• Title/Summary/Keyword: 금속계수

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Separation of Alkali and Alkaline Earth Metal Ions using Novel HDBPDA Ion Exchanger and Its Ion Exchange Characteristics (새로운 HDBPDA 이온교환체를 사용한 알칼리 및 알칼리토금속 이온들의 분리와 그의 이온교환특성)

  • Kim, Dong-Won;Kim, Chang-Suk;Choi, Ki-Young;Jeon, Young-Shin;Yoon, Yeo-Hag
    • Journal of the Korean Chemical Society
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    • v.37 no.9
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    • pp.820-825
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    • 1993
  • The ion exchange capacity of HDBPDA ion exchanger, {(4,5) : (13,14)-dibenzo-6,9,12-trioxa-3,15,21-triazabicyclo[15.3.l]heneicosa-(1,17,19)(18,20,21) triene ion exchanger: HDBPDA ion exchanger} was 3.8 meq/g. The distribution coefficients of alkali and alkaline earth metal ions in water and the various concentration of hydrochloric acid were determined. Concentration of hydrochloric acid have almost not influenced on the distribution coefficients of alkali and alkaline earth metal ions, but generally, the distribution coefficient was slightly increased with decrease of concentration of hydrochloric acid. The distribution coefficients of metal ions in water are larger than those of various hydrochloric acid concentrations. Also, alkali and alkaline earth metal ions are separated by column ion exchange chromatography using HDBPDA ion exchange with water as eluent. The distribution coefficents of alkali and alkaline earth metal ions were increased with increase of ionic radii of metal ions.

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An Evaluation of Slip Coefficient in High Strength Bolt Joint using Zn/Al Metal Spray Corrosion Resistance Method (Zn/Al 금속용사 방식공법을 적용한 고력볼트 접합부의 미끄럼계수 평가)

  • Kim, Tae-Soo;Lee, Han-Seung;Tae, Sung-Ho;Ahn, Hyun-Jin;Oh, Sang-Hoon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.11 no.5
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    • pp.114-122
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    • 2007
  • In high strength bolted joints, the corrosion of base material causes the reduction of slip resistance of the joints. In this study, tensile tests on slip-critical joints utilizing Zn/Al metal spraying corrosion resistance method were carried out in order to prevent the corrosion and meet the required mechanical characteristics of joints. In addition, slip coefficient and surface roughness were calculated. The key parameters were surface finishing condition and thickness of coating with the identical geometry in all specimens. From the results, it is found that the slip coefficient of the joints with coated finish after sand blast treatment as well as those of non-coated joints with only sand blast treatment were similar or superior to 0.45, which is a specification criteria of slip coefficient in friction-typed joints.

Study of Tribological Characteristics Between Metallic friction materials and Brake Disk (금속계 마찰재와 제동디스크 간의 마찰특성 연구)

  • Kim, Sang-Ho;Park, Hyung-Chul;Lee, Hi-Sung
    • Proceedings of the KSR Conference
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    • 2008.06a
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    • pp.2080-2093
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    • 2008
  • Disk brake system take charge of maximum braking energy among the mechanical brake systems for high speed train. For this reason, Metallic friction materials and heat resistant steel disk is adopted at disk brake system for high speed train. It was investigated tribological characteristics(friction coefficient, friction stability, wear rate and braking temperature) between some kinds of metallic friction materials and heat resistant steel disk. Cu-based friction material for high speed train have suitable tribological characteristics.

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Effects of Salts on the Partition of Proteins in Poly (ethylene glycol)-Dextran Aqueous Two Phase System (Poly(ethylene glycol)-dextran 수용액 2상계에서 단백질 분획계수에 미치는 금속염의 효과)

  • Lee, Sam-Pin;Lee, Cherl-Ho
    • Korean Journal of Food Science and Technology
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    • v.19 no.2
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    • pp.146-150
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    • 1987
  • The effects of pH and added salts on the partition coefficients of proteins in a polyethylene glycol)-dextran aqueous two-phase system were investigated. The partition coefficients attained the lowest value at the isoelectric point of proteins in an equal volume aqueous two-phase system containing 5% PEG and 9.5% dextran in 5 mM phosphate buffer solution. The coefficients increased dramatically at pH 11; BSA which had highest effective hydrophobicity marked 50-fold increase, while ${\beta}-lactoglobulin$ and ovalbumin which had low hydrophobicity 10-fold increase, respectively. The effect of added salts varied with the pH. The partition coefficient increased by the addition of salt at pH 3.0 but decreased drastically at pH 7.0. The partition coefficient increased in the order of added Li < Na < K at pH 3.0 and decreased in the order of added Li < Na < K at pH 11.0.

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A Study on the Burning Characteristics of N-5 Propellant Embedded with Metal Wires (금속선을 삽입한 N-5복기 추진제의 연소 특성)

  • 유지창;박영규;김인철
    • Journal of the Korean Society of Propulsion Engineers
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    • v.3 no.1
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    • pp.78-85
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    • 1999
  • Burning characteristics of solid propellants embedded with four kinds of metal wires(Ag, Cu, Al, Ni-Cr wire) were studied with varying wire diameters(O.10.8 mm) lot N-5 propellant. It was found that the order of the burning rate increment ratio($r_w$/$r_sb$) was Ag wire > Cu wire > Al wire> Ni-Cr wire which was the same as the order of the magnitude of thermal diffusivity. The burning rate increment ratio($r_w$/$r_sb$) of N-5 propellant was less than that of composite Propellant because of the difference of adiabatic flame temperature and flame structure. When Ag, Cu and Al wire having high thermal diffusivity were embedded in N-5 propellant, the plateau and mesa characteristics of the double base propellant were disappeared, but not disappeared in the case of propellant embedded with Ni-Cr wire due to its poor thermal conductivity.

