• Title/Summary/Keyword: 광음향 분광

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Measurement of the Radiative Quantum Efficiency of a Solid-State Laser Using Photoacoustic Spectroscopy (광음향 분광을 이용한 고체레이저의 방사양자효율 측정)

  • Kim, Byung-Tai
    • Korean Journal of Optics and Photonics
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    • v.26 no.2
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    • pp.98-102
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    • 2015
  • The radiative quantum efficiency of a solid-state laser was measured by photoacoustic spectroscopy with a PZT as the detector. The radiative quantum efficiency was about 58.3 % for a laser-diode pumped Nd:S-VAP laser under lasing conditions. The measurement of radiative quantum efficiency was presented as an effective method for the optimization of a laser resonator.

Analysis of the oscillation condition optimized at laser-diode end-pumped solid-state laser (반도체레이저 단면여기 고체레이저에서의 최적 공진조건에 관한 해석)

  • 김병태;김태석
    • Korean Journal of Optics and Photonics
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    • v.8 no.4
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    • pp.303-307
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    • 1997
  • The energy transfer of a laser-diode-pumped Nd : S-VAP laser was detected by the photoacoustic technique using a PZT detector. The photoacoustic method suggests an effectvie approach to understand the energy transfer mechanism of the laser cavity, and to find out the optimum output coupler of the oscillator with comparative ease.

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Enhancing the Reproducibility of a Photoacoustic Signal Using a Minimum-volume Cell (최소 부피 광음향 셀의 광음향 신호 재현성 향상에 관한 연구)

  • Kim, Kyong-Seok;Lee, Kew-Seung;Ahn, Hong-Gyu;Lee, Eung-Jang;Kim, Dae-Kyu;Park, Seung-Han
    • Korean Journal of Optics and Photonics
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    • v.22 no.2
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    • pp.77-82
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    • 2011
  • Reproducibility obtained by a minimum-volume cell for photoacoustic (PA) signals is strongly dependent upon the sealing materials and sealing efficiency. Therefore, we have proposed, designed, and constructed an apparatus to enhance the sealing efficiency, and we have examined the reproducibility of amplitude and phase of PA signals with a minimum-volume cell. In particular, we have measured the PA signal as a function of modulation frequency for various rubber O-rings by using our apparatus. The results show that a silicon rubber O-ring can improve the reproducibility of the PA signal and phase by up to 53.4% and 80.4%, respectively, compared to that obtained by using the conventional sealing material, vacuum grease.

Development of Portable Dissolved Gas Analyzer Using photoacoustic spectroscopy (광음향 분광법을 이용한 휴대용 유중가스분석장치 개발)

  • Kim, Choon-Dong;Kim, Chol-Gyu;Park, Sh-Hyun
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.17 no.10
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    • pp.2431-2438
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    • 2013
  • The paper presents a procedure for how to development and theoretical review on Dissolved Gas Analyzer. the information of abnormal thermal stress on electrical power equipment by testing the gas is validated to easy by the gas analyzer presented in the paper. the analyzed information is used to evaluate the stability of electrical power equipment. the existing and selling DGA(dissolved gas analyzer) is so expensive and vast that all DGA product comes from foreign country. The objective of the paper is to prove that PAS(photoacoustic spectroscopy) based on a compact portable DGA solve the fixed type of DGA in order to eliminate the occurring issue directly or indirectly. the proposed DGA is easy to handle, and this can also analysis in real time for testing electrical power equipment. By applying the proposed portable, DGA be utilized in the currently electrical power equipment that are being implemented to reduce cycle of analysis of dissolved gas, it can contribute to improving safety by providing the agility of the evaluation of degradation.

Photoacoustic Investigation of Carrier Transport and Thermal Diffusivity in GaAs and Si (광음향분광법을 이용한 GaAs와 Si 반도체의 열확산도 측정과 운반자특성 연구)

  • Lim, Jong Tae;Han, Ho Youn;Park, Seung Han;Kim, Ung;Choi, Joong Gill
    • Journal of the Korean Chemical Society
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    • v.41 no.7
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    • pp.329-336
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    • 1997
  • Photoacoustic spectroscopy was utilized to investigate the carrier transport and the thermal diffusivity in GaAs and Si. From the frequency dependence of the photoacoustic signal, it is found that heat source was originated from the instantaneous thermalization process in low frequency region. In high frequency region, however, the heat was generated by the nonradiative bulk recombination and the nonradiative surface recombination processes. It was also shown that the photoacoustic effects in GaAs of a direct band gap were governed by all three processes and those in Si of an indirect band gap were produced by the instantaneous thermalization and the nonradiative bulk recombination only. The phase of the photoacoustic signal showed a minimum value in GaAs. In Si, the phase of the photoacoustic signal was monotonically decreased as the modulation frequency was increased, demonstrating the above-mentioned mechanisms of the generation of heat. By measuring the photoacoustic signal, thermal diffusivities of semiconductors were determined to be ∼0.35 ㎠/s for GaAs and ∼1.24 ㎠/s for Si. In addition, the similar values of thermal diffusivities were obtained from the curve fitting of photoacoustic phase spectra.

