• Title/Summary/Keyword: 과포화

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Crystal Chemistry and Paragenesis of Aluminum Sulfphates from Mudstones of the Yeonil Group (II): Alunite-halloysite (연일층군 이암에서 산출되는 알루미늄 황산염 광물의 결정화학 및 생성 (II): 알루나이트-할로이사이트)

  • 노진환;최진범
    • Journal of the Mineralogical Society of Korea
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    • v.13 no.1
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    • pp.1-14
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    • 2000
  • 알루나이트는 포항지역의 제3기 연일층군의 이암 층내의 탄산염 결핵체 주변에서 할로이사이트와 함께 극미립 변질물 (1-2 $\mu\textrm{m}$)로서 산출된다. 알루나이트는 정육면체와 유사한 능면체 결정형을 이루고 침상 내지 단주상의 할로이사이트와 밀접한 공생관계를 이룬다. X-선회절 분석에 의해서 이 알루나이트는 a=6.9897(1) $\AA$, c=17.2327(4)$\AA$, V=728.75(3) $\AA$3의 격자상수값을 갖는 것으로 밝혀졌다. X-선형광된 이 알루나이트의 화학식은 (K0.94N0.06)(Al2.55Fe3+0.45)(SO4)2(OH)6 으로서, 나트로알루나이트 단성분을 6-7 mole%정도 함유하는 것으로 분석되었다. 또한 시차열분석 (TG-DTG-DTA)을 통해서 알루나이트의 승화성 성분들 (H2O와 SO3)의 존재와 함유 정도를 조사하였고, 고온X-선회절분석을 병행하여 이 광물의 OH기의 이탈 반응 (52$0^{\circ}C$)과 고온상으로의 전이 반응 ($600^{\circ}C$$700^{\circ}C$)을 감정 하였다. K/Ar 법으로 측정된 알루나이트의 생성 연대 ($0.342\pm$0.008 Ma)와 안정동위원소들의 분석 결과 ($\delta$18Oso4=-1.7, $\delta$DSMOW=-31, $\delta$34S=-10.8)는 이 알루미늄 황산염 광물이 연일충군의 융기 이후에 야기된 민물의 유입에 의한 표성기원의 변질작용의 결과로 생성되었음을 지시한다. 알루나이트+할로이사이트 공생군의 침전은 이암 내에서 조성된 강산성 (pH=2-3)의 알루미늄 황산염 용액이 탄산염 결핵체를 만나 반응하여 pH가 국지적으로 증가되어 (pH=4) 과포화되는 과정에 의해서 야기되었다. 컴퓨터를 이용한 Al3+의 포화지수에 관한 화학적 평형 모델링 실험 결과, 알루미늄 황산염 용액으로부터의 알루나이트와 할로이사이트의 침전은 pH=4 및 \ulcornerSO42-=10-4M 조건에서 K+과 Si(OH)4의 농도가 10-4M 이상 유지되어야 가능한 것으로 밝혀졌다.

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A Traffic congestion judgement Algorithm development for signal control using taxi gps data (택시 GPS데이터를 활용한 신호제어용 혼잡상황 판단 알고리즘 개발)

  • Lee, Choul Ki;Lee, Sang Deok;Lee, Yong Ju;Lee, Seung Jun
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.15 no.3
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    • pp.52-59
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    • 2016
  • COSMOS system which was developed in Seoul for real-time signal control was designed to judge traffic condition for practicing signal operation. However, it occurs efficiency problem that stop line detection and queue length detection could not judge overflow saturation of street. For that reason, following research process GPS data of Seoul city's corporationowned taxi to calculate travel speed that excluded existing system of stop line detection and queue length detection. Also, "Research of calculating queue length by GPS data" which was progressed with following research expressed queue length. It is based on establishing algorithm of judging congestion situation. The algorithm was applied to a few areas where appeared congestion situation consistently to confirm real time traffic condition with established network. [Entrance of the National Sport Institute ${\rightarrow}$ Gangnam station Intersection, Yuksam station intersection ${\rightarrow}$ National Sport Institute.

