The iron doped colossal magnetoresistance materials with La-Ba-Mn-O perovskites structure have been synthesized by chemical reaction of sol-gel methods. Their crystallographic and magnetic properties have been studied with x-ray diffraction, VSM, RBS, Mossbauer spectroscopy, and magnetoresistance measurements. The crystal structure of the La$\_$0.67/Ba$\_$0.33/Mn$\_$0.99/Fe$\_$0.01/ $O_3$ at room temperature was determined to be orthorhombic of Pnma. The lattice parameters a$\_$0/ and c$\_$0/ increased gradually, but b$\_$0/ deceased with increase of iron substitution. The magnetization and coercivity deceased, also the Curie temperature decreased from 360 K as x increased from 0.00 to 0.05. Magnetoresistence measurements were carried out, and the maximum MR ($\Delta$$\rho$/$\rho$(0)) was observed at 281 K, about 9.5 % in 10 kOe. The temperature of maximum resistance (R$\_$MAX/) decreased with increasing substitution of Fe ions and a semiconductor-metal transition temperature (T$\_$SC-M/) decreased too. This phenomena show that ferromagnetic transition temperature decreased by substituting Fe for Mn ions, it decreases double exchange interaction. This result accords with magnetic structure of neutron diffraction. Mossbauer spectra of La$\_$0.67/Ba$\_$0.33/Mn$\_$0.99/Fe$\_$0.01/ $O_3$were taken at various temperatures ranging from 15 to 350 K. With lowering temperature of the sample, two magnetic phases were increased and finally it showed the two sharp sextets of spectra at 15 K. The isomer shift at all temperature range is about 0.3 mm/s relative to Fe metal, which means that both Fe ions are Fe$\^$3+/ states.Fe$\^$3+/ states.
Synchrotron radiation (SR) has several advantages over convetional x-rays, including its phase, collimation, and high flux. A synchrotron radiation beamline 5C1 at Pohang Light Source (PLS) was recently built for imaging applications. We have shown that a SR imaging system is useful in imaging microscopic structures. SR with broad-band energy spectrum were adjusted to an object by Si wafers and their energy were approximately ranging from 6 keV to 30 keV. SR were passed through an object and finally transformed into visible lights by CdWO$_4$ scintillator screen. The visible lights which were reflected at an angle of 90 degrees by gold plated mirror were detected by a CCD camera and the image data were acquired using image acquisition system. A high-resolution phantom, capacitor, adult tooth, child tooth, cancerous breast tissue, and mouse lumbar vertebra were imaged with SR imaging system. The Objects were rotated within the field of view of the CCD detector, and their projection image data were obtained at 250 steps over 180 degrees rotation. Image reconstructions were carried out in a PC by using IDLTM(Research systems, Inc., US) program. The spatial resolution of the images acquired by the SR imaging system was measured with a high-resolution chart manufactured for several micrometer resolution. The specimens were also imaged with conventional x-ray radiography system to compare the image quality of radiography obtained with the SR imaging system. The results showed more structural details and high contrast images with SR imaging system than conventional x-ray radiography system. The SR imaging system may have a potential for imaging in biological researches, material applications, and clinical radiography.
With the media's shift into the digital era in the 2000s, comic book publishers attempted a transition into the new medium by establishing a distribution structure using internet networks. But that effort shied from escaping the parallel-page reading structure of traditional comics. On the other hand, webtoons are showing divers changes by redesigning the structure of traditional sequential art media; they tend to separate and allot spaces according to the vertical scroll reading method of the internet browser and include animations, sound effects and background music. This trend is also in accordance with the preferences of modern readers. Modern society has complicated social structures with the development of various media; the public is therefore exposed to different stimuli and shows characteristics of differentiated perceptions. In other words, webtoons display more relevant and entertaining characteristics by inserting sounds and using moving texts and characters in specific frames, while traditional comics require an appreciation of withdrawal and immersion like other published media. Motions in webtoons are partially applied for dramatic tension or to create an effective expression of action. For example, hand-drawn animation is adopted to express motions by dividing motion images into many layers. Sounds are also utilized, such as background music with episode-related lyrics, melodies, ambient sounds and motion-related sound effects. In addition, webtoons provide readers with new amusement by giving tactile stimuli via the vibration of a smart phone. As stated above, the vertical direction, time-based nature of animation motions and tactile stimuli used in webtoons are differentiated from published comics. However, webtoons' utilization of innovative techniques hasn't yet reached its full potential. In addition to the fact that the software used for webtoon effects is operationally complex, this is a transitional phenomenon since there is still a lack of technical understanding of animation and sound application amongst the general public. For example, a sound might be programmed to play when a specific frame scrolls into view on the monitor, but the frame may be scrolled faster or slower than the author intended; in this case, sound can end before or after a reader sees the whole image. The motion of each frame is also programmed to start in a similar fashion. Therefore, a reader's scroll speed is related to the motion's speed. For this reason, motions might miss the intended timing and be unnatural because they are played out of context. Also, finished sound effects can disturb the concentration of readers. These problems come from a shortage of continuity; to solve these, naturally activated consecutive sounds or animations, like the simple rotation of joints when a character moves, is required.
