• Title/Summary/Keyword: 공기 예측

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Estimation of Personal Exposure to Air Pollutants for Workers Using Time Activity Pattern and Air Concentration of Microenvironments (시간활동 양상과 국소환경 농도를 이용한 근로자의 유해 공기오염물질 노출 예측)

  • Lee, Hyunsoo;Lee, Seokyong;Lee, Byoungjun;Heo, Jung;Kim, Sunshin;Yang, Wonho
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.4
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    • pp.436-445
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    • 2014
  • Objectives: Time-activity studies have become an integral part of comprehensive exposure assessment and personal exposure modeling. The aims of this study were to estimate exposure levels to nitrogen dioxide($NO_2$) and volatile organic compounds(VOCs), and to compare estimated exposures by using time-activity patterns and indoor air concentrations. Methods: The major microenvironments for office workers were selected using the Time-Use Survey conducted by the National Statistical Office in Korea in 2009. A total of 9,194 and 6,130 workers were recruited for weekdays and weekends, respectively, from the Time-Use Survey. It appears that workers were spending about 50% of their time in the house and about 30% of their time in other indoor areas during the weekdays. In addition, we analyzed the time-activity patterns of 20 office workers and indoor air concentrations in Daegu using a questionnaire and time-activity diary. Estimated exposures were compared with measured concentrations using the time-weighted average analysis of air pollutants. Conclusions: According to the time-activity pattern for the office workers, time spent in the residence indoors during the summer and winter have been shown as $11.12{\pm}2.20$ hours and $12.48{\pm}1.77$ hours, respectively, which indicates higher hours in the winter. Time spent in the office in the summer has been shown to be 1.5 hours higher than in the winter. The target pollutants demonstrate a positive correlation ($R^2=0.076{\sim}0.553$)in the personal exposure results derived from direct measurement and estimated personal exposure concentrations by applying the time activity pattern, as well as measured concentration of the partial environment to the TWA model. However, these correlations were not statistically significant. This may be explained by the difference being caused by other indoor environments, such as a bar, cafe, or diner.

퇴적 마그네슘의 승온속도와 열분해특성

  • Han, U-Seop;Lee, Su-Hui
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2013.04a
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    • pp.116-116
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    • 2013
  • 마그네슘은 스마트폰, 전자기기 케이스, 내화벽돌과 아크용접봉 제조시의 첨가물 등으로 사용되고 있는데, 최근에는 재활용을 위한 마그네슘 용해로를 취급하거나 가공하는 사업장이 증가하고 있어 사고위험성이 높아지고 있다. 금속분을 취급하는 사업장에서의 금속분진은 저장이나 축적 등과 같이 주로 퇴적물로서 존재한다. 퇴적분진의 발화온도는 퇴적물 형상과 두께, 입경, 분위기 가스의 유속, 산소농도, 부유분진의 농도, 퇴적밀도, 수분 등의 많은 영향인자가 관여하기 때문에 이론적 예측이 힘들고 실험적인 측정에 의존할 수 밖에 없는 것이 현실이다. 본 연구에서는 연소성이 높고 화재폭발사고사례가 많은 마그네슘(Mg) 분진을 사용하여 승온속도 변화에 따른 열분해특성을 조사하였다. 퇴적분진의 열적특성을 조사하기 위하여 METTLER TOLEDO의 TGA/DSC1를 사용하였으며, Mg 시료의 평균입경은 38, $142{\mu}m$이다. 입경 $38{\mu}m$의 Mg 시료의 열중량분석 결과, 중량증가는 $400{\sim}500^{\circ}C$의 범위에서 시작되며 $550^{\circ}C$에서 급격하게 중량이 증가하고 있으며, 증량증가개시온도(Temperature of weight gain)는 $460^{\circ}C$에서 시작하여 $900{\sim}950^{\circ}C$ 범위에서 중량 증가 포화값에 도달하였다. 입경 $142{\mu}m$의 Mg에 대하여 공기중 승온속도를 5, 10, $20^{\circ}C/min$으로 변화시키면서 실온에서 $900^{\circ}C$까지 가열 시키는 경우의 시료의 중량 변화에 따른 열분해 특성은 승온속도가 증가할수록 2단계의 S자 곡선은 완만하게 상승을 나타내며 중량증가개시온도가 높아지는 경향을 보이고 있다. 중량증가개시온도가 승온속도에 따라 변화하는 결과를 나타내고는 있지만, 시료량의 증가에 따른 영향을 열중량분석 실험방법의 제약으로 인하여 확인할 수 가 없었다. 그러나 만일 시료량이 크게 증가하는 경우에는 동일한 승온조건에서 중량증가 개시온도는 낮아질 가능성이 있다. 중량증가는 시료의 산화반응에 의한 것이므로 시료량의 증가는 시료 내부에의 열의 축적을 용이하게 하여 보다 낮은 온도에서도 산화반응이 충분히 일어나는 조건이 형성되기 때문이다. 승온속도가 증가할수록 산화 반응한 괴상형태의 연소입자가 크게 증가하고 있는 것을 알 수 있다. 승온속도에 따른 중량개시온도 곡선을 보면 [그림 24]와 같으며 승온속도 5, 10, $20^{\circ}C/min$의 증가에 따라 중량개시온도는 각각 490, 510, $530^{\circ}C$가 얻어졌으며 승온속도의 증가에 따라 중량개시온도가 증가하는 경향을 보이고 있다.

