• Title/Summary/Keyword: 금속리싸이클링

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Overview on the Technologies for Extraction of Rare Earth Metals (희토류금속(稀土類金屬) 제련기술(製鍊技術) 개요)

  • Park, Hyung-Kyu;Lee, Jin-Young;Cho, Sung-Wook;Kim, Joon-Soo
    • Resources Recycling
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    • v.21 no.3
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    • pp.74-83
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    • 2012
  • Rare earth metals have been made from rare earth compounds which were prepared from rare earth ore concentrates through successive processes such as leaching(i.e. extraction of rare earth elements to liquid media), separation, purification, precipitation. Here, process for treating monazite and bastnasite ore concentrates were briefly reviewed, and metallothermic reduction and fused salt electrolysis methods were introduced as the extraction technologies for rare earth metals.

Smelting of Platinum Group Metals and Recycling of Spent Catalyst (백금족 금속의 제련과 폐촉매의 리사이클링)

  • Son, Injoon;Sohn, Ho-Sang
    • Resources Recycling
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    • v.30 no.3
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    • pp.18-29
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    • 2021
  • Platinum group metals (PGMs) are used in a wide range of application fields such as catalysts, electronic devices, electrodes, electrical devices, fuel cells and high temperature materials due to their excellent electrical and thermal conductivity as well as chemical resistivity. Platinum group elements are generally associated with nickel-copper sulfides in magmatic rocks. Depending on the relative concentrations of the PGMs, they are produced either as the primary products or as by-products of the nickel and copper. However, PGMs natural resource deposits are strictly limited in countries such as South Africa and Russia. The annual supply of PGMs is only under 500 t. Considering the limited supply of PGMs, there will be a noticeable increase in the supply risk associated with PGMs in the near future. Therefore, it is extremely important to recover PGMs from secondary resources such as spent catalysts. This paper reviews on overview of PGMs extraction and recycling processes.

Separation of Cobalt and Nickel from Aqueous Solution (수용액(水溶液)에서 코발트와 니켈 분리(分離))

  • Liu, Yang;Lee, Manseung
    • Resources Recycling
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    • v.22 no.1
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    • pp.11-19
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    • 2013
  • Recovery of pure cobalt and nickel from diverse resources is important due to the increased demand for these metals. In order to get cobalt and nickel with high purity, separation of them from other metal ions is necessary. In this review, several methods to obtain pure cobalt or nickel solution, such as solvent extraction, ion exchange, precipitation were introduced and compared. For solvent extraction, the advantage and disadvantage of the separation process together with detailed process conditions were investigated.

고온환원 및 전해법을 조합한 전기로제강분진 처리기술에 관한 연구

  • 윤기병
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2002.05a
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    • pp.66-73
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    • 2002
  • 전기로제강분진을 적절한 공정을 통하여 처리하여 유가금속을 회수하고 처리잔사를 철원으로 재활용한다면 환경오염방지 및 폐자원의 재자원화 효과가 기대된다. 본 연구에서는 고온환원과 전해공정을 조합한 새로운 전기로제강분진 처리공정을 제안하고, 각 공정에 대한 기초실험을 수행하여 그 가능성을 조사, 검토 하였다. 전기로제강분진의 고온환원실험과 환원과정에서 분위기와 증기압의 차이를 이용한 Zn및 Pb 성분의 분리, 휘발실험의 결과들이 분석되었으며, 아울러 환원처리잔사 중의 Fe성분함량을 증가시켜 철원으로 재활용할 수 있는 가능성을 확인하기 위하여 전기로제강분진과 millscale을 혼합, 환원하는 실험을 수행하였다. 또한 환원과정의 휘발산물인 조산화아연의 침출 및 전해에 관한 기초실험을 수행하여 고순도금속아연회수의 가능성도 조사, 검토하였다.

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A Study on the Leaching of Valuable Metals from Spent Silver-Oxide Battery (폐산화은 전지로부터 유가금속의 침출에 관한 연구)

  • 박경호;손정수
    • Resources Recycling
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    • v.4 no.1
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    • pp.46-51
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    • 1995
  • After removal of mercury in the silver oxide batteries with the distillation process, the leaching of valuable metals from the residue was studied. The distilled residue was reacted with the various HNO, concentration, reactlon temperature, readion time and pulp density. It was found that the optimum condition for leachmg was 2N HNO,, 40-60% reaction temperature, 6 hours reaction tlme and 10g/200ml pulp density. More than 99% of silver and zinc were dissolved in this process while less than 50% of iron and nickel were leached

