• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.6 no.1
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• pp.35-44
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• 2008

Long-term degradation of coment barrier by diffusion was studied with reactive transport modeling. The result of modeling showed that cement barrier was altered about 30cm thickness after 50,000 years. The pH decreased from 13.0 to 11.9 because of depletion of alkali ions, and dissolution/precipitation of portlandite and CSH (Calcium Silicate Hydrate). In addition, porosity increased about 0.3 because of dissolution of portlandite and $CSH2.0(Ca_2SiO_3(OH)_2:0.17H_2O)$. The solubility of uranium also increased with the increase of pe value The results of this study indicate that long-term degradation of comet can enhance the transport of nuclide by changing pH, pe, porosity in barrier.

• Korean Chemical Engineering Research
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• v.50 no.1
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• pp.66-71
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• 2012

We deal with a problem to determine experimentally as well as theoretically permeability of incompressible viscous flow through packed bed of bidisperse hard spheres in size. For the size ratios of large to small spheres ${\lambda}$=1.25 and 2, we set up bidisperse packing and measured porosity and permeability at various volumetric ratios of small to large spheres ${\gamma}$. Bidisperse packing shows lower porosity and permeability than monodisperse packing does. Variation of porosity as a function of ${\gamma}$ does not match with that of permeability. A theoretical expression for predicting permeability of a viscous flow for packed bed of bidisperse packing is derived based on calculation of drag force acting on each sphere and its predictions are compared with the experimental data and those from some relations previously suggested. It is found that our theory shows better agreement with experimental results than the previous studies and is proved to be quite simple and accurate in estimating the permeability.

• The Journal of Engineering Geology
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• v.21 no.4
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• pp.323-336
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• 2011

The hydro-mechanical behavior of the Earth's crust is strongly dependent on the fractional volume and geometrical structure of effective pore spaces. This study aims to understand the characteristics of pores using electrical impedance. We measured the electric impedance of core samples (diameter, 38-50 mm; length, 70-100 mm) of three types of granite (Hwangdeung, Pocheon, and Yangsan) and two types of sandstone (Boryung and Berea) with different porosities and pore structures, after saturation with saline water of varying salinities. The results show that resistance decreases but capacitance increases with increasing salinity of the pore fluid. For a given salinity, the resistivity and formation factor are reduced with increasing porosity of the rocks, and the capacitance increases. Berea sandstone shows anisotropy in resistance, tortuosity, and cementation factor, with these factors being highest normal to bedding planes. This result indicates that the connectivity of pores is weakest normal to bedding. In conclusion, the electrical characteristics of the tested samples are related not only to their porosity but also to the pore geometry.

• Journal of the Korea Concrete Institute
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• v.15 no.3
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• pp.443-453
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• 2003

The diffusivity of carbon dioxide in concrete is very important in that it directly affects the degree of carbonation in concrete structures. The purpose of the present study is to explore the diffusivity of carbon dioxide and to derive a realistic equation to estimate the diffusion coefficient of carbon dioxide in concrete. For this purpose, several series of concrete specimens have been tested. Major test variables were the water-cement ratios. The total porosities and the diffusion coefficients of carbon dioxide were measured for the specimens. The present study indicates that the measured porosities agree well with the calculated ones. The effects of porosity and relative humidity on the diffusion coefficient of carbon dioxide were examined. A prediction equation to estimate the diffusion coefficient of carbon dioxide was derived and proposed in this study. The proposed equation shows reasonably good correlation with test data on the $CO_2$ diffusion coefficient of concrete

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.5A
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• pp.737-746
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• 2008

Recently, NDTs (Non-Destructive Techniques) using electromagnetic(EM) properties are applied to the performance evaluation for RC (Reinforced Concrete) structures. Since nonmetallic materials which are cement-based system have their unique dielectric constant and conductivity, they can be characterized and changed with different mixture conditions like W/C (water to cement) ratios and unit cement weight. In a room condition, cement mortar is generally dry so that porosity plays a major role in EM properties, which is determined at early-aged stage and also be affected by curing condition. In this paper, EM properties (dielectric constant and conductivity) in cement mortar specimens with 4 different W/C ratios are measured in the wide region of 0.2 GHz~20 GHz. Each specimen has different submerged curing period from 0 to 28 days and then EM measurement is performed after 4 weeks. Furthermore, porosity at the age of 28 days is measured through MIP (Mercury Intrusion Porosimeter) and saturation is also measured through amount of water loss in room condition. In order to evaluate the porosity from the initial curing stage, numerical analysis based on the modeling for the behavior in early-aged concrete is performed and the calculated results of porosity and measured EM properties are analyzed. For the convenient comparison with influencing parameters like W/C ratios and curing period, EM properties from 5 GHz to 15 GHz are averaged as one value. For 4 weeks, the averaged dielectric constant and conductivity in cement mortar are linearly decrease with higher W/C ratios and they increase in proportion to the square root of curing period regardless of W/C ratios.

