• Title/Summary/Keyword: 금속화

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Studies on Chromatographic Behaviors of the Metal Complexes by Various Eluents (용리제의 종류에 따른 금속착물의 크로마토그래피적인 거동에 관한 연구)

  • Chang Eon Oh;Doo Cheon Yoon
    • Journal of the Korean Chemical Society
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    • v.31 no.1
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    • pp.31-36
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    • 1987
  • We examined eluting behaviors for cationic complexes with the eluting cations. Retention volumes of hydrophilic complexes when eluted by the high concentration of aqueous KCl, NaCl and $NH_4Cl solutions, have been increased in the order NH_4^+ > Na^+ > K^+$, but in the low concentration, retention volumes of hydrophilic complexes bave been increased in the order $Na^+ > NH4^+ > K^+$. On the order hand, retention volumes of hydrophobic complexes when eluted by aqueous KCl, NaCl and $NH_4Cl solutions, have been increased in the order NH_4^+ > Na^+ > K^+$ in the whole concentration range. And we examined eluting behaviors for cationic complexes with the eluting anions. Hydrophilic complexes were associated more strongly with chloride ion among halide ions. However, hydrophobic complexes were associated more strongly with iodide ion. Sulfate ion, a highly hydrated anion, was associated more strongly with hydrophilic complexes than with hydrophobic complexes.

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Study on the Damage Characteristics Under the High-Velocity Impact of Composite Laminates Using Various Sensor Signals (다양한 센서 신호를 이용한 복합적층판의 고속충격 손상 특성 연구)

  • Cho, Sang-Gyu;Kim, In-Gul;Lee, Seok-Je;You, Won-Young
    • Composites Research
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    • v.24 no.6
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    • pp.49-55
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    • 2011
  • The use of advanced composite materials in main structures of military and civil aircraft has been increased rapidly because of their considerable metals in high specific strength and stiffness. However, the mechanical properties of composite materials may severely degrade in the presence of damage. Especially, the high-velocity impact such as a hailstorm, and a small piece of tire or stone during high taxing, can cause considerable damage to the structures and sub-system in spite of a very small mass. However, it is not easy to detect the damage in composite plates using a single sensor or any conventional methods. In this paper, the PVDF sensors and AE sensors were used for monitoring high-velocity impact damage initiation and propagation in composite laminates. The WT(wavelet transform) is used to decompose the sensor signals. In the PVDF sensor and AE sensor signal analysis, amounts of high-frequency signals are increased when the impact energy is increased. PVDF sensor and AE sensor signal appeared similar results. This study shows how various sensing techniques can be used to characterize high-velocity impact damage of advanced composite laminates.

Convergence Study on Composite Material of Unidirectional CFRP and SM 45C Sandwich Type that Differs in Stacking Angle (적층각도가 다른 단방향 CFRP와 SM45C샌드위치형 복합재료에 관한 융합적 연구)

  • Park, Jae-Woong;Cho, Jae-Ung
    • Journal of the Korea Convergence Society
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    • v.8 no.7
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    • pp.231-236
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    • 2017
  • In this study, the inhomogeneous material composed of CFRP(carbon fiber reinforced plastic) and structural metal of SM45C is used for the light material. The finite element analysis on the basis of compact tension test was carried out by using the composite material for sandwich type bonded with the unidirectional CFRP that differs in fiber stacking angle at both sides with the core of SM 45C. CT test is the representative method to confirm the fracture behaviour due to crack in material under the load. The effect on crack and hole must be investigated in order to apply inhomogeneous material to mechanical structure. As the result of this study, the fracture behaviour by CT test of the composite material for sandwich was studied by simulation analysis. The sandwich composite of unidirectional CFRP with the stacking angle of [0/60/-60/0] has the superior strength and the maximum equivalent stress of about 182GPa.Also, the esthetic sense can be shown as the designed factor of shape with composite material is grafted onto the convergence technique.

Anode Characteristics of $SnO_x$ Films with Various Oxygen Contents (산소량에 따른 $SnO_x$ 박막의 음극 특성)

  • Moon Hee-Soo;Seong Sang-Hyun;Kim Young-Il;Park Jong-Wan
    • Journal of the Korean Electrochemical Society
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    • v.3 no.3
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    • pp.178-181
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    • 2000
  • In this experiments, tin oxide thin film anode for microbattery was deposited by using RF magnetron sputtering. The RF power and operating pressure during deposition were fixed at $2.5W/cm^2$ and 10mTorr respectively. The partial pressure of oxygen was varied from $0\%\;to\;100\%$ to control oxygen content and metal Sn chips were used further reducing of oxygen content. According to reduction in the oxygen content formation of the irreversible $Li_2O$ was reduced a thin film anode of $SnO_x$ of high capacity was fabricated. The optimum $SnO_x$, thin film was $SnO_{1.43}$ which exhibited a reversible capacity of $ 500{\mu}Ah/cm^2{\mu}m$ and exhibited good reversibility.

