• Title/Summary/Keyword: 공침법

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A Study on the Removal of Fluorine from Leachate of Reclaimed Mine Waste Dump Site Using Alum Coagulation (알럼 응집을 이용한 광산폐기물 적치장 침출수 내 불소 제거 연구)

  • Sang-Woo Lee;Woo-Chun Lee;Seong Hee Kim;Sang Heon Jeong;Bo Young Lee;Sang-Hwan Lee;Soon-Oh Kim
    • Korean Journal of Mineralogy and Petrology
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    • v.36 no.1
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    • pp.19-32
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    • 2023
  • This study was conducted to remove fluorine (F) (initial concentration of 9.5 mg/L) from leachate of reclaimed mine waste dump site via different methods: (1) co-precipitation using Ca-based materials; (2) adsorption using activated carbon and fly ash; and (3) coagulation and sedimentation using alum. The F removal efficiencies of each case were estimated as 65.6% (Ca co-precipitation), 27.9% (adsorption of activated carbon), 71.5% (adsorption of fly ash), and 96.6% (alum coagulation and sedimentation). In addition, the applicability of the continuous treatment process using alum coagulation was evaluated by lab-scale experiments using simulated mine drainage containing F of lower (6.4 mg/L) and higher (15.7 mg/L) concentrations, and it was confirmed that the treatment of both cases met the domestic standard (below 3 mg/L) for discharged water in clean areas. Furthermore, the results of bench-scale field tests indicated that the water quality standard of discharged water could be satisfied with the proper operation and management of the process.

Direct Methanol Synthesis by Partial Oxidation of Methane (메탄의 부분산화에 의한 메탄올 직접 합성)

  • Kim, Young-Kook;Lee, Kwang-Hyeok;Hahm, Hyun-Sik
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.4
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    • pp.649-655
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    • 2013
  • Methanol was directly produced by the partial oxidation of methane with perovskite and mixed oxide catalysts. Perovskite ($ABO_3$) catalysts were prepared by the malic acid method with changing A and B site components. Three-component mixed oxide catalysts that have Mo and Bi as a main component were prepared by the co-precipitation method. Among the perovskite catalysts, $SrCrO_3$ showed the highest methanol selectivity of 11% at $400^{\circ}C$. For the three-component mixed oxide catalysts, there were no remarkable changes in methane conversion. Among the mixed oxide catalysts, Mo-Bi-Cr mixed oxide catalyst showed the highest methanol selectivity of 15.3% at $400^{\circ}C$. The catalytic activity and methanol selectivity of the three-component mixed oxide catalysts were directly proportional to the surface area of the catalysts.

Properties of NiCuZn Ferrite by Variation of Element Materials (원료의 계열성분 변화에 따른 NiCuZn Ferrite 물성연구)

  • Kim, Tae-Hyoung;Koh, Jae-Gui
    • Journal of the Korean Magnetics Society
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    • v.14 no.5
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    • pp.180-185
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    • 2004
  • The electromagnetic properties and microstructures of the basic composition of (Ni$\sub$0.2/Cu$\sub$0.1/Zn$\sub$0.2/)$\sub$0.5/ (Fe$_2$O$_3$)$\sub$0.5/ were invested by changing of SO$_4$, Cl and NO$_3$ series. We were prepared by coprecipitation method and sintered at temperatures 950$^{\circ}C$, 1150$^{\circ}C$, l350$^{\circ}C$, respectively. When sintering at temperature 950$^{\circ}C$, Cl and NO$_3$ series became perfection sintering. On the other hand, SO$_4$ series showed perfection sintering at temperature 1150$^{\circ}C$. According to particle size analysis result, higher magnetic permeability and magnetization value were observed by Cl series than SO$_4$ or NO$_3$ series.

Bioactivity behavior of biphasic calcium phosphate powders prepared by co-precipitation method (공침법으로 합성된 biphasic calcium phosphate 분말의 생체활성 거동)

  • Kim, Tae-Wan;Kim, Dong-Hyun;Jin, Hyeong-Ho;Lee, Heon-Soo;Park, Hong-Chae;Yoon, Seog-Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.2
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    • pp.99-104
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    • 2012
  • The co-precipitation technique has been applied to synthesize biphasic calcium phosphate (BCP). $Ca(NO_3)_2{\cdot}4H_2O$ and $(NH_4)_2HPO_4$ as the starting materials was used. X-ray diffraction (XRD) and Fourier transformed infrared (FT-IR) spectroscopy were used to characterize the structure of as-synthesized and calcined BCP powders. After immersion in Hanks' Balanced Salt Solution (HBSS), for 1 week a precipitation started to be formed with individual small granules on the specimen surface. An MTT assay indicated that BCP powders have no cytotoxic effects on MG-63 cells, and that they have good biocompatibility.

A Study on the Microwave Absorber Properties of Ni-Cu-Zn Ferrites Composite (Ni-Cu-Zn Ferrite의 복합형 전파흡수체 특성 연구)

  • Min, Eui-Hong;Kim, Moon-Suk;Koh, Jae-Gui
    • Journal of the Korean Magnetics Society
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    • v.17 no.6
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    • pp.238-241
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    • 2007
  • Ni-Cu-Zn ferrites were prepared by the co-precipitation. Physical properties and Microwave absorbing properties were investigated in Ni-Cu-Zn ferrite for the aim of microwave absorbers. From the analysis of X-ray diffraction patterns, we can see that all the particles have only a single phase spinel structure. The loss factor was maximum at sintering temperature $1100^{\circ}C$. The initial permeability of sintered ferrite obtained was an average of 50. We found that the $(Ni_{0.7}Cu_{0.2}Zn_{0.1}O)_{1.02}(Fe_2O_3)_{0.98}$ can be used in ferrite rubber composite microwave absorber when sintering temperature at $1100^{\circ}C$.

Preparation of Cu and Mn Bimetallic Catalyst Based on Co-Precipitation Method for Removal of Ethyl Acetate (아세트산 에틸 제거를 위한 공침법 기반의 Cu 및 Mn 이종금속 촉매의 제조)

  • Kim, Min Jae;Yoon, Jo Hee;Jeong, Jae-Min;Choi, Bong Gill
    • Applied Chemistry for Engineering
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    • v.33 no.5
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    • pp.466-470
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    • 2022
  • The catalytic thermal oxidizer process has recently attracted considerable attention for the oxidation and decomposition of volatile organic compounds at low temperatures (< 450 ℃) with high efficiency (> 95%). Although many noble metal catalytic materials are well established, they are expensive and hazardous. Herein, highly active and low-cost Cu-Mn bimetallic catalysts were prepared using a simple and facile synthesis method involving the co-precipitation of Cu and Mn precursors. The synthesis of the catalyst was optimized by controlling the composition ratio of Cu and Mn. The optimized catalyst exhibited a large surface area of 230.8 m2/g with a mesoporous structure. To demonstrate the catalytic performance, the Cu-Mn catalyst was tested for the oxidation reaction of ethyl acetate, showing a high conversion efficiency of 100% at a low temperature of 250 ℃.