• The Journal of Engineering Geology
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• v.14 no.1
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• pp.61-69
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• 2004

Building stones are used mainly as a material for making decoration and sculpture, and consequently they must have predominant physical properties extensively. Among various physical properties, the coefficient of pore dominates the usefulness of building stones, so the plans were made for establishing the quality classification of building stones with respect to the nature of pore. For this study, bore-hole core samples according to the depth of the biotite granites and the granitic gneiss were applicated. From the related chart between porosity and absorption ratio, Mungyeong granitic gneiss($Gn_1$) shows the widest phase of distribution in the range of measurement values, and the values decrease in the order of Pocheon granite($Gr_2$) and Mungyeong granite($Gr_1$) in the range. The strength of each rock mass varies with the degree of alteration. Also in correlation between compressive strength and tensile strength, the range of measurement values decrease in the order of $Gn_1$, $Gr_2$and $Gr_1$. Porosity is adopted as a representative physical property for establishing the quality classification of building stones, and then relative evaluation was made with regard to various physical properties. From the related chart between porosity(n)-specific gravity(G), absorption ratio(Ab), compressive strength(${\sigma}_{c}$), tensile strength(${\sigma}_{t}$), shore hardness(Hs) and Young's modulus($E_{t}$), standard of each grade is established.

• Journal of the Korea Concrete Institute
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• v.14 no.3
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• pp.402-408
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• 2002

The permeable polymer-modified concrete has a lot of internal voids, which has more excellent performance in permeability and durability than asphalt and cement concrete. Therefore, the purpose of this study is to ascertain the strength properties of water-permeable polymer concretes with SBR latex and redispersible polymer powder. The water-permeable polymer concretes using SBR latex and redispersible polymer powder with water-binder ratio of 29 ％, polymer-cement ratios of 0, 5, 10, 15 and 20 ％ are prepared, and tested for compressive strength, splitting tensile strength, flexural strength, water permeablility. From the test results, improvements in the strength properties of the water-permeable polymer concretes due to the addition of the SBR latex and redispersible polymer powder are discussed.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.2
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• pp.97-104
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• 2023

In order to maximize the utilization of recycled fine aggregate, high strength mortar made of 100 % recycled fine aggregate was prepared, and its physical properties were evaluated to determine the possibility of using recycled fine aggregate as structural aggregate. The effect caused by the amount of nanosilica on the physical properties of w/b 0.2 recycled fine aggregate mortar consisting of cement, silica fume, and blast furnace slag. To improve the dispersion of nanosilica inside mortar, an aqueously dispersed nanosilica solution by ultrasonic tip sonication was prepared, and incorporated into the mortar to evaluate changes in mortar flow, porosity and compressive strength depending on nanosilica content. According to the experimental results, mortar flow decreased as the replacement ratio of nano-silica increased. As the replacement ratio of nanosilica increased up to 0.75 %, the porosity decreased and the compressive strength increased, but, at a replacement ratio of 1 %, the porosity increased and the compressive strength decreased. It was confirmed that the nano-silica replacement ratio of 0.75 % was optimum proportion to maximize the mechanical performance of high-strength recycled fine aggregate mortar.

• Tunnel and Underground Space
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• v.34 no.1
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• pp.71-87
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• 2024

In deep geological disposal of high-level radioactive waste, the surrounding rock at the immediate vicinity of the deposition hole may experience localized changes in permeability due to in-situ stress at depth, swelling pressure from resaturated bentonite buffer, and the heat generated from the decay of radioactive isotopes. In this study, experimental data on changes in permeability of granite, a promising candidate rock type in South Korea, were obtained by applying various confining pressures and temperature conditions expected in the actual disposal environment. By conducting the permeability test on KURT granite specimens under three or more hydrostatic pressure conditions, the relation in which the permeability decreases exponentially as the confining pressure increases was derived. The temperature-induced changes in permeability were found to be negligible at temperatures below the expected maximum of 90℃. In addition, by establishing a relation in which the initial permeability is proportional to the power of the initial porosity, it was possible to estimate permeability value for granite with a specific porosity under a certain confining pressure.

• Journal of the Korea Concrete Institute
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• v.17 no.4 s.88
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• pp.595-602
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• 2005

The purpose of this study is to utilize recycled concrete aggregates as permeable pavement materials. This study evaluates mechanical properties and durability of porous concrete depending on mixing rates of recycled aggregates and polyme. As a result, void ratio and permeability coefficient of porous concrete for pavement increased a little as mixing rate of recycled aggregates increased. Void ratio and permeability coefficient increased a lot as mixing rate of polymer increased. As polymer was mixed $20\%$, national regulation of permeable concrete for pavement($8\%$ and 0.01cm/sec) was met. Compressive strength and flexural strength decreased as mixing rate of recycled aggregates increased but they increased a lot as mixing rate of polymer increased. Even when recycled aggregates were mixed $75\%\;with\;10\%$ polymer mixed, national regulation of pavement concrete(18MPa and 4.5MPa) was met. In addition, regarding sliding resistance, BPN increased as mixing rate of recycled aggregates increased. But BPN decreased as polymer was mixed. Compared to crushed stone aggregates, abrasion resistance and freeze-thaw resistance decreased as mixing rate of recycled aggregates Increased. When polymer was mixed, abrasion resistance and freeze-thaw resistance improved remarkably. Compared to non-mixture, $10\%$ mixture of polymer improved abrasion resistance and freeze-thaw resistance about $8.6\%$ and 3.8times respectively.