• Polymer(Korea)
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• v.28 no.5
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• pp.397-403
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• 2004

The sulfonated PET-g-GMA ion-exchange fine fibers were synthesized by UV radiation-induced graft copolymerization using a photoinitiator, and their chemical structure and adsorption properties were investigated. The optimum values for synthetic conditions - UV intensity, reaction time, and reaction temperature were 450 W, 60 min, and $40^{\circ}C$, respectively. Maximum values of the degree of sulfonation and ion exchange capacity were 8.12 mmol/g and 3.25 meq/g, respectively. Tensile strength of sulfonated PET-g-GMA fine ion exchange fibers was lower than that of PET trunk polymer as the grafting reaction rates increased. It was shown that as for the adsorption rate of $Ca^{2+}$ and $Mg^{2+}$ by the sulfonated PET-g-GMA fine ion exchange fibers, magnesium ion is slower than calcium ion in the solution. However, in the mixture of the calcium and magnesium ions, the adsorption rate of calcium ion was much slower than that of magnesium ion.

• Composites Research
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• v.37 no.1
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• pp.40-45
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• 2024

In this research, we introduce a novel approach that employs a 3D convolutional neural network (CNN) model to predict the permeability of Gas Diffusion Layers (GDLs). For training the model, we create an artificial dataset of GDL representative volume elements (RVEs) by extracting morphological characteristics from actual GDL images obtained through X-ray tomography. These morphological attributes involve statistical distributions of porosity, fiber orientation, and diameter. Subsequently, a permeability analysis using the Lattice Boltzmann Method (LBM) is conducted on a collection of 10,800 RVEs. The 3D CNN model, trained on this artificial dataset, well predicts the permeability of actual GDLs.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.3D
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• pp.325-330
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• 2008

This study carried out the repeated freezing-thawing test in order to understand the long-term degradation mechanism of GFRP dowel bars. The mechanical property measured by shear test. In addition, analyzes repeated freezing-thawing degradation mechanism of GFRP dowel bars by observe the microstructure through Scanning Electron Microscope (SEM) and Gas Physisorption techniques. As the result of test, it was found that the mechanical property didn't decreased as the exposure time to water and repeated freezing-thawing environment. It shows clearly observed microstructure investigations.

• Journal of the Korean Electrochemical Society
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• v.15 no.2
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• pp.95-100
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• 2012

$LiFePO_4$ is an attractive cathode material due to its low cost, good cyclability and safety. But it has low ionic conductivity and working voltage impose a limitation on its application for commercial products. In order to solve these problems, the iron($Fe^{2+}$)site in $LiFePO_4$ can be substituted with other transition metal ions such as $Mn^{2+}$ in pursuance of increase the working voltage. Also, reducing the size of electrode materials to nanometer scale can improve the power density because of a larger electrode-electrolyte contact area and shorter diffusion lengths for Li ions in crystals. Therefore, we chose electrospinning as a general method to prepare $Li[Fe_{0.9}Mn_{0.1}]PO_4$ to increase the surface area. Also, there have been very a few reports on the synthesis of cathode materials by electrospinning method for Lithium ion batteries. The morphology and nanostructure of the obtained $Li[Fe_{0.9}Mn_{0.1}]PO_4$ nanofibers were characterized using scanning electron microscopy(SEM). X-ray diffraction(XRD) measurements were also carried out in order to determine the structure of $Li[Fe_{0.9}Mn_{0.1}]PO_4$ nanofibers. Electrochemical properties of $Li[Fe_{0.9}Mn_{0.1}]PO_4$ were investigated with charge/discharge measurements, electrochemical impedance spectroscopy measurements(EIS).

• Journal of the Korea Concrete Institute
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• v.23 no.3
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• pp.273-280
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• 2011

Ten high-strength concrete beam specimens, which have various combinations of different types of flexural reinforcement and short fibers were constructed and tested. Six beams were reinforced with two layers of steel, CFRP, and GFRP bar combinations. The other four beams were reinforced with two layers of single type CFRP and GFRP bars, with steel and synthetic short fibers. An investigation was performed on the influence of the parameters on the load-carrying capacity, post cracking stiffness, cracking pattern, deflection behavior, and ductility. The low post cracking stiffness, large deflection, deep crack propagation, large crack width, and low ductility of FRP bar-reinforced beams were controlled and improved by positioning steel bars in the inner layer of the FRP bar layer. In addition, the addition of fibers increased the first-cracking load, ultimate flexural strength, and ductility as well as the deep propagating cracks were controlled in the FRP bar-reinforced concrete beams. The increased ultimate concrete strain of fiber-reinforced concrete should be determined and considered when FRP bar-reinforced concrete members with fibers are designed.

