• Title/Summary/Keyword: 글리세린

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Experimental Study on Bubble Deformation of Two-Phase Fluids (이상(Two-phase) 유체의 변형거동에 대한 실험적 연구)

  • 김시조;황덕철;임영빈
    • Journal of the Korea Institute of Military Science and Technology
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    • v.2 no.2
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    • pp.234-241
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    • 1999
  • 본 논문에서는 얇은 직사각형 단면 형상을 가지는 세 가지 서로 다른 유동로 안에서 움직이는 공기버블의 변형 거동에 대한 실험을 수행하였다. 압력 차이로 유체는 유동되며, 유동장을 따라서 변형하는 버블의 정상상태 모양을 관찰하였다. 벽면효과를 알아보기 위해 세 종류의 얇은 사각단면을 사용하였으며, 두 가지 종류의 작동 유체, 버블의 초기 크기, 작동 유체의 유량 등을 변화시켰을 때 이에 대한 공기 버블의 변형을 체계적으로 관찰하고 이들의 관계를 고찰하였다. 실험데이타를 정량화하여 캐필러리 수에 대한 버블의 무차원 속도비와의 관계를 상세하게 고찰하였다. 글리세린의 경우는 항상 버블 선단부의 곡률이 후단의 곡률보다 더 작게 나타났으며 실리콘 오일의 경우와 반대 경향이 관찰되었다. 두 경우 모두 캐필러리 수에 대한 속도비와 세장비 값은 1 보다 큰 값을 가졌다. 실리콘 오일의 경우는 주어진 Ca 수에 대하여 속도비가 글리세린의 경우보다 더 크게 나왔으며 버블 크기에 따른 속도비 분산도가 더 조밀하게 나타났다. 사각 단면 폭이 감소할수록 벽면 효과는 증대되었으며 같은 폭에 대해서는 버블 변형이 축소관의 경우가 가장 크게 나타났다.

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Release Characteristics of Silver Sulfadiazine from Dextran-based Polymeric Matrices (Dextran을 기초로 한 고분자 Matrix로 부터의 Silver Sulfadiazine의 방출 특성)

  • Na, Jae-Woon;Park, Yung-Hoon;Kim, Sung-Hyun;Kim, Sun-Il
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.735-742
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    • 1996
  • Polymeric matrices were prepared with dextran and silver sulfadiazine by adding glycerine as a plasticiser. Namely, the release rate of the drug from the polymeric matrix formulations in dissolved phases was determined in a phosphate buffer solution. The results were as follows : The drug release time was delayed as drug loading contents increased, whereas it decreased as the glycerine concentration increased. The drug release time was not changed with varying the molecular weight of the dextran. The apparent release rate constant (k) increased as the composition of silver sulfadiazine and glycerine was increased. But the apparent release rate constant (k) was not changed with increasing molecular weight of the dextran.

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A Case of Ischemic Colitis Presenting as Bloody Diarrhea after Glycerin Enema in a Patient on Modified Fasting Therapy (절식요법 중 글리세린 관장 직후 혈성 설사로 발현한 허혈성 대장염 1예)

  • Choi, Hyo-Jeong;Park, Hyun-Gun;Maeng, Tae-Ho;Yoo, Duk-Joo;Kim, Sung-Soo;Chung, Won-Suk
    • Journal of Korean Medicine Rehabilitation
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    • v.23 no.2
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    • pp.185-191
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    • 2013
  • Case of ischemic colitis after enema for bowel cleansing have been rarely reported, but there has been no case report of a patient on modiefied fasting therapy. A 26-year old male patient with obesity admitted Korean medical hospital of Kyung Hee university for losing weight. He is on a special diet called modiefied fasting therapy, only took the fermented herbal drink. At 2nd day, he received an enema for bowel cleansing. A few hours after enema, he had a bloody diarrhea with lower abdominal pain. His colonoscopic and histologic findings presented ischemic colitis. He was advised to fast for two days and couldn't complete his diet program. We suggest 4 possible reasons : Increased intraluminal pressure by enema, vascular spasm caused by room-temperature glycerin solution colder than intraluminal temperature, predisposition to bleeding disturbances by taking selective serotonin reuptake inhibitor(SSRI) for depression history and mucosal injury by osmotic effect of glycerin solution itself. For reducing the risk of bowel cleansing, glycerin enema should be carefully prescribed and practiced concerning the condition of each patient.

