• Korean Chemical Engineering Research
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• v.57 no.4
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• pp.565-574
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• 2019

Fischer-Tropsch synthesis process is a typical method for synthesizing hydrocarbons from syngas and is mainly known as iron (Fe) and cobalt (Co) catalysts. Currently, some technologies such as CTL (Coal to Liquid) and GTL (Gas to Liquid) are operated on a commercial scale depending on the products, but the research to produce light hydrocarbons and middle distillates directly has not been commercialized. Therefore, in this study, domestic studies for direct production of light hydrocarbons and middle distillates are summarized and the effect of catalyst preparation, promoter addition, zeolite combination on product selectivity is investigated.

• Journal of the Korean Society of Propulsion Engineers
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• v.22 no.5
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• pp.125-131
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• 2018

Some propellants in a liquid rocket engine are burned in the pre-burner of a staged combustion cycle engine, resulting hot gas drives the turbine. The burned gas passing through the turbine is supplied to the combustor at high temperature and pressure. The form of the gas can be fuel rich or oxidizer rich dependent upon the mixture ratio or the engine scheme. When the cycle works at oxidizer-rich condition, the metal pipes composing the engine can be ignited or even exploded by an impact of very a small particle. In this study, we developed the powder combination and processes for an anti-oxidation coating through the analysis of various coating materials.

• Applied Chemistry for Engineering
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• v.22 no.5
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• pp.486-489
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• 2011

In the present work, diazinon which is known as nondegradable and environmental toxic material was efficiently treated by the cell surface-displayed organophosphorus hydrolase (OPH) biocatalyst. The culture temperature of $25^{\circ}C$ culture temperature and the addition of 0.2 mM ethylenediamine tetraacetate (EDTA) were effective conditions for the production of recombinant OPH in Escherichia coli. 25 and 50 ppm diazinon were treated with removal rate of 4.5 and $7.2mg/g{\cdot}min$, respectively and with all over 90% removal efficiencies using recombinant cell lysates through ultrasonication disruption process. Thus, these experimental results could be utilized in environmental friendly biological treatment system for toxic chemicals such as diazinon.

• Journal of Korea Society of Industrial Information Systems
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• v.27 no.1
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• pp.27-35
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• 2022

In the most IPS (Indoor Positioning System), it is available to specify the user's movement by sending a specific signal from a tag such as a beacon to multiple receivers. This method is very efficiently used in places where the number of people is limited. On the other hand, in large commercial facilities, it is nearly difficult to apply the existing IPS method because it is necessary to attach a tag to each customer. In this paper, we propose a system that uses an external sensor grid to identify people's movement without using tags. Each sensor node uses both an ultrasonic sensor and an infrared sensor to monitor people's movements and sends collected data to the main server through wireless transmission for easy system maintenance. The operation was verified using the FPGA board, and we designed a VLSI circuit in 180nm process.

• Clean Technology
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• v.16 no.4
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• pp.245-253
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• 2010

Optimum conditions for UV-radiated photopolymerization of unsaturated polyester that could be used as protecting layer of large diameter pipe were investigated in this paper. UV photopolymerization method was selected to solve the problems, arising when thermal polymerization by organic peroxide was used, such as the instability of peroxide initiator, the evolution of volatile organic compound, and thermal deformation of product. Two of the photo-initiators (Irgacure 819 and Darocure 1173) well known for its penetrating ability deep into the polymer layer were selected, and the optimum conditions for photopolymerization (1.5 phr initiator content, 1:1.2 initiator ratio, Ga lamp for UV source) were found from the thermal and mechanical test results of the resultant UP polymers. In addition, composite materials containing UP polymer and glass fiber were tested for hardness, impact strength, and flexural strength to find that the impact strength of composite significantly improved.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.6A
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• pp.1023-1032
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• 2006

In this paper, a new method for the bridge maintenance is proposed to overcome the limit of the existing methods and to implement the preventive bridge maintenance system. The proposed method can establish the lifetime optimum maintenance strategy of the deteriorating bridges considering the life-cycle performance as well as the life-cycle cost. The lifetime performance of the deteriorating bridges is evaluated by the safety index based on the structural reliability and the condition index detailing the condition state. The life-cycle cost is estimated by considering not only the direct maintenance cost but also the user and failure cost. The genetic algorithm is applied to generate a set of maintenance scenarios which is the multi-objective combinatorial optimization problem related to the life-cycle cost and performance. The study examined the proposed method by establishing a maintenance strategy for the existing bridge and its advantages. The result shows that the proposed method can be effectively applied to deciding the bridge maintenance strategy.

