• Title/Summary/Keyword: 공중

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Relaxation phenomena of electro-optic coefficient in P(VDF-TrFE) copolymers (강유전성 고분자인 P(VDF-TrFE)공중합체의 전기광학계수의 완화현상)

  • 임종선;박광서
    • Korean Journal of Optics and Photonics
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    • v.12 no.3
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    • pp.225-229
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    • 2001
  • Relaxation phenomena of the electro-optic coefficient in ferroelectric copolymer P (VDF- TrFE) were studied. The electro-optic coefficient of copolymers was measured by simple reflection method and the decay curves were fitted by KWW stretched exponentials. The copolymers poled near Tc. Were shown to be more stable than the copolymer poled at lower temperatures. Further, the relaxation time t depending on temperature was found to follow Arrhenius behavior and it was found that the activation energy of 50/50 mol% P (VDF-TrFE) copolymer is larger than that of 72/28 mol% copolymer. As a result, the ferroelectric copolymer with VDF of 50 mol% is was more stable.stable.

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Behavior of Microdomains in Block Copolymer/Nanoparticle Nanocomposite Thin Films under Electric Field (공중합체/나노입자 복합체 박막 내 미세구조의 전기장 하에서의 거동)

  • Bae, Joonwon
    • Applied Chemistry for Engineering
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    • v.28 no.3
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    • pp.290-293
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    • 2017
  • In this study, the fundamental behavior of microdomains in block copolymer/nanoparticle composite thin films was examined. In this experiment, polystyrene-b-poly(2-vinylpyridine) block copolymer and CdSe nanoparticles having a noncentrosymmetric property were employed. Composite hybrid thin films were produced by a spin coating method, and changes in the internal structure of composite thin films were monitored mainly by transmission electron microscopy. In summary, nanoparticles resided inside the thin film relatively intact, however, the block copolymer microdomains rotated parallel to the electric field direction. This study will be very helpful for future research activities regarding behaviors of heterogeneous composite materials under external fields.

Study of Aerial Fire Line Construction and Suppression Method on Forest Fire (산불 공중진화 방화선 구축형태 및 진화방법에 관한 연구)

  • Bae, Taek-Hoon;Lee, Si-Young
    • Fire Science and Engineering
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    • v.24 no.5
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    • pp.26-31
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    • 2010
  • In this study, attack process and aerial control line construction type which were considered forest fire type and a case of operations were suggested using the experience of aerial fire attack of all type of forest fires. As the spread rate of forest fire is effected by terrain, slope, wind speed, forest species and etc., we needed to analyze spreading direction, behavior type and intensity before heli-team constructed a aerial control line. Especially, It is important to consider safety of attack team as a their views were obstructed. In this study, we suggested a 13 methods from type A to type M about attack and construction of aerial indirect control line.

Fabrication of the Silicon Nano Structure applicable to Non-volatile Memory Device using Block Copolymer (비휘발성 메모리 소자 응용을 위한 블록 공중합체를 이용한 실리콘 나노 구조 제작)

  • Jung, Sung-Wook;Kim, Hyun-Min;Park, Dae-Ho;Sohn, Byeong-Hyeok;Jung, Jin-Chul;Zin, Wang-Cheol;Parm, I.O.;Yi, Jun-Sin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.95-96
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    • 2005
  • 나노 구조 제작을 위한 다양한 시도 중 블록 공중합체를 이용한 방법은 현재 활발한 연구가 진행되고 있는 분야이다. 본 연구에서는 비휘발성 메모리 소자의 용량 증가를 위하여 블록 공중합체 박막을 나노 마스크로 이용하고, 평행판헝 반응관 내에서 반응성 이온 에칭을 사용하여 나노 구조의 표면을 제작하였다. 에칭동안에 나노 마스크로서 사용할 블록 공중합체 박막은 PS-b-PMMA를 이용하여 제작하였고, UV를 주사하여 PMMA를 제거하고 수직적인 나노 흩을 구성하여 나노 패터닝이 가능하도록 하였다. 실험을 통하여 매우 균일한 나노 바늘 형태의 구조를 생성할 수 있으며, 반응기체와 유량의 조절을 통하여 다양한 표면 구조를 확인할 수 있었다. 블록 공중합체는 나노 마스크로서 뛰어난 기능을 나타내며, 이를 이용하여 나노 사이즈의 패터닝이 가능하고, 표면적 증가를 통하여 비휘발성 메모리 소자의 용량 증가에 기여할 수 있다.