Improvement of Rate Capability and Low-temperature Performances of Graphite Negative Electrode by Surface Treatment with Copper Phthalocyanine (구리 프탈로시아닌으로 표면처리된 흑연 음극의 속도특성 및 저온성능 개선)

  • Jurng, Sunhyung;Park, Sangjin;Ryu, Ji Heon;Oh, Seung M.
    • Journal of the Korean Electrochemical Society
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    • v.18 no.3
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    • pp.130-135
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    • 2015
  • The rate capability and low-temperature characteristics of graphite electrode are investigated after surface treatment with copper phthalocyanine (CuPc) or phthalocyanine (Pc). Uniform coating layers comprising amorphous carbon or copper are generated after the treatment. The rate performance of graphite electrodes is enhanced by the surface treatment, which is more prominent with CuPc. The resistance of the graphite electrode estimated from electrochemical impedance spectroscopy and pulse resistance measurement is the smallest for the CuPc-treated graphite. It is likely that the amorphous carbon layer formed by the decomposition of Pc facilitates $Li^+$ diffusion and the metallic copper derived from CuPc improves the electrical conductivity of the graphite electrode.

Evaluation of Electrochemical Stability and Performance of Graphite Sheets as Current Collectors for Lead Acid Battery (납축전지 전류집전체로서 그라파이트 시트의 전기화학적 안정성과 방전성능 평가)

  • An, Sang-Yong;Kim, Eung-Jin;Yoon, Youn-Saup;Kim, Hee-Jung
    • Journal of the Korean Electrochemical Society
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    • v.13 no.2
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    • pp.128-131
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    • 2010
  • Graphite sheet electro-deposited with lead was evaluated as a possible candidate for current collectors of lead acid batteries. Cyclic voltammetry was performed on the materials to evaluate the electrochemical properties. The graphite sheet electro-deposited with lead is electrochemically stable in the cathodic potential sweep. However, in the anodic potential sweep, the graphite sheet electro-deposited with lead is electrochemically unstable due to the oxygen evolution and the intercalation of sulfuric acid. Lead acid batteries were prepared by using a graphite sheet and a cast grid as current collectors for anode and performance test using those batteries was carried out. A lead acid battery with graphite sheets showed higher capacity and energy density than a conventional lead acid battery with cast grid.

Measurement and Analysis of Electric Filed Distributions under 154[kV] Overhead Tranamission Lines (154[KV] 가공송전선로 아래에서 전장분포의 측정과 분석)

  • 이복희;이정기;안창환;이경옥;박동화;곽희로;송진호
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.11 no.1
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    • pp.92-98
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    • 1997
  • In this paper, the results of the measurement and analysis of extremely low freqency(ELF) eletric field in the vicinity of 154[kV] overhad transmission lines have been described. The planar-type electric field sensor has been fabricated by three dimensional structure with special consideration of taking the power frequency and lower components. The calibration experiments have been carried out according to the procedures of IEEE recommendation. The electric field measuring system has the frequency bandwidth of 7[Hz] to 2.7[MHz] and the response sensitivity of 0.094[mV/V/m]. Also the practical measurements of electric field under an 154[kV] double corcuit overhead transmission lines have been made abd abalyzed. It was known that the lateral electric field profiles under an 154[kV] double circuit overhead transmission lines show the asymmetrical distributions owing to the environmental metal frame structures and their maximum electric field magnitude is less than 3[kV/m]. It can be concluded that the measured results of the electric fields satisfy with all limits or guide -lines of the various authorized international institutes' recommendations.

