• Title/Summary/Keyword: 기능성 산화물

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Preparation of PVdF Composite Nanofiber Membrane by Using Manganese-Iron Oxide and Characterization of its Arsenic Removal (망간-철 산화물을 이용한 PVdF 나노섬유복합막의 제조 및 비소 제거 특성 평가)

  • Yun, Jaehan;Jang, Wongi;Park, Yeji;Lee, Junghun;Byun, Hongsik
    • Membrane Journal
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    • v.26 no.2
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    • pp.116-125
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    • 2016
  • This study described a synthesis of MF having a arsenic removal characteristics and the fundamental research was performed about the simultaneous removal system of both As(III) and As(V) ions with the composite nanofiber membrane (PMF) based on PVdF and MF materials for the water-treatment application. From the TEM analysis, the shape and structure of MF materials was investigated. The mechanical strength, pore-size, contact angle and water-flux analysis for the PMF was performed to investigate the possibility of utilizing as a water treatment membrane. From these results, the PMF11 showed the highest value of mechanical strength ($232.7kgf/cm^2$) and the pore-diameter of composite membrane was reduced by introducing the MF materials. In particular, their pore diameter decreased with an increase of iron oxide composition ratio. The water flux value of PMF was improved about 10 to 60% compared with that of neat PVdF nanofiber membranes. From the arsenic removal characterization of prepared MF materials and PMF, it was shown the simultaneous removal characteristics of both As(III) and (V) ions, and the MF01, in particular, showed the highest adsorption-removal rate of 93% As(III) and 68% As(V), respectively. From these results, prepared MF materials and PMF have shown a great potential to be utilized for the fundamental study to improve the functionality of water treatment membrane.

Effects of the Physiological Activities and Oxidation Inhibitory Action of Turmeric (Curcuma longa L.) by Various Solvents (울금(Curcuma longa L.)의 용매 별 추출물이 생리활성 및 산화억제에 미치는 영향)

  • Oh, Da-Young;Kim, Han-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.3
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    • pp.622-632
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    • 2018
  • The aim of the present study was to evaluate of turmeric (Curcuma longa L.) on the physiological activities and oxidation inhibitory action. The effects of various solvents (distilled water DW, 70% ethanol and n-butanol) on the total phenolics content (TPC) of turmeric and their corresponding biological activity were studied. Bioactive compound of total saponin $7.506{\pm}0.349mg\;SE/g$ dry weight. Turmeric extracts yield were DW (17.11%), 70% ethanol (15.26%) and n-butanol (4.12%), respectively. Oxidation inhibitory action of the samples exhibited a dose-dependent increase. However, in the current study, none of the samples evaluated showed activity as strong as the BHA, ascorbic acid and EDTA. Results showed that extraction solvent had significant effects on TPC and oxidation inhibitory action (DPPH radical scavenging activity, ABTS radical scavenging activity, reducing power and ferric reducing antioxidant power) of n-butanol. Turmeric exhibited the antioxidant properties, which suggests that the plant material could be used for further studies as a potential source for bioactive and natural antioxidant.

A Study on Roasting Refinement of Crude-ZnO from Electric Arc Furnace Steel Dust (전기로 제강분진으로부터 분리 회수한 조산화아연의 산화배소 정제에 관한 연구)

  • Yoon, Chi Hyun;Lee, Myungwon;Seo, Junghwa;Yoon, Jaehong
    • Resources Recycling
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    • v.23 no.1
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    • pp.58-63
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    • 2014
  • Variety of volatile materials is present in crude-Zinc oxide recovered from EAFD(Electric arc furnace steel dust). Commonly, it is purified by oxidizing roasting. In this study, spherical each specimen prepared crude-zinc oxide like 1~3 mm and 10 mm was tested in vertical tube furnace at the temperature range $600^{\circ}C$ to $1200^{\circ}C$ in oxidizing atmosphere. Oxidizing roasting properties of zinc oxide were investigated using XRD, XRF and ICP-OES. At temperature blow $950^{\circ}C$ volatilization rate were remarkably low. As the temperature increases, the concentration of Zn increased and the concentration and XRD peaks of impurities decreased. The result indicated that volatilization rate depended on specimen size and roasting temperature.

