• Title/Summary/Keyword: 공정표

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Study on Pre-treatment of Tropical Crop Oil for Bio-diesel Production (열대작물 오일로부터 바이오디젤 생산을 위한 전처리 공정 연구)

  • Kim, Deogkeun;Park, Jiyeon;Lee, Joonpyo;Park, Soonchul;Lee, Jinsuk
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.249.2-249.2
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    • 2010
  • 최근의 고유가와 환경오염에 대한 대응 수단으로 수송용 바이오연료의 보급에 대한 관심이 세계적으로 높아지고 있다. 이 중 바이오디젤은 동식물성 기름으로부터 메탄올과의 전이에스테르화 반응에 의해 생산되는 경유대체 연료로서 환경 친화성과 지속가능성이 인정됨에 따라 그 생산량이 급격히 증가하고 있다. 바이오디젤의 생산량이 증가함에 따라 대두유, 유채유, 팜유 등의 원료유 가격 상승 및 수급 불안정 문제가 대두되고 있으며 식량자원과의 충돌 문제도 발생되고 있다. 이를 해결하기 위한 방안으로 유리지방산 함량이 높은 저가유지 자원(폐식용유, 폐돈지, 폐우지, soapstock, trapped grease)을 이용한 공정 개발 연구가 활발히 진행되고 있다. 본 연구에서는 비활용되고 있는 해외 열대작물 열매씨앗에서 착유한 식물성 오일의 바이오디젤 원료유로서의 사용 가능성을 검토하였다. 열대작물 오일의 물성 분석 결과 고형물, 수분, 인, 유리지방산 함량이 대두원유보다 매우 높게 나타났다. 오일 중의 인지질은 바이오디젤 제조 반응후 에스테르와 글리세린의 층분리를 방해하여 공정 효율을 감소시키고 유리지방산은 염기촉매와 결합하여 지방산염을 생성해 생산수율을 감소시키는 문제를 일으킨다. 고형물과 수분은 여과와 감압증발에 의해 쉽게 제거가 가능하였다. 15~20%의 유리지방산 함유 열대작물 오일의 전처리를 위해 균질계 산촉매와 비균질 고체 산촉매를 이용해 에스테르화 반응 효율을 조사한 결과 황산이 가장 높은 효율을 보였다. 반응표면분석법(Response Surface Method, RSM)을 적용해 메탄올과 촉매량의 2변수 에스테르화반응 최적화를 수행한 결과 메탄올 26%, 촉매 0.98%로 최적 조건이 도출되었으며 초기 산가 33mgKOH/g에서 0.98mgKOH/g으로 감소됨을 확인하였다. 전처리 정제한 오일의 물성분석 결과 고형물 0.1%, 수분 0.10%, 산가 1.0mgKOH/g, 인함량 20ppm 이하로 바람직한 원료유가 생산됨을 알 수 있었다. 제조된 원료유를 이용해 전이에스테르화 반응 최적화 실험을 RSM에 근거하여 진행한 결과 KOH 0.8%, 메탄올:오일 몰비 6.2:1, 반응온도 $60^{\circ}C$, 교반속도 200rpm, 반응시간 30분으로 나타났으며 증류 정제전 97.3%, 증류후 100.0%의 바이오디젤을 생산 할 수 있었다. 열대작물 오일의 전처리 공정은 메탄올을 과잉양으로 사용함으로 효과적인 알콜 회수 공정이 중요하다. 전처리 후 층분리를 통해 회수되는 메탄올 중의 수분함량은 2%~7%로서 이를 전처리 반응에 재사용하기 위해서는 0.3%이하의 수분함량으로 정제가 필요하다. 본 연구에서는 고가의 증류탑 형태가 아닌 단증류방식으로 2단계 내지 3단계로 0.3% 수분의 메탄올 회수 조건을 도출하였으며 파일롯 공정 설계를 진행하고 있다. 이로서 본 연구의 열대작물 오일은 저가로 충분한 물량의 확보가 가능하다면 바이오디젤 원료 자원으로서 큰 활용가치가 있는 것으로 판단된다.

