, 특히 DC bias에 따르는 박막의 구조 변화와 다른 성장 조건(온도, 유량비)이 critical DC bias나 결정화, 결정성 등에 미치는 영향에 대한 분석결과를 보고하고자 한다.등을 이용하여 광학적 밴드갭, 광흡수 계수, Tauc Plot, 그리고 파장대별 빛의 투과도의 변화를 분석하였으며 각 변수가 변화함에 따라 광학적 밴드갭의 변화를 정량적으로 조사함으로써 분자결합상태와 밴드갭과 광 흡수 계수간의상관관계를 규명하였고, 각 변수에 따른 표면의 조도를 확인하였다. 비정질 Si1-xCx 박막을 증착하여 특성을 분석한 결과 성장된 박막의 성장률은 Carbonfid의 증가에 따라 다른 성장특성을 보였고, Silcne(SiH4) 가스량의 감소와 함께 박막의 성장률이 둔화됨을 볼 수 있다. 또한 Silane 가스량이 적어지는 영역에서는 가스량의 감소에 의해 성장속도가 둔화됨을 볼 수 있다. 또한 Silane 가스량이 적어지는 영역에서는 가스량의 감소에 의해 성장속도가 줄어들어 성장률이 Silane가스량에 의해 지배됨을 볼 수 있다. UV-VIS spectrophotometer에 의한 비정질 SiC 박막의 투과도와 파장과의 관계에 있어 유리를 기판으로 사용했으므로 유리의투과도를 감안했으며, 유리에 대한 상대적인 비율 관계로 투과도를 나타냈었다. 또한 비저질 SiC 박막의 흡수계수는 Ellipsometry에 의해 측정된 Δ과 Ψ값을 이용하여 시뮬레이션한 결과로 비정질 SiC 박막의 두께를 이용하여 구하였다. 또한 Tauc Plot을 통해 박막의 optical band gap을 2.6~3.7eV로 조절할 수 있었다. 20$0^{\circ}C$이상으로 증가시켜도 광투과율은 큰 변화를 나타내지 않았다.부터 전분-지질복합제의 형성 촉진이 시사되었다.이것으로 인하여 호화억제에 의한 노화 방지효과가 기대되었지만 실제로 빵의 노화는 현저히 진행되었다. 이것은 quinua 대체량 증가에 따른 반죽의 안정성이 저하되어 버린 것으로 생각되어진다. 더욱이 lipase를 첨가하면 반죽이 분화하는 경향이 보여졌지만 첨가량 75ppm에 있어서 상당히 비용적의 증대가 보였다. 이것은 lipase의 가수분해에 의해

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단일벽 탄소나노튜브의 직경 분포에 미치는 합성 템플레이트 및 공정변수의 영향

  • Gwak, Eun-Hye;Yun, Gyeong-Byeong;Jeong, Gu-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.250-250
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    • 2013
  • 단일벽 탄소나노튜브(Single-walled nanotubes, SWNTs)는 나노스케일의 크기와 우수한 물성으로 인하여, 전자, 에너지, 바이오 분야로의 응용이 기대되고 있다. 특히 SWNTs의 직경을 제어하게 되면 튜브의 전도성 제어가 훨씬 수월하게 되어, 차세대 나노전자소자의 실현을 앞당길 수 있으며 이러한 이유로 많은 연구들이 현재 행해지고 있다. SWNTs의 직경제어 합성을 위해서는 현재 열화학기상증착법(Thermal chemical vapor deposition; TCVD)이 가장 일반적으로 이용되고 있으며, 합성 촉매와 합성되는 튜브의 직경과의 크기 연관성이 알려진 후로는, 촉매의 크기를 제어하여 SWNTs의 직경을 제어하고자 하는 연구들이 활발하게 보고되고 있다. 특히, 촉매 나노입자의 직경이 1~2 nm 이하로 감소될 경우, SWNTs의 직경 분포가 어떻게 변화할 것인지가 최근 가장 중요한 관심사로 남아 있으나, 이러한 크기의 금속입자는 나노입자의 융점저하 현상이 발현되는 영역이므로, SWNTs의 합성온도 영역에서 촉매 금속입자는 반액체(Semi-liquid) 상태로 존재할 것으로 추측하고 있다. 본 연구에서는 고온의 SWNTs 합성환경에서 금속나노촉매의 유동성을 제한하기 위하여 나노사이즈의 기공이 규칙적으로 정렬된 다공성 물질인 제올라이트를 촉매담지체로 이용하였고, 이 때 다양한 합성변수가 SWNTs의 직경에 미치는 영향을 살펴보고자 하였다. SWNTs의 합성을 위해 실리콘 산화막 기판 위에 제올라이트를 도포한 후, 합성 촉매로서 전자빔증발법을 통하여 수 ${\AA}$에서 수 nm 두께의 철 박막을 증착하였다. 합성은 메탄을 원료가스로 하여 TCVD법으로 실시하였다. 주요변수로는 제올라이트 종류, 증착하는 철 박막의 두께, 합성온도를 설정하였으며, 이에 따라 합성된 SWNTs의 합성수율 및 직경분포의 변화를 체계적으로 살펴보았다. SWNTs의 전체적인 합성수율의 변화는 SEM 관찰결과를 이용하였으며, SWNTs의 직경은 AFM 관찰 및 Raman 스펙트럼의 분석에서 도출하였다. 실험결과, 제올라이트 종류에 따라서는 명확한 튜브직경 분포의 변화 없이 비교적 좁은 직경분포를 갖는 SWNTs가 합성되었으며, 합성온도가 $850^{\circ}C$ 이하로 감소되면 합성수율이 현저히 감소되는 것을 알 수 있었다. 촉매박막의 두께가 1 nm 이상인 경우에서는 직경 5 nm 전후의 나노입자가 형성되었으며, 이때 SWNTs의 합성수율은 높았으나 다양한 직경의 튜브가 합성이 된 것을 확인할 수 있었다. 반면, 촉매입자의 크기가 2 nm 이하에서는 합성수율은 다소 저하되었으나, SWNTs의 직경분포의 폭이 상대적으로 훨씬 좁아지는 것을 알 수 있었다. 추후, 극미세 촉매와 저온합성 환경에서의 합성수율 향상을 위한 합성공정의 개량이 지속적으로 요구된다.

