• Economic and Environmental Geology
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• v.12 no.3
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• pp.127-146
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• 1979

Though tungsten minerals have been mined for over fifty years in Korea, which has become one of the worlds largest tungsten producers since 1951, knowledge of their mineralogy and geochemistry is somewhat limited to the school of tungsten students. There is a considerable amount of literature throughout the world on the tungsten mineralogy, the geochemical behaviour of tungsten, the nature of tungsten deposits and geological environments for tungsten mineralisation. Commonly known tungsten minerals such as scheelite and wolframite belong to one of two series, the scheelite or the wolframite series, as the primary tungsten minerals. Secondary tungsten minerals are known rather rare, however, some of them plays an important role-of exploration guide in search for tungsten deposits. The geochemistry of tungsten is imperfectly known, and apparently the behaviour of tungsten in geological processes has been the subject of few studies. Recently, some aspects of the fundamental geochemistry of tungsten has been worked out and compiled the data in broad the up to date by many authors. In order to facilitate the better understanding and future exploration of tungsten deposits, an attempt has been made to summarise the existing knowledge of the fundamental geochemistry of tungsten, together with its common geochemical association with various types of tungsten deposits.

• Applied Chemistry for Engineering
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• v.16 no.2
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• pp.187-193
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• 2005

The photocatalyst $TiO_2$ thin film was made from titanium (IV) isopropoxide, ethanol, and HCl by sol-gel method. The surface observation by SEM showed the sample that was coated 5 times at $500^{\circ}C$ had good properties. The component ratio, in atom% of O : Ti by EDX analysis, of 61 : 39 by spin coating was superior than dip coating. It was found that crystal structure changed from anatase phase to rutile phase as a function of the temperature of thin film fabrication, and this was measured by XRD. The photolysis efficiency of total organic compounds (TOC) by lighting UV beam on $TiO_2$ thin film showed 20%~65% within 1 h, and decreased slowly thereafter.

• Korean Journal of Organic Agriculture
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• v.20 no.4
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• pp.703-713
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• 2012

Three types of aeration system were installed in experimental liquid fertilization tanks to investigate the change of characteristics of pig slurry used as a raw material for making livestock liquid fertilizer. The aeration systems of the reaction tanks were composed of three major part: the air suppling part (blower), the air pipe part, and the air diffuser part. In the first tank (reactor A), the air was supplied from the bottom of the reaction tank through air pipe system connecting air diffuser with commercial ordinary blower. In the second tank (reactor B), the air diffuser was located 10cm above the bottom of the reactor. In the third tank (reactor C), the pure air was supplied with circulating pjg slurry. The oxygen content of pure air was about 90%. The pure air was mixed with pig slurry by mechanically in the air suppling part (blower) and the air pipe part. The agitation effect was highest in the reactor C than other reactors. The contents of SS, COD, T-N and T-P of each samples collected at middle part of all reactors were 8,500, 4,188, 694 and 422mg/L; 9,000, 4,247, 813 and 356mg/L; 8,667, 6,910, 973 and 269mg/L, respectively.

• Journal of Animal Environmental Science
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• v.14 no.1
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• pp.23-30
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• 2008

The objective of this study was to estimate the optimum scale of PLMTP (Public Livestock Manure Treatment Plant) for the efficient management of public sector by long-run cost function. An economic analysis was performed using the survey of 52 PLMTP records collected by Ministry of Environment in 2007. The main results obtained in this study can be summed up as follows. The optimum scale under given environmental conditions turned out to be $180{\sim}200m^3$/day which is almost $1.5{\sim}1.6$ times of the average scale of sample plants, $146m^3$/day. This gap between the optimum and current scale suggests that there remains the possibility of further expansion of scale.