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Supermodulus Effects of Composition Modulated Metallic Foils (조성조절 금속박막의 Supermodulus 효과)

  • 최일동
    • Journal of Advanced Marine Engineering and Technology
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    • v.16 no.4
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    • pp.31-37
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    • 1992
  • 조성조절한 박막금속합금에서 supermodulus효과가 관찰되었음을 소개하였다. 이 현상을 Fermi표면과 Brillouin 대의 접촉, 그리고 정합변형효과에 의해 설명하였으나 합금계에 따라 어느 한쪽으로만 설명이 가능하며 아직도 명쾌한 해석은 어려운 상황이다. Fermi표면으로 해석한 측면에서 보면 조성조절한 박막에서 측정되는 supermodulus 현상으로 그 합금계의 Fermi표면의 구조와 크기를 예측할 수 있고, 또는 그 반대로, Fermi표면의 조성에 따른 구조와 크기를 알면 supermodulus 효과를 나타내는 합금계를 설계할 수도 있을 것이다. 지금까지는 강성계수의 향상에 대해서만 관찰되었으나 그 반대로 강성계수가 급격히 감소하는 현상도 관찰될 가능성은 남아있어 앞으로의 연구가 기대된다.

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Measuring Intrinsic Damping of Material with Acoustic method (음향학적 방법에 의한 물질의 고유감쇠 측정)

  • 정성수;이용봉;남효덕;신수현
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2004.05a
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    • pp.97-100
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    • 2004
  • 물질의 진동감쇠 특성을 평가하는 대표적인 시험법은 ISO 6721, ASTM E 756 등에서 찾아 볼 수 있다. 이들 규격에서는 비접촉 가진방법으로 전자석 시스템을 사용한다. 하지만 이와 같은 방법은 강판 단독으로의 시험은 간편하나 비자성체 물질이나 도료를 도포 할 경우, 별도의 금속판이 필요하다. 또한 그에 따른 금속판의 감쇠특성을 별도로 평가해야 되며, 접착제에 대한 영향도 고려해야 된다. 이에 대한 보완으로 음압가진 방법을 이용한 비접촉 가진을 강철과 플라스틱에 적용하였다. 실험결과, 강철과 플라스틱의 공진주파수에 따른 손실계수와 탄성계수는 전자석을 이용한 실험결과와 일치하였다.

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Calculation of the Impedance of Waveguide with Two Discontinuities (2개의 불연속 구조물을 갖는 도파관의 임피던스 계산)

  • 김원기;양기덕;김민택;박익모;신철재
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.8 no.5
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    • pp.462-475
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    • 1997
  • In this paper, the accurate characterization of the input impedance of a rectangular waveguide with a conducting post and the other discontinuity is presented using mode matching method and the equivalent transmission line theory. By the proposed method, the input impedance of rectangular waveguide with a conducting post and the other discontinuity as a function of the radius and height of the post, the reflection coefficient of the other discontinuity, and the distance between the post and the other discontinuity is calculated. The simulated result shows good agreement with the experimental result by Marcuvitz.

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Study on Non-contact Detection of Surface Cracks of the Metals Using an Open-Ended Coaxial Line Sensor at X-band (마이크로파 X-밴드에서의 종단 개방 동축선 센서를 이용한 금속표면균열의 비접촉 검출 연구)

  • Yang, Seung-Hwan;Kim, Dong-Seok;Kim, Ki-Bok;Kim, Jong-Heon;Kang, Jin-Seob
    • Journal of the Korean Society for Nondestructive Testing
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    • v.32 no.2
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    • pp.192-197
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    • 2012
  • In this paper, a non-contact microwave technique was presented to detect the surface crack of the metals. An open-ended coaxial cable line was used as a sensor at 11 GHz, and the reflection coefficients were measured by scanning along the metal surface including artificial surface cracks. A parameter, the K value which was defined as the difference between maximum and minimum reflection coefficients, was measured and used to estimate the crack depth. A linear relationship between the K value and crack depth was found. This study showed that non-contact detection of the surface cracks of metals is possible using the open-ended coaxial line sensor at X-band.

비대칭 마그네트론 스퍼터링 장치에 의한 Ti 나노금속 함량에 따른 탄소박막의 물리적, 전기적 특성

  • Park, Yong-Seop;Lee, Jong-Deok;Hwang, Hyeon-Seok;Hong, Byeong-Yu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.444-444
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    • 2012
  • 본 연구에서는 흑연(graphite)과 티타늄(titanum; Ti) 타겟이 양쪽에 부착되어 있는 비대칭 마그네트론 스퍼터링 장치를 이용하여 Ti가 도핑되어진 탄소(a-C:Ti) 박막을 증착하였다. 흑연 타겟의 파워는 고정하고 Ti 타겟 파워를 증가시켜 탄소 박막내에 Ti의 함량을 증가시켰으며, Ti 금속 함량에 따른 탄소박막의 경도와 마찰계수, 표면의 거칠기, 접촉각 등의 물리적 특성과 비저항 등 전기적 특성을 고찰하였으며, XPS와 라만등을 이용하여 a-C:Ti 박막의 구조적 특성을 고찰하여 Ti 금속 함량에 따른 구조적 특성과 물리적 특성, 전기적 특성과의 관계를 규명하였다.

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