• Title/Summary/Keyword: 구조진동

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고에너지 이온빔에 의한 고분자의 micro-hardness 특성변화

  • Choi, Han-Woo;Woo, Hyung-Joo;Hong, Wan;Kim, Gi-Dong;Kim, Jun-Gon;Kim, Young-Seok;Lee, Sam-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.112-112
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    • 1999
  • 고분자 표면에 MeV급 이온을 주입하게 되면 화학적, 광학적, 물리적, 전기적 특성 등 기존의 재래식 공정으로는 불가능한 다양한 특성변화가 일어나게 된다. 본 실험에서는 이온 조사에 따른 micro-hardness의 변화에 중점을 두어 관찰하였다. 수 MeV로 가속시킨 Cl과 C 이온을 Kapton, Teflon, PMMA에 조사량을 바꾸어가며 조사하였다. 이때 조사 전후 고분자 시료의 표면 경도는 depth-sensing nanoindentation technique (Nano Indenter II, USA)을 이용하여 측정하였다. 측정깊이는 극표면 효과와 기측효과의 영향을 무시할 수 없는 100nm로 결정하였다. 또한 이와 같은 경도변화를 규명하기 위하여 각각의 시료에 대해 FTIR, Raman, UV-VIS, RBS, XPS 스펙트럼을 측정하였으며, 조사중에 발생되는 가스상 분자들을 RGA를 이용하여 측정하였다. 1 MeV Cl 이온을 Kato에 4x1015ions/cm2 조사하면 경도가 0.35 GPa에서 7.1GPa로 약 20배 정도 증가하게 되며, 이 경도는 stainless steel 경도 2~3 GPa, martensite steel 8~12와 비교하여 보면 상당히 높은 수준임을 알 수 있다. Teflon과 PMMA 시료의 경우 1MeV Cl 이온 4X1015ions/cm2를 조사시키면 각각 경도가 0.31GPa에서 4.1a, 0.30 GPa에서 3.9GPa로 변화하였으며 Kapton에 비하여 상대적으로 경도의 변화가 적음을 알 수 있었다. 이온 주입된 Kapton의 경우 FT-IR측정에 의하여 이온 조사량이 증가함에 따라 C=O 진동, 이미드그룹의 CONH, tertiary amine의 C-N 흡수 피크가 감소되며, 1X1014ions/cm2 이상의 양이 조사되어야 개질변화가 일어남을 알 수 있었다. XPS 측정 결과 Kapton에 조사되는 이온양이 증가할수록 C=O, C-O 및 C-N의 탄소는 감소하고 페닐고리 탄소가 증가함을 알 수 있었다. 또한 이온 조사 중 측정한 RGA에서도 CO 가스가 대량 방출되는 현상을 관찰하였으며 FTIR 및 XPS에서의 C=O 결합의 감소와도 일치하였다. RBS에 의한 CNO 원소의 변화에서도 다른 원소보다 O의 감소가 현저하게 나타남을 확인하였다. UV-VIS 측정을 통해 조사 이온량에 따라 에너지 준위가 변동하여 흡수스펙트럼이 장파장으로 확대됨을 알 수 있었으며, 이는 공액 2중 결합의 형성에 의한 $\pi$-전자 및 기타 결함에 기인한다. PMMA 및 Teflon의 경우 FTIR 측정에 의하여 이온 조사됨에 따라 function group 들의 peak가 세기가 감소되면서 완만해지는 경향을 보이며 원래의 구조를 상실하게 된다. PMMA와 Teflon은 이온 조사가 되면 가교형서보다는 사슬절단이 주로 일어나므로 가교형성이 잘 일어나는 Kapton보다는 상대적으로 경도의 증가가 적음을 알 수 있었다.

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A Study on Integraion Method for Improvement of Numerical Stability of Meshfree Method (무요소법의 수치적 안정성 개선을 위한 적분기법 연구)

  • Kang, JaeWon;Kang, Da Hoon;Cho, Jin Yeon;Kim, Jeong Ho
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.46 no.3
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    • pp.210-218
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    • 2018
  • In order to generate meshes automatically for finite element analysis of complex structures such as aircraft, a large number of triangular elements are typically created. However, triangular elements are less accurate than rectangular elements, so it is difficult to obtain a reliable solution. This problem can be improved through the meshfree method using the back cell integration. However, this method also causes some problems such as over-use of the integration points and inefficiency of the integral domain. In order to improve these problems, a method of performing integration by setting the integral area based on a node basis has been proposed, but in the case of incompressible material problems, the numerical accuracy deteriorates due to the vibration phenomenon of the solution. Therefore, in this paper, the modified meshfree method is proposed which sets the integral domain as an element domain instead of the nodal domain, and the proposed method improves the numerical instability caused by the conventional meshfree method without decreasing the accuracy regardles of the shape of integral domain. The effectiveness of the modified meshfree method is verified by using 2-D examples.

