• Title/Summary/Keyword: 광물학

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Qualitative and Quantitative Analysis of Space Minerals using Laser-Induced Breakdown Spectroscopy and Raman Spectroscopy (레이저 유도 분해 분광법과 라만 분광법을 이용한 우주 광물의 정성 및 정량 분석 기법)

  • Kim, Dongyoung;Yoh, Jack J.
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.46 no.6
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    • pp.519-526
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    • 2018
  • In order to analyze space resources, it had to be brought to earth. However, using laser-induced breakdown spectroscopy(LIBS) and Raman spectroscopy, it is possible to analyze qualitative and quantitative analysis of space minerals in real time. LIBS is a spectroscopic method in which a high energy laser is concentrated on a material surface to generate a plasma, and the emitted light is acquired through a spectroscope to analyze the atomic composition. Raman spectroscopy is a spectroscopic method that analyzes the molecular structure by measuring scattered light. These two spectroscopic methods are complementary spectroscopic methods for analyzing the atoms and molecules of unknown minerals and have an advantage as space payloads. In this study, data were analyzed qualitatively by using principal component analysis(PCA). In addition, a mixture of two minerals was prepared and a quantitative analysis was performed to predict the concentration of the material.

Investigation of Phosphorus Species in Marine Sediment (해저 퇴적물에 함유된 인의 존재 형태에 대한 연구)

  • 김영규
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.2
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    • pp.151-159
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    • 2003
  • $^{31}$ /P NMR and XRD have been used to study the mineralogical compositions and the phosphorus species in marine sediments near Wolsung nuclear power plant. The core samples with 30cm depth were investigated and no mineralogical changes have been found. The studied marine sediments were composed of quartz, albite, microcline, calcite, and some clay minerals such as illite, smectite, chlorite, and kaolinite. Only orthophosphate-monoester and very small amount of ortho-phosphate-diester were identified as phosphorus species in the studied sample, different from the species reported in other countries. These phosphorus species are mainly from organisms and was exposed to the oxic conditions. The consistent mineralogical compositions as well as the same phosphorus species throughout the entire core samples indicate that the constant oxic condition was kept without any changes in sedimentary conditions or the sediments were deposited with different sedimentary conditions, but later they were disturbed by other activities and exposed to the surface oxic conditions continuously.

Mineralogical Characterization of Mine Tailings in Okdong Mine, Euiseong, Korea (의성 옥동광산 광미에 대한 광물학적 연구)

  • Kim, Jun-Young;Ryu, Chung-Seok;Choi, Seung-Won;Jang, Yun-Deuk;Kim, Jeong-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.21 no.3
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    • pp.297-305
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    • 2008
  • Tailings piled up at Okdong mine in Euiseong consists of fine powder, and are mainly composed of pyrite, sphalerite, chlorite, illite, plagioclase, smectite, gypsum, etc. Smectite is concentrated in the upper part of tailings and chlorite is downwardly increased. Gypsum is generally observed on the surface of the mine tailings, suggesting that it was formed by the reaction of Ca and $SO_4$ in leachate after evaporation. Through the electron microscope study of sphalerite within the tailings, it was observed that there is significant weathering both on surface and in the inner part of the sphalerite, suggesting that the reaction of the failings with groundwater for long period of time contributed a significant addition of Zn and $SO_4$ into the leachate.

An Experimental Study for The Solidifying of Clay Sediments Consisting Soft Foundation By Using Cement and Mineral Admixtures (시멘트 및 광물재료를 이용한 연약지반 점토의 고화실험)