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Current State of Domestic·Overseas Quality Standards of Tin and Comparison of Qualities between Virgin and Recycled Tin Products (주석 소재의 국내·외 품질기준현황 및 재활용 제품의 성능 비교)

  • Kim, Yong Hwan;Son, Seong Ho;Shin, Ho Jung;Han, Chul Woong;Park, Sung Cheol;Lee, Man Seung
    • Resources Recycling
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    • v.28 no.6
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    • pp.9-17
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    • 2019
  • The use of rare metals in increasing along with the growth of the Fourth industrials revolution and new energy industries, and the recycling of rare metals becomes more important as the used of rare metals increase. In this paper, the domestic and international quality standards of tin metal, one of the rare metals, and the performance test of recycled tin were investigated. As a results of the performance test, it was analyzed that there is no difference in performance between the natural and recycled tin.

Recovery of $LiCoO_2$ from Spent Lithium Ion batteries by using flotation (부유선별 기술을 이용한 폐리튬이온전지로부터 유가 금속의 회수)

  • Kim, Young-Hun;Kong, Bong-Sung;Lee, Sang-Hoon
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2005.10a
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    • pp.173-177
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    • 2005
  • 리튬이온 2차전지(Lithium ion battery, LIB)는 기존에 사용되던 전지에 비해 에너지 밀도가 높고 충방전 사이클이 우수하다. 이 때문에 휴대전화와 노트북 등에 수요가 급속하게 증가하고 있으며 1995년 LIB의 생산량은 4천만 개에서 2004년에는 약 8억 개로 20배 이상 증가하였다. 이에 따라 폐LIB도 급속하게 증가하게 되어 전국적인 재활용 시스템의 확보가 필요한 실정이다. 본 연구에서는 폐LIB에 함유되어 있는 유가금속 중에서 리튬코발트옥사이드(이하 $LiCoO_2$)를 회수하기 위하여 분쇄기(orient vertical cutting mill)와 진동 Screen을 사용하여 유기분리막, 금속류(Aluminium foil, Copper foil, case 등) 그리고 전극물질(lithium cobalt oxide와 graphite 등의 혼합 분말)로 분리하였다. 전극물질에서 $LiCoO_2$와 graphite 분리를 위한 전처리 단계로서 $500^{\circ}C$ 정도의 열처리를 하여 $LiCoO_2$의 표면 성질을 변화시켜 부유선별에 의해 $LiCoO_2$와 graphite의 분리가 가능하도록 하였다. 부유선별 실험 결과 93% 이상의 순도를 가지는 $LiCoO_2$를 92% 이상 회수할 수 있었다.

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Smelting and Refining of Silicon (실리콘의 제련과 정제)

  • Sohn, Ho-Sang
    • Resources Recycling
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    • v.31 no.1
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    • pp.3-11
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    • 2022
  • Silicon is the most abundant metal element in the Earth's crust. Metallurgical-grade silicon (MG-Si) is an important metal that has wide industrial applications, such as a deoxidizer in the steelmaking industry, alloying elements in the aluminum industry, the preparation of organosilanes, and the production of electronic-grade silicon, which is used in the electronics industry as well as solar cells. MG-Si is produced industrially by the reduction smelting of silicon dioxide with carbon in the form of coal, coke, or wood chips in electric arc furnaces. MG-Si is purified by chemical treatments, such as the Siemens process. Most single-crystal silicon is produced using the Czochralski method. These smelting and refining methods will be helpful for the development of new recycling processes using secondary silicon resources.

Mixing and Gas Removal Behavior in Scrap Remelt of Light Metal by Impeller Agitation (임펠러 교반에 의한 경량금속 스크랩 용해로에서의 혼합 및 탈 가스 거동)

  • 한정환;이주한;김석범;변지영;심재동
    • Resources Recycling
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    • v.7 no.3
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    • pp.42-51
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    • 1998
  • Hydrogen in atmosphere can easily dissolve in melt of light metal alloys. Increasing demand for recycling of light metal a alloys has, therefore, focused attention on the removal of hydrogen gas, and alloy addition in melt has become an imporLant r refining process. For this purpose behaviors of mixing and hydrogen degassing in impeller agitated refming vessel with/without barnes were investigated. Flow patterns, mixing time behavior and kinetics of degassing in various agitating conditions were analysed in watet model experiments. And, numerical analysis on turbulent flow pattern in impeller agitated vessels was performed.

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