• Title/Summary/Keyword: 고체연료

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Comparative analysis on range of application of technology convergence as a means of technological innovation (기술혁신 수단으로써 기술융합 이론의 적용 범위에 대한 비교 연구)

  • Choi, Hyukjoon;Lee, Youah
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.142-142
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    • 2010
  • 일반적으로 기술융합이라는 용어는 IT, BT, NT 등 성격이 다른 큰 범주에서 기술간의 결합으로 인식되고 있다. 현재까지의 기술융합 연구들은 IT기술을 중심으로 한 융합과 관련 국가 정책에 관한 것이 대부분을 차지하고 있어 큰 기술 범주 위주에 국한되어 있다. 하지만 동일한 목적을 위해 수행하는 유사 기술영영에서의 기술융합 역시 기술혁신의 수단으로 간과할 수 없는 영역이다. 실제로 미국, 유럽 등의 선진국에서는 기술융합 전담기관을 신설하여 프로젝트 내의 기술간 융합에 관심을 갖고 있지만, 국내에서는 프로젝트 범위의 기술융합 가능성 및 실효성에 대한 연구가 부족한 실정이다. 이에 본 연구에서는 지식경제부에서 수행하는 가스하이드레이트 연구개발사업을 실증사례로 하여 프로젝트 범위의 기술 융합에 관하여 기술융합의 필요성, 적용가능성, 실효성에 초점을 맞추어 고찰하였다. 가스하이드레이트 개발 사업은 지식경제부 내 가스하이드레이트 개발사업단 주관으로 2005년에 시작되었으며 2014년까지 I 지역 탐사 및 시추, II 지역 탐사 및 시추, 시험생산의 3단계의 달성목표를 가지고 있다. 가스하이드레이트는 천연가스가 저온 고압 상태에서 물과 결합해 형성된 고체 에너지로 화석연료 고갈에 따라 이를 대체할 가장 유력한 청정에너지원으로 주목받고 있다. 현재 가스하이드레이트 개발사업단에서는 지구물리탐사분야 지질지화학분야 개발생산분야로 세부 기술모듈을 형성하여 목표달성을 위해 노력하고 있지만, 중과제간 교류가 부족한 상황으로 인해 목표달성을 위한 기술력의 확보 및 향후 상업생산에 대한 불확실성이 증가하고 있는 상황이다. 이와 같은 상황을 해결하기 위해서 기술개발 및 혁신의 수단인 기술융합의 필요성이 증가하고 있다. 기술혁신은 기초연구, 응용연구, 개발, 학습, 투자 등의 일련의 과정을 거쳐 경제적 성과와 사회적 영향을 만들어내는 개념으로 정의 할 수 있다. 기술혁신을 이루어내는 가장 중심적인 역할을 담당하는 기술융합은 2개 이상의 요소기술들이 결합하여 기술이 갖지 않는 새로운 기능을 발휘하는 기술혁신의 한 현상으로 정의할 수 있다. 기술융합은 21세기 초에 접어들어 급속하게 변화하는 양상을 보이며 예상보다 경제에 더 큰 영향을 미치고 있다. 가스하이드레이트 각 단계에서의 애로점을 극복하기 위한 기술혁신을 위해 지구물리탐사 지질지화학 개발생산분야간의 융합의 가능성 등을 타진해본 결과, 각 기술융합들을 기술융합 유형에 맞춰 분류할 수 있었으며 유형별 적용가능성과 기대효과 측면에서 비교분석을 수행하였다. 분석의 정밀도를 높이기 위하여 기술융합 유형에 대한 이론과 실제 가스하이드레이트 전문가들과의 설문을 통해 비교분석을 실시하였다. 가스하이드레이트 실증 사례에 대한 분석 결과, 기술융합 이론은 기존의 큰 기술범주뿐만 아니라 작은 범주에도 적용할 수 있으며, 필요성과 적용가능성, 실효성 면에서도 충분한 고찰을 통해 기술융합 이론의 적용 범위를 좁히면 더 많은 연구와 융합기술을 얻을 수 있다는 결론을 얻을 수 있다.

