• Title/Summary/Keyword: 기공형태

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Studies on Improved Carbon Cathode Performance in High Rate $Li/SOCl_2$ Cell (고율 방전용 $Li/SOCl_2$ 전지의 카본 양극 개선에 관한 연구)

  • 최정자;조성백;박희숙
    • Journal of the Korean Ceramic Society
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    • v.34 no.3
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    • pp.225-232
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    • 1997
  • The performance characteristics of high rate discharge LiSOCl2 cells are highly affected by carbon cathode. During the cell discharge, SOCl2 reduction takes place at the porous carbon cathode, resulting in the precipitation of reaction products, mainly LiCl, within the pores of the substrate. This leads to eventual passivation of the cathode surface and resulting cell failure. To improve the cathode performance, we ex-amined discharge reactions of cathodes (half-cell, 50 mA/$\textrm{cm}^2$ constant current) with various surface density and thickness. The carbon cathode with the optimum capacity for our application is surface density 0.04 g/$\textrm{cm}^2$ and thickness 1.4mm carbon. The carbon cathode with surface density 0.04g/$\textrm{cm}^2$ and thickness 1.4 mm exhibits decreased polarization, increased discharge duration time and capacity (Ah/$\textrm{cm}^2$) as compared with that with surface density 0.04g/$\textrm{cm}^2$ and thickness 0.8mm. The porosities analyses on the two carbon cathodes show that total pore volume of the carbon cathode with thickness 1.4 mm is larger than that with thickness 0.8mm. The increased volume of mesopores (0.05$\mu$m~0.5$\mu$m) and macropores(>0.5$\mu$m) is ob-served with the carbon cathode with thickness 1.4mm as compared with that with thickness 0.8mm, which can be related with the observed capacity increase. We observed LiCl crystals, cubic crystallites and fused, plate-like aggregates, and some elemental S as discharge products by EDS and XRD.

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Frequency and Growth Characteristics of Polyploids Occurred Spontaneously in Some Mandarin Hybrids (만다린 잡종에서 자연발생 배수체의 발생 빈도와 생장 특성)

  • Song, Kwan-Jeong;Kim, Sat-Byul;Park, Jae-Hyun;Oh, Eun-Ui;Lee, Kyung-Uk;Kim, Dong-Wook;Kang, Jong-Hoon;Kim, Jeong-Soon;Oh, Jeong-Hwan;Gmitter, Fred G.
    • Horticultural Science & Technology
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    • v.29 no.6
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    • pp.617-622
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    • 2011
  • The study was conducted to determine the efficiency in producing spontaneous polyploids in some mandarin hybrids with different seed embryony. Seed formation by open pollination, frequency of spontaneous polyploids, and plant growth characteristics were evaluated in four mandarin hybrids with polyembryony such as 'Amakusa', 'Haruka', 'Hayaka', and 'Seminole' and two with monoembryony such as 'Benibae' and 'Harehime'. The mean number of the developed seeds per fruit was 10.0 and frequency of small seeds was 25.1%. Polyploids were selected from plants germinated in vitro by a flow cytometry and confirmed by chromosome analysis. One triploid was produced from 'Harehime', one tetraploid, 'Amakusa', and one tetrapoid, 'Benibae'. There were little differences in leaf shape, thickness, petiole length, and internode length between diploids and polyploids such as tri- or tetraploid. However, polyploids had larger stomata and lower density of stomata in abaxial epidermis than diploids. SPAS indicating chlorophyll content and photosynthetic rate were significantly affected by ploidy level. The results indicated that spontaneous polyploids might be produced by open pollination in some mandarin hybrids and monoembryony had higher frequency in polyploid occurrence than polyembryony.

The Analysis of Physical Characteristics and Raw Materials on Hard and Soft Whiteware at Excavated Kiln in Dudong-ri Gyeongsangnam-do, Korea (경남 두동리가마터 출토 경질과 연질백자에 대한 물성 및 원료 분석)

  • Koh, Min-Jeong;Kim, Ji-Tae;Koh, Kyong-Shin;Kim, Gyu-Ho
    • Journal of Conservation Science
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    • v.18 s.18
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    • pp.75-88
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    • 2006
  • This study tries to find out the properties of soft ind hard white wares of white wares from Dudong-ri in a scientific way, especially by meant of physical chemical analysis, microstructural observation. As a result, In the physical analysis, soft white wares are found to have higher absorption and porosity. In the composition analysis, the chemical property, of body and glaze, shows that the composition of them varies with excavation areas. However, no clear difference is identified between the soft and hard white wares which are from the ssme kiln. The microstructural observation visibly shows the difference of hard and soft white wares which it verified in the physical property Minerals with round pores and vitrified feldspar are observed in the body of hard white wares, but no vitrified particles but widely distributed pores with long and sharp irregular shapes are found in the body of soft white wares. In conclusion, the hard and soft white wares from Dudong-ri kiln are mainly influenced by physical property and microstructural rather than chemical composition and firing atmospheres. However, more and various comparative studies are needed since the resources with various physical properties vary among kilns of each production area.