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Effects of Wasabi (Wasabia japonica Matsum) on the Physicochemical Characteristics of Baechu Kimchi during Fermentation (고추냉이가 배추김치의 발효 중 이화학적 특성에 미치는 영향)

  • Park, Jung-Eun;Jang, Myung-Sook
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.36 no.9
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    • pp.1219-1224
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    • 2007
  • In this study, we explored the application of Wasabi addition to baechu kimchi with regard to quality improvement, by reviewing the optimum Wasabi level and its effects on the product physicochemical characteristics during fermentation. The final weight percentages of Wasabi in the baechu kimchi were adjusted to 0, 2, 3, 4, and 5% per weight of baechu, respectively, and the samples were fermented for 35 days at $10^{\circ}C$. Following fermentation, the treatments over 3% Wasabi contained the highest pH and lowest total acidity values. Total vitamin C and reducing sugar content increased initially, up to certain fermentation times depending on the level of Wasabi contents within the treatments over 3% Wasabi, and decreased afterwards. The water soluble pectin content increased as the fermentation period increased; however, it decreased with increasing levels of Wasabi. In conclusion, the optimum levels of added Wasabi in the baechu kimchi were 3% and 5% per weight of baechu, to have a fermentation-retarding effect on the product.

Solubilization of Arabinogalactan by Extrusion from Portulaca oleracea L. and Its In Vitro Antioxidant Activity (마치현 아라비노갈락탄의 압출 수용화와 항산화 특성)

  • Choi, Ae-Jin;Jee, Ho-Kyun;Ko, Bo Sung;Kim, Yangha;Lee, Soo-Jeong;Kim, Chul-Jin;Cho, Yong-Jin;Kim, Chong-Tai
    • Food Engineering Progress
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    • v.13 no.3
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    • pp.169-175
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    • 2009
  • Water soluble polysaccharides (WSP) and arabinogalactan of Portulaca oleracea L. (POL) were increased after extrusion and commercial cellulase treatment. Arabinose and galactose content increased more about 1.5 times than those of raw POL, and rhamnose also increased about 2.6 times in WSP. High molecular weight fraction (I) of POL depending on extrusion condition including Ext I, Ext II and Ext III degraded into low molecular weight fraction (II) about 37, 29, and 26%, respectively, ranged from 67,000-69,000 Da of molecular weight. Especially, the molecular weight and composition of WSP with extruded, were increased from 9 to 13% in low molecular weight fraction, compared to those of raw POL. Solubilization and degradation of polysaccharides were a directly propotional to specific mechanical energy in POL extrusion. WSP obtained by extrusion at Ext I and Ext II were found to be effective antioxidants in different in vitro assays with regards to 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical scavenging activity and Trolox equivalent antioxidant capacity (TEAC). However, these results suggest that WSP obtained using extrusion and subsequent enzymatic treatment may be an effective method to produce arabinogalactan from POL and be used as a functional food ingredients.