KSCE Journal of Civil and Environmental Engineering Research
/
v.37
no.1
/
pp.9-17
/
2017
Characteristics of aerodynamic damping ratios of a helical $180^{\circ}$ model which shows better aerodynamic behavior in both along-wind and across-wind responses on a super tall building was investigated by an aeroelastic model test. The aerodynamic damping ratio was evaluated from the wind-induced responses of the model by using Random Decrement (RD) technique. Further, various triggering levels in evaluation of aerodynamic damping ratios using RD technique were also examined. As a result, it was found that when at least 2000 segments were used for evaluating aerodynamic damping ratio for ensemble averaging, the aerodynamic damping ratio can be obtained more consistently with lower irregular fluctuations. This is good agreement with those of previous studies. Another notable observation was that for square and helical $180^{\circ}$ models, the aerodynamic damping ratios in along-wind direction showed similar linear trends with reduced wind speeds regarding of building shapes. On the other hand, for the helical $180^{\circ}$ model, the aerodynamic damping ratio in across-wind direction showed quite different trends with those of the square model. In addition, the aerodynamic damping ratios of the helical $180^{\circ}$ model showed very similar trends with respect to the change of wind direction, and showed gradually increasing trends having small fluctuations with reduced wind speeds. Another observation was that in definition of triggering levels in RD technique on aerodynamic damping ratios, it may be possible to adopt the triggering levels of "standard deviation" or "${\sqrt{2}}$ times of the standard deviation" of the response time history if RD functions have a large number of triggering points. Further, these triggering levels may result in similar values and distributions with reduced wind speeds and either may be acceptable.
Ultrafine $CoFe_{1.9}Bi_{0.1}O_4$ particles were fabricated by using a sol-gel method and their magnetic and structural properties were investigated with an x-ray diffractometer (XRD), a vibrating sample magnetometer (VSM), and a M$\"{o}$ssbauer spectrometer. The result of x-ray diffraction and M$\"{o}$ssbauer spectroscopy showed that the powders fired at and above 523 K had only cubic spinel structures. M$\"{o}$ssbauer spectra measurements showed that the powders annealed at 523,723 and 823 K possessed ferrimagnetic nature and paramagnetic nature due to superparamagnetism, simultaneously at room temperature and the powders annealed at and above 923 K behaved ferrimagnetically. In the case of the powder annealed at 923 K, the lattice constant was $a_0=8.398$\pm$0.005{\AA}$ and the hyperfine fields were $H_{hf}(A)=479kOe,\; H_{hf}(B)=502kOe$. The isomer shifts indicate that the iron ions are ferric at tetrahedral[A] and octahedral sites [B], respectively. The magnetization as a function of annealing temperature increased as increasing annealing temperature. The largest coercivity values were $H_C=1368\;Oe$ AT 923 K annealing temperature. In the case of the powder annealed at 1123 K, the magnetization value was $M_S=75\;emu/g$ and this value was similler to that of $CoFe_2O_4$.Fe_2O_4$.
Journal of the Earthquake Engineering Society of Korea
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v.9
no.5
s.45
/
pp.75-86
/
2005
In performance-based design methods, it is clear that the evaluation of the nonlinear response is required. Analysis methods available to the design engineer today are nonlinear time history analyses, or monotonic static nonlinear analyses, or equivalent static analyses with simulated inelastic influences. The nonlinear time analysis is the most accurate method in computing the nonlinear response of structures, but it is time-consuming and necessitate more efforts. Some codes proposed the capacity spectrum method based on the nonlinear static analysis to determine earthquake-induced demand. The nonlinear direct spectrum method is proposed and studied to evaluate nonlinear response of structures, without iterative computations, given by the structural linear vibration period and yield strength from pushover analysis. The purpose of this paper is to compare the accuracy and the reliability of approximate nonlinear methods with respect to shear buildings and various earthquakes. The conclusions of this study are summarized as follows: 1) Linear capacity spectrum method may fail to find a convergent answer or make a divergence. Even if a convergent answer is found, it has a large error in some cases and the error varies greatly depending on earthquakes. 2) Although nonlinear capacity spectrum method need much less calculation than capacity spectrum method and find an answer in any case, it may be difficult to obtain an accurate answer and generally large error occurs. 3) The nonlinear direct spectrum method is thought to have good applicability because it produce relatively correct answer than other methods directly from pushover curves and nonlinear response spectrums without additional and iterative calculations.