  • Hwang Jin-Yeon;Kang Byung-Joo;Lee Hyomin;Um Jeong-Gi;Cho Tae-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.4 s.46
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    • pp.301-312
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    • 2005
  • The present study investigated the physical changes and reaction products with setting time after mixing of various mineral admixtures such as lime, hydrated lime, gypsum, kaolin, zeolite and diatomaceous earth with four types of cement (portland cement, slag cement, quick lime, hydrated lime) and clay rich sediments in soft foundation. As results, slag cement showed the greater compressive strength than normal portland cement. The mixing experiments with various mineral admixtures and slag cement resulted that gypsum showed the greatest compressive strength. Additionally, we conducted mixing experiments with various mixing ratios of gypsum and slag cement. The experiments showed that the mixing ratio of $30\%$ gypum and $70\%$ slag cement has the greatest compressive strength. Ettringite was produced as a reaction Product. This fact indicates that gypsum effectively promotes hydration reaction and contributed to the greater compressive strength. These experimental results can be used as fundamental data for the stabilization of soft clay foundation.

Mineralogy and Genesis of Hydrothermal Deposits in the Southeastern Part of Korean Peninsula: (3) Miryang Napseok Doposits (우리나라 동남부지역의 열수광상에 대한 광물학적 및 광상학적 연구: (3) 밀양납석 광상)

  • Kim, Soo-Jin;Kim, Jeong-Jin;Choo, Chang-Oh
    • Journal of the Mineralogical Society of Korea
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    • v.5 no.2
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    • pp.93-101
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    • 1992
  • Several "Napseok" mines are distribute in the Miryang area where the volcanic rocks are hydrothermally altered. The "Napseok" are pyrophyllite and dickite, with a small amount of silicates such as quartz, illite, tosudite and dumortierite. Other associated minerals are oxides, hydroxides, sulfides, sulfates and phosphates. Pyrophyllite which occurs as 2M polytype exhibits that the basal spacing increases due to dehydroxylation at 750${\circ}C$. Halloysite shows tubular forms. Wavellite is precipitated in fissures during the latest stage of the hydrothermal alteration process. Five mineral zones, that is pyrophyllite-deckite, illite, halloysite, silica, and albite-chlorite zones, are recognized with decreasing alteration degree. Clay minerals were formed by leaching of Si and alkali ions fron the country rocks, considering mineral assemblages, pyrophyllite polytype and thermodynamical data reported in the literature, temperatures of formation of main clay deposits are assumed to be 270 to 350${\circ}C$.

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Biomineralization and Biomimetics from the Point of Mineral Processing (광물 합성 공정의 관점에서 본 생광물화과정 및 생체모방공학)

  • Lee, Seung-Woo;Jang, Young-Nam;Park, Seung-Bin
    • The Korean Journal of Malacology
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    • v.26 no.1
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    • pp.1-18
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    • 2010
  • Biological organisms produce organic-inorganic nanocomposite composites that are hierarchically organized in composition and microstructure, containing both inorganic and organic components in complicated mixtures. The process related to the generation and regeneration of organic-inorganic complex in nature is called biomineralization process. Understanding how the process operates in a biological environment is a valuable guide to the synthesis of novel advanced material and developing important industrial processes. Like the mechanism of organisms, mollusks were also synthesized from interaction between organic matrices and minerals and their morphology was designed through biomineralization. In this study, shell formation has been studied as a bio-model and the application of biomimetics based on biomineralization is focused.

A Comparative Study on Adsorption Behavior of Heavy Metal Elements onto Soil Minerals : Illite, Halloysite, Zeolite, and Goethite (토양광물에 대한 중-금속원소의 흡착특성 비교연구: 일라이트, 할로이사이트, 제올라이트, 및 침철석)

  • 추창오;성익환
    • Journal of Korea Soil Environment Society
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    • v.4 no.1
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    • pp.57-68
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    • 1999
  • Adsorption behavior of metal elements onto soil minerals such as illite, halloysite. zeolite(clinoptilolite). and goethite was comparatively investigated at $25^{\circ}C$ using pollutant water collected from a gold-bearing metal mine. Speciation of solutions reacted was determined by WATEQ4F program, indicating that most of metal ions exist as free ions and that there is little difference in chemical species and their relative abundances between initial soultion and reacted solutions. The experimental data exhibit that the adsorption extent of elements varies depending on mineral types and reaction time. The adsorption process practically took place within one hour, with Fe and As significantly removed from solutions. On the whole, halloysite is regarded as the most effective adsorbent among minerals used in the experiment. Adsorption properties of alkali elements do not consistent with a manner predicted from hydrated ionic radii.