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Trajectory Simulation of ASR Particles in Induction Electrostatic Separation (유도형 정전선별에서 ASR 입자의 궤적모사)

  • Kim, Beom-uk;Park, Chul-hyun
    • Resources Recycling
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    • v.28 no.6
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    • pp.96-105
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    • 2019
  • Automobile shredder residue (ASR) is the final waste produced when end-of-life vehicles (ELVs) are shredded. ASR can be separated using mineral-processing operations such as comminution, air classification, magnetic separation, and/or electrostatic separation. In this work, trajectory analyses of conductors (copper) and non-conductors (glass) in the ASR have been carried out using induction electrostatic separator for predicting or improving the ASR-separation efficiency. From results of trajectory analysis for conductors, the trajectories of copper wire by observation versus simulation for coarse particles of 0.5 and 0.25 mm showed consistent congruity. The observed 0.06 mm fine-particles trajectory was deflected toward the (-) attractive electrode owing to the charge-density effects due to the particle characteristics and relative humidity. In the case of non-conductors, the actual trajectory of dielectric glass deflected toward the (-) electrode, showing characteristics similar to those of conductive particles. The analyses of stereoscopic microscope and SEM & EDS found heterologous materials (fine ferrous particles and conductive organics) on the glass surface. This demonstrates the glass decreasing separation efficiency for non-ferrous metals during electrostatic separation for the recycling of ASR. Future work will require a pretreatment process for eliminating impurities from the glass and advanced trajectory-simulation processes.

A Study on Strength of Plat-Plate Wall-Column Connections (Wall Column을 적용한 플랫플레이트 접합부 강도발현에 관한 연구)

  • Lee, Do-Bum;Park, Hong-Gun;Lee, Li-Hyung
    • Journal of the Korea Concrete Institute
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    • v.18 no.2 s.92
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    • pp.257-266
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    • 2006
  • Flat-plate building systems are utilized extensively for construction of apartments, hotels and office buildings because of short construction period, low floor-to-floor height and flexibility in plan design. Recently, to increase lateral seismic resistance of flat-plate building systems, wall-columns are used frequently. Therefore, to estimate strength of flat-plate column connection accurately, the effect of column section shape on the behavior of flat-plate column connection should be considered properly, In the present study, a numerical analysis was performed for interior connections of continuous flat-plate to analyze the effect of column section shape. For the purpose, a computer program for nonlinear FE analysis was developed, and the validity was verified. Through the parametric study, the variations of shear stress distribution around the connection were investigated. According to the result of numerical analysis, as the length of the cross section of column in the direction of lateral load increases, the effective area and the maximum shear strength providing the torsional resistance decrease considerably. Therefore, these effects should be considered properly to estimate the strength of flat-plate connection accurately.