KSCE Journal of Civil and Environmental Engineering Research
/
v.32
no.3B
/
pp.175-183
/
2012
In this study, Galerkin scheme and SU/PG scheme of Petrov-Galerkin family were applied to the shallow water equations and a finite element model for shallow water flow was developed. Numerical simulations were conducted in several flumes with convection-dominated flow condition. Flow simulation of channel with slender structure in the water course revealed that Galerkin and SU/PG schemes showed similar results under very low Fr number and Re number condition. However, when the Fr number increased up to 1.58, Galerkin scheme did not converge while SU/PG scheme produced stable solutions after 5 iterations by Newton-Raphson method. For the transcritical flow simulation in diverging channel, the present model predicted the hydraulic jump accurately in terms of the jump location, the depth slope, and the flow depth after jump, and the numerical results showed good agreements with the hydraulic experiments carried out by Khalifa(1980). In the oblique hydraulic jump simulation, in which convection-dominated supercritical flow (Fr=2.74) evolves, Galerkin scheme blew up just after the first iteration of the initial time step. However, SU/PG scheme captured the boundary of oblique hydraulic jump accurately without numerical oscillation. The maximum errors quantified with exact solutions were less than 0.2% in water depth and velocity calculations, and thereby SU/PG scheme predicted the oblique hydraulic jump phenomena more accurately compared with the previous studies (Levin et al., 2006; Ricchiuto et al., 2007).
Seo, Hye-Won;Park, Min-Suk;Lee, Swoo-Heon;Shin, Kyung-Jae
Journal of Korean Society of Steel Construction
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v.22
no.5
/
pp.477-485
/
2010
Various monitoring sensors are used to predict and detect structural damage. Smart sensors, such as glass-fiber sensors, PZT, and MEMS, among others, have replaced traditional sensors. They are now being used in many areas. This study aims to predict the damage by measuring the PZT voltage attached on the specimen by the applied impact load. In the experiment to detect damages in beam connection, simple $H-400{\times}200{\times}8{\times}13$ beams were spliced with bolts. The results of FFT between PZT sensor and accelrometer were compared to measure the sensitivity of the PZT sensor. The damage to the beam was presumed by loosening the bolt, and then the damage measurement was accompanied. Secondly, a steel $PL600{\times}65{\times}5.8$ plate beam was fabricated for the purpose of experimenting on damage measurement. Impact loading test on three different locations was carried out. Damage width varied between 6~42mm on both sides by cutting, using a steel saw. The ratio of frequencies before and after the damage was computed to quantify the damage level by using FFT, and the change in mode pattern with the increased damage was investigated to measure the damage.
Journal of the Korean Crystal Growth and Crystal Technology
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v.9
no.1
/
pp.94-100
/
1999
Mercurous chloride($Hg_2Cl_2$) crystals hold promise for many acousto-optic and opto-electronic applications, which are prepared in closed ampoules by the physical vapor transport(PVT) growth methods. The thermal boundary conditions established by imposing different temperature on sidewalls of the enclosure cause simultaneous horizontal and vertical convectie flow in the PVT processes of$Hg_2Cl_2$ . It is found that for the ratios of horizontal to vertical thermal Rayleigh numbers$Ra_H/Ra{\ge}1.5$, the convective flow structure changes from multicellular to unicellular for the base parametric state of Ra=($2.79{\times}10^4$) , Pr=0.91, Le=1.01, Pe=4.60, Ar=0.2 and$C_V =1.01$. For the $\Delta T^{*}_H$ greater than 0.3, the $$\mid$U$\mid$_{max}$is increased with increasing $\Delta$ T^{*}_H$ and decreasing the aspect ratio. For the aspect ratios ranging from 0.1 to 1.0, there is a direct and linear relationship between $$\mid$U$\mid$_{max}$ and $\sqrt{{\Delta}T^_H\;^{\ast}}$.A decrease in the aspect ratio destabilizes the convective flow and results in an increase of the magnitude of convection in the crystal growth reactor. The vertical gradient tends to destabilize the convective flow which leads to oscillations, whereas the horizontal gradient stabilizes the convection.
Journal of The Korean Association For Science Education
/
v.37
no.1
/
pp.63-75
/
2017
The purpose of this study is to explore the effect of responsive teaching on students' productive argumentation practice. The participating students predicted the results of an activity to measure in which location on the body (the head, spine, or back of the hand) they would feel a cellphone's vibrations faster. They then engaged in the activity and built an argument to justify it. We interviewed the teacher to understand her thoughts regarding what was expected in the class. We also recorded and transcribed the class and the interview, for use in the analysis of the students' epistemological framing and the teacher's responsive practice in small group argumentation. We discovered that the teacher intervened in the groups with questions that elicited students' thoughts as starting points for her responsive practice. Her eliciting questions led the students to talk about their ideas, supporting their engagement in the argumentation. The teacher's understanding of the argumentation lesson and her behavior to understand the students' ideas reflected her productive framing, which led her to elicit students' ideas and to support their active interaction during the small-group argumentation. She presented rebuttals against students' ideas, engaging in the argumentation as another participant, not as an evaluator. This supported the equality of intellectual authority in the group and showed students how to engage in the argumentation, supporting students' productive framing. As a result of these responsive teaching practices, the students shifted their epistemological framing, resulting in productive argumentation practice. The results of this study will contribute to developing teachers' responsive teaching strategies to support students' productive framing in science classrooms.
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