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Synthesis and Characterization of Linear and Branched Copolymers of Poly(ethylene glycol) and $Poly({\varepsilon}-caprolactone)$ (선형 및 분지 구조의 폴리(에틸렌 글리콜)/폴리카프로락톤 공중합체의 합성 및 특성 검토)

  • Hyun Hoon;Kim Moon-Suk;Khang Gil-Son;Rhee John-M.;Lee Hai-Bang
    • Polymer(Korea)
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    • v.30 no.2
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    • pp.146-151
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    • 2006
  • Linear and branched copolymers consisting of poly(ethylene glycol) (PEG) and $Poly({\varepsilon}-caprolactone)$ (PCL) were prepared to compare the characterization of star-shaped copolymers with various molecular architecture. Linear and branched PEG-PCL (1-arm, 2-arm, 4-arm, and 8-arm) copolymers were synthesized by the ring-opening polymerization of ${\varepsilon}-caprolactone$ in the presence of HCl $Et_2O$ as a monomer activator at room temperature. The synthesized copolymers were characterized with $^1H-NMR$, GPC, DSC, and XRD. As a result of the DSC and XRD, each copolymers showed different thermal properties and crystallinity according to the number of ms. The micellar characterization of linear and branched copolymers in an aqueous phase was carried out by using NMR, dynamic light scattering, AM, and fluorescence techniques. The critical micelle concentration (CMC) and diameters of micelles depended on the number of arms. Most micelles exhibited a spherical shape in AFM. In this study, we characterized star-shaped PEG-PCL copolymers and investigated their molecular architecture effect on the various properties. Furthermore, we confirmed that the micelles termed with linear and branched PEG-PCL copolymers have possibility as a potential hydrophobic drug delivery vehicle.

The Study on the Public Typology based on Twitter's Political Opinion Analysis: Focusing on 10.26 by-election of Mayor of Seoul (트위터에서 형성된 정치적 의견 분석을 통한 분화된 공중 연구: 10.26 서울시장 재보궐 선거를 중심으로)

  • Hong, Ju-Hyun;Lee, Chang-Hyun
    • Korean journal of communication and information
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    • v.59
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    • pp.138-161
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    • 2012
  • This study is designed to explore the function of Twitter as a campaign platform during election campaign. For exploring the function of Twitter the form of tweet, the type of information on tweet and the way of opinion expression via Twitter were discussed by content analysis. This study finds, first, that, netizens express their opoinion of candidates without foundation and with emotional reactions. Second, they showed somewhat conflictive reactions according to their supporting candidates. This study conceptualized various kinds of public as 'blindly support public,' and 'blindly opposition public' in case of Park's supporters, 'rational support public,' and 'critical opposition public' in case of Na's supporters. Third, Park's supporters debated Na candidate's attitude of debate and her appearance blindly without foundation. Na's supporters argued Park's attitude of debate and his ignorance of Seoul Metropolitan government's policy blindly without foundation. Finally, this study discussed the relationship between the political discourse according to netizens' supporting via Twitter and the results of election. Park whose supporters attacked the opposing candidate by blaming her appearance and her attitude of debate won the election. Na didn't overcome her negative images. For her Twitter functioned as a media which is spreading negative factors about her. In conclusion, Twitter as a campaign platform during election times plays a key role in discussing candidates. However, netizens need to express their opinions with foundation and the candidates have to consider negative issue management. This study highlights the importance of peripheral factors which have a decisive effect on the results of election. The results of this study is useful for building political campaign strategy by candidates.

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Modeling and Simulation on One-vs-One Air Combat with Deep Reinforcement Learning (깊은강화학습 기반 1-vs-1 공중전 모델링 및 시뮬레이션)

  • Moon, Il-Chul;Jung, Minjae;Kim, Dongjun
    • Journal of the Korea Society for Simulation
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    • v.29 no.1
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    • pp.39-46
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    • 2020
  • The utilization of artificial intelligence (AI) in the engagement has been a key research topic in the defense field during the last decade. To pursue this utilization, it is imperative to acquire a realistic simulation to train an AI engagement agent with a synthetic, but realistic field. This paper is a case study of training an AI agent to operate with a hardware realism in the air-warfare dog-fighting. Particularly, this paper models the pursuit of an opponent in the dog-fighting setting with a gun-only engagement. In this context, the AI agent requires to make a decision on the pursuit style and intensity. We developed a realistic hardware simulator and trained the agent with a reinforcement learning. Our training shows a success resulting in a lead pursuit with a decreased engagement time and a high reward.

