• Korean Chemical Engineering Research
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• v.46 no.2
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• pp.423-429
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• 2008

Currently, Ash-free clean coal producing process by solvent extraction is under development. The produced ash-free clean coal can be directly combusted in a gas turbine which results in substantial improvement of power generation efficiency. However, the clean coal produced by the solvent extraction still contain trace amount of alkali metal which may cause corrosion on turbine blades during the direct combustion. In present work ${\alpha},{\beta}$-metal (Zr and Ti) phosphates and H-Y zeolite were synthesized and their ion exchange characterizations were investigated for the application on alkali metal removal for clean coal production. $Na^+$ ion removal capacities of the metal phosphates and H-Y zeolite were measured and compared in both aqueous solution (100 ppmw, $Na^+$) and coal dissolved N-methyl-2-pyrrolidone (NMP, 12 ppmw $Na^+$) at elevated temperature. In aqueous solution, the ${\beta}$ form metal phosphates showed very high ion exchange capacities compared to ${\alpha}$ form. ${\beta}$ form metal phosphates also showed higher $Na^+$ removal capacities than H-Y zeolite. In ion exchange medium of NMP, all the ${\alpha}$ form metal phosphates showed over 90% of $Na^+$ ion removal efficiency in the temperature range of 200 to 400 while that of H-Y zeolite decreased as a half when the temperature was over 350. In addition, the regenerated metal phosphates by acid treatment showed no sign of degradation in $Na^+$ removal efficiency. Among the metal phosphates used, $Zr_{0.75}Ti_{0.25}(HPO_4)_2$ showed the best performance in $Na^+$ removal and is expected to be the most suitable inorganic ion exchanger for the alkali metal removal process.

• Journal of the Korean Chemical Society
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• v.37 no.2
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• pp.191-198
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• 1993

The crystal structures of $Cd_{6-}A$ evacuated at $2{\times}10^{-6}$ torr and $750^{\circ}C$ (a = 12.204(1) $\AA$) and dehydrated $Cd_{6-}A$ reacted with 0.1 torr of Cs vapor at $250^{\circ}C$ for 12 hours (a = 12.279(1) $\AA$) have been determined by single crystal X-ray diffraction techniques in the cubic space group Pm3m at $21(1)^{\circ}C.$ Their structures were refined to final error indices, $R_1=$ 0.081 and $R_2=$ 0.091 with 151 reflections and $R_1=$ 0.095 and $R_2=$ 0.089 with 82 reflections, respectively, for which I > $3\sigma(I).$ In vacuum dehydrated $Cd_{6-}A$, six $Cd^{2+}$ ions occupy threefold-axis positions near 6-ring, recessed 0.460(3) $\AA$ into the sodalite cavity from the (111) plane at O(3) : Cd-O(3) = 2.18(2) $\AA$ and O(3)-Cd-O(3) = $115.7(4)^{\circ}.$ Upon treating it with 0.1 torr of Cs vapor at $250^{\circ}C$, all 6 $Cd^{2+}$ ions in dehydrated $Cd_{6-}A$ are reduced by Cs vapor and Cs species are found at 4 crystallographic sites : 3.0 $Cs^+$ ions lie at the centers of the 8-rings at sites of $D_{4h}$ symmetry; ca. 9.0 Cs+ ions lie on the threefold axes of unit cell, ca. 7 in the large cavity and ca. 2 in the sodalite cavity; ca. 0.5 $Cs^+$ ion is found near a 4-ring. In this structure, ca. 12.5 Cs species are found per unit cell, more than the twelve $Cs^+$ ions needed to balance the anionic charge of zeolite framework, indicating that sorption of Cs0 has occurred. The occupancies observed are simply explained by two unit cell arrangements, $Cs_{12}-A$ and $Cs_{13}-A$. About 50% of unit cells may have two $Cs^+$ ions in sodalite unit near opposite 6-rings, six in the large cavity near 6-ring and one in the large cavity near a 4-ring. The remaining 50% of unit cells may have two Cs species in the sodalite unit which are closely associated with two out of 8 $Cs^+$ ions in the large cavity to form linear $(Cs_4)^{3+}$ clusters. These clusters lie on threefold axes and extend through the centers of sodalite units. In all unit cells, three $Cs^+$ ions fill equipoints of symmetry $D_{4h}$ at the centers of 8-rings.

• 한국HCI학회:학술대회논문집
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• 2006.02a
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• pp.1283-1288
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• 2006

실감모델링(Immersive modeling)이란 모델링하는 사람이 물체의 특성을 고려하여 오감을 활용하여 모델링하는 것을 의미한다. 실감모델링을 위한 오감 중에서 시각은 모델링하는 사람에게 가장 영향을 많이 주기 때문에 실제와 같은 색상과 형상을 생성하는 것이 중요하다. 그러나 가상현실을 위한 데이터를 실시간으로 다루기 위해 많은 데이터를 사용할 수 없고 처리 과정이 단순해야 하기 때문에 시각데이터를 획득하는 과정에도 이를 고려해야 한다. 그 중에서 반짝이는 특성을 가진 물체의 색을 정확히 표현하기 위한 방법으로 색상선(color line)을 사용한다. 색상선은 반짝이는 특성의 표면의 색을 이색성반사 모델(dichromatic reflection model)로 간주하면 색 특성을 표현하는 선이 생성되게 된다. 본 연구는 반짝이는 물체로부터 색상선을 추출하기 위한 방법으로 노출 시간이 다른 여러 장의 이미지로부터 색상을 추출하는 방법을 제안한다. 노출 시간이 다른 이미지를 사용함으로써 한 장에 의해 분류하기 어려운 색상도 분류 가능하고 하이라이트가 발생하여 색상이 왜곡된 경우도 본래 색이 어떤 색상인지 추정되기 때문에 정확한 색상 추출이 된다. 본 연구에서는 3차원 측정 장비를 이용하여 3차원 형상과 색상이 동시 추출된 모델을 이용하여 렌더링된 결과와 제안된 방법으로 추출된 색상을 적용하여 렌더링된 결과를 비교할 것이다.

