• Title/Summary/Keyword: 공학분석

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Measurement of the Quantity of Hydrogen Peroxide Produced in the Ultrasound-irradiated Aqueous Solution of Organic Compounds (초음파를 조사(照射)한 유기화합물 수용액 속에서의 과산화수소 생성량의 측정)

  • Mo, Se-Young;Chang, Hong-Ki;Lee, Kyung-Jae;Jang, Gun-Eik;Sohn, Jong-Ryeul
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.1
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    • pp.61-71
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    • 2000
  • When irradiate the power ultrasound into the aqueous solutions, water vapor is decomposed by the heat of very high temperature in the cavitation bubble to produce OH (hydroxyl radical) and H (hydrogen radical), and these radicals play a role in decomposing the substances in aqueous solution by oxidation and/or reduction, and in producing the hydrogen peroxide. Accordingly it is possible to predict that the quantity of hydrogen peroxide produced may correlate with the sonolysis mechanism of the substance in aqueous solution. Thus to confirm this prediction, the quantities of hydrogen peroxide produced from each of the air saturated distilled water and three aqueous solutions of TCE, benzene, and 2,4-DCP that are prepared by dissolving them into distilled water are measured. As a result, it showed that the quantity of hydrogen peroxide produced from the distilled water and three aqueous solutions are increased in order of distilled water>TCE solution>2,4-DCP solution>benzene solution, and decrease with decrease in concentration of organic substance, which coincide with the sonolysis mechanisms reported that TCE in aqueous solution is decomposed directly by the pyrolysis in and around the cavitation bubbles when its concentration is high and by the radical reaction when low, however, benzene and 2,4-DCP are decomposed not only by the pyrolysis but also by the radical reactions. Effects of such experimental parameters as the acoustic frequency and power and as the concentration showed that the higher the acoustic frequency and the lower the acoustic power, the less the quantity of hydrogen peroxide was produced. This result coincide with the theory of ultrasound for the relation between the cavitation that is the energy source of the power ultrasound in aqueous solution and these experimental parameters.

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Computing the Dosage and Analysing the Effect of Optimal Rechlorination for Adequate Residual Chlorine in Water Distribution System (배.급수관망의 잔류염소 확보를 위한 적정 재염소 주입량 산정 및 효과분석)

  • Kim, Do-Hwan;Lee, Doo-Jin;Kim, Kyoung-Pil;Bae, Chul-Ho;Joo, Hye-Eun
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.10
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    • pp.916-927
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    • 2010
  • In general water treatment process, the disinfection process by chlorine is used to prevent water borne disease and microbial regrowth in water distribution system. Because chlorines were reacted with organic matter, carcinogens such as disinfection by-products (DBPs) were produced in drinking water. Therefore, a suitable injection of chlorine is need to decrease DBPs. Rechlorination in water pipelines or reservoirs are recently increased to secure the residual chlorine in the end of water pipelines. EPANET 2.0 developed by the U.S. Environmental Protection Agency (EPA) is used to compute the optimal chlorine injection in water treatment plant and to predict the dosage of rechlorination into water distribution system. The bulk decay constant ($k_{bulk}$) was drawn by bottle test and the wall decay constant ($k_{wall}$) was derived from using systermatic analysis method for water quality modeling in target region. In order to predict water quality based on hydraulic analysis model, residual chlorine concentration was forecasted in water distribution system. The formation of DBPs such as trihalomethanes (THMs) was verified with chlorine dosage in lab-scale test. The bulk decay constant ($k_{bulk}$) was rapidly decreased with increasing temperature in the early time. In the case of 25 degrees celsius, the bulk decay constant ($k_{bulk}$) decreased over half after 25 hours later. In this study, there were able to calculate about optimal rechlorine dosage and select on profitable sites in the network map.

Performance Characteristics of PM10 and PM2.5 Samplers with an Advanced Chamber System (챔버 기술 개발을 통한 PM10과 PM2.5 시료채취기의 수행 특성)