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Structural characterization of $Al_2O_3$ layer coated with plasma sprayed method (플라즈마 스프레이 방법으로 코팅 된 $Al_2O_3$막의 구조적 특성)

  • Kim, Jwa-Yeon;Yu, Jae-Keun;Sul, Yong-Tae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.3
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    • pp.116-120
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    • 2006
  • We have investigated plasma spray coated $Al_2O_3$ layers on Al-60 series substrates for development of wafer electrostatic chuck in semiconductor dry etching system. Samples were prepared without/with cooling bar on backside of samples, at various distances, and with different powder feed rates. There were many cracks and pores in the $Al_2O_3$ layers coated on Al-60 series substrates without cooling bar on the backside of samples. But the cracks and pores were almost disappeared in the $Al_2O_3$ layers on Al-60 series substrates coated with cooling bar on the back side of samples, 15 g/min. powder feed rate and various 60, 70, 80 mm working distances. Then the surface morphology was not changed with various working distances of 60, 70, 80 mm. When the powder feed rate was changed from 15 g/min to 20 g/min, the crack did not appear, but few pores appeared. Also the $Al_2O_3$ layer was coated with many small splats compared with $Al_2O_3$ layer coated with 15 g/min powder feed rate. The deposited rate of $Al_2O_3$ layer was higher when the process was done without cooling bar on the back side of sample than that with cooling bar on the back side of sample.

Synthesis and Characterization of Zeolite 4A on Activated Carbon Supports (활성탄 지지체상에서 제올라이트 4A 합성 및 특성)

  • Park, Jeong-Hwan;Suh, Jeong-Kwon;Jeong, Soon-Yong;Lee, Jung-Min;Doh, Myung-Ki
    • Applied Chemistry for Engineering
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    • v.8 no.2
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    • pp.204-210
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    • 1997
  • Zeolite 4A-impregnated complex molecular sieve was prepared by hydrothermal reaction after aluminosilicate gel was penetrated into the pore of activated carbon granule. The crystals of zeolite 4A mainly were formed in the macropore of activated carbon, and their average diameter is $0.8{\mu}m$. The pore volume of activated carbon granule is $0.67m{\ell}/g$, and the pore volume of the sample including 21.6wt% of zeolite 4A crystal is $0.41m{\ell}/g$ decreasing the pore volume by 40% due to the crystallization of zeolite 4A crystals on the internal surface of activated carbon. The calcium ion exchange capacity of zeolite 4A-impregnated sample is 320mg $CaCO_3/g$ zeolite, and this value is almost the same as that of zeolite 4A powder. The crystal of zeolite 4A was not separated from the support of activated carbon granule in the course of ultrasonic dispersion. The adsorption isotherm of water on zeolite 4A-impregnated sample shows the intermediate shape between types, I and III. In addition, zeolite 4A-impregnated sample shows the hydrophilic and hydrophobic properties simultaneously.

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Effect of Plant Crowth Regulators on Production of Good Quality Plant for Korean Gerbera Lines (국내 육성 거베라의 우량묘 생산에 미치는 식물생장조절제의 영향)

  • Chung, Yong-Mo;Sin, Hyang-Jung;Park, So-Young;An, Dong-Chun;Son, Beung-Gu;Jo, Yong-Cho;Kwon, Oh-Chang
    • Journal of Life Science
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    • v.17 no.6 s.86
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    • pp.831-835
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    • 2007
  • This study was carried out to obtain information about the valuable combination and concentration to produce good plants of cut gerbera flowers of 19 domestically - bred gerbera cultivars. BA and kinetin combination is more effective than NAA and BA combination to produce good plants and mass propagation of domestically - bredgerbera cultivars. Normally almost of 19 cultivars, mass propagation was more effective on the medium containing 1.0 mg/L BA + 0.5, 1.0 mg/L kinetin. But some cultivars, 'Sunnyeo', 'Oksaem','Piny', and 'Pink Light', vitrified plants were induced on MS medium high level of BA concentration(BA 1.0 mg/L), in comparison with those on the medium with low level of BA(0.1 mg/L).Fresh and dry weight, more effective on the medium containing BA 0.5 mg/L . Kinetin 0.1, 0.5 mg/L. Anatomical investigation of vitrified leaf, stomata of vitrified leaves were circular and inflated, where-as those of normal leaves.