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Study of Shield Method for EMC of Digital Circuit (디지털 회로에서 EMC를 위한 실드 방식에 대한 고찰)

  • Lee, Seong-Jae;Kim, Jae-Yang;Kim, Cheol-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.521-522
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    • 2008
  • 21세기를 접하면서 산업전자 분야의 비약적인 발전과 함께 과학문명은 눈부시게 발전해 나아가고 있다. 이것의 원천은 바로 전기(Electric)이다. 우리는 풍요로운 삶 자체를 전기 공급에서 누리고 있으며 또 비극적인 사태를 맞이할 때도 있다. 즉, 전기기기를 이용하면 원하건 원치 않건 전자기파가 발생이 된다 이것이 자연현상이며 전자기파는 IT, BT, CT를 비롯하여 산업 전체에 많은 영향을 미치고 있다. 일반적으로 우리가 말하는 전자기파 장해의 기본 요소는 노이즈원(잡음원), 경로매체, 피해장치 등으로 구성되는 데 잡음원(Noise Source)은 각종 시스템에서 구성되고 있는 전자기 에너지의 발생원으로 볼 수 있으며 이 발생원에서 경로매체(금속:전도성, 대기중:전파성 등)를 통하여 피해장치(전기전자통신기기류)에 방해를 주고 있는 상태를 전자기파 장해라고 설명할 수 있다. 전자기파 잡음원에서 경로를 거쳐 전자기파에 대하여 피해장치가 안정된 상태로 동작하도록 규정하는 용어 즉, 전자파 양립성 또는 적합성 (EMC : Electro Magnetic Compatibility))이란 용어를 가지고 전기 전자 통신기기에서 발생되는 불필요한 전자파와 전자파 내성시험을 만족하도록 의무화하고 있다. EMC 는 EMI (불요 전자파 또는 전자파 간섭 : Electro Magnetic Interference) + EMS (전자파 내성 : Electro Magnetic Susceptibility) 2가지 시험을 함께 전자파 적합성 (EMC) 시험으로 표현되고 있다. 전자파 적합성 시험의 목적으로 EMl는 전도성 또는 전파성에 대한 주파수 대역(잡음)을 보호하기 위한 것이 목적이고 EMS는 프로세서가 내장된 기기류의 오동작을 방지하기 위하여 감응평가를 하는 것이다. 즉, 감응(Susceptibility)이란 어떤 장비나 시스템이 전자기파 장해에 쉽게 영향을 받는 것을 뜻하는 데 전자파 장해를 견디면서 본래의 기능을 충분하게 발휘하며 동작할 수 있는 능력을 말한다.

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Characterization of Thin Film Passivation for OLED by PECVD (PECVD에 의한 OLED 소자의 Thin Film Passivation 특성)

  • Kim, KwanDo;Jang, SeokHee;Kim, JongMin;Chang, SangMok
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.574-581
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    • 2012
  • The relatively short lifetime is a major obstruction for the commercial applications of OLED. One of the reason for the short lifetime is that the organic materials are interacted with water or oxygen in the atmosphere. Protection of water or oxygen from diffusing into the organic material layers are necessary to increase the lifetime of OLED. Although encapsulation of OLED with glass or metal cans has been established, passivation methods of OLED by organic/inorganic thin films are still being developed. In this paper we have developed in-situ passivation system and thin film passivation method using PECVD by which deposition can be performed at room temperature. We have analyzed the characteristics of the passivated OLED device also. The WVTR (Water Vapor Transmission Rate) for the inorganic thin film mono-layer can be reached down to $1{\times}10^{-2}g/m^2{\cdot}day$ and improved lifetime can be obtained. Thin film passivation methods are expected to be applied to flexible display.

Overview and Recent Development of Recycling Small Waste Electrical and Electronic Equipment (WEEE) (폐소형가전제품 재활용 현황과 전망)

  • Jung, Insang;Park, Jihwan;Hwang, Jongsoo;Choi, Wonhee
    • Resources Recycling
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    • v.24 no.4
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    • pp.38-49
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    • 2015
  • The importance of recycling came to the fore by increasing of waste electrical and electronic equipment(WEEE) generation. Small WEEE recycling in particular represents a big challenge in Korea because it has various items and components. Main materials of small WEEE are typically well known for metals (copper, iron, aluminum, etc.), PCBs and plastics. Not only Korea but also overseas, the laws for small WEEE were in effect in order to recycle effectively, but the technology is not catched up with the regulation which has to recycle an allocated account of WEEE. In addition, recycling technologies and processes for small WEEE are not developed enough to recycling center properly. In that sense, if we develope the recycling process, have not only technology competitiveness but also resource conservation, improving the environment and economic profits. Therefore, through the analysis of economic value of recycled small WEEE, and current technologies both domestically and internationally, we design conceptual recycling process of small WEEE, and consider the way forward.