• Journal of The Korean Society of Agricultural Engineers
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• v.54 no.5
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• pp.25-34
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• 2012

It has been well known that concrete structures exposed to acid and sulfate environments such as sewer etc. show significant decrease in their durability due to chemical attack. Such deleterious acid and sulfate attacks lead to expansion and cracking in concrete, and thus, eventually result in damage to cement mortar by forming expansive hydration products due to the reaction between cement hydration products and acid and sulfate ions. In this study, the effect of fly ash and blast furnace slag on the bond performances of structural synthetic fiber in latex modified cement mortar under sulfate environments. Fly ash and blast furnace slag contents ranging from 0 % to 20 % are used in the mix proportions. The latex modified cement mortar specimens were immersed in fresh water, 8 % sodium sulfate ($Na_2SO_4$) solutions for 28 and 50 days, respectively. Pullout tests are conducted to measure the bond performance of structural synthetic fiber from latex modified cement mortar after sulfate environments exposure. Test results are found that the incorporation of fly ash and blast furnace slag can effectively enhance the PVA fiber-latex modified cement mortar interfacial bond properties (bond behavior, bond strength and interface toughness) after sulfate environments exposure. The microstructural observation confirms the findings on the interface bond mechanism drawn from the fiber pullout test results under sulfate environments.

• Korean Chemical Engineering Research
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• v.60 no.4
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• pp.574-581
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• 2022

Nanofibers comprising reduced graphene oxide (rGO) and Mo₂C/Mo₂N nanoparticles (Mo₂C/Mo₂N rGO NFs) were prepared for a functional interlayer of Li-S batteries (LSBs). The well-dispersed Mo₂C and Mo₂N nanoparticles in the nanofiber structure served as active polar sites for efficient immobilization of dissolved lithium polysulfide. The rGO nanosheets in the structure also provide conductive channels for fast ion/electron transport during charging-discharging and ensured reuse of lithium polysulfide during redox reactions through a fast charge transfer process. As a result, the cell assembled with Mo₂C/Mo₂N rGO NFs-coated separator and pure sulfur electrode (70 wt% of sulfur content and 2.1 mg cm^-2 of sulfur loading) showed a stable discharge capacity of 476 mA h g^-1 after 400 charge-discharge cycles at 0.1 C. Furthermore, it exhibited a discharge capacity of 574 mA h g^-1 even at a high current density of 1.0 C. Therefore, we believe that the proposed unique nanostructure synthesis strategy could provide new insights into the development of sustainable and highly conductive polar materials as functional interlayers for high performance LSBs.

• Korean Chemical Engineering Research
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• v.49 no.6
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• pp.769-774
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• 2011

Porous carbon nanofibers(CNF) were synthesized via NaOH activation at 700~$900^{\circ}C$, and the porous CNF-supported PtRu catalysts were evaluated for the anode in direct methanol fuel cells. The change of surface characteristics by NaOH activation was examined by analyses of the specific surface area and pore size distribution. The morphological and structural modification was investigated under scanning electron microscopy. The activity of catalysts supported on porous CNFs was examined by cyclic voltammograms and single cell tests. The pore formation on CNF by the NaOH activation was discussed, concerning the catalyst activity, when they were applied as catalyst supports.

• Applied Chemistry for Engineering
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• v.20 no.2
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• pp.140-144
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• 2009

Triethanolamine-type cationic surfactants were synthesized and their applications were established. The production of mono-, di-, and tri-TEA-EQ (triethanol-amine-esterquater) were dependent on the molar ratio of fatty acid and triethanolamine under the controlled reaction temperature. The structures were elucidated by $H^{1}$ NMR. Long-term stability was dependent on the amount of mono- and tri-TEA-EQ. When the amount of mono-TEA-EQ was increased, long-term stability was increased. However, the more tri-TEA-EQ made long-term stability decreased. Softening was dependent on the amount of saturated fatty acid, and re-wettability was counted on the amount of unsaturated fatty acid. Softening was measured by the method of sense estimation e.g. touching to home-towel. Absorption was determined to calculate the height of water on a towel after treatment.

• Polymer(Korea)
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• v.27 no.6
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• pp.528-535
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• 2003

The effects of surfactants, organic solvents, and functional monomers on the emulsion polymerization of perfluoroalkyleoylacryaltes and n-alkylacrylates were investigated. In particular, the dependence of the surface properties, contact angle and water repellency on the crystal melting temperature (T$\_$m/) of the fluorocopolymer and the variation of polymer latex particle sizes was investigated. Using WAXD experiments and synthesizing different types of fluorocopolymers which have fallowing fluoroacrylaytes [CH$_2$=CHCO$_2$CH,$_2$(CF$_2$CF$_2$) nH] (n = 4, 5 or 6), the relationship between the molecular packing structure of pendent side groups of fluorocopolymers and the surface properties was also investigated. We observed that the structure of primary carbon atoms of pendent side groups of fluorocopolymers plays key role in determining the surface properties.s.