Formation Behavior of Precipitated Calcium Carbonate Polymorphs by Supersaturation (과포화도에 의한 침강성 탄산칼슘 다형체의 생성거동)

  • Ahn, Young jun;Jeon, ong Hyuk;Lee, Shin Haeng;Yu, Young Hwan;Jeon, Hong Myeong;Ahn, Ji Whan;Han, Choon
    • Resources Recycling
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    • v.24 no.4
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    • pp.22-31
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    • 2015
  • From results obtained by adjusting experimental variables based on the kinetic, the nucleation rate for formation of precipitated calcium carbonate (PCC) was investigated. Formation behavior of PCC was investigated for various concentrations of NaOH solution and $Na_2CO_3$ addition methods in the $Ca(OH)_2$ slurry. The range of nucleation rate was investigated for dissolution rates of major ion concentrations, $Ca^{2+}$ and $CO{_3}^{2-}$. In case of high concentration of major ions, vaterite and calcite were synthesized. The high nucleation rate was achieved for lower either $Ca^{2+}$ or $CO{_3}^{2-}$ ion concentration, calcite was mainly synthesized and when concentration of major ions was low, aragonite was synthesized. Furthermore, the formation of calcite was decreased with increasing concentration of NaOH. homogeneous aragonite could be obtained by addition 5 M NaOH. Therefore, in this study, specific shape of polymorphs could be prepared through controlling supersaturation.

Korean Institute of Electrical and Electronic Materials (규소강판 코어소재의 가공 방법에 따른 철손 특성)

  • Kim, I.S.;Jeong, S.J.;Min, B.K.;Kim, H.W.;Song, J.S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.343-344
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    • 2006
  • 방향성 규소강판을 tape-wound core 형태로 제작하여 가공방법에 따른 자기적 특성을 조사 하였다. 그 결과 곡률반경이 40mm인 시료에서 보자력(Hc)과 포화자속밀도(Bs)는 우수한 값을 나타내었고, 보자력은 0.02Oe, 포화자속밀도는 1.85T 이었다. 현재 국내에서 생산되고 있는 방향성 규소강판의 자속밀도값 보다 우수한 값을 나타내었다. 본 연구로부터 방향성 규소강판을 이용하여 권자심을 제작할 때 도입되는 탄성변형에 대한 대책의 중요성과 코어 소재의 가공방법이 자기적 특성에 미치는 영향을 통해 고효율 방향성 규소강판 개발의 가능성을 확인하였다.

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Capillary Hysteresis Model in Unsaturated Flow - Development of Model - (비포화 흐름에서 모세관 이력현상 모형의 고찰 - 모형의 개발 -)

  • Park, Chang Kun;Sonu, Jung Ho
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.13 no.4
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    • pp.131-140
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    • 1993
  • A new model which requires one branch of main curves for the model calibration is developed based on the assumption that the weighting factor accounting for the pore blockage effect against air entry, $P_a({\theta})$, in Mualem's Model III-1 has a linear relation to the dimensionless pore radius r. The proposed model simulates experimental data more accurately than existing models which require one branch of main curves for the model calibration. Previous study showed that Model III-1 is the most appropriate model among domain models which require two branches of main curves for the model calibration. In comparison of the proposed model with Model III-1, both simulate hysteresis curves with almost the same accuracy. The proposed model can be applied efficiently in analyzing the unsaturated flow.

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Electromigration Characteristics in Al-1%Si hin Film Interconnections for Microelectronic Devices (극소전자 디바이스를 위한 Al-1%Si 박막배선에서의 electromigration 특성)

  • 박영식;김진영
    • Proceedings of the Korean Vacuum Society Conference
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    • 1995.06a
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    • pp.48-49
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    • 1995
  • 전자소자의 축소화에 따라 electromigration은 점차 반도체 디바이스의 주요 결함 원 인으로 부각되고 있다. 본 실험은 현재 배선 재료로 널리 사용되고 있는 Al-1%Si 금속박막 배선의 electromigration에 대한 온도 및 배선길이 의존성에 관하여 연구하였다. ppLCC(pplastic Leaded Chipp Carrier) ppackage된 ppSG(8000$\AA$)/SiO2(1000$\AA$)/Al-1%Si(7000 $\AA$)/SiO2(5000$\AA$)/pp-typpe Si(100)의 보호막처리된 시편과 Al-1%Si/SiO2(5000$\AA$)/pp-typpe Si(100)의 보호막처리되지 않은 시편등을 standard pphotolithograpphy 공정을 이용하여 각각 제작하였다. 선폭 3$mu extrm{m}$, 길이 100, 400, 800, 1600$\mu\textrm{m}$의 등의 Al-1%Si 박막배선구조를 사용하 였다. 가속화실험을 위해 인가된 D.C 전류밀도는 4.5$\times$106A/cm2이었고 실온에서 10$0^{\circ}C$까지 의 분위기 온도에서 electromigration를 실행하였다. 박막배선길이에 따른 MTF(Mean Time-to-Failure)는 임계길이 이상에서 포화되는 경향을 보이며 임계길이는 Al-1%Si 박막 배선에서 분위기온도에 따라 길이 400$\mu\textrm{m}$과 800$\mu\textrm{m}$범위에서 나타났다. 각 시편에서 electromigration에 대한 활성화에너지도 MTF의 특성과 유사하게 임계길이 이상에서 포화 되는 특성을 타나내었다.