  • Kim, Do-Hyeon;Kim, Seon-Hong;Kim, Ji-Hoon;Cho, Seung-Yeon;Park, Ju-Myon
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.8
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    • pp.739-746
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    • 2010
  • The purposes of this study are 1) to develop an advanced chamber system within ${\pm}10%$ of air velocity at the particulate matter (PM) collection area, 2) to research theoretical characteristics of PM10 and PM2.5 samplers, 3) to assess the performance characteristics of PM10 and PM2.5 samplers through chamber experiments. The total six one-hour experiments were conducted using the cornstarch with an mass median aerodynamic diameter (MMAD) of $20\;{\mu}m$ and an geometric standard deviation of 2.0 at the two different air velocity conditions of 0.67 m/s and 2.15 m/s in the chamber. The aerosol samplers used in the present study are one APM PM10 and one PM2.5 samplers accordance with the US federal reference methods and specially designed three mini-volume aerosol samplers (two for PM10 and one for PM2.5). The overall results indicate that PM10 and PM2.5 mini-volume samplers need correction factors of 0.25 and 0.39 respectively when APM PM samplers considered as reference samplers and there is significant difference between two mini-volume aerosol samplers when a two-way analysis of variance is tested using the measured PM10 mass concentrations. The PM10 and PM2.5 samplers with the cutpoints and slopes (PM10: $10{\pm}0.5\;{\mu}m$ and $1.5{\pm}0.1$, PM2.5: $2.5{\pm}0.2\;{\mu}m$ and $1.3{\pm}0.03$) theoretically collect the ranges of 86~114% and 64~152% considering the cornstarch characteristics used in this research. Furthermore, the calculated mass concentrations of PM samplers are higher than the ideal mass concentrations when the airborne MMADs for the cornstarch used are smaller than the cutpoints of PM samplers and the PM samplers collected less PM in another case. The chamber experiment also showed that PM10 and PM2.5 samplers had the bigger collection ranges of 37~158% and 55~149% than the theocratical calculated mass concentration ranges and the relatively similar mass concentration ranges were measured at the air velocity of 2.15 m/s comparing with the 0.67 m/s.

Removal Characteristic of Arsenic by Sand Media Coated with both Iron-oxide and Manganese-oxide (산화철 및 산화망간이 동시에 코팅된 모래 매질을 이용한 비소오염 제거특성 연구)

  • Kim, Byeong-Kwon;Min, Sang-Yoon;Chang, Yoon-Young;Yang, Jae-Kyu
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.7
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    • pp.473-482
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    • 2009
  • In this study, iron and manganese coated sand (IMCS) was prepared by mixing Joomoonjin sand with solutions having different molar ratio of manganese ($Mn^{2+}$) and iron ($Fe^{3+}$). Mineral type of IMCS was analyzed by X-ray diffraction spectroscopy. Removal efficiency of arsenic through As(III) oxidation and As(V) adsorption by IMCS having different ratio of Mn/Fe was evaluated. The coated amount of total Mn and Fe on all IMCS samples was less than that on sand coated with iron-oxide alone (ICS) or manganese-oxide alone (MCS). The mineral type of the manganese oxide on MCS and iron oxides on ICS were identified as ${\gamma}-MnO_2$ and mixture of goethite and magnetite, respectively. The same mineral type was appeared on IMCS. Removed amount As(V) by IMCS was greatly affected by the content of Fe rather than by the content of Mn. Adsorption of As(V) by IMCS was little affected by the presence of monovalent and divalent electrolytes. However a greatly reduced As(V) adsorption as observed in the presence of trivalent electrolyte such as $PO_4\;^{3-}$. As(III) oxidation efficiency by MCS in the presence of NaCl or $NaNO_3$ was two times greater than that in the presence of $PO_4\;^{3-}$. Meanwhile a greater As(III) oxidation efficiency was observed by IMCS in the presence of $PO_4\;^{3-}$. This was explained by the competitive adsorption between phosphate and arsenate on the surface of IMCS.

Evaluation of the Removal Characteristics of Pollutants in Storm Runoff Depending on the Media Properties (여재 특성에 따른 강우 유출수 내 오염물질 제거특성 평가)

  • Kim, Tae-Gyun;Cho, Kang-Woo;Song, Kyung-Guen;Yoon, Min-Hyuk;Ahn, Kyu-Hong;Hong, Sung-Kwan
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.7
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    • pp.483-490
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    • 2009
  • The aims of this study were to evaluate the removal efficiency for various pollutants in urban storm runoff by a filtration device, and to determine design parameters depending on filter media properties. Appropriate selection of filter media will affect the size and life time of the filtration device. Sets of column tests were performed in order to evaluate the removal efficiency by perlite and a synthetic resin. An investigation of surface properties including CEC (cation exchange capacity) and zeta-potential suggested that the perlite had a superior adsorption capability for cationic pollutants. TCODcr and turbidity were analyzed to investigate the removal characteristic of particulate pollutant. In both columns, the particles in the collected storm runoff was almost completely capture with a small EBCT (empty bed contact time) of 2.5 minutes. Complete clogging at the EBCT of 2.5 minutes occurred after 630 minutes in the perlite column and 810 minutes in the resin column. The removal efficiency of TCODcr and turbidity at the EBCT of 2.5 minutes decreased to below 70% due to an wall effect. The removal efficiency for dissolved pollutant (SCODcr) was negligible due to the insufficient contact time for adsorption. The removal of heavy metals (Cu, Zn, Pb) was mostly ascribed to the filtration of particles containing metals, since the relationship between CEC and the removal efficiency was not apparent. The result of this study would be valuable for the application of filtration device to control of urban storm runoff.