Mineralogical Characteristics of Calcite observed in the KAERI Underground Research Tunnel (고준위폐기물 지하처분연구시설(KURT)에서 관찰되는 방해석의 광물학적 특징)

  • Lee, Seung-Yeop;Baik, Min-Hoon;Cho, Won-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.4 s.50
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    • pp.239-246
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    • 2006
  • KAERI Underground Research Tunnel (KURT) was recently constructed through the site investigation from the yea. of 2003 at KAERI site, Dukjin-dong, Yuseong-gu, Daejeon city. The geo-logic setting of the site has been slightly metamorphosed. There are small fractures developed in the rock and several kinds of secondary filling minerals exist in the fractures. We examined mineralogical characteristics of fracture-filling calcite, which is not only largely distributed, but also can significantly affect the radionuclides migration. The calcite is found along fractures like other secondary minerals, forming thick veins in part. Most calcite-filled fractures contain quartz, iron oxides, and dolomite as minor minerals. The calcite crystals show an characteristic appearance with an uniformly oriented growth, coated with goethite on the edge and the etch-pit sites of their surface. Some calcite crystals have been newly formed by the precipitation of elements dissolved from the tunnel shotcrete wall, and their morphology changed according to the chemistry and flow of groundwater. The calcite can modify the groundwater chemistry and significantly affect the sorption behavior of radionuclides. The characteristic crystal structure and surface morphology of the calcite examined in the KURT site will be used as important basic data for the radionuclide migration experiment in the future.

The Sewol Ferry Disaster and Fire-service Environment Changes (세월호사고와 소방서비스환경변화)

  • Kim, Jin-Dong;Cha, Jong-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.12
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    • pp.321-328
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    • 2017
  • The effects of the Sewol ferry disaster have infiltrated into various fields, such as politics, the economy, and social fields in Korea, and the population's consciousness of the importance of safety has been strengthened by the disaster. The purpose of, this study is to empirically verify whether there has been any change in the fire service environment following the Sewol ferry disaster. Such a change would be expected to have produced a change in the consciousness of the government about safety and increased the level of support. This study sets out five research hypotheses and verifies their adoption. The years studied are those before and after the accident occurred, viz. 2013 and 2015, respectively, and the main statistical technique is the t-test. The main results of this study are as follows. First, there was no significant difference in the fire-service demand between the two years. Second, the fire-service budget showed a significant difference between the two years. Third, the regional resources facilities tax showed a significant difference between the two years. Fourth, the fire-service budget considering the fire-service demand showed no statistically significant difference. Fifth, the fire service-demand considering (the number of) fire-fighters was significantly different in the rescue and emergency medical services between the two years. Sixth, the fire service-demand considering fire-equipment showed no significant difference between the two years.

A Simulation Study of Artificial Cochlea Based on Artificial Basilar Membrane for Improving the Performance of Frequency Separation (인공기저막 기반 인공와우의 주파수 분리 성능향상을 위한 인공기저막 전산모사)

  • Kim, Tae-In;Chang, Seong-Min;Song, Won-Joon;Bae, Sung-Jae;Kim, Wan-Doo;Cho, Maeng-Hyo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.4
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    • pp.457-463
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    • 2012
  • The basilar membrane (BM), one of organs of cochlea, has the specific positions of the maximum amplitude at each of related frequencies. This phenomenon is due to the geometry of BM. In this study, as the part of the research for the development of fully implantable artificial cochlea which is based on polymer membrane, parametric studies are performed to suggest the desirable artificial basilar membrane model which can detect wider range of frequency separation. The vibro-acoustic characteristics of the artificial basilar membrane are predicted through finite element analysis using commercial software Abaqus. Simulation results are verified by comparing with experimental results. Various geometric shapes of the BM and residual stress effects on the BM are investigated through the parametric study to enable a wider detectable frequency separation range.