• Journal of the Korea Society of Computer and Information
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• v.25 no.3
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• pp.19-26
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• 2020

Steel production requires high-quality surfaces with minimal defects. Therefore, the detection algorithms for the surface defects of steel strip should have good generalization performance. To meet the growing demand for high-quality products, the use of intelligent visual inspection systems is becoming essential in production lines. In this paper, we proposed a ShuffleDefectNet defect detection system based on deep learning. The proposed defect detection system exceeds state-of-the-art performance for defect detection on the Northeastern University (NEU) dataset obtaining a mean average accuracy of 99.75%. We train the best performing detection with different amounts of training data and observe the performance of detection. We notice that accuracy and speed improve significantly when use the overall architecture of ShuffleDefectNet.

• Applied Chemistry for Engineering
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• v.4 no.3
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• pp.488-496
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• 1993

Natural zeolites have recently been the subject of intensive research due to their versatilities in possible industrial applications. Among several different types of domestic natural zeolites, clinoptilolite, is one of the highly prospective domestic natural zeolites. However, it is always possible for heulandite, the isostructure of clinoptilolite, to coexist with clinoptilolite. Unfortunately, heulandite is thermally very unstable restricting its application to industrial process. In this paper, the effects of ion exchanges and heat-treatments on the thermal stability for domestic natural zeolite, heulandite are described. Two different ion-exchanging experiments were carried out followed by heat-treatments at different temperatures. X-ray, IR and AA spectroscopic analyses showed the enhancements in thermal stabilities of heulandite by $Na^+$ cation exchanges.

• Applied Chemistry for Engineering
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• v.2 no.1
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• pp.1-11
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• 1991

Xenon-129 NMR technique has been developed since 1980 as a new method for the characterization of microporous materials such as zeolites, activated carbons and alumina by using chemical shift and linewidth variations in $^{129}Xe$ NMR of adsorbed xenon gas. This NMR technique has been known to be very effective to probe the locational and the chemical changes of the supported metallic species as well as the physicochemical change of the support material. Recently, this method has been successfully applied for the characterization of amorphous materials such as activated carbons, silica and alumina. Basic principles, experimental techniques and recent applications of the $^{129}Xe$ NMR method for the study of heterogeneous catalysts are introduced in this paper.

• Archives of design research
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• v.16 no.2
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• pp.15-22
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• 2003

This is a study on the roles in the association of sound as subtext for animation. On this study, it will be helpful to develop sound concepts and to create animations with creativity. For animation without sound can be produced as an artistic purpose, however, most animations are created with sound. It is not means that sound is less important than visual in animations. Sound is also one of significant element to create animations. Sound have many important rolls for subtext such as parts of action, leitmotif, characteristic, time, ethnic, localization in the animations. It will be analyzed two animations such as Shrek (DreamWorks Pictures production/ Director: Andrew Adams) and Monsters Inc. (Walt Disney Pictures/ Director: Peter Doctor).

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2000.10a
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• pp.153-156
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• 2000

The remarkable progress of electronics and radio communications technology has made our life abundant. On the other hand, the countermeasure of EMC becomes more important socially according to the increased use of electromagnetic waves. It had been required that the absorbing ability of an electromagnetic wave absorber is more than 20 dB, the bandwidth of which is required through 30 MHz to 1,000 MHz for satisfying the international standard about an anechoic chamber for EMI/EMS measurement. From November of 1998, however, the CISPR11 has accepted the extended frequency band from 30 MHz to 18 GHz in the bandwidth of EMI measurement. In this paper, we proposed the cutting com-shaped type satisfying the above requirments and carried out broadband design using the equivalent material constants method. Moreover, we have fabricated it and compared its characteristics with simulated one.

• Solar Energy
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• v.17 no.3
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• pp.59-66
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• 1997

The present study adopted the PTV method for the velocity acquisition. The system consists of an image grabber built-in a personal computer and a laser-based sheet light projector and particle identification softwares. Velocity vectors are obtained, by PTV and they are used as velocity components for Poisson equation for pressure. Related boundary conditions and no-slip condition at solid wall and the linear velocity extrapolation on the upper side of cavity are well examined for the present study. For calculation of pressure, resolution of grid is basically $40{\times}40$ and 2-dimensional uniform mesh using MAC staggered grid is adopted. The result of experiment reveal that, newly suggested measuring method is capable of estimating pressure and velocity distribution of flow field reasonably.

• The Journal of the Petrological Society of Korea
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• v.22 no.4
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• pp.299-305
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• 2013

It is well known that the Hongcheon iron-rare earth deposit is composed of carbonatite-phoscorite complex. We conducted zircon U-Pb age determination for the gneissic country rocks of this deposit. As the result we obtained ca. 1830 Ma, which is somewhat younger than igneous and metamorphic ages of ca. 1870 Ma generally reported from the Gyeonggi massif, suggesting further investigations for the timing and evolution of the Paleoproterozoic activities of the Gyeonggi massif.