• Journal of the Korea Convergence Society
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• v.8 no.3
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• pp.169-176
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• 2017

Casting process includes wax pattern, investment, dewaxing, curing, casting, etc., and each single process is important to achieve a good result. Since 2000, 3D printers have been developed and widely used; as more prefer UV Curavle resin method over wax method, resultant casting defects have become worse. To resolve such problem, preceding research revealed casting defects of existing wax method. In particular, defects of UV Curavle resin method showed difference in investment, dewaxing, deresinating and curing compared to the existing one. Accordingly, results were presented through casting tests; especially, a temperature rising curve only for UV Curavle resin was shown rather than one for the existing method. Lastly, this research classified those not available with direct casting and suggested mold manufacturing. This research is expected to be useful for 3D printer users or those who would conduct direct casting with UV Curavle resin.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2004.05a
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• pp.13-13
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• 2004

나노테크놀러지 중의 한 가지인 나노임프린트 리소그래피 기술은 수 ∼ 수십 나노 급의 선폭을 가지는 스탬프(stamp)를 전자빔 리소그래피(electron beam lithography)를 이용하여 제작한 후 스탬프에 형성된 패턴과 동일한 형상을 원하는 곳에 모사하는 기술이다. 이 기술은 크게 열을 가하는 방식과 UV 경화성 수지를 이용한 방식으로 나뉜다. 열을 가하는 나노임프린트 리소그래피 방식의 경우는 열 경화성 수지를 이용하여 고온 조건에서 스탬프를 고압으로 눌러 원래의 형상을 모사하며, UV 나노임프린트는 광경화 반응을 이용하여 수지를 경화 시켜 모사하는 차이점이 있다.(중략)

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2004.05a
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• pp.238-238
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• 2004

폴리머는 20세기 중반부터 그 사용량이 급격히 늘어나고 있고 또한 사용범위도 매우 광범위해진 중요한 재료이다. 석유화학공업의 발달과 더불어 초기의 고분자공업은 범용수지의 생산에 주로 의존하였으나 최근에는 용도가 다양해지고 기능화 되면서 소량, 고가의 기능성 고분자재료들이 많이 나타나고 있다.(중략)

• Journal of the Korean Society for Precision Engineering
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• v.23 no.6 s.183
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• pp.174-179
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• 2006

The curing characteristics of a photocurable resin are critical factors that often decide the ultimate resolution and structural sharpness of a final product fabricated by microstereolithography$(\mu-STL)$. In this study, we investigated the curing characteristics of the FA1260T photopolymer under a visible laser light of 42nm wavelength. Modification of the curing property of the FA1260T is attempted to reduce the cure depth $(D_c)$ by adding a radical quencher to the resin. Also, an organic solvent was used to reduce the resin viscosity for an improvement of the flatness of the liquid surface during layer-by-layer curing. As a result, the minimum $D_c$ has been reduced over a factor of 3 with no abrupt increase. Samples of three dimensional microstructures fabricated using the modified FA1260T are presented.

• Polymer(Korea)
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• v.34 no.5
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• pp.469-473
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• 2010

The curing mechanism and characteristics of UV curable acrylate resins were studied using Photo-DSC, FTIR, and Raman spectroscopy. Effects of chemical structures of acrylate, numbers of functional group, and UV intensity on curing kinetics were investigated with Photo-DSC. FTIR and Raman spectroscopy has been used to understand curing mechanisms and reaction conversion. In order to investigate the effect of oxygen on the photo-curing reaction, the curing process was compared between the acrylate and thiol-ene resins. The reaction conversion was found to be less than 80% for acrylate resins. The photo-curing reaction of the acrylate resin could not proceed to the end because of oxygen which acts as a reaction inhibitor while the thiol-ene resin was hardly affected from oxygen during the curing process.

• Polymer(Korea)
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• v.37 no.1
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• pp.121-126
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• 2013

UV-curable high refractive index di-functional epoxy acrylate, 4,4'-thiodibenzenethiol diglycidyl ether diacrylate, was synthesized from acrylic acid and 4,4'-thiodibenzenethiol diglycidyl ether that was obtained by reacting 4,4'-thiodibenzenethiol and epichlorohydrin using a direct method (Taffy process). Its chemical structure was identified by $^1H$ NMR and FTIR. After its dilution with a reactive diluent, 2-phenoxythiol ethyl acrylate as 5, 10, 15, 20, and 30 wt% content, the relationship between their viscosity and refractive index was investigated. Their degree of cure decreased with increasing the amount of reactive diluent, and the refractive index of UV-cured film increased with increasing the degree of cure.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.5
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• pp.1773-1777
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• 2010

The Application of UV curing technique for poly (vinyl chloride) (PVC) floor tiles coating has improved the quality of PVC floor. Several formulations were made including acrylated oligomers based on a polyurethane were blended with reactive monomers, photoinitiators and other additives. The used oligomers are commercial aliphatic urethane acrylates. Thin films were prepared on PVC tiles by bar coating with different formulations using UV radiation. The coating resins were characterized by FTIR. The properties of UV-cured films such as gloss and adhesion were examined. The properties of UV-cured films dependent on the influence of composition and processing conditions was studied.

• Journal of the Korean Society for Precision Engineering
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• v.25 no.7
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• pp.27-32
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• 2008

• Proceedings of the KIEE Conference
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• 1995.07b
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• pp.889-891
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• 1995

3차원 CAD System의 보급이 확대되고, 또한 설계단계에 3D CAD의 적용이 진행되어 가면서 CAD System에 의한 3차원 입체모형 제작기술에 많은 관심이 주목되고 있다. 특히 최근에는 상품개발 Cycle의 단축화와 Concurrent Engineering 실현의 중요한 도구로써 다양한 기능을 제공하고 있다. 그 방법중의 하나가 특정한 파장에서 반응하는 광경화성 수지에 자외선의 Laser 광을 조사하여 원하는 입체형상을 제작하는 기술이다. 본 논문에서는 광조형물의 제작원리와 시스템 개발에 대하여 논하고자 한다.

• Applied Chemistry for Engineering
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• v.23 no.1
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• pp.18-22
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• 2012

Photocurable binder for a transparent glass fiber composite was prepared with alicyclic methacrylate and fluorene-based diacrylate. ANOVA (analysis of variance) analysis was used to know main factors affecting the conversion of photocurable binder. It showed radiation intensity and photoinitiator (PI) concentration were main factors. The conversion of photocurable binder was simply increased with radiation intensity. Its increment however was abated with increasing PI concentration. We found that average conversion of the binder measured by FTIR-ATR was 87% when it was exposed to $5J/cm^2$ of UV dose with 5 wt% of PI. Oxime ester type PI was very effective to get a high degree of conversion, but it caused a yellowing problem. Owing to post-baking process, UV cured film showed an improved thermal stability by increase of conversion and removal of volatile organic compounds. TG% at $260^{\circ}C$ of film cured with 5 wt% of PI (TPO+MBF) and $5J/cm^2$ of UV radiation increased from 95.4 to 99.0% by post-baking at $230^{\circ}C$ for 5 min.