PHYSICAL PROPERTIES OF VAR10US BRANDS OF ELASTOMERIC CHAINS (수종의 합성 고무탄성재의 성질에 관한 연구)

  • Kim, Kyung-Ho;Hwang, Chung-Ju;Sung, Sang-Jin
    • The korean journal of orthodontics
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    • v.27 no.6 s.65
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    • pp.943-954
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    • 1997
  • Forces needed for orthodontic tooth movement are obtained from various appliances such as orthodontic wires or elastic rubber. Orthodontic elastic rubber is widely used clinically, but permanent deformation and force decay may occur from the environmental changes, time of clinical use and the extent of the stretch, making the Prediction of force being applied difficult. The Present study examined and compared the changes in residual force between three brands of elastomeric chains (Ormco Generation II Power Chains ; brand A, RMO : Energy-Chain ; brand B, Unitek : AlastiK ; brand C) under various environmental conditions, amount of initial force, types of elastomer and the rate of extension. The characteristic physical properies of the elastomeric chains were as follows. 1. In all three brands, the residual force ratio was largest when the chains were stored in air, with no difference between water and saliva. 2. In all three brands, after 24 hours, there was no statistical difference in residual force ratio according to the initial force level. 3. In Brand A and B, the presence of filament had no correlation with the residual force ratio. In Brand C force decay was more severe when the chain contained filament. 4. In each brand, rate of extension had no effect on residual force ratio. 5. Brand B showed relatively higher residual force ratio compared to other brands.

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The Predicted Normal Value of Volume of Isoflow on Smokers and Nonsmokers (흡연자와 비흡연자에서 등기류용량(Volume of Isoflow)의 추정정상치에 관한 연구)

  • Park, Jung-Gook;Jung, Tae-Hoon
    • Tuberculosis and Respiratory Diseases
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    • v.39 no.2
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    • pp.141-149
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    • 1992
  • In order to establish predicted normal values of volume of isoflow($V_{iso}\dot{V}$), $V_{iso}\dot{V}$ were measured in a total 234 healthy adults, consisting of 78 male nonsmokers, 108 male smokers and 48 female nonsmokers. The volumes of isoflow were determined through analysis of maximal expiratory flow volume curves recorded with a mixture of 80% helium and 20% oxygen(He-$O_2$ gas) following one(1VC) and three vital capacity(3VC) maneuver and with room air. Based upon the correlation of the observed values of the parameters to age and physical characteristics, the following regression formulars for the prediction of the parameters, using age in year(A) as a variable, were obtained. 1VC method ($V_{iso}\dot{V}_1$) Male smoker : 0.614A+2.347 Male nonsmoker : 0.370A-2.792 Female nonsmoker : 0.588A-2.459 3VC method ($V_{iso}\dot{V}_3$) Male smoker : 0.467A+1.696 Male nonsmoker : 0.288A-1.538 Female nonsmoker : 0.367A-0.114.

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Gas Hydrate Exploration by using PCS(Pressre Core Sampler): ODP Leg 204 (압력코어를 이용한 가스 하이드레이트 탐사: ODP Leg 204)