Application of Nanoparticles in Food Preservation and Food Processing

  • Prakash, J.;Vignesh, K.;Anusuya, T.;Kalaivani, T.;Ramachandran, C.;Sudha, Rani R.;Rubab, Momna;Khan, Imran;Elahi, Fazle;Oh, Deog-Hwan;DevanandVenkatasubbu, G.
    • Journal of Food Hygiene and Safety
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    • v.34 no.4
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    • pp.317-324
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    • 2019
  • This study focuses on the role of nanotechnology in the field of food industries. Bioactive components with antimicrobial activity against food pathogens are encapsulated into nanoparticles (NPs) to improve and extend their efficiency in food preservation. However, these NPs should be biocompatible and nontoxic for humans. Advancement in this field has resulted in the development of NPs for food packaging in some industries. The most commonly used group of NPs in the food industry is metal oxide. As metal oxide NPs such as zinc oxide and titanium dioxide exhibit antimicrobial activity in food materials, the NPs can be used for food preservation with enhanced functional properties. The application and effects of nanotechnology in correlation with the nutritional and sensory properties of foods were briefly discussed with a few insights into safety regulations on nano-based food formulation and preservation.

Cirsium japonicum Extracts Show Antioxidant Activity and PC12 Cell Protection against Oxidative Stress (좁은잎 엉겅퀴 추출물의 산화방지 활성 및 산화적 스트레스에 대한 PC12 세포 보호효과)

  • Jang, Miran;Kim, Gun-Hee
    • Korean Journal of Food Science and Technology
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    • v.48 no.2
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    • pp.172-177
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    • 2016
  • The phenolic compounds, antioxidant activity and neuronal cell protective effect of Cirsium japonicum extract were evaluated in this study. High performance liquid chromatography mass analysis showed that C. japonicum was composed of chlorogenic acid, linarin, and pectolinarin. C. japonicum extract showed its antioxidant activity with half-maximal inhibitory concentrations of 567 and $130{\mu}g/mL$ by DPPH and ABTS radical scavenging activity, respectively. The total antioxidant capacities of C. japonicum via DPPH, ABTS, and FRAP assays were 11.32, 100.15, and $12.76{\mu}g/mL$ trolox equivalents, respectively. In addition, the neuroprotective effect of C. japonicum extract was investigated by measuring cell viability via MTT, LDH and DCF-DA assay using $H_2O_2-damaged$ PC12 cells. C. japonicum extract showed neuronal cell protective effects in a dose-dependent manner. These results indicated that C. japonicum extract has potent antioxidant and neuronal protective effects. Therefore, C. japonicum can be regarded as an effective and safe functional food resource as natural antioxidants, and may decrease the risk of neurodegenerative disorders.

Effect of Fermented Garlic Extract on Adhesion of THP-1 Cells to Bovine Aortic Endothelial Cells (혈관내피세포에 부착하는 THP-1에 대한 발효마늘추출물의 효과)

  • Kwon, Ohseong;Song, Jina;Yu, Heui Jong;Park, Heonyong
    • Journal of Life Science
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    • v.27 no.5
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    • pp.553-560
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    • 2017
  • Fermented garlic extract (FGE) is a well-known functional food containing cycloalliin. Here we tested if FGE has an effect on the vascular system. We found that FGE had an effect on monocytic adhesion to endothelial cells, which occurs at the initial step of processes of inflammation. From dose-dependent experiments, 0.1 to $1{\mu}g/ml$ of FGE appeared to inhibit lipopolysaccharide (LPS)-enhanced heterotypic cell adhesion between THP-1 and BAECs. This result indicates that FGE blocks vascular inflammation. Then we found that FGE activates eNOS and Akt in BAECs. The phosphorylation of eNOS was maximally elevated 10 min after FGE treatment. Parallely, the phosphorylation of Akt was also maximally increased 10 min after FGE treatment. Consistently, it was found that FGE enhanced the production of nitric oxide. We then examined whether NO mediates THP-1 cell adhesion to BAECs. Both Akt and eNOS inhibitors appeared to reverse an inhibitory effect of FGE. These findings indicate that FGE inhibits LPS-enhanced heterotypic cell adhesion via Akt and eNOS. In conclusion, FGE plays an important role in prevention of inflammatory diseases.