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Chemistry and Cathodoluminescence Properties of the Carbonate Minerals From the Tertiary Marine Sediments, SE Korea (제3기 해성퇴적층에서 산출되는 탄산염광물의 화학적 및 음극선 발광 특성)

  • Son, Byeong-Kook;Kim, Hyun-Tae
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.2
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    • pp.123-133
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    • 2004
  • Carbonate minerals are examined by cathodoluminescence microscopy and chemical analysis to characterize the carbonate materials occurring in the Tertiary marine basin. The microscopic technique with cathodoluminescence gives new informations that are not obtainable by conventional microscopic techniques. The carbonate cements in sandstones appear to be uniform with transmitted light or with crossed prisms. but the inspection with cathololuminescence reveals foraminiferal tests and rhomb crystals in the carbonate cements. The chemical analysis indicates that the intense luminescence depends mainly on the presence of$ Mn^{ 2+}$ and $Fe^{2+}$ as activator ions, but the $Fe^{2+}$ also acts as an important quencher ion when Fe concentration in dolomite is over 10,000 ppm. The dolomites, which are rich in calcium, are formed at the early stage of diagenesis at a temperature of about 60 ~ $70^{\circ}C$.

Occurrence of REE-bearing Allanite with Th-mineral (thorite) in Wolhoengri, Hadong, Korea (하동군 월횡리에서 토륨광물과 수반된 함REE 갈렴석의 산출상태)

  • Choi, Jin Beom;Kwak, Ji Young
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.4
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    • pp.295-304
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    • 2012
  • Ilmenite mine was developed in the anorthosites which intruded Precambrian Jirisan gneiss complex in Wolheongri, Okjong-myeon, Hadong. Ti-ore bodies are confined to the intercumulated type anorthosites, where REE-bearing allanite occurred as veins. The chemistry of allanites shows relatively low in CaO (11.02~12.81 wt%), but high in ${\Sigma}R_2O_3$ (R = Ce, La, Nd) (17.21~21.58 wt%), respectively. Abnormally high radioactive detection ascribes to the presence of small particles of thorium mineral known as thorite ($ThSiO_4$). Thorite shows 65~72.78 wt% ($ThO_2$) and 5.49~12.78 wt% ($UO_2$) in composition. The radioactive prospecting could be a strong tool to find REE-bearing allanite which is closely associated with Ti-ore deposits.

The Investigation of Mineral Distribution at Spirit Rover Landing Site: Gusev Crater by CRISM Hyperspectral data and Target Detection Algorithm (CRISM 초분광 영상과 표적 탐지 알고리즘을 이용한 Spirit 로버 탐사 지역: Gusev Crater의 광물 분포 조사)

  • Baik, Hyun-Seob;Kim, Kwang-Eun
    • Korean Journal of Remote Sensing
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    • v.32 no.5
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    • pp.403-412
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    • 2016
  • Compact Reconnaissance Imaging Spectrometer for Mars(CRISM) is 489-band hyperspectral camera of Mars Reconnaissance Orbiter(MRO) that provided data used on many mineral researches over Martian surface. For the detection of minerals in planet, mineral index using a few spectral bands have been used. In this study, we applied Matched Filter and Adaptive Cosine Estimator(ACE) target detection algorithm on CRISM data over Gusev Crater: landing site of Spirit(Mars Exploration Rover A) to investigate its mineral distribution. As a result, olivine, pyroxene, magnetite, etc. is detected at Gusev Crater's Columbia Hills. These results are corresponding to the Spirit rover's field survey result. It is expected that hyperspectral target detection algorithms can be used as effective and easy to use method for the detection and mapping of surface minerals in planet.