• 제목/요약/키워드: 과냉각 수용액

검색결과 10건 처리시간 0.021초

가압조건이 정지상태 과냉각 수용액의 해소에 미치는 영향 (Effect of pressurization on dissolution of a supercooled aqueous solution with a stationary state)

  • 김병선;백종현;홍희기;강채동
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2006년도 하계학술발표대회 논문집
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    • pp.132-137
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    • 2006
  • Supercooled type ice slurry system is hard to keep a proper supercooling degree when solution becomes supercooling state. This is the reason of the ice blockage in pipe or cooling part due to an unstable cooling state. In this study, a cooling experiment was performed to pressurized solution in a stationary state. The behaviors during the supercooled aqueous solution were investigated at fixed flow rate of brine and aqueous solution of ethylene glycol 7 mass%. Also the effect to the freezing point of supercooled aqueous solution was investigated to the different pressure 101, 202, 303, and 404 kPa. At results, the pressure of the aqueous solution in the cylinder increased the supercooling degree increased and dissolution of supercooled point decreased.

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Xanthomonas translucens KCTC 2751의 최적배양과 빙핵 활성 검토 (The Investigation on the Optimum Culture Conditions and the Ice Nucleating Activity of Bacterium Xanthomonas translucens KCTC 2751)

  • 김영문;강성일;장영부;전병진;공재열
    • 한국식품과학회지
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    • 제38권2호
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    • pp.249-255
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    • 2006
  • 본 실험에서는 기존의 실험 방법인 Vail에 의해 고안된 drop freezing method에 의하여 빙핵활성을 측정하는 방법보다 정확한 빙핵활성을 연구하기 위하여 thermocouple을 사용한 Thermoelectric thermometry를 응용하여 장치를 제작하여 과냉각도와 과냉각 시간을 보는 방법으로 빙핵활성을 측정하였다. 본 실험에 사용된 균주는 KCTC에서 분양받은 Xanthomonas translucens KCTC 2751을 이용하여 균체 생장과 빙핵활성의 최적 조건을 검토하였다. 탄소원의 영향에서는, 1.0%(w/v) maltose에서, 질소원으로는 1.4% yeast extract(w/v)와 0.8% digested of gelatin(w/v), 무기 염류에서는 0.03% KCI, 온도와 초기 pH는 각각 $25^{\circ}C$, 6.5에서 균체 생장이 뛰어났고 과냉각도가 가장 높게 나타났다. 따라서 본 연구의 최적 배양 조건은 초기 배양 조건 보다 균체의 양은 5배나 증가하였으며 과냉각도도 $-1.76^{\circ}C$에서 $-1.36^{\circ}C$로 상승하였다. 그리고 Xanthomonas translucens KCTC 2751를 첨가한 증류수의 과냉각도는 균체를 첨가하지 않은 증류수의 과냉각도$(-7.9^{\circ}C)$보다 $6.54^{\circ}C$ 높게 나타났으며, 상업적으로 사용되는 빙핵제인 silver iodide를 첨가한 증류수의 과냉각도$(-1.56^{\circ}C)$ 보다 $0.2^{\circ}C$ 높게 나타났다. 동결 농축 실험은 균체를 첨가한 saccharose 수용액은 200 min 경과 후에는 동결 실험 전에 비하여 약 2.5배가 증가하였고, 동결 부분의 용질 농도는 약 30% 정도 로 감소하였는데 비해 균체를 첨가하지 않은 수용액은 약 2.1배가 증가하였고, 동결 부분의 용질 농도는 약 40% 정도로 감소하였다.

정지상태 수용액에서 가압과 냉각속도가 과냉각해소에 미치는 영향 (Effect of Pressurization and Cooling Rate on Dissolution of a Stationary Supercooled Aqueous Solution)

  • 김병선;백종현;홍희기;강채동
    • 설비공학논문집
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    • 제19권12호
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    • pp.850-856
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    • 2007
  • In a supercooled or capsule type ice storage system, aqueous solution (or water) may have trouble with non-uniform dissolution though the system contributes to the simplicity of system and ecological improvement. The non-uniform dissolution increases the instability of the system because it may cause an ice blockage in pipe or cooling part. In order to observe the supercooled state, a cooling experiment was performed with pressurization to an ethylene glycol(EG) 3 mass% solution in stationary state. Also, the effect of the pressurization from 101 to 505 kPa to the dissolution of supercooled aqueous solution was measured with the dissolution time of the supercooled aqueous solution at a fixed cooling rate of brine. At results, the dissolution of supercooled point decreased as the pressure of the aqueous solution in the vessel increased. Moreover, the dissolution point increased as the heat flux for cooling increased.

수용액의 동결에 영향을 미치는 계면활성제의 효과에 관한 연구 (A Study on the Effect of Surfactant on the Freezing of Aqueous Solution)

  • 김명준
    • Journal of Advanced Marine Engineering and Technology
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    • 제31권6호
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    • pp.694-698
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    • 2007
  • This present study has dealt with the effect of surfactant on the freezing of aqueous solution Sodium chloride aqueous solution was used to measure the effect of surfactant and the main parameters of this experiment were temperature of bath, revolution of stirrer. and the radial velocity of NaCl solution. The acquired main conclusions are as follows; 1) the lower super-cooling temperature make hardly to attach the ice on beaker, 2) the size of ice become smaller to add the surfactant, 3) the ice packing factor increase with increasing of stirrer revolution.

