• Title/Summary/Keyword: 교호법

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Optimization of a Crystallization Process by Response Surface Methodology (반응표면분석법을 이용한 결정화 공정의 최적화)

  • Lee, Se-Eun;Kim, Jae-Kyeong;Han, Sang-Keun;Chae, Joo-Seung;Lee, Keun-Duk;Koo, Kee-Kahb
    • Applied Chemistry for Engineering
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    • v.26 no.6
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    • pp.730-736
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    • 2015
  • Cyclotrimethylene trinitramine (RDX) is a high explosive commonly used for military applications. Submicronization of RDX particles has been a critical issue in order to alleviate the unintended and accidental stimuli toward safer and more powerful performances. The purpose of this study is to optimize experimental variables for drowning-out crystallization applied to produce submicron RDX particles. Effects of RDX concentration, anti-solvent temperature and anti-solvent mass were analyzed by the central composite rotatable design. The adjusted determination coefficient of regression model was calculated to be 0.9984 having the p-value less than 0.01. Response surface plots based on the central composite rotatable design determined the optimum conditions such as RDX concentration of 3 wt%, anti-solvent temperature of $0.2^{\circ}C$ and anti-solvent mass of 266 g. The optimum and experimental diameters of RDX particles were measured to be $0.53{\mu}m$ and $0.53{\mu}m$, respectively. The regression model satisfactorily predicts the average diameter of RDX particles prepared by drowning-out crystallization. Structure of RDX crystals was found to be ${\alpha}$-form by X-ray diffraction analysis and FT-IR spectroscopy.

Optimization of the preparation method of citron (Citrus junos Sieb.) beverage containing hibiscus using response surface methodology (반응표면 분석법을 이용한 히비스커스 첨가 유자 음료 제조의 최적화)

  • Lee, Chang Joo;Lee, Woo Jin;Park, Jong Seok;Kim, Sung Woo;Jung, Sung Keun
    • Korean Journal of Food Science and Technology
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    • v.53 no.2
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    • pp.187-194
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    • 2021
  • This study aimed to optimize the preparation method of citron (Citrus junos Sieb.) beverages with hibiscus using response surface methodology (RSM). The experimental conditions were established using a central composite design with three independent variables as follows: ratios of citron (40~60%), citric acid (0.34~0.94%), and hibiscus (0.3~0.7%). The results indicate that an increase in the citron ratio contributed to increased sweetness and as the concentration of citron and hibiscus increased, the brightness of the citron beverage decreased and the yellowness increased. The citron ratio showed a significant correlation with the ABTS radical scavenging capacity. Among the 15 experimental groups, 4 representative samples showing statistical significance were selected, and sensory tests were performed, in comparison with commercially available products. As a result of the sensory test, four beverages prepared with the selected recipes showed higher preference than commercial beverages, and optimal recipe conditions were 40% citron, 0.34% citric acid, and 0.5% hibiscus.

Seeding Rate and Planting Date Effects on Forage Performance and Quality of Winter Rye (호밀의 사초특성, 수량 및 품질에 미치는 파종량 및 파종기의 영향)