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Influence of AZO Thin Films Grown on Transparent Plastic Substrate with Various Working Pressure and $O_2$ Gas Flow Rate (공정 압력과 산소 가스비가 투명 플라스틱 기판에 성장시킨 AZO 박막에 미치는 영향)

  • Lee, Jun-Pyo;Kang, Seong-Jun;Joung, Yang-Hee;Yoon, Yung-Sup
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.47 no.2
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    • pp.15-20
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    • 2010
  • In this study, AZO (Al: 3 wt%) thin films have been prepared on PES Plastic substrates at various working pressure (5~20 mTorr), $O_2$ gas flow rate(0~3%) and the fixed substrate temperature of 200 f by using the RF magnetron sputtering and their optical and electrical properties have been studied. The XRD measurement shows that AZO thin films exhibit c-axis preferred orientation. From the results of AFM measurements, it is known that the lowest surface roughness (3.49 nm) is obtained for the AZO thin film fabricated at 5 mTorr of working pressure and 3% of $O_2$ gas flow rate. The optical transmittance of AZO thin films is measured as 80% in the visible region. We observe that the energy band gap of AZO thin films increases with decreasing the working pressure and the $O_2$ gas flow rate. This phenomenon is due to the Burstein-Moss effect. Hall measurement shows that the maximum carrier concentration ($2.63\;{\times}\;10^{20}\;cm^{-3}$) and the minimum resistivity ($4.35\;{\times}\;10^{-3}\;{\Omega}cm$) are obtained for the AZO thin film fabricated at 5mTorr of working pressure and 0% of $O_2$ gas flow rate.

Application Method of Phase Division of Fast Track for Construction Project with Complex Structures (복합공종으로 구성된 건설공사의 패스트트랙 단계구분 적용 방식 분석)

  • Kim, Hyun Soo;Hwang, Jae Yoeng;Kang, Hyo Jeong;Park, Sang Mi;Lee, Jae Hee;Kang, Leen Seok
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.42 no.1
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    • pp.95-105
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    • 2022
  • Recently, as the scale of a construction project has become larger and more complicated, there are many cases where construction projects with complex structures are carried out in a fast track method to save construction duration. In the fast track method, the proper division of construction phases is an important issue in determining the overall project period. This study presents a rational phase division method that can be applied when a construction project with complex structures is carried out as a fast track. For this study, a subdivided work breakdown structure (WBS) is developed using the construction of 4 soccer stadiums as application examples, and the schedule is analyzed by dividing the construction process of major phases. To this end, five proposals are applied to analyze the adequacy of the fast track phase division. For the draft with the minimum construction period, the fast track phase division and the schedule model of by each phase were presented. This methodology can have an application in the appropriate phase division and schedule model by construction phase when fast track is applied in large construction project of a similar size.

The Industrial Economic Costs of Unsupplied Electricity in OECD Countries using Input-Output Analysis (산업연관분석을 활용한 전력의 산업별 공급지장비용 평가 : OECD 국가를 중심으로)

  • Lee, Seung-Jae;Jeong, Dong-Won;Yu, Jae-Gab
    • Journal of the Korea Convergence Society
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    • v.7 no.4
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    • pp.191-198
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    • 2016
  • As the electricity produced from the electricity industry, a national key industry in Korea, are supplied to other industries as an intermediate goods, the supply shortage of electricity industry has a large impact on the national economy. This paper attempts to analyze the supply shortage effects which are defined as the negative impact of one won of supply failure in the electricity on the production of other industries. To this end, an input-output analysis using an input-output (I-O) table describing inter-industry flow of intermediate goods is applied. More concretely, the supply-driven model is applied subject to the OECD countries. The value of the supply effects interfere with Denmark's best large 1.682 was followed by South Korea, Japan, Australia, the UK.