• Journal of Animal Environmental Science
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• v.17 no.3
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• pp.181-188
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• 2011

With an increasing livestock population, animal manure production has been steadily increasing in Korea. This trend has forced farmers to spend more money for animal manure treatment in their farm. Therefore, research utilizing animal manure as a renewable resources has become increasingly important. The purpose of this study was to develop a stable advanced wastewater treatment system can be applied to conventional animal wastewater treatment processes and evaluate its contribution to reduce effluent discharge volume by recycling as flushing water. AOP (advanced oxidation process) process improved wastewater treatment efficiency in terms of color, suspended solids (SS) and chemical oxygen demand (COD). Due to the addition of Hydrogen peroxide ($H_2O_2$), pathogens, Salmonella and E. coli, reduction was accomplished. To enhance ozone treatment effect, three levels of ozone test on secondary effluent of pig slurry purification system were conducted. At the level of 5 g/hr, 6.7 g/hr and 8.4 g/hr color of secondary effluent of pig slurry purification system were decreased from 2,433 to 2,199, 2,433 to 1,980 and 2,433 to 243, respectively.

• Journal of Bio-Environment Control
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• v.28 no.4
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• pp.461-470
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• 2019

This study was carried out to quantify the drought stress in grafted watermelon seedlings non-destructively by using chlorophyll fluorescence (CF) imaging technique rather than the visual judgment. Six-day old watermelon seedlings were grown under uniform irrigation for 3 days, and then given drought stress. Afterward, the sensor for the measurement of water content in plug tray cell unit was used to classify the drought-stress level into nine groups from D1 (53.0%, sufficient moisture state) to D9 (15.7%, extremely dry stress), and the 16 CF parameters were measured. In addition, re-irrigation was performed on the drought stressed seedlings(D5 - D9) to determine the growth and photosynthesis recovery level, which was not confirmed by visual judgment. The kinetic curve patterns of CF in three different drought stressed seedling groups were found to be different for the early detection of drought stress. All the 16 CF parameters decreased continuously with exposure to drought stress and drastically decreased from D5 (32.1%) where the visual judgment was possible. The fluorescence decline ratio (Rfd_Lss) started to decrease from the initial drought stress level (D5 - D6), and the Maximum PSII quantum yield (Fv/Fm) was significantly decreased in the later extreme drought stress range (D7 - D9) by re-irrigation recovery test. Thus, Rfd_Lss and Fv/Fm parameters were finally selected as potent indicators of growth and photosynthesis recovery in the initial and later stages of drought stress. Also, to the differences in the numerical values of the individual chlorophyll fluorescence parameters, the drought stress level was intuitively confirmed through the image. These results indicate that Rfd and Fv/Fm can be considered as potential CF parameters for the detection of low and extremely high drought stress, respectively. Furthermore, Fv/Fm can be considered as the best CF parameters for recovery at re-irrigation.

• Journal of Bio-Environment Control
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• v.27 no.2
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• pp.132-139
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• 2018

The photosynthetic rate is an indicator of the growth state and growth rate of crops and is an important factor in constructing efficient production systems. The objective of this study was to develop a canopy photosynthetic rate model of romaine lettuce using the three variables of $CO_2$ concentration, light intensity, and growth stage. The canopy photosynthetic rates of the lettuce were measured at five different $CO_2$ concentrations ($600-2,200{\mu}mol{\cdot}mol^{-1}$), five light intensities ($60-340{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$), and four growth stages (5-20 days after transplanting) in three closed acrylic chambers ($1.0{\times}0.8{\times}0.5m$). A simple multiplication model expressed by multiplying three single-variable models and the modified rectangular hyperbola model including photochemical efficiency, carboxylation conductance, and dark respiration, which vary with growth stage, were also considered. In validation, the $R^2$ value was 0.923 in the simple multiplication model, while it was 0.941 in the modified rectangular hyperbola model. The modified rectangular hyperbola model appeared to be more appropriate than the simple multiplication model in expressing canopy photosynthetic rates. The model developed in this study will contribute to the determination of an optimal $CO_2$ concentration and light intensity with the growth stage of lettuce in plant factories.