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An Application of Optoacoustic Technique for the CO Oxidation Reaction Catalyzed by $Gd_{1-x}Sr_xCoO_{3-y}$ (광음향분광법을 이용한 CO 산화반응에서의 $Gd_{1-x}Sr_xCoO_{3-y}$ 촉매효과 연구)

  • Kang Hee-Seok;Oum Ka-Won;Hwang Jin-Soo;Yo Chul-Hyun;Choi Joong-Gill
    • Journal of the Korean Chemical Society
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    • v.37 no.1
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    • pp.55-61
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    • 1993
  • An application of the optoacoustic detection method to investigate the catalytic effect of a perovskite, $Gd_{1-x}Sr_xCoO_{3-y}$ (x = 0.00, 0.25, 0.50, 0.75) system, in the oxidation reaction of CO is described. The optoacoustic signals Of $CO_2$ produced from the oxidation reaction were measured for differing x values in $Gd_{1-x}Sr_xCoO_{3-y}$. By monitoring optoacoustic signals with respect to the time, the concentration ratios of CO and $O_2$, and the temperature, the kinetic information on the catalytic properties of the perovskite for CO oxidation reaction can be obtained. The effect of Sr substitution in $Gd_{1-x}Sr_xCoO_{3-y}$ has been found to show the maximum catalytic effect at x = 0.25 and the substantial increase in catalytic activity at temperatures above 200$^{\circ}C$. It demonstrates that the optoacoustic detection method allows the investigation of the integrated catalytic effect not only for the oxidation reaction of CO, but also for many reactions, in general, by continuously and directly detecting the species associated with the reactions.

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A Study on Single-Beam Photoacoustic Spectroscopy (Single-Beam을 이용한 광음향 분광법에 관한 연구)

  • 김중환
    • Proceedings of the Acoustical Society of Korea Conference
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    • 1984.12a
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    • pp.33-35
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    • 1984
  • A new type single beam photoacoustic spectrometer suitable for measuring optical absorption of condensed powder matter with the automatic calibration capability of a source power spectrum is introduced. The signal processing until of this spectrometer consists of a photoacoustic cell a lock-in amp., a switching circuit and a personal computer. The measured optical absorption spectra of a few material by this method are good agreement with the results obtained by the double-beam photoacoustic spectrometer.

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Acousto-Optic Detection for Photoacoustic Spectroscopy (광음향 분광학의 광학적 측정)

  • 최중길
    • Korean Journal of Optics and Photonics
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    • v.2 no.1
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    • pp.50-56
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    • 1991
  • This paper describes several optical microphones, "optophone", where a low-power He-Ne laser beam is deflected by a reflecting diaphragm mounted on a photoacoustic cell. A comparision of an acousto-optic detection to a conventional microphone shows comparable sensitivities for the photoacoustic detection. The greatest application of these detections may be found where small volume spectro-phone cells are employed, or where conventional microphones cannot be employed because of high or low temperature or chemical corrosion problems. problems.

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Three-Dimensional Fluid Flow Analysis of Photoacoustic Spectroscopy Cell for Measurement of Automotive Exhaust Gas (자동차 배출가스 측정을 위한 Photoacoustic Spectroscopy Cell의 3차원 유동장 해석)

  • 김현철;박종호
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.2
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    • pp.111-118
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    • 2003
  • Recently, environmental damage to urban area becomes serious problem due to the exhaust emissions by increasing the number of vehicle. Especially, exhaust emission from diesel vehicles are blown to be harmful to human health and environment. Photoacoustic Spectroscopy system is very useful technology for simultaneous and continuous measurement of the various components of the automotive exhaust gas. In this study, in order to reduce emission gases from automobile, we tried to develop the measurement system of Photoacoustic Spectroscopy. To improve performance of high sensitive Photoacoustic Spectroscopy system for automotive exhaust emissions, the shape of Photoacoustic Spectroscopy cell was optimized to use the flow analysis. And Exhaust emission data of the 1,500cc gasoline engine was fixed the working fluid. The characteristics of fluid flow for cell were analyzed by various conditions in detail.