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The Hydrogen Loading Method for FBG Fabrication (광섬유격자 제작을 위한 수소 처리 방법 연구)

  • Song, Jeong-Hwan;Lee, Kyung-Shik
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.37 no.7
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    • pp.29-35
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    • 2000
  • The relationship between calculated hydrogen molecular concentration in fiber core and measured index change during the grating growth is analyzed. The index change increases by ${\sim}2{\times}10^{-5}$ per 100ppm of $H_2$ concentration in standard telecommunication optical fiber and the defects related photosensitivity generate ${\sim}3.8{\times}10^{17}$ per 100ppm of $H_2$.

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Analysis of Parameters Affecting LiDAR Intensity on Rock (암석에 대한 라이다 반사강도의 영향 인자 분석)

  • Kim, Moonjoo;Lee, Sudeuk;Jeon, Seokwon
    • Tunnel and Underground Space
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    • v.30 no.4
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    • pp.417-431
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    • 2020
  • In this study, a fundamental investigation was made on how to use LiDAR technology to determine the degree of weathering and alteration of rock mass. The purpose of the study was to identify the affecting parameters to LiDAR intensity and to quantitatively assess the relations among them through laboratory-scale experiment. A few potential affecting parameters were selected including scanning distance, incidence angle, surface roughness, surface color, mineral composition, and water saturation. In the experiment, FARO LiDAR unit was used for twelve different types of specimen. It was observed that the intensity was affected by, in the order of importance, surface color, incidence angle, scanning distance, property of rock, water condition, and surface roughness.

Further Systematic Studies on Cornus and Relatives by Immunoelectrophoresis (면역학적 전기영동에 의한 층층나무속과 그 근연군의 계통학적 추가연구)

  • Lee, Yoo-Sung
    • Journal of Plant Biology
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    • v.28 no.2
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    • pp.95-104
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    • 1985
  • Additional serological data from radial immunodiffusion and conventional immunoelectrophoresis with combination of presaturation of antibody were obtained for further interpretation of Cornus (and relatives) systematics. Pollen proteins were compared by qualitative and quantitative means. Cornus drummondi and C. stolonifera are very similar to C. florida, and C. amomum and C. recemosa are less similar. Nyssa constitutes the next distinct and most similar family, Nyssaceae to the Cornaceae. The serological affinities indicate that Corokia and Griselinia should not be included within the Cornaceae. Their taxonomic treatment to elevate to the family level is now awaiting until more data are accumulated.

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Ferromagnetic Resonance Study of an YIG Thin Film Grown by LPE Method (LPE법으로 제조한 YIG 박막에 대한 강자성공명 연구)

  • 이수형;염태호;윤달호;김약연;한기평;이상석
    • Journal of the Korean Magnetics Society
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    • v.9 no.2
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    • pp.85-90
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    • 1999
  • The ferromagnetic resonance study of the magnetostatic wave modes for an YIG thin film, grown by a liquid phase epitaxy method, was performed by an FMR spectrometer at room temperature. The magnetostatic surface wave and backward volume wave modes show periodic excitations in parallel configuration, whereas the complex spectra were observed in perpendicular configuration. The resonance spectra in parallel configuration can be well explained by the Walker and Damon-Eshbach theory. The peak-peak line width of uniform mode was 0.4 Oe. The saturation magnetization $M_s$ of the YIG thin film was calculated as 137 emu/㎤. In order to know the dependence of the magnetostatic modes as a function of the saturation magnetization and the thickness, the (1,1) and (3,1) modes of the magnetostatic backward volume wave were compared and theoretically calculated.

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