Archaeometric Characterization of Raw Materials and Tempers of Bricks Used in the Brick Tombs during Ungjin Period of Baekje (백제 웅진기 벽돌무덤에 사용된 벽돌의 재료와 첨가물 특성 분석)

  • Sungyoon Jang;Hong Ju Jin
    • Economic and Environmental Geology
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    • v.55 no.6
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    • pp.571-582
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    • 2022
  • In this study, the raw material and tempers of bricks used in three brick tombs built in Gongju, during the Ungjin period of Baekje were investigated. The royal tomb of King Muryeong, the 6th tomb in the royal tombs, and Kyochonri brick tomb remained in Gongju and the bricks of each site had different shape and physical properties despite their similarity in raw materials. As the results of the mineralogical and microstructural analysis, the bricks of the royal tombs were made of refined raw materials, and were infrequently added crushed bricks(grogs) as a tempering material. On the other hand, thick and elongated pores of bricks from the Kyochonri brick tomb were frequently found, and the remains of plant carbonization are observed in their microstructures. Since the pores are mainly distributed in a thickness of 0.3 to 1 mm, it is estimated that bricks were produced by adding a certain size of the plant to refined soil, and grogs also were added as a tempering material. In particular, it was found that adding plants and grogs in raw materials of bricks caused thick pores or cracks in the internal structure. Since the bricks of the Kyochonri brick tomb have internal cracks and low firing temperature, the ultrasonic velocity of the bricks was lower than that of the royal tomb bricks. It means that the mechanical strength of these bricks were relatively low. Accordingly, it is estimated that the tempering materials, firing temperature, and internal structures of bricks can affect durability of the brick, and it can be thought as a difference in the manufacturing technology of brick making.

Superimposition: a simple method to minimize occlusal adjustment of monolithic restoration (디지털 장비의 중첩기능을 이용하여 단일체 수복물의 교합조정을 최소화한 증례)

  • Choi, Changhun;Kim, Sunjai
    • The Journal of Korean Academy of Prosthodontics
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    • v.54 no.3
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    • pp.253-258
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    • 2016
  • The development of translucent zirconia enabled clinicians to choose a monolithic zirconia crown as one treatment modality in the posterior dentition. Careful occlusal adjustments are recommended for monolithic zirconia crowns because grinding zirconia inevitably causes phase transformation, which may deteriorate mechanical properties. intraoral scanners enable the clinician to scan and superimpose a complete tooth structure before preparation onto the prepared abutment. This technique helps to reproduce the original tooth form and occlusion of the patient. In this case report, prostheses were fabricated for patients with cracked or fractured tooth by applying intraoral scanner, Computer aided design-computer aided manufacturing (CAD-CAM) and monolithic zirconia crown to reproduce the occlusion of original tooth and to minimize occlusal adjustment. The clinical results were satisfactory in both esthetic and functional aspects.

A morphological reexamination on the genus Adonis L. sensu lato (Ranunculaceae) in Korea (한국산 복수초속(미나리아재비과)의 형태분류학적 재검토)

  • Lee, Chunghee;Lee, Sangtae;Suh, Youngbae;Yeau, Sung-Hee;Lee, Nam Sook
    • Korean Journal of Plant Taxonomy
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    • v.33 no.4
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    • pp.435-454
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    • 2003
  • The morphology of plants and scanning electro-microscopical features of fruits were examined to evaluate the taxonomic entities of Korean Adonis L. in sensu lato (Ranunculaceae). The species of Korean Adonis were readily diagnosed by the branching pattern of stem, the number of flowers, the bifurcation of leaf main axis, the number of tepals, the flowering periods in relation to leaf sprouting, and the number of stomata and the texture of fruit surface. This study demonstrates that there are three species, A. amurensis, A. pseudoamurensis, and A. multiflora., found in Korea. However, A. ramosa, which has been often claimed to be distributed in Korea, is not present in Korea.

Observation of Diverse Aluminum Oxide Structures in a Phosphoric Acid Solution according to the Applied Anodization Voltage (인산용액에서 양극산화 인가전압에 따른 알루미늄 산화피막 성장 관찰)

  • Jeong, Chanyoung
    • Journal of the Microelectronics and Packaging Society
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    • v.26 no.1
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    • pp.35-39
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    • 2019
  • To date, porous alumina structures have been implemented by electrochemical anodization technique. The anodizing methods can easy to make a porous aluminum oxide film with a regular arrangement, but oxide film with complex structure type such as pillar-on-pore is relatively difficult to implement. Therefore, this study aims to observe the change of anodized oxide pore size, thickness, and structure in a phosphoric acid solution according to applied anodization voltage conditions. For the implementation of hybrid composite oxide structures, it is possible to create by modulating anodization voltage. The experimental conditions were performed at the applied anodization voltage of 100 V and 120 V in 10% phosphoric acid solution, respectively. The experimental results were able to observe the structure of oxides in the form of porous and composite structures (pillar-on-pore), depending on each condition.