Low Frequency Squeal Noise Reduction using Mode Participation Factor in Complex Eigenvalue Analysis (복소고유치해석에서 모드기여도 인자를 이용한 저주파 스퀼소음 저감)

  • Park, Jeong Min;Kim, Hyun Soo;Yoon, Moon Young;Boo, Kwang Seok;Kim, Heung Seob
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.3
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    • pp.325-331
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    • 2013
  • In this study, a complex eigenvalue analysis is implemented to verify the unstable mode of a brake system using ABAQUS software. The component participation factors and component modal participation factors are used to analyze the total contributions from each component and each component mode to a particular unstable system mode. This study shows that the 1.4-kHz unstable system mode comes from mode coupling between the 2nd nodal diametric mode and 3rd lateral axial mode (LAM) in the baseline model. A sensitivity analysis with a linking index is performed to prevent the mode coupling of the component modes. This linking index analysis shows the optimum mass loading position to move away the natural frequency of the 3rd LAM, which contributes to the unstable mode. Finally, a complex eigenvalue analysis is implemented with mass loading in the tie bar position, and no unstable system mode is generated in the low-frequency range (below 2 kHz).

Characterization of Synthetic Na-beidellite (합성 Na-베이델라이트의 광물특성)

  • Ryu Gyoung-Won;Chae Soo-Chun;Bae In-Kook;Choi Sang-Hoon;Jang Young-Nam
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.2
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    • pp.109-115
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    • 2005
  • Beidellite, a member of the smectite group, was synthesized hydrothermally from dickite. Physical and chemical properties of the synthetic Na-beidellite were characterized by the analytical methods of XRD, IR, TG, DTA, EDS, XRF and ICP. The result of Greene-Kelly test indicates that the synthesized smectite is Na-beidellite. IR spectrum of synthesized beidellite exhibited Al-O-H bending vibration at $818\;cm^{-1}\;and\;770\;cm^{-1}$ which was observed particularly in pure beidellite. TGA analysis revealed that the synthesized Na-beidellite comprises $16\;wt\%$ of water. DTA curve showed an endothermic peak at $117^{\circ}C$ due to dehydration reaction and peaks at $482^{\circ}C$ and $685^{\circ}C$ due to dehydroxylation reaction. The clay mineral was transformed to mullite and cristobalite at the temperature of $1028^{\circ}C$. The CEC value, Methylene Blue test and swelling capacity was determined to be $116\~118\;cmol/kg,\;84\~91\%,\;29\~32\;mL/2g$, respectively. The chemical composition of the synthesized phase was identified as $Na_{0.5}Al_{2.5}Si_{3.5}O_{10}(OH)_2$ from EDS and XRF analyses.

Synthesis and Magnetic Properties of $Fe-TiO_2$ Nanocomposite Powders by Mechanical Alloying (기계적 합금화법에 의한 $Fe-TiO_2$ Nanocomposite의 합성 및 자기적 성질)