Effects of Chrysanthemum indicum L. Extract on the Function of Osteoblastic MC3T3-E1 Cells under Oxidative Stress Induced by Hydrogen PeroxideJee (감국(Chrysanthemum indicum L.) 추출물이 H2O2로 유도한 산화적 스트레스에서 MC3T3-E1 조골세포 기능에 미치는 영향)

  • Yun, Jee-Hye;Hwang, Eun-Sun;Kim, Gun-Hee
    • Korean Journal of Food Science and Technology
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    • v.44 no.1
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    • pp.82-88
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    • 2012
  • Chrysanthemum indicum L. (Asteraceae) is a traditional herbal medicine that has been used for the treatment of inflammation, hypertension, and respiratory diseases due to its strong antagonistic activity against inflammatory cytokines. The effects of Chrysanthemum indicum L. Extract (CIE) for increasing cell growth, alkaline phosphatase (ALP) activity, and collagen content were totally inhibited, suggesting that the effect of CIE might be partly involved with estrogen activity. Furthermore, the protective effects of CIE on the response of osteoblasts to oxidative stress were evaluated. Osteoblastic MC3T3-E1 cells were incubated with hydrogen peroxide and/or CIE, and markers of osteoblast function and oxidative damage were examined. CIE significantly increased cell survival, ALP activity, and calcium deposition, and decreased the production of Reactive Oxygen Species (ROS) and Tumor Necrosis Factor-${\alpha}$ (TNF-${\alpha}$) in osteoblasts. Taken together, these results indicate that the enhancement of osteoblast function by CIE may prevent osteoporosis and inflammatory bone diseases.

Selective Transmission Properties of Al-Ti Based Oxide Thin Films (Al-Ti계 산화물 박막의 조성에 따른 선택적 투과 특성)

  • Bang, Ki Su;Jeong, So Un;Lim, Jung Wook;Lee, Seung-Yun
    • Journal of the Korean Vacuum Society
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    • v.22 no.1
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    • pp.13-19
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    • 2013
  • It is expected that progress in building-integrated photovoltaic (BIPV) systems, improving the functionality and design of buildings, will be accelerated in the coming years. While the dye sensitized solar cell is considered one of the most important technologies in the BIPV field, the transparent silicon based thin film solar cell fabricated by thin film processes has drawn attention as a novel alternative. When the selective transmitting layer is applied to the solar cell, the conversion efficiency is improved due to the re-reflection of infrared light into an absorber layer with the transmission of visible light through the solar cell. In this work, we prepared Al-Ti based oxide thin films using cost-effective sputter deposition and examined their selective transmitting characteristics with various compositions. The transmittance and reflectance of the Al-Ti based oxide thin film changed with the variation of its composition, and the selective transmitting property was observed in the sample with the 25 nm-thick AlTiO layer. It is considered that the realization of transparent solar cells and the improvement of their conversion efficiency can be achieved by introducing the Al-Ti based selective transmitting layer.

Study on Antioxidant Activities of Extracts from Different Parts of Korean and Iranian Pomegranates (국내산과 이란산 석류 부위별 추출물의 항산화 활성)