  • Park, H.S.;Kim, D.A.;Kim, J.D.
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.19 no.2
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    • pp.105-114
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    • 1999
  • This experiment was carried out to determine seeding rate and planting date effects on the forage performance and quality of winter rye(Secale cereale L.) at Suweon in 1997 and 1998. The experiment was arranged in a spilt plot design with three replications. Main plots consisted of three seeding rates; 100, 150, and 200kg/ha. Sub-plots consisted of four planting dates; 5 September, 20 September, 5 October and 20 October. The first heading date of rye was not strongly influenced by planting dates. On a day basis, a 1:15 ratio was existed between heading and planting dates of rye, as a 1-day delay in spring heading date for each 15-day delay in fall planting date. Dry matter content of rye for a seeding rate of 200kg/ha was the lowest of 13.6%, and that for the planting dates was decreased to 15.2, 14.2, 14.3, and 13.8% with delayed seeding (P<0.05). There was an interaction between seeding rate and planting date in dry matter content of rye(P<0.01). Acid detergent fiber (ADF) percentage of rye for the seeding rates was not significant and that for the planting dates was decreased to 32.1, 31.6, 31.6, and 29.3%, as the planting was delayed(P<0.05). There was an interaction between seeding rate and planting date for ADF. Effect of seeding rate and planting date on neutral detergent fiber(NDF) of rye was similar to the observations made on ADF. Crude protein content of rye for the seeding rates was not significant, but that for the planting dates was increased to 17.3, 17.7, 18.2, and 18.9%, as the planting was delayed(P<0.05). In vitro dry matter digestibility(IVDMD) of rye for the seeding rates was not significant, but that for the planting dates was increased to 77.5, 80.6, 80.9, and 80.9%, as the planting was delayed(P<0.05). Dry matter yield of rye for a seeding rate of 100 kg/ha was the highest of 9,059 kg/ha, and that for a seeding rate of 200 kg/ha was the lowest of 7,647 kg/ha(P<0.01). In this experiment, the highest forage yield(8,945 kg/ha) was obtained when planting was completed by early October(5 October), with yield decreased as planting was delayed until 20 October (7,249 kg/ha)(P<0.01). This trend was also observed for the crude protein(CP) and in vitro digestible dry matter(IVDDM) yields of rye. A significant interaction between seeding rate and planting date for the dry matter yield was occurred(P<0.01). Based on the results of this experiment, it appears that the forage dry matter yield of rye could be enhanced by sowing from 20 September to 5 October under upland condition in the middle plain area of Korea. The seeding rates from 100 to 150 kg/ha and that of 200 kg/ha would be suitable for the early-fall and late fall sowing, respectively.

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Effects of Aromatherapy on Depression, Anxiety and the Autonomic Nervous System in Breast Cancer Patients Undergoing Adjuvant Radiotherapy (방사선 요법을 받는 유방암 환자에게 적용한 아로마 요법이 우울, 불안 및 자율신경계 반응에 미치는 효과)

  • Yun, Sun-Hee;Cha, Jung-Hee;Yoo, Yang-Sook;Kim, Yeong-In;Chung, Su-Mi;Jeong, Hea-Lim
    • Journal of Hospice and Palliative Care
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    • v.15 no.2
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    • pp.68-76
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    • 2012
  • Purpose: The study was designed to verify effects of aromatherapy on depression, anxiety and the autonomic nervous system in breast cancer patients who are undergoing adjuvant radiotherapy. Methods: Data were collected from November 2006 through March 2007 at the C university hospital in Seoul. The study included 33 patients and they were assigned to three groups. Group I had aroma oil inhalation for 2 minutes per time, three times a day for six weeks whereas Group II and a control group inhaled aroma oil for 2 minutes per time, once a day for six weeks. For Groups I and II, a mixture of lemon, lavender, rosewood and rose essential oils were used while control group inhaled tea tree oil. Results: Depression was significantly decreased in patients in the experimental groups only. In Groups I and II patients, anxiety level was lower than that in control patients. Patients in Groups I and II also showed stronger physical resistance to stress than control group patients. Conclusion: Aromatherapy should be considered as a method that can significantly decrease depression in breast cancer patients who are undergoing adjuvant radiotherapy.

Synthesis of Naphthalimidopropyl Acrylate and GMA Copolymers and Their Physical Properties (나프탈이미도프로필 아크릴레이트와 GMA 공중합체의 합성과 물성)