동결농축법을 이용한 염수 및 중금속 수용액의 동결거동에 관한 실험 연구 (An Experimental Study on Freezing Behavior of NaCl and Heavy Metal Aqueous Solution Using Freeze Concentration Method)

  • 김정식;임승택;오철
    • 한국항해항만학회지
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    • 제37권2호
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    • pp.129-135
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    • 2013
  • 동결농축폐수처리의 기술은 열역학적 효율이 높고 에너지 소비량이 작아 중소규모로 적합하며, 용수 재활용과 융해열의 냉열 재이용이 가능한 장점을 가지고 있다. 본 연구에서는 폐수 처리효율이 높은 동결농축폐수처리장치의 개발을 위해 수직원관 형태의 제빙관을 대상으로 염화나트륨수용액을 이용한 기초 실험을 통해 냉각면 온도, 기포 분사 방법에 따른 분리 성능을 확인 후 대표적 중금속인 Pb, Cr 수용액을 대상으로 냉각면 온도, 기포 직접 분사, 과냉각을 방지하기 위한 용질을 포함하지 않은 초기 빙층 두께의 영향에 따른 중금속 분리 성능을 실험 통해 확인하였다. 실험결과 두 수용액에서 모두 냉각면의 온도가 낮을수록 동결층의 성장속도가 빨라지고 용질의 분리효율이 저하되었다. 기포를 분사하는 방법 중에는 환모양의 노즐을 통해 동결계면에 직접 분사하는 방법이 원통벽면을 통해 간접 분사하는 것 보다 분리효율이 높게 나타났으며, 초기 빙층의 두께에 따른 실험에서는 1mm 보다는 5mm의 두께에서 분리효율이 더 우수한 것으로 나타났다.

수평냉각관내에서 유동하는 유기수용액의 제빙형태 (Ice Marking Pattern of Flowing Organic Water Solution in a Horizontal Cooled Tube)

  • 박기원
    • Journal of Advanced Marine Engineering and Technology
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    • 제24권5호
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    • pp.52-57
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    • 2000
  • Recently large capacity of electric equipment and increasing in atomic power generation are shown. One of the reason is shortage of the electric power supply for air conditioning load during summer. And every consumer is concerning about economical refrigeration and air conditioning system to decreases electric power consumption and decrease in global warming. For these necessities, ice making thermal storage system is required. Therefore, in this paper, the possibility of continuous slurry ice making using flowing organic water solution in cooled circular tube has been investigated. The experiments was carried out under some parameters of concentration and velocity of water solution, temperature of cooled tube wall, and control pressure in tube, As a result, four types of operating conditions in the pipe, that was supercooling, continuous ice making, intermittent ice making and ice blockage, were classified . And it was found that the critical condition for continuous ice making was acquired as a function of these experimental parameters.

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가압 판형 열교환기에 의한 수용액의 아이스슬러리 생성 (Ice Slurry Formation of a Solution in a Pressurized Plate Heat Exchanger)

  • 이동규;김병선;백종현;홍희기;강채동
    • 설비공학논문집
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    • 제18권7호
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    • pp.596-602
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    • 2006
  • Ice adhesion and blockage problems have been issued in continuous ice slurry making process. So we composed continuous ice slurry making device using a commercial small plate heat exchanger (PHX), and investigated character of ice formation. An experiment of ice formation was peformed with an aqueous solution of ethylene glycol 7 mass%. In the experiment, the effect of the pressurization on ice slurry formation during the cooling process was investigated. The pressurization test for the aqueous solution was performed by setting valves at the PHX inlet and outlet. At the results, the time of continuous ice formation increased as the pressure of the plate heat exchanger increased for cooling temperature of $-5^{\circ}C$. Also continuous ice formation at the cooling temperature of $-7^{\circ}C$ showed a possibility. It was found that the pressurization may contribute to suppress the dissolution of supercooled aqueous solution in the PHX.

판형 열교환기를 이용한 과냉각수용액에서 유동과냉도 및 냉각속도가 연속제빙에 미치는 영향 (Influence of the Supercooling Degree and Cooling Rate on a Continuous Ice Formation by a Supercooled Aqueous Solution in Flow Using a Plate Heat Exchanger)

  • 이동규;백종현;홍희기;강채동
    • 설비공학논문집
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    • 제19권9호
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    • pp.647-653
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    • 2007
  • In dynamic ice storage system(DISS), ice slurry is formed not only from solution freezing by mechanical removing parts but also supercooled solution. However, in order to perform continuous ice formation in the system without mechanical moving parts, supercooled aqueous solution should be formed stable through cooling heat exchanger and be dissolved uniformly in storage tank. In previous study, the time of ice slurry increased as the pressure of the cooling heat exchanger(PHX) increased. In this study, a cooling experiment of an ethylene glycol 7mass% solution was performed with various inlet temperature of the PHX, which has constant brine inlet temperature of $-7^{\circ}C$. The temperature in the storage tank maintained to freezing point of the solution. At results, the time of ice slurry formation increased as the supercooling degree decreased and the cooling rate increased.