Analysis of the Context of Inclusion and Awareness of Classical Literature Materials in Literature - With a Focus on High School Literature Textbooks (고전문학 제재의 수록 맥락과 교육적 인식의 탐색 -고등학교 문학 교과서를 대상으로-)

  • Choi, Hong-won
    • Journal of Korean Classical Literature and Education
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    • no.35
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    • pp.5-46
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    • 2017
  • This study aims to investigate the context of materials in literature textbooks and the awareness about the educational value of classical literature, as part of an interest in literature education phenomena. This study accepts the premise that textbooks affect the practice of classical literature education and, in particular, materials in textbooks are chosen according to the intentions, demands, and perspectives of education in specific social conditions. I divided the educational value of classical literature into two categories, classical and literary value, and investigated the actual conditions and context of materials of literature textbooks based on the 2009 revised curriculum and the 2011 revised curriculum. Classical literature is generally alienated and excluded; contemporary literature materials are mostly included and organized in the domains of 'the role of literature', 'reception and production of literature' and 'literature and life.' In addition, the tendency to heighten classical value and diminish literary value is deepening. In order to solve the problem that classical literature is only included as the product of the past, changes must be made not just to the curriculum, which are external changes, but to the awareness of the essence of classical literature, which are internal changes. Above all, generality as 'literature' and the sense of distance about space and time as 'classic' should be connected to various relationships which respond to problematic situations and the demands of learners. Based on the relationships, we can expect a rich diversity of contexts and aspects of included classical literature. In addition, an extension of the width and scope of included classical literature is anticipated. The reduction of workload, the advent of the concept of capability and the dissolution of traditional literature concepts are the changes of external environment, which is continuously requiring renewed investigation into classical literature beyond simple appropriateness.

A Study on Disposal Diagnosis Algorithm of PV Modules Considering Performance Degradation Rate (태양광모듈의 성능저하율을 고려한 폐기진단 알고리즘에 관한 연구)

  • Park, Ji-Hyun;Lee, Hu-Dong;Tae, Dong-Hyun;Ferreira, Marito;Rho, Dae-Seok
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.10
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    • pp.493-502
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    • 2019
  • Recently, the installation of renewable energy including PV systems in distribution systems has increased energetically to cope with climate change and energy shortages according to the government's policy of renewable energy 3020. On the other hand, the electrical performance and lifespan of PV modules installed outdoors can be decreased considerably due to a range of deterioration phenomena depending on the ambient environmental factors. To overcome these problems, replacement of degraded PV modules with new ones is increased before the lifespan guaranteed by the makers of PV modules. Therefore, this paper proposes a disposal diagnosis algorithm to evaluate the time interval of the optimal replacement for PV modules according to performance degradation rate of PV modules. In addition, this study modeled an economic evaluation, which is composed of the cost and benefit of PV systems. From the simulation results based on the proposed modeling and algorithm to consider the performance degradation rate specifically, the replacement approach was found to have the best B/C ratio in 10th year with a 3[%] degradation rate and the disposal diagnosis algorithm of PV modules are useful and practical tools for economic evaluations of the replacement of PV modules.

A Study on Learner Variables Influencing State Curiosity and State Anxiety in Confronting Scientific Task Situation (과학 문제 대면 상황에서 상태호기심 및 상태불안 유발에 영향을 미치는 학습자 변인에 대한 연구)

  • Kang, Jihoon;Kim, Jina
    • Journal of Korean Elementary Science Education
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    • v.40 no.3
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    • pp.343-365
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    • 2021
  • The purpose of this study was to clarify the effect of learner variables on triggering state curiosity and state anxiety in confronting scientific task situation for fifth to sixth grades of elementary school. Science curiosity, interest, need for cognition, science self-concept, science anxiety, prior knowledge, and perceived difficulty were selected as learner variables that are expected to affect state curiosity and state anxiety. As a result of this study, the variables that had a significant influence on evoking state curiosity in confronting scientific task situation were in the order of interest, need for cognition, science curiosity, and prior knowledge, and all of these variables had a positive effect. In addition, the variables that significantly affect on evoking state anxiety in confronting scientific task situation were in the order of science anxiety, perceived difficulty, need for cognition, science self-concept, and prior knowledge. Of these, only prior knowledge had a negative effect on evoking state anxiety, and the other variables had a positive effect. The results of this study are expected to broaden the comprehension of students' emotional states in science education, and provide a theoretical foundation for the studies of state curiosity and state anxiety in science learning.