Improvement Plan of Quality Control for 3D Geospatial Database (3차원 국토공간정보 품질관리 개선방안에 관한 연구)

  • Seo, Chang-Wan;Choi, Yun-Soo;Kim, Jae-Myeong;Kim, Young-Hak;Kim, Young-Gil
    • Spatial Information Research
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    • v.17 no.2
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    • pp.231-241
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    • 2009
  • Recently, The importance of a quality control for implementing 3D geospatial database has being emphasized to build a 21st century knowledge society and an ubiquitous land. The improvement of 3D geospatial database quality control through establishing an integrated quality control makes data suppliers update data efficiently and users get high quality data. The purpose of this study was to derive the improvement plan of 3D geospatial database quality control through the analyses of the existing 3D geospatial database quality control and case studies. The results of this study are as follows. Firstly, we defined the concept of 3D geospatial database quality control. Secondly, we set the boundary, factors and process of 3D geospatial database quality control through classifying it in detail. Lastly, we drew improvement contents such as the quality control checklist by implementation process according to the improvement plan of 3D geospatial database implementation.

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Two-Stage Design Optimization of an Automotive Fog Blank Cover for Enhancing Its Injection Molding Quality (자동차용 안개등 커버의 사출성형 품질 향상을 위한 2 단계 설계 최적화)

  • Park, Chang-Hyun;Ahn, Hee-Jae;Choi, Dong-Hoon;Pyo, Byung-Gi
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.8
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    • pp.1097-1103
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    • 2010
  • Injection pressure, an important factor in the filling procedure, should be minimized to enhance injection molding quality. In addition, warping deformation and weld lines, which are representative failures, should be avoided to enhance injection molding quality. To improve injection molding quality, the design procedure for an automotive fog blank cover is divided into two stages. In the first stage, we optimally obtain injection molding process variables that minimize injection pressure and warping deformation by using design of experiments, approximation and optimization techniques equipped in PIAnO (Process Integration, Automation and Optimization), a commercial PIDO (Process Integration and Design Optimization) tool. Then, we determine the thickness of the automotive fog blank cover that enables us to avoid generating weld lines. The design results we obtain in this study are found far better than those of the initial design, which demonstrates the effectiveness of our design method.

A Study on the Relation between Working Time and Tree Formal Characteristics (임업(林業)에서의 순수작업시간(純粹作業時間)과 임목형상조건(林木形狀條件)과의 관계연구(關係硏究))

  • Kang, Gun-Uh
    • Journal of Korean Society of Forest Science
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    • v.78 no.4
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    • pp.381-395
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    • 1989
  • The main purpose of this research is to provide scientific informations about standard wage and performance tariffs in forest management with special reference to working time for thinning. To identify relationships between net working time and tree characteristics, three geographically different sample plots were established at Yangsan, Bongpyung and Jinan and 460 oaks, 372 Japanese larches, 232 red pine and 240 pitch pine mere selected at each sample plots. The results of statistical analysis using multiple regression are as follows ; 1. Five independent variables of breast height diameter(DBH), mid-diameter(MD) large end diameter(LD), log-length(L), No. of branches(NOB) were stable independent of worker and tree species. 2. Comparing correlation coefficient of five independent variables, the best predictive variables, breast height diameter and No. of branches, were selected. Breast height diameter and No. of branches were identified as the most important independent variables in terms of effect on the dependent variable of the working time. 3. Comparing coefficient of determination (Rp) and residual mean square (MSEp), the best Linear regression equation for each tree species was selected as follower : $WT=a+b1{\times}NOB+b2{\times}DBF$ 4. Proportion of hang-up time to total working time in thinning were 66% in oak stand, 74%, in Japanese larch stand, 55%, in red pine stand and 52% in pitch pine stand, respectively. 5. Based on the best regression equation, a table of working time was made by strata of number of branches and breast height diameter. 6. Total working time using the best regression equation in Table 5 can be predicted in terms of felling time, limbing time, hang-up time, i.e., total working time increases by 11 to 13 seconds with every 1 centimeter increase in breast height diameter from 7 to 16 centimeter.