Calculation of the Eco-Design Index for Components of the Multi-function Printer (공용 복합기 출력 기능 소모품들의 Eco Design Index 산정)

  • Lee, Joo-Young;Lee, Jong-Seok;Kim, Jong-Min;Lee, Kun-Mo
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.6
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    • pp.334-342
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    • 2016
  • Conventional eco-design has been implemented based only on the environmental aspects of a product. Key components of a product identified from the analysis of the environmental aspects have been the target for improvement in the conventional eco-design. The use of eco-design index (EDI) considering both the environmental and economic aspects, and utility value (UV) of a product can be envisaged as an alternative way of implementing and assessing the eco-design. The objective of this study was to propose the logic of the EDI and apply it to the components for performing printing function of the multi-function printer. The EDI was formulated by quantifying the UV, life cycle environmental impact (LCE) and life cycle cost (LCC) of the components of a product, here components of the printer. Of the eight components investigated, roller was identified as the best performing consumable in both the environmental and economic aspects. However, its UV was the lowest among the eight. The EDI of the roller was mere $4^{th}$ in ranking out of the eight. Transfer belt ranked $8^{th}$ and $5^{th}$ in the environmental and economic aspects, respectively, while $2^{nd}$ in the utility value with its EDI ranked $3^{rd}$. This indicates that not only the environmental aspects but also economic and utility value aspects should be considered when identifying the key components for improvement in the eco-design.

A Study on Characteristics of Airborne Asbestos Concentrations at Demolition Sites and Surrounding Areas of Asbestos Containing Buildings in Seoul (서울시내 건축물 석면해체·제거 사업장 및 주변에서의 공기 중 석면농도 특성에 관한 연구)

  • Lee, Jinhyo;Lee, Suhyun;Kim, Jeongyeun;Kim, Jihui;Chung, Sooknye;Kim, Jina;Kim, Iksoo;Eo, Soomi;Jung, Kweon;Lee, Jinsook;Koo, Jayong
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.6
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    • pp.434-441
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    • 2014
  • This study is purposed to measure airborne asbestos concentrations at demolition sites and surrounding areas of asbestos containing buildings in Seoul and examine whether the measurement results correspond with allowable exhaust standard for asbestos of the Asbestos Safety Control Act. The airborne asbestos concentrations for 37 sites were below the detection limit ($7fiber/mm^2$) in 101 (35%) out of 288 samples. The whole average airborne asbestos concentration in 37 sites was $0.003{\pm}0.002f/cc$(max 0.0013 f/cc) and almost the whole airborne asbestos concentrations were satisfied with allowable exhaust standard for asbestos, 0.01 f/cc, of the Asbestos Safety Control Act. So possibility of asbestos exposure is not yet a major concern at current levels for sites demolished of asbestos containing buildings in Seoul. Looking at each sampling point, the average airborne asbestos concentrations in boundary line of site, entrance of sanitation, around the workplace (in), around the workplace (out), negative pressure units, storage area for waste, outlet for waste and residential area of residents were respectively $0.002{\pm}0.002f/cc$, $0.004{\pm}0.002f/cc$, $0.004{\pm}0.002f/cc$, $0.004{\pm}0.002f/cc$, $0.004{\pm}0.002f/cc$, $0.005{\pm}0.004f/cc$, $0.005{\pm}0.003f/cc$ and $0.003{\pm}0.002f/cc$. As a result, all sampling points of study were satisfied with allowable exhaust standard for asbestos, 0.01 f/cc, of the Asbestos Safety Control Act.