• Journal of Powder Materials
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• v.30 no.6
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• pp.463-469
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• 2023

Aluminum alloys, known for their high strength-to-weight ratios and impressive electrical and thermal conductivities, are extensively used in numerous engineering sectors, such as aerospace, automotive, and construction. Recently, significant efforts have been made to develop novel aluminum alloys specifically tailored for additive manufacturing. These new alloys aim to provide an optimal balance between mechanical properties and thermal/electrical conductivities. In this study, nine combinatorial samples with various alloy compositions were fabricated using direct energy deposition (DED) additive manufacturing by adjusting the feeding speeds of Al6061 alloy and Al-12Si alloy powders. The effects of the alloying elements on the microstructure, electrical conductivity, and hardness were investigated. Generally, as the Si and Cu contents decreased, electrical conductivity increased and hardness decreased, exhibiting trade-off characteristics. However, electrical conductivity and hardness showed an optimal combination when the Si content was adjusted to below 4.5 wt%, which can sufficiently suppress the grain boundary segregation of the α-Si precipitates, and the Cu content was controlled to induce the formation of Al₂Cu precipitates.

• Journal of the Korea institute for structural maintenance and inspection
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• v.11 no.4
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• pp.109-120
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• 2007

In this study, a bridge maintenance system is developed to generate performance-based optimum maintenance strategy by considering the life-cycle cost. A multi-objective combinatorial optimization problem is formulated to generate a tradeoff maintenance scenarios which satisfies the balance among the conflicting objectives such as the performance and cost during the bridge lifetime and a genetic algorithm is applied to the system. By using the developed program, this study proposes a process of optimum maintenance scenario applying to the steel girder bridge of national road. The developed system improves the current methods of establishing the bridge maintenance strategy and can be utilized as an efficient tool to provide the optimum bridge maintenance scenario corresponding to the various constraints and requirements of bridge agency.

• Applied Chemistry for Engineering
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• v.35 no.5
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• pp.429-437
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• 2024

Dry reforming of methane (DRM) uses natural gas and carbon dioxide as reactants to produce hydrogen, potentially providing a solution for reducing greenhouse gas emissions and offering an alternative carbon-free energy source. However, since DRM is highly endothermic, its application and commercialization are limited by rapid temperature decrease and resulting catalyst inactivation. Consequently, research into catalyst development and reactor design to mitigate temperature decline is essential. In this study, computational fluid dynamics (CFD) is utilized to develop a multiphysics simulation platform for DRM within a fixed-bed reactor, employing two types of spherical catalysts: eggshell and uniform types. Our findings indicate that the eggshell model can maintain a higher temperature at the reactor's core than the uniform catalyst model by approximately 20 K. Furthermore, the eggshell model demonstrates superior methane conversion and hydrogen yield due to its ability to suppress excessively rapid reactions. These results underscore the benefits of eggshell catalysts in highly endothermic reactors, such as those used in DRM processes. The developed simulation platform can be used to assess various combinations of reactor and catalyst designs and further optimize their dimensions and operational protocols.

• Clean Technology
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• v.25 no.2
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• pp.107-113
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• 2019

Numerical model that considered the shrinking core model and elutriation and degradation of particles was developed to predict selective chlorination of ilmenite and carbo-chlorination of $TiO_2$ in a two stage fluidized bed chlorination furnace. It is possible to analyze the fluidized bed chlorination reaction to be able to reflect particle distribution for mass balances and the chlorination reaction. The numerical model showed an accuracy with error less than 6% compared with fluidized bed experiments. The chlorination degree with particle size change was greater with a smaller particle size, and there was a 100 min difference to obtain a chlorination degree of 1 between $75{\mu}m$ and $275{\mu}m$. This was not shown to such a great extent with variation of temperature ($800{\sim}1000^{\circ}C$), and there was only a 10 min difference to obtain a chlorination degree of 0.9. In the first selective chlorination process, the mass reduction rate approached to the theoretical value of 0.4735 after 180 min, and chlorination changed the Fe component into $FeCl_2$ or $FeCl_3$ and showed nearly 1. In the second carbo-chlorination process, the chlorination degree of $TiO_2$ approached 0.98 and the mass fraction reached 0.02 with conversion into $TiCl_4$. In the first selective chlorination process, 98% of $TiO_2$ was produced at 180 min, and this was changed into 99% of $TiCl_4$ after an additional 90 min. Also the mass reduction rate of $TiO_2$ was reduced to 99% in the second continuous carbo-chlorination process.