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Enhancement of Anti-inflammatory Activities of Fermented Scutellaria baicalensis Extracts using Lactobacillus rhamnosus (유산균 발효를 통한 황금 추출물의 항염증 효과 증진)

  • Choi, Woo Seok;Kwon, Hee-Souk;No, Ra Hwan;Choi, Geun Pyo;Lee, Hyeon Yong
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.39 no.4
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    • pp.303-311
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    • 2013
  • This study was performed to investigate the anti-inflammatory activities of fermented Scutellaria baicalensis extracts using Lactobacillus rhamnosus. The extracts were WE (water extract at $100^{\circ}C$ for 24 h), EE (70% ethanol extract at $60^{\circ}C$ for 24 h), FWE (fermented and water extract at $60^{\circ}C$ for 24 h), FEE (fermented and 70% ethanol extract at $60^{\circ}C$ for 24 h). The cytotoxicity of the extracts was in the range of 11.2 ~ 15.6 % at 1.0 mg/mL concentratioin. The FEE showed the lowest activity at 1.0 mg/mL concentratioin. Compared to the WE, hyaluronidase inhibitory activity contents in the FEE increased to 9.2% at 1.0 mg/mL concentratioin. Nitric oxide production of WE, EE, FWE and FEE at 1.0 mg/mL concentration was mesured as 7.6, 7.9, 6.9, 6.4 ${\mu}M$, respectively. $PGE_2$ secretion of the human fibroblast of the FEE were lower than 810 pg/mL. Our results suggested that the extracts from fermentation process after 70% ethanol extraction had relatively high anti-inflammatory activities and that the Scutellaria baicalensis could be more extracted in FEE than others.

Recoverty of Lithium Carbonate and Nickel from Cathode Active Material LNO(Li2NiO2) of Precursor Process Byproducts (전구체 공정부산물 LNO(Li2NiO2)계 양극활물질로부터 탄산리튬 및 니켈 회수연구)

  • Pyo, Je-Jung;Wang, Jei-Pil
    • Resources Recycling
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    • v.28 no.4
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    • pp.30-36
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    • 2019
  • In this study, Li powder was recovered from the by-product of LNO ($Li_2NiO_2$) process, which is the positive electrode active material of waste lithium ion battery, through the $CO_2$ thermal reaction process. In the process of recovering Li powder, the $CO_2$ injection amount is 300 cc/min. The $Li_2NiO_2$ award was phase-separated into the $Li_2CO_3$ phase and the NiO phase by holding at $600^{\circ}C$ for 1 min. After this, the collected sample:distilled water = 1:50 weight ratio, and after leaching, the solution was subjected to vacuum filtration to recover $Li_2CO_3$ from the solution, and the NiO powder was recovered. In order to increase the purity of Ni, it was maintained in $H_2$ atmosphere for 3 hours to reduce NiO to Ni. Through the above-mentioned steps, the purity of Li was 2290 ppm and the recovery was 92.74% from the solution, and Ni was finally produced 90.1% purity, 92.6% recovery.

Construction Lean Process Development and Application for Field Productivity Improvement (건설 현장 생산성 향상을 위한 Lean 프로세스 개발과 적용에 대한 연구)

  • Kim, Yong-pyo;Jeong, Yong-ho;Lee, Min-jae
    • Korean Journal of Construction Engineering and Management
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    • v.21 no.2
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    • pp.88-97
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    • 2020
  • Practical and efficient application of lean construction, which has been proposed as an alternative to the limitations of traditional construction management methods, was developed to facilitate application on site and improve productivity through the fusion of traditional construction management methods. The concepts of Lean Time and Lean Cycle Time, which are the principles of lean construction, were introduced to eliminate waste and smooth flow production and pursuit of perfection, and the goal of establishing and improving the criteria for measurement and improvement was established and the information collection template was configured and applied to ensure reliability of measurement and analysis. Based on this, the project feasibility, reliability, and continuous improvement process were applied to the Field case to verify its effectiveness.