A Study on Detection and Monitoring in land creeping area by Using the UAV (무인기를 활용한 산지 땅밀림 피해지점 탐지 및 모니터링 방안 연구)

  • Seo, Jun-Pyo;Woo, Choong-Shik;Lee, Chang-Woo;Kim, Dong-Yeob
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.11
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    • pp.481-487
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    • 2018
  • This paper proposes a method to detect and monitor the land creeping area using a UAV to analyze the damaged area efficiently. Using a UAV, it was possible to secure the safety of the investigators before the field survey and effectively utilize it to establish an investigation plan because an orthophoto can be used to detect and scale the cracks in a land creeping area. In addition, it was possible to analyze the scale of the crack quantitatively by extracting the topographic information from the orthophoto. The study sites were found to have a total crack area of 1.01 ha, a length of 1.07 km, an average width of 10 m, and a step distance of 1 to 10 m. Periodic UAV measurements can be used to detect displacements on the land creeping area and monitor the direction and scale of crack spread. Therefore, it is expected to be used effectively during recovery planning. Applying the UAV to the land creeping area resulted in the qualitative and quantitative results quickly and easily in dangerous mountainous watersheds. Therefore, it is expected that it will contribute to the development of related industries because of the high availability of a UAV in forest soil sediment disasters, such as landslides, debris flow, and land creeping area.

The Study on the Fire Monitoring Dystem for Full-scale Surveillance and Video Tracking (전방위 감시와 영상추적이 가능한 화재감시시스템에 관한 연구)

  • Baek, Dong-hyun
    • Fire Science and Engineering
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    • v.32 no.6
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    • pp.40-45
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    • 2018
  • The omnidirectional surveillance camera uses the object detection algorithm to level the object by unit so that broadband surveillance can be performed using a fisheye lens and then, it was a field experiment with a system composed of an omnidirectional surveillance camera and a tracking (PTZ) camera. The omnidirectional surveillance camera accurately detects the moving object, displays the squarely, and tracks it in close cooperation with the tracking camera. In the field test of flame detection and temperature of the sensing camera, when the flame is detected during the auto scan, the detection camera stops and the temperature is displayed by moving the corresponding spot part to the central part of the screen. It is also possible to measure the distance of the flame from the distance of 1.5 km, which exceeds the standard of calorific value of 1 km 2,340 kcal. In the performance test of detecting the flame along the distance, it is possible to be 1.5 km in width exceeding $56cm{\times}90cm$ at a distance of 1km, and so it is also adaptable to forest fire. The system is expected to be very useful for safety such as prevention of intrinsic or surrounding fire and intrusion monitoring if it is installed in a petroleum gas storage facility or a storing place for oil in the future.

The Study on the Construction Criteria and Dujabee Technique of the Construction of the Cheomseongdae (첨성대축조 규준방식과 드잡이기술에 대한 기술사적 접근 연구)

  • Kim, Derk Moon
    • Korean Journal of Heritage: History & Science
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    • v.45 no.4
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    • pp.92-103
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    • 2012
  • The Cheomsungdae was built in the Silla dynasty during the reign of queen Seondeok. It has a round cylindrical structure with a flowing curved fa ade. The identity of the Cheomsungdae has not been revealed since there is not much historical evidence or documents about the building. This study is trying to investigate the building technique and method from the technical point of view of the past when it was constructed. There have been much work and studies done for the Cheomsungdae, but not much were focusing on the technical aspects of the building. In addition there are many questions and doubts about the hypothesis of the building technique of Cheomsungdae since there aren't any remaining documents or historical evidence supporting it. Among many questions, we think that the discussion on falsework technique is not considering traditional construction method of the Dujabee (a traditional construction technique using various tools and equipment for the stability of the building) technique. Therefore, it is hard to identify them as reliable historical facts. As the result of the study, we want to provide the basic data on the construction techniques of Korean traditional architecture and broaden the study scope of technical history by narrowing the errors. The study could be summarized into three points. 1. The historical architecture Cheomseongdae was constructed by using traditional crane techniques such as a Noklo (pulley ladder). Cheomseongdae was re-evaluated as a high level technology for the history of architecture. 2. The benchmark method on Cheomseongdae construction has been applied with a precise scientific method based on the geometrical principals using the central axis. 3. In terms of the history of Korean traditional architecture technology, as there aren't many studies done we proposed various basic data for the traditional crane techniques and criteria of Korean traditional architecture technology. We could expect various and active studies for the technical approach of the history of architecture.