Preparation of High Range Water Reducer Containing Carboxylic Acid and Their Cement Absorptivity(I) (카르본산계 고성능감수제의 제조 및 그들의 시멘트 흡착성(I))

  • 김화중;강인규;김성훈;김우성;권영도
    • Magazine of the Korea Concrete Institute
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    • v.7 no.2
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    • pp.175-182
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    • 1995
  • Styrene-Maleic anhydride copolymer (SMA) was prepared by the radical copolmerization of styrene and maleic anhydride using ${\alpha}-{\alpha}'$ azobis(isobutyronitrile) as an initiatrr. SMA was further reacted with m-amino phenol to obtain aminophenol-substituted SMR (mSMA). Sulfonated SMA and mSMA were also prepared by the reaction of copolymers with sulfuric acid The copolyniers were characterized by infrared spectroscopy. It was found from the results of elemental analysis that the substitution degree of aminophenol in the mSMR is 44% and the degree is lowered to 35% after sulfonation. The percentage of copolymers adsorbed on the surface of cement particles was increased with a decrease of added copolymers. While, the arnourit of sulfonated SMA absorbed on the surface of cement particles was larger than that of the sulfonated mSMA The copolymers synthesized in this study are probably expected as a high range water reducer for coiicxte.

Preparation and Properties of Poly(dimethylsiloxane-co-N-phenylsiloxazane) Modified Acrylate Resin (Poly(dimethylsiloxane-co-N-phenylsiloxazane) 변성 Acrylate Resin의 제조와 그 특성)

  • Kang, Doo-Whan;Kum, Min-Woo;Yoon, Jae-Seon
    • Polymer(Korea)
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    • v.34 no.2
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    • pp.154-158
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    • 2010
  • We first synthesized N-phenylcyclotrisiloxazane ($D_3^{NPh}$) through a cyclization of $\alpha$,$\omega$- dichlorohexamethyltrisiloxane with aniline and prepared poly(dimethylsiloxane-co-N-phenylsiloxazane) copolymer (PDMS-NPSOX) by a ring opening copolymerization of them with hexamethylcyclotrisiloxane $D_3$. An acrylate monomer modified with PDMS-NPSOX was synthesized by using chloroethyl methacrylate and copolymerized with methylmethacrylate (MMA) and n-butylacrylate. The composition of the copolymer was chosen to control their glass transition temperature ($T_g$) to 25 $^{\circ}C$. By changing the comonomer from PDMS to PDMS-NPSOX, $T_g$ and adhesive strength of the copolymer were increased from 20 to 25 $^{\circ}C$ and from 1.76 to 2.23 N/cm, respectively.

The Effects of Participation Motivation of Corporate Social Responsibility Using Social Media on Organization-Public Relationship and Brand Loyalty (소셜 미디어를 통한 기업 사회공헌활동의 참여동기가 조직-공중관계성과 브랜드 충성도에 미치는 영향)

  • Yi, Junsub
    • Journal of Korea Society of Industrial Information Systems
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    • v.22 no.1
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    • pp.139-159
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    • 2017
  • This Study Examines the Relationships Among Participation Motivation for Corporate Social Responsibility(CSR) Using Social Media, Organization-public Relationship between Companies Conducting CSR and Participants, and Companies' Brand Loyalty. Using Questionnaire Data, Confirmatory Factor Analyses were used to Figure out Participation Motivation Factors Including Empathy and Interest. The Confirmatory Factor Analyses Also Derived Organization-public Relationship Factors Including Trust, Commitment, Control Mutuality, and Intimacy Created between Companies Conducting CSR and Participants. The Proposed Research Model was Tested through Structural Equation Modeling. The Results Showed that the Empathy Factor Positively Affects all the Organization-public Relationship Factors, and the Interest Factor Positively Affects trust and Commitment Factors. The Trust Factor Positively Influences other Organization-public Relationship Factors Including Commitment, Control Mutuality, and Intimacy. The results also Showed that each one of the Organization-public Relationship Factors Improves the Companies' Brand Loyalty.