  • Lim, Deok Jum;Oh, Seung Min;Kim, Boo Yoon;Park, Jae Kyung;Kang, Inn-Kyu;Seo, Kwan-Ho;Oh, Dae Hee
    • Polymer(Korea)
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    • v.38 no.4
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    • pp.535-543
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    • 2014
  • This work, which was about the synthesis of naphthalimidopropyl acrylate and GMA copolymers and their physical properties, investigated the compositions of the copolymer, the reactivity ratios of the monomer, resonance effect (Q), polar effect (e) and fluorescence of naphthalene. Azobisisobutyronitronitryl (AIBN) as an initiator was employed at $60^{\circ}C$ with dimethylformamide (DMF) of solvent for the copolymerization of NIPA. $r_1$ was found to be higher than $r_2$ from the reactivity ratios of the monomer obtained from Fineman-Ross (F-R), Kelen-$T{\ddot{u}}d{\ddot{o}}s$(K-T) methods. NIPA was found to be more copolymerized than GMA. $r_1{\cdot}r_2$ product was lower than 1, copolymerization was maked random-alternating type. The fluorescence spectrum of these polymers showed a weak monomer fluorescence band at 380 nm and a strong excimer fluorescence band at about 460 nm. Fluorescence life time of NIPA monomer showed fluorescence cover with UV 355 nm at room temperature, and life time showed $5.1449{\times}10^{-7}s$.

Compatibility of MODIS Vegetation Indices and Their Sensitivity to Sensor Geometry (MODIS 식생지수에 미치는 센서 geometry의 영향과 센서 간 자료 호환성 검토)

  • Park, Sunyurp
    • Journal of the Korean Geographical Society
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    • v.49 no.1
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    • pp.45-56
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    • 2014
  • Data composite methods have been typically applied to satellite-based vegetation index(VI) data to continuously acquire vegetation greenness over the land surface. Data composites are useful for construction of long-term archives of vegetation indices by minimizing missing data or contamination from noise. In addition, if multi-sensor vegetation indices that are acquired during the same composite periods are used interchangeably, data stability and continuity may be significantly enhanced. This study evaluated the influences of sensor geometry on MODIS vegetation indices and investigated data compatibility of two difference vegetation indices, the Normalized Difference Vegetation Index(NDVI) and the Enhanced Vegetation Index(EVI), for potential improvement of long-term data construction. Relationships between NDVI and EVI turned out statistically significant with variations among vegetation covers. Due to their curvilinear relationships, NDVI became saturated and leveled off as EVI reached high ranges. Correlation coefficients between Terra- and Aqua-based vegetation indices ranged from 0.747 to 0.963 for EVI, and from 0.641 to 0.880 for NDVI, showing better compatibility for EVI compared to NDVI. In-depth analyses of VI outliers that deviated from regression equations constructed from the two different sensors remain as a future study to improve their compatibility.

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Development of Antagonistic Microorganism for Biological Control of Pythium Blight of Turfgrass (잔디 피시움마름병(Pythium blight)의 생물학적 방제를 위한 길항 미생물의 선발과 효력 검정)

  • Jung, Woo-Chul;Shin, Taek-Su;Do, Ki-Suk;Kim, Won-Kuk;Lee, Jae-Ho;Choi, Ki-Hyun
    • Research in Plant Disease
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    • v.12 no.3
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    • pp.260-266
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    • 2006
  • Pythium blight caused by Pythium spp. is one of major diseases in putting green of golf course. In this study, microorganisms which are anatgonistic to Pythium aphanidermatum, a pathogen of pythium blight, were selected primary through in vitro tests, dual culture method and triple layer agar diffusion method. In vivo test against pythium blight were conducted to select the best candidate biocontrol microorganism by pot experiment in a plastic house. Bacillus subtilis GB-0365 was finally selected as a biocontrol agent against pythium blight. Relative Performance Indies(RPI) was used as a criterion of selecting potential biocontrol agent. B. subtilis GB-0365 showed resistance to major synthetic agrochemicals used in golf course. Alternative application of synthetic agrochemicals and B. subtilis GB-0365 was most effective to successfully contol pythium blight. B. subtilis GB-0365 suppressed the development of pythium bight of bentgrass by 56.4% as compared to non-treated control and its disease control efficacy was 60.9% of a synthetic fungicide Oxapro(WP) efficacy. B. subtilis GB-0365 has a potential to be a biocontrol agent for control of pythium blight.