Experimental Analysis of Nodal Head-outflow Relationship Using a Model Water Supply Network for Pressure Driven Analysis of Water Distribution System (상수관망 압력기반 수리해석을 위한 모의 실험시설 기반 절점의 압력-유량 관계 분석)

  • Chang, Dongeil;Kang, Kihoon
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.6
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    • pp.421-428
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    • 2014
  • For the analysis of water supply network, demand-driven and pressure-driven analysis methods have been proposed. Of the two methods, demand-driven analysis (DDA) can only be used in a normal operation condition to evaluate hydraulic status of a pipe network. Under abnormal conditions, i.e., unexpected pipe destruction, or abnormal low pressure conditions, pressure-driven analysis (PDA) method should be used to estimate the suppliable flowrate at each node in a network. In order to carry out the pressure-driven analysis, head-outflow relationship (HOR), which estimates flowrate at a certain pressure at each node, should be first determined. Most previous studies empirically suggested that each node possesses its own characteristic head-outflow relationship, which, therefore, requires verification by using actual field data for proper application in PDA modeling. In this study, a model pipe network was constructed, and various operation scenarios of normal and abnormal conditions, which cannot be realized in real pipe networks, were established. Using the model network, data on pressure and flowrate at each node were obtained at each operation condition. Using the data obtained, previously proposed HOR equations were evaluated. In addition, head-outflow relationship at each node was analyzed especially under multiple pipe destruction events. By analyzing the experimental data obtained from the model network, it was found that flowrate reduction corresponding to a certain pressure drop (by pipe destruction at one or multiple points on the network) followed intrinsic head-outflow relationship of each node. By comparing the experimentally obtained head-outflow relationship with various HOR equations proposed by previous studies, the one proposed by Wagner et al. showed the best agreement with the exponential parameter, m of 3.0.

Study on Ventilation Efficiency of A Naturally Ventilated Broiler House-( I ) Summer Season (자연환기식 육계사내의 환기효율성 조사연구-( I )하절기)

  • 이인복;유병기;정문성;윤진하;전종길;김경원;성시흥
    • Journal of Animal Environmental Science
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    • v.9 no.1
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    • pp.9-18
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    • 2003
  • Most of broiler houses in Korea have the trouble of environmental control such as suitability, stability, and uniformity of internal climate, resulting in serious stress on chickens. Accordingly, it is very urgent to develop optimum designs of naturally and mechanically ventilated broiler houses for Korean climate. In this study, the internal climates such as air temperature, humidity, dust, ammonia gas, and air velocity were measured at a naturally ventilated broiler house. The data were collected during summer season including local weather data. It was found that the difference between measured and optimum air temperatures was $14.0^{\circ}C$ in maximum during the summer time. The daily maximum range of internal averaged air temperature was found $10.5^{\circ}C$ while the uniformity was $5.2^{\circ}C$ in maximum. The maximum, average, and minimum internal averaged relative humidity were 89.3%, 73.7%, and 49.2%, respectively while locally measured were 95.1% and 47.2%, respectively in maximum and minimum. Considering Temperature-humidity index, during summer season, over 97% of totally rearing period was shown that counter plan is needed for thermal stress while it was very dangerous situation for 22% of the rearing period. The ammonia gas and dust concentrations were seriously affected by the broilers activity, growth level, and relative humidity.

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Classification of Weathering for the Granite and Granite Gneiss in Okcheon Belt-Jecheon${\cdot}$Geumsan${\cdot}$Gimcheon in Korea (옥천대지역 -제천${\cdot}$금산${\cdot}$김천 - 에 분포하는 화강암 및 화강 편마암의 풍화분류에 관한 고찰)

  • Woo, Ik;Park, Hyuk-Jin
    • Economic and Environmental Geology
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    • v.37 no.3
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    • pp.355-364
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    • 2004
  • A study on the weathering grade classification has been performed for granite and granite gneiss in Korea. The qualitative classification criteria of weathering were reviewed and then modified with field studies for the weathered rock masses. The thin section observations and XRD analyses for the different weathering grades rock samples showed the petrographical and petrophysical difference with respect to the weathering : the proportion of weathering-resistant minerals suck at quartz and orthoclase has a tendency to increase with the development of weathering, but that of weathering-sensible minerals such as anorthite and biotite is decreased. The ranges of physical and mechanical rock properties for different weathering grades were obtained from the laboratory rock tests and field tests for the studied rocks. And then, along with $RDI_{sq}$(Fookes et al., 1988), the weathering index $I_{a}$, (Woo, 2003) has been developed in this study to demarcate the weathering grade. Those two indices rely mainly on the water absorption ratio of rock and on the different rock strength. The range of these weathering indices have been determined with the physical and mechanical rock properties that can be obtained from simple field or laboratory tests in 4 grades $I_{a}$> 7 for F, 3.5 < $I_{a}$ < 10 for SW, 1.0 $I_{a}$< 6.0 for MW and $I_{a}$< 2.5 for HW. Consequently, the weathering index could be utilized to classify quantitatively the rock weathering grade, especially for the studied granites and the granite gneiss in Korea.