  • 홍대석;이성희;이충효;김지순;권영순
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2002.11a
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    • pp.63-63
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    • 2002
  • 현재 기계적 합금화법에서는 주로 합금을 구성하는 성분원소 분말을 불활성분위기에서 볼밀처리 함으로써 함금화를 시키거나 모합금에 산화물을 분산시켜 복합화시키는 공정을 통하여 각종 화합물, 비정질상 및 과포화고용체등의 준안정상의 합성 뿐만이 아니라 초미세조직의 생성에 관한 폭 넓은 분야의 연구가 행하여지고 있다. 한편 MA에서는 볼멀처리중 기계적 에너지의 투여에 의하여 실제 반응온도보다 낮은 온도에서 발생하는 특이한 화학반응 즉 Mechanochemical 반응을 일으키 기도 한다. 본 연구에서는 헤마타이트($Fe_20_3$)와 금속윈소인 Ti의 MA처리에 의하여 고상환원반응 을 유기시켜 $Fe-TiO_2$계 nanocomposite 분말재료를 제조하고자 한다. 특히 MA 공정에 있어서 자기 물성의 변화와 X선 회절을 통하여 고상환원반응에 의한 복합분말의 생성과정을 조사하였다. 출발원료는 $Fe_20_3$(고순도화학제,99.9%, 평균입경 0.1$\mu\textrm{m}$)와 금속원소인 Ti(99.9%, 명균업경 150$\mu\textrm{m}$)을 몰비 2:3의 조성이 되도록 하여 MA를 실시하였다. 볼멀은 고에너지 유성형 볼밀장치(독일 제, Fritsch P-5)를 이용하였으며 진공치환형 용기에 원료분말을 장입하여 2회정도 진공배기한 후 아르곤 가스를 충전하여 볼밀을 행하였다. 얻어진 분말시료에 대하여 x-선 회절장치, 전자현미경 (SEM) 및 진동시료형자력계(VSM)를 통하여 결정구조, 미셰조직 빛 자기특성을 조사하였다. $Fe_2O_3-Ti$ 혼합분말의 MA처리 에 의하여 초기단계부터 환원반응과 함께 $Fe_3TIO_{lO}$ 중간상이 관찰 되었으나 30hrs의 MA처리 후 Fe와 산화물 $TiO_2$로 모두 환원되어 $Fe-TiO_2$계 나노복합분말이 얻어짐을 알 수 있었다. 이 때 X션 회절피크의 line broadening으로부터 복합분말의 Fe 명균 결정립 크기는 24nm로 초미세 결정럽의 분말합금이었다. 포화자화값은 볼밀처리에 따라 점점 증가하여 MA 30시간에는 20.3emu/g로 포화됨을 알 수 있었다. 또한 보자력 Hc는 MA초기단계에 350e로 매우 낮으나 30시간 후에는 Hc값이 2600e로 매우 큰 값을 나타내었다. 이것은 환원반응결과 초기에 생성된 Fe의 결정립이 비교적 크고 결정결함이 적으나 볼밀처리를 30시간까지 행하면 Fe 결정렵의 미세화 빛 strain 증가로 magnetic hardening이 일어나기 때문인 것으로 사료된다.

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Analysis of the railway noise prediction result using Schall03 in noise mapping (소음지도 작성 시의 Schall03에 의한 철도소음 예측결과 분석)

  • Koh, Hyoin;Jang, Jinwon;Jang, Seungho;Hong, Jiyoung
    • Journal of Environmental Impact Assessment
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    • v.25 no.3
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    • pp.175-189
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    • 2016
  • The guideline for railway noise mapping is notificated in the administration law for noise/vibration which is announced by the ministry of environment, Korea. Here input parameters for the railway sound sources are proposed for each prediction models. In case of the application of the vehicle characteristics it is suggested to choose "0(%)" for the disc brake parameter. However new trains have been in revenue service since the announcement of the guideline, an investigation of the effect of the input parameters of the foreign railway prediction models on the prediction results of korean railway systems are needed. In this paper the sound prediction results are analyzed with a focus on the input parameters such as disc brake percentage, rail roughness, rail joints. Schall03 is used for the railway noise prediction which has been using most frequently in Korea. The results are shown and discussed.

Characteristics and Causes of Wave-Induced Settlement in Caisson Breakwater: Focusing on Settlement Data (파랑에 의한 방파제 케이슨 침하 경향 및 원인 분석: 침하 계측자료를 중심으로)

  • Kim, Tae-Hyung;Nam, Jung-Man;Kim, In-Sok;Yun, Seong-Kyu
    • Journal of the Korean Geotechnical Society
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    • v.30 no.7
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    • pp.27-40
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    • 2014
  • So far, studies on the settlement of breakwater have mainly been conducted through numerical model tests focusing on an analysis or through the laboratory wave tank tests using a scaled model. There has not been a study on the settlement that is measured in an actual breakwater structure. This study analyzed the data of settlement that has been measured in an actual caisson breakwater for a long time and the characteristics and causes of wave-induced settlement in the caisson (including beneath ground), based on qualitative aspect, were examined. The analysis revealed that wave clearly has an effect on the settlement in caisson, especially in the condition of high wave such as typhoon. Caisson settlement is caused by the liquefaction of ground, which is due to the increase of excess pore pressure, the combination of oscillatory excess pore pressure and residual excess pore water pressure, and the solidification process of ground due to dissipation of the accumulated excess pore pressure. The behavior of excess pore pressure in the ground beneath the caisson is entirely governed by the behavior of the caisson. Ground that has gone through solidification is not likely to go through liquefaction in a similar or a smaller wave condition and consequently, the possibility of settlement is reduced.