Objective Effects and Satisfaction of Mouth Gymnastics Program (입체조 프로그램의 객관적 효과와 만족도 조사)

  • Jang, Kyeung-Ae;Hwang, In-Chul
    • The Journal of the Korea Contents Association
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    • v.11 no.10
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    • pp.388-395
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    • 2011
  • This study was performed to grasp the relation between the effect and the satisfaction of a mouth gymnastics program on the promotion of oral function of old persons. The experimental group of 47 old persons conducted a mouth gymnastics exercise two times every week for 12 weeks, while the control group of 39 old persons carrying out physical examinations. The mean salivary secretion in the experimental group was 0.075 ml and more than 0.046 ml in the control group. Maximum mouth opening in the experimental group, 4.12 cm, was higher than 3.92 cm in the control. Oral diadochokinesis in experimental and control group was 1.69 times per second and 1.65, respectively. The result of principal component analysis by Quartimax method with Kaiser normalization showed that program prevalence prediction of mouth-gymnastics exercise was high, and it is estimated that this exercise program would be more popular for health promotion of old persons. From the correlation analysis, mouth gymnastics exercise made salivary flow increase(r=.592), this exercise should be recommended actively for improving mouth health of old persons. Also more modification is required for old persons with difficulty in mouth gymnastics exercise. Some movements of the mouth gymnastics exercise need be modified, and then the exercise should be publicized as one of the ways to improve holistic health of the aged.

Current Status and Perspective of Weed Management in Herbicide-Resistant Crops (제초제 저항성작물에서 잡초관리기술 동향 및 전망)

  • Pyon, Jong Yeong;Chang, Kyu Seob;Lee, Jeung Joo;Park, Kee Woong
    • Weed & Turfgrass Science
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    • v.2 no.3
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    • pp.221-229
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    • 2013
  • This paper reviews current status of weed control practices in herbicide-resistant crops to examine weed management strategies in cope with cropping herbicide-resistant crops in the near future. Herbicide-resistant crops were rapidly adopted weed management technologies due to broad-spectrum weed control without crop injury. Transgenic glyphosate-resistant cultivars in soybean, corn, canola, and cotton were adopted to manage weeds at lower cost in a simplified weed management system. Dual stack crops with glyphosate and glufosinate resistance were developed to control glyphosate resistant weeds in corn, soybean and cotton. New multiple herbicide-resistant crops with resistance to glyphosate and glufosinate, acetolactate synthase (ALS) inhibitors, synthetic auxin herbicides, 4-hydroxyphenyl pyruvate dioxygenase (HPPD) inhibitors or acetyl Coenzyme A carboxylase (ACCase) inhibitors will expended the utility of existing herbicide technologies to manage the evolution of resistant weeds. However, herbicide resistant crops alone cannot solve weed problems and thus studies on diverse weed managements using an array of alternating herbicides of mode of action, mechanical, and cultural practices are needed for integrated weed management systems in the future.

Variation in Larvae Development and Moth Emergence of Striped Rice Borer (Chilo suppressalis Walker) and Damages in Rice Cultivars under Different Levels of Nitrogen and Silicate Fertilizers (질소 및 규산시비수준에 따른 수도품종간 이화명충의 발육ㆍ우화 및 피해정도의 변이)

  • 손상목;김기준
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.27 no.1
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    • pp.11-19
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    • 1982
  • The average weight of larvae, the percentage of survival larvae and the percentage of moth emergence in first and second generation of striped rice borer showed lower values in Akibare(Japonica variety) compared with those in Milyang 23 (Indica variety). At higher nitrogen level the larvae weight in second generation of striped borer was increased. The percentage of survival larvae in second generation was gradually decreased by applying the silicate fertilizer in both cultivars. The moth emergences in both generations of striped rice borer were also lower at high levels of silicate fertilizer. The percentage of white head of rice plant was reduced by the application of silicate fertilizer. The ratio of SiO$_2$ to T-N of the rice stem was related negatively with the percentage of survival larvae and the moth emergence in second generation of striped rice borer, and also with the percentage of white head of rice plant.

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