  • Jin, So-Yeon
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.40 no.8
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    • pp.1063-1072
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    • 2011
  • This study analyzed the functional components and antioxidant activities of pomegranate juice and pomegranate husk, endocarp and seed extracts by comparing Korean and Iranian pomegranates. Korean pomegranate husk (KPH) had the highest total polyphenol content among the pomegranate extracts, and total phytoestrogen content was highest in Korean pomegranate endocarp (KPE). Iranian pomegranate endocarp (IPE) and Iranian pomegranate husk (IPH) showed the highest flavonoid levels. Overall, Korean pomegranate had more functional components than those in Iranian pomegranate. KPE had the highest DPPH radical scavenging activity and superoxide dismutase like-activity among all of the extracts, and KPH had the highest nitrite scavenging activity. IPE showed the highest superoxide anion scavenging activity. The ABTS$^+$ assay also indicated that IPH had the highest antioxidant activities. This study also showed that the more total polyphenols, flavonols, and phytoestrogens the pomegranate contained, the higher antioxidant activities. A positive correlation was observed between total polyphenol, flavonol and phytoestrogen levels and antioxidant activities. Korean pomegranates contained more functional components and had higher antioxidant activity than those of Iranian pomegranates. Additionally, pomegranate endocarp and seed extracts were better than pomegranate juice in terms of functional components and antioxidant activity. These results suggest that pomegranate husk, endocarp and seed extracts as well as pomegranate juice may have value as natural antioxidants with their high quality functional components and antioxidant activity.

Photocatalysis: From Environmental Remediation to Energy Conversion (환경, 에너지 분야에서의 광촉매 활용기술)

  • Choe, Ji-Na;Kim, Beom-Sik;Gwon, Sun-Il;Yu, Ji-Seon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.72.1-72.1
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    • 2013
  • 광촉매 활용 기술은 수질 및 대기 중의 난분해성 오염 물질 처리 등의 환경 분야에서부터 항균 및 초친수성 기능을 활용한 소재 분야, 그리고 태양광을 이용한 물분해 수소 제조 및 이산화탄소의 전환 등의 인공 광합성 연구 분야까지 그 응용분야가 대단히 넓은 기술이다. 본 강연에서는 이러한 광촉매의 반응 원리와 대표적인 응용분야인 환경 정화 분야 및 에너지 분야에서의 광촉매 기술의 활용, 그리고 현재 광촉매 관련 연구 분야의 주요 관심사 및 미래 성장을 위한 과제 등을 포괄적으로 다루고자 한다. 광촉매 반응은 반도체의 따간격 에너지 흡수에 따라 전자와 정공(+전하를 가진 전자와 같은 거동을 하는 입자)가 발생한 뒤에 일어나는 계면에서의 전자전달 반응을 기초한다. 발생한 정공과 전자는 각각 산화와 환원 반응을 유발하며 이러한 산화, 환원반응을 통해 다양한 분야로의 응용이 가능하다. 환경 정화 분야의 경우, 정공이 물 혹은 공기 속에 존재하는 수분과 반응하여 생성되는 OH 라디칼 ($OH{\cdot}$)의 강력한 산화력을 주로 이용하게 된다. OH 라디칼에 의한 다양한 난분해성 유기물질의 산화분해 반응을 활용하여 고도처리공정이 가능하게 되며, 수계 난분해성 유기오염물질의 제거뿐만 아니라 대기 중에 존재하는 VOCs, 악취물질 등의 분해도 가능하며, 아울러 바이러스나 박테리아와 같은 세균을 제거할 수 있는 것으로 알려져 있다. 한편, 물 분해 수소제조 및 이산화탄소의 전환과 같은 에너지 분야 응용의 경우, 전도대의 전자를 활용한 환원반응에 기초한다. 앞서 언급한 다양한 응용분야에서 활용될 수 있는 광촉매의 종류 또한 매우 다양하며, 이사화티탄(TiO2)는 대표적인 고효율 상용 광촉매이다. 아울러, 원하는 응용 분야에서의 광활성이 높은 새로운 광촉매의 제조 및 평가가 꾸준히 진행되고 있으며, 그 가운데 태양광의 가장 많은 영역을 차지하고 있는 가시광 활성을 갖는 광촉매 개발에 관한 연구가 활발히 수행되고 있다. 이에, 현재까지 개발된 다양한 가시광 광촉매 시스템에 대한 소개 및 각 광촉매 응용분야에서 최근 새롭게 대두되고 있는 이슈들에 대하여 중점적으로 고찰하고자 한다.

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