Study on free and bond glycerines in Biodiesel from PKO(Palm Kernel Oil) and coconut oil (PKO 및 코코넛유래 바이오디젤 중 글리세린함량 분석 방법 개선 연구)

  • Lee, Don-Min;Park, Chun-Kyu;Ha, Jong-Han;Lee, Bong-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.2
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    • pp.348-361
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    • 2015
  • To reduce the effects of greenhouse gas (GHG) emissions, the government has announced the special platform of technologies as parts of an effort to minimize global climate change, and the government distributed biodiesel since 2006 as the further efforts. Although there are some debates about some quality specifications and unbalanced of source (44% from palm oil), more than 400kton/year of biodiesel was produced in 2013. Moreover the amounts will be increased when the RFS is activated. To solve the unbalanced situation and to achieve the diversity of feeds, it is essential that many researches should be considered. Especially, free and bond glycerines are one of the important properties seriously affected to the combustion system in vehicle & cold properties. Previous method (KS M 2412) couldn't cover the biodiesel derived from lauric oil($C_{12:0}$) such as PKO (Palm Kernel Oil), Coconut oil because those compositions are lighter than other conventional biodiesel sources. In this study, we review the existed method and figure out the factors should improve to analysis the glycerine from PKO and Coconut oil biodiesel. Modifying the analysis conditions to enhance the resolution and change the internal standards to avoid the overlapped- peaks between Capric acid ME ($C_{10:0}$) and standard#1(1,2,4-butantriol). From this revised method, we could solve the restrictions of previous methods. And check the possibility of new method to analyze the glycerine in biodiesel regardless of sources.

Changes in the Membrane Properties of Zygosaccharomyces rouxii in Response to Osmotic Stress (삼투압 스트레스에 대응하는 Zygosaccharomyces rouxii의 막성질의 변화)

  • 구니아기호소노;류병호
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.22 no.1
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    • pp.101-107
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    • 1993
  • Zygosaccharomyces rouxii is a salt-tolerant yeast which plays an important role during the ripening stage of soy sauce fermentation. Z. rouxii used in the experiment could grow in YPD (1 % yeast extract, 2% peptone and 2% glucose, pH5.0) medium with 18% (w/v) NaCl, whereas Saccharomyces cerevisiae could only grow in YPD medium with less than 8% NaCl. In the presence of 15% NaCl, Z. rouxii accumulates a large amount of glycerol as a compatible solute within the cells in the exponential phase. It is a characteristic of salt-tolerant yeasts. From the chemical analyses on membrane lipid fluidity, the membrane structure of the cells grown in 15% NaCl was suggested to become more rigid and its fluidity was decreased to keep glycerol within the cells in response to surrounding medium with high concentrations of salt.

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Effect of glycerin on the surface hardness of composites after curing (글리세린이 복합레진의 중합 후 표면경도에 미치는 영향)

  • Park, Hyun-Hee;Lee, In-Bog
    • Restorative Dentistry and Endodontics
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    • v.36 no.6
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    • pp.483-489
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    • 2011
  • Objectives: The purpose of this study was to examine the effect of glycerin topical application on the surface hardness of composite after curing. Materials and Methods: A composite (Z-250, 3M ESPE) was packed into a disc-shaped brass mold and light cured according to one of the following protocols. Group 1 (control) was exposed to air and light cured for 40 sec, group 2 was covered with a Mylar strip and light cured for 40 sec, group 3 was surface coated with glycerin and light cured for 40 sec, and group 4 was exposed to air and light cured for 20 sec and then surface coated with glycerin and cured for additional 20 sec. Twenty specimens were prepared for each group. The surface hardnesses of specimens were measured with or without polishing. Five days later, the surface hardness of each specimen was measured again. Data were analyzed by three-way ANOVA and Tukey's post hoc tests. Results: The surface hardnesses of the unpolished specimens immediately after curing decreased in the following order: group 2 > 3 > 4 > 1. For the polished specimens, there was no significant difference among the groups. Within the same group, the hardness measured after five days was increased compared to that immediately after curing, and the polished specimens showed greater hardness than did the unpolished specimens. Conclusions: The most effective way to increase the surface hardness of composite is polishing after curing. The uses of a Mylar strip or glycerin topical application before curing is recommended.