  • Lee Young-Joo
    • Economic and Environmental Geology
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    • v.38 no.2 s.171
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    • pp.165-176
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    • 2005
  • Natural gas in deep sediment may occur in three phases based on the physical and chemical conditions. If the concentration of gas in pore water is less than the solubility, gas is dissolved. If the concentration of gas is greater than its solubility (water is saturated or supersaturated with gas), gas occurs as a fee gas below the gas hydrate stability Lone (GHSZ) and is present as solid hydrate within the GHSZ. The knowledge of gas concentration in deep sediment appears critical to determine the phase of natural gases and to understand the formation and distribution of gas hydrate. However, reliable data on gas concentration are usually available only from the upper section of marine sediment by the headspace gas technique, which is widely used for sampling of gases from the sediments. The headspace gas technique represents only a fraction of gases present in situ because sediments release most of the gases during recovery and sampling. The PCS (Pressure Core Sampler) is a downhole tool developed to recover a nominal $1{\cal}m$ long, $4.32{\cal}cm$ diameter core containing $1,465cm^3$ of sediment, pore water and gas at in situ pressure up to 68.9 MPa. During Leg 204, the PCS was deployed at 6 Sites. In situ methane gas concentration and distribution of gas hydrate was measured by using PCS tool. Characteristics of methane concentration and distribution is different from site to site. Distribution of gas hydrate in the study area is closely related to characteristics of in situ gas concentration measured by PCS.

Effects of Annealing on Properties of Tin Oxide films prepared by r.f. magnetron sputtering (R.F. magnetron sputter를 이용한 SnO_2$ film 특성에 대한 Annealing효과)

  • 박용주;박진성
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.208-208
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    • 2003
  • RF 마그네트론 스퍼터링법을 이용하여 Ar과 $O_2$의 유량을 25sccm씩 흘리면서 $SiO_2$/Si기판 위에 Sn $O_2$ 박막을 증착하였다. 증착된 박막은 columnar 구조로 성장하였으며 많은 입자들이 뭉쳐서 형성된 양배추꽃(cauliflower) 형태의 뭉친 입자(agglomerates)를 가지는 표면형상이 관찰되었다. 분위기에 따른 어닐링 효과를 확인하기 위하여 50$0^{\circ}C$에서 공기와 질소 분위기하에서 열처리하였다. 열처리한 후 표면거칠기가 개선되었으며, 표면형상의 변화가 발생하였다. 특히 50$0^{\circ}C$, 질소분위기에서 어닐링한 경우는 양배추꽃 형태의 표면형상이 소수의 작은 입자가 뭉친 형태로 분리되면서 입도분포가 개선되었다. 이러한 결과는 어닐링 과정에서 발생되는 응력을 완화시키기 위하여 표면형상의 변화가 발생하는 것으로 판단된다. XPS 측정 결과, 질소 분위기에서 어닐링한 후에 OIs와 Sn5/3d 피크가 낮은 결합에너지에 위치하고 있어 산소공공의 농도가 어닐링 전에 비하여 증가하였음을 확인할 수 있다. 어닐링 전후에 Sn $O_2$ 박막의 면저항 측정 값은 XPS 결과와는 달리 질소 분위기 어닐링한 후에 오히려 면저항값이 크게 증가하였다. 이러한 결과는 질소 분위기 어닐링한 후 표면형상의 변화에 기인하여 입자간의 연결성이 저하되어 면저항값이 증가한 것으로 추정된다. 산소분위기에서 어닐링한 후에 전체적으로 전기적 특성의 재현성이 개선되었으며 Sensitivity( $R_{air}$/ $R_{gas}$)가 향상되었음을 확인하였다.하였다.석을 통하여 La의 분포를 확인하였으며, HRTEM 분석을 통하여 미세구조분석을 실시하였다.2463eV였다. 10K에서 광발광 봉우리의 919.8nm (1.3479eV)는 free exciton(Ex), 954.5nm (1.2989eV)는 donor-bound exciton 인 I2(DO,X)와 959.5nm (1.2921eV)는 acceptor-bound exciton 인 I1(AO,X) 이고, 964.6nm(1.2853eV)는 donor-acceptor pair(DAP) 발광, 1341.9nm (0.9239eV)는 self activated(SA)에 기인하는 광발광 봉우리로 고찰되었다.가 높을수록 방출전류가 시간에 따라 급격히 감소하였다. 각 duty비에서 방출전류의 양이 1/2로 감소하는 시점을 에미터의 수명으로 볼 때 duty비 대 에미터 수명관계를 구해 높은 duty비에서 전계방출을 시킴으로써 실제의 구동조건인 낮은 duty비에서의 수명을 단시간에 예측할 수 있었다. 단속적으로 일어난 것으로 생각된다.리 폐 관류는 정맥주입 방법에 비해 고농도의 cisplatin 투여로 인한 다른 장기에서의 농도 증가 없이 폐 조직에 약 50배 정도의 고농도 cisplatin을 투여할 수 있었으며, 또한 분리 폐 관류 시 cisplatin에 의한 직접적 폐 독성은 발견되지 않았다이 낮았으나 통계학적 의의는 없었다[10.0%(4/40) : 8.2%(20/244), p>0.05]. 결론: 비디오흉강경술에서 재발을 낮추기 위해 수술시 폐야 전체를 관찰하여 존재하는 폐기포를 놓치지 않는 것이 중요하며, 폐기포를 확인하지 못한 경우와 이차성 자연기흉에 대해서는 흉막유착술에 더 세심한 주의가 필요하다는 것을 확인하였다. 비디오흉강경수술은 통증이 적고, 입원기간이 짧고,