• Journal of Bio-Environment Control
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• v.21 no.1
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• pp.57-65
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• 2012

Fertilization is essential to seedling production in nursery culture, but excessive fertilization can contaminate surface and ground water around the nursery. The objective of this study was to find optimal fertilization practice of container seedling production for reducing soil and water contamination around the nursery without compromising seedling quality. This study was conducted to investigate chemical properties of the growth medium, growth performance, chlorophyll fluorescence, and chlorophyll contents of larch ($Larix$ $kaempferi$) growing under three different fertilization treatments (Constant rate, Three stage rate, and Exponential rate fertilization). Root collar diameter and height of larch were not significantly different among treatments even though the nutrient supply of the exponential treatment was half that of the constant and three stage treatments. Chemical properties of the growth medium showed the same trends as root collar diameter and height. The total biomass and seedling quality index (SQI) were higher at Constant than at other treatments, but both SQI of Constant and Exponential were not significantly different. Photochemical efficiency and chlorophyll contents were lower at Exponential than at other treatments, but not significantly different among treatments. Therefore, Exponential fertilization which is 50% fertilizer of other treatments would maximize seedling growth and minimize nutrient loss.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.50 no.2
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• pp.143-151
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• 2024

Ozone is a colorless, toxic gas that is produced when nitrogen oxides and hydrocarbons undergo a photochemical oxidation reaction in the sun's rays. Even at low concentrations, it affects the respiratory system, causing coughing and other harmful effects. It was confirmed that ozone was generated from nitrogen plasma among cosmetic raw materials, and it was found that the concentration of ozone decreased after 1 day. On the other hand, ozone was not detected in ozone-free plasma generated with argon gas. Therefore, we aimed to produce ozone-free cosmetics by utilizing ozone-free plasma. For efficient plasma processing, the non-sinking method was utilized to inject the plasma into layer separation mists, toners, and ampoules, and the stability was observed. It was found that the successful injection of plasma in the layer separation mist was higher than the other two formulations, but decreased sharply compared to the toner and ampoule. It was found that the ozone-free plasma used did not affect the stability of the layer separation mist, toner, and ampoule under low temperature (4 ℃), room temperature (25 ℃), and high temperature (37 ℃, 50 ℃) conditions. Therefore, this study suggests the importance of ozone-free plasma for cosmetic potential and stability of each formulation.

• Journal of the Korean Electrochemical Society
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• v.23 no.2
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• pp.25-38
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• 2020

Photoelectrochemical water splitting has been considered as the most promising technology for generating hydrogen energy. Transition metal dichalcogenide (TMD) compounds have currently attracted tremendous attention due to their outstanding ability towards the catalytic water-splitting hydrogen evolution reaction (HER). Herein, we report the synthesis method of various transition metal dichalcogenide including MoS₂, MoSe₂, WS₂, and WSe₂ nanosheets as excellent catalysts for solar-driven photoelectrochemical (PEC) hydrogen evolution. Photocathodes were fabricated by growing the nanosheets directly onto Si nanowire (NW) arrays, with a thickness of 20 nm. The metal ion layers were formed by soaking the metal chloride ethanol solution and subsequent sulfurization or selenization produced the transition metal chalcogenide. They all exhibit excellent PEC performance in 0.5 M H₂SO₄; the photocurrent reaches to 20 mA cm^-2 (at 0 V vs. RHE) and the onset potential is 0.2 V under AM1.5 condition. The quantum efficiency of hydrogen generation is avg. 90%. The stability of MoS₂ and MoSe₂ is 90% for 3h, which is higher than that (80%) of WS₂ and WSe₂. Detailed structure analysis using X-ray photoelectron spectroscopy for before/after HER reveals that the Si-WS₂ and Si-WSe₂ experience more oxidation of Si NWs than Si-MoS₂ and Si-MoSe₂. This can be explained by the less protection of Si NW surface by their flake shape morphology. The high catalytic activity of TMDs should be the main cause of this enhanced PEC performance, promising efficient water-splitting Si-based PEC cells.