Studies on the Preparation and the Properties of Chitosan Oligosaccharide and its Derivatives (키토산 올리고사카라이드 및 그 유도체의 제조와 특성에 관한 연구)

  • Ha, Byeong-Jo;Kim, Jun-O;Lee, Ok-Seop
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.23 no.2
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    • pp.48-62
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    • 1997
  • Chitosan oligosaccharides having aldehyde group at reducing end were prepared by oxidative-deamination reaction of chitosan by using sodium nitrite, and the resulting aldehyde group was reduced to 2, 5-anhydro-D-mannitol group. The obtained chitosan oligosaccharides showed an average degree of polymerization 2~3 by gel permeation chromatography analysis. It was highly soluble in hydrophilic solvents and thermally stable. N, N-diacyl, O-acyl chitosan oligosaccharides were obtained from the reaction between chitosan oligosaccharides and acyl chloried under dimethylaminopyridine. From differential scanning calorimetric measurement, N, N-dilauroyl, O-lauroyl chitosan oligosaccharides showed mesophase region, which was confirmed by polarized microscope as a thermotropic liquid crystalline state. X-ray diffraction pattern revealed that N, N-dilauroyl, O-lauroyl chitosan oligosaccharedes were highly crystalline, whereas chitosan oligosaccharides were not.

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A Study on the Development of the Charcoal with Low Carbon Monoxide Emission using Biomass Combustion Improver (바이오매스 조연제를 이용한 CO저감형 착화탄 개발에 대한 연구)

  • Kim, Seunghee;Lee, Yeonkyung;Lee, Junseok;Jeon, Chunghwan
    • Journal of Energy Engineering
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    • v.25 no.3
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    • pp.9-17
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    • 2016
  • In this study, a method for CO reduction using char-coal combustions was developed with lignin and glycerin as combustion improvers. The relationship between CO emission and the combustion improvers was confirmed by measuring the CO concentration. The experiment to determine the combustion characteristics was conducted using glycerin, which shows high combustibility at low temperatures, impregnated with lignin, which has a specific surface area. The combustibility, volatility, and CO concentration were measured using thermo-gravimetric analysis(TGA), and gas chromatography-mass spectrometry(GC-MS). This study presents the optimal CO reduction ratio, which occurred when the combustible material contained a 20% blend of combustion improvers. This resulted in a 20-30% CO reduction rate compared to that achieved with normal char-coal.

A Study on Absorber in Absorption Heat Pump with Methanol-Glycerine System as a Working Fluid (메탄올-글리세린계를 작동유체로 하는 흡수열펌프에서 흡수기 연구)

  • Min, Byong-Hun
    • Applied Chemistry for Engineering
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    • v.17 no.1
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    • pp.111-117
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    • 2006
  • The improvement of energy conservation mandates decrease consumption of fossil fuels and minimize negative impacts on the environment, which originates from large cooling and heating demand. The absorption heat pump technology has a large potential for energy saving in this respect. Adsorption heat pump is a means to upgrade waste heat without addition of extra thermal energy. The increase of absorbed amount is of great importance for absorption heat pump cycle. In this study, in order to improve the performance of absorber, the absorbers of two different types have been investigated using methanol-glycerine as a working fluid. The former was tangential feed of liquid phase without spiral tube in the absorber and the latter was with spiral tube in the absorber. The latter was found to be more effective in enhancing the mass and heat transfer to increase the absorption performance.

Biodiesel Production by Transesterification of Crude Soybean Oil with Methanol (대두원유의 전이에스테르화 반응에 의한 바이오디젤 제조)

  • Kim, Deog-Keun
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.533-536
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    • 2006
  • 재생 가능한 자원인 동 식물성 기름으로부터 제조되는 수소용 연료 바이오디젤은 낮은 대기오염 배출과 $CO_2$ Neutral 특성으로 환경 친화적인 연료로 인정을 받으며 전 세계적으로 그 생산량이 급격히 증가하고 있다. 바이오디젤 생산 기술에는 직접이용법, 마이크로 에멀젼법, 열분해법, 에스테르화법, 초임계 메탄올 이용 생산법 등이 있으며 현재의 대부분의 상용 공정은 전이에스테르화법에 근거하고 있다. 이 공정은 크게 나누어 원료 유지 물질의 전처리 단계, 촉매를 사용하여 알콜과 에스테르화시키는 단계, 그리고 생성된 바이오디젤/글리세린의 분리와 정제 단계로 이루어지며 각 단계의 세부기술은 바이오디젤 생산비에 직접적인 영향을 미친다. 본 연구에서는 대두 원유의 전처리 반응, 전처리된 대두원유의 전이에스테르화 반응, 그리고 분리 및 정제 공정의 운전 변수들의 영향에 대한 연구결과와 본 연구를 통해 확립된 생산 공정으로 생산한 연료 grade의 바이오디젤 연료 물성 평가하였다.

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