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Gas Explosion Hazard Analysis in Domestic (가정집에서 가스폭발 위험성 분석)

  • Jo Young-Do;Kim Ji-Yun;Kim Sang-sub
    • Journal of the Korean Institute of Gas
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    • v.5 no.2 s.14
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    • pp.36-42
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    • 2001
  • A leak of fuel gas in partially confined area creates a flammable atmosphere and give rise to an explosion, which is one of the most common accident in domestic. Observations from accident in domestic suggest that some explosions are caused by a quantify of fuel significantly less than lower explosion limit(LEL) amount required to fill the room, which is attributed to inhomogeneous mixing of leaked gas. The minimum amount of leaked gas for explosion is highly dependent on the mixing degree in the area. For lighter gas, such as methane, a high concentration tends to build up in the space from ceiling of room. But heavy gas, such as propane, a high concentration tends to build up in the space from bottom of room. This paper presents a method for analysing the explosion hazard in a room with very small amount of leaked gas. Based on explosion limit concentration, the gaussian distribution model is used to estimate the minimum amount of leak which yields a specified explosion pressure. The results demonstrate that catastrophic structural damage can be achieved with a volume of fuel gas which is less than 0.5 percent of the total enclosed volume in domestic. The method will help analyzing hazard to develop new safe device as well as investigating accident.

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Numerical study on the pressure drop and heat transfer enhancement in a flat-plate solar collector (평판형 태양열 집열기의 압력강하 및 열전달 성능 향상에 관한 수치해석적 연구)

  • Heo, Joo-Nyoung;Shin, Jee-Young;Lee, Dooho;Son, Young-Seok
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.4
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    • pp.316-323
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    • 2013
  • The use of artificial roughness in various forms of shapes and sizes is the most common and effective way to improve the performance of a flat-plate solar collector. In the present study, numerical analysis on heat transfer and pressure drop was performed in a rectangular channel with various rib arrays. The uniform heat flux is applied to the channel from the upper side. The forms of ribs considered in this study were rib $90^{\circ}$, groove $90^{\circ}$, groove $60^{\circ}$, baffle $90^{\circ}$, baffle $60^{\circ}$, wave $90^{\circ}$ and wave $60^{\circ}$. Air is the working fluid, and the Reynolds number ranges from 3200 to 17800. Nusselt number and friction factor were investigated to predict the performance of the system with various type of ribs. The average Nusselt number and pressure drop were increased with the increase of velocity in all types of ribs. The highest heat transfer and pressure drop occurred for the baffle $90^{\circ}$, but highest performance factor considering heat transfer and pressure drop together occurred for the groove $60^{\circ}$. Therefore, heat transfer and pressure drop should be considered together when a flat plate solar collector is designed.