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Analysis of the Actual Conditions of the Asphalt Regulations by Fire Service Organizations and Explosion Cases (아스팔트에 대한 소방기관의 규제 실태와 폭발사례의 분석)

  • Lee, Eui-Pyeong
    • Fire Science and Engineering
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    • v.31 no.3
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    • pp.97-105
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    • 2017
  • Because asphalt is a solid at normal temperature and is not a hazardous material as stipulated in the Safety Management Act on Hazardous Materials, it is often recognized as having no risk of fire or explosion. On the other hand, it is as dangerous as flammable liquid because it is heated to $170-180^{\circ}C$ and stored in a storage tank. This study analyzed the risk of fire and explosion during the storage and handling of asphalt and the actual conditions of asphalt regulations by fire service organizations. Moreover, this study analyzed the domestic case of explosions in the production process of asphalt concrete (ASCON) and domestic and foreign cases of asphalt storage tank explosions. The analysis suggested that unlike Japan, Korea has no asphalt regulations in fire service organizations. Explosions can occur when ignition is delayed after fuel is sprayed on the dryer drum burner of the aggregates during the production of ASCON. A physical explosion can occur in the storage tank when environmental purification facilities suddenly work strongly to remove air pollutants or bad smells during the heating of asphalt in an asphalt storage tank. In addition, explosions can occur when fires such as welding is performed in the asphalt storage tank.

Numerical Study of Flow Characteristics in a Solid Particle Incinerator for Various Design Parameters of Injectors (고체 입자 소각로에서 분사기의 설계 인자에 따른 유동 특성에 관한 수치해석적 연구)

  • Son, Jin Woo;Kim, Su Ho;Sohn, Chae Hoon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.12
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    • pp.1079-1089
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    • 2013
  • The flow characteristics in a solid particle incinerator are investigated numerically for high burning rate of wastes. The studied incinerator employs both a swirl flow used in the furnace of powerplants and a design concept applied to a rocket combustor. As the first step, the non-reactive flow field is analyzed in the incinerator with primary and secondary injectors through which solid fuel and air are injected. The deflection angle of a primary injector, inclination angle of a secondary injector, and gap between the two types of injectors are selected as design parameters. The swirl number is adopted for evaluating the degree of swirl flow and estimated over wide ranges of three parameters. The swirl number increases with deflection angle, but it is affected little by inclination angle. Recirculation zones are formed near the injectors, and their size affects the swirl number. The swirl number decreases with the zonal size of recirculation. From the numerical results, the design points can be found with strong swirl flow.

Effect of the A-site Deficieny of ABO3 type (La0.75Sr0.25)1-xFeO3-δ Used as Cathode Materials for SOFC on the Electrode Properties (고체산화물 연료전지의 공기극용 ABO3구조의 (La0.75Sr0.25)1-xFeO3-δ의 A-site변화에 따른 전극 특성 연구)

  • Park, Ju-Hyun;Lee, Seung-Bok;So, Hui-Jeong;Lim, Tak-Hyoung;Yoon, Soon-Gil;Shin, Dong-Ryul;Song, Rak-Hyun
    • Journal of the Korean Electrochemical Society
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    • v.11 no.2
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    • pp.89-94
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    • 2008
  • We synthesized and investigated $(La_{0.75}Sr_{0.25})_{1-x}FeO_{3-\delta}$ perovskite oxides having different stoichiomety (x = 0, 0.02, 0.04, 0.06, 0.08) as cathode materials. SEM images and XRD patterns reveal that the synthesized powder has uniform size distribution and high degree of crystallinity. The electrochemical performances of the synthesized powders were investigated by AC impedance spectroscopy. Both the electric conductivity and the electrochemical performance showed the highest properties at the stoichiometry x = 0.02. Finally, we concluded that the variation of A-site deficiency results in the variation of the amount of oxygen vacancy and micro structure, which leads to the variation of electric conductivity and polarization resistance.

Cathode Characteristics in the Synthesis of $(La,\;Sr)MnO_{3+{\delta}$ of Precursor ($(La,\;Sr)MnO_{3+{\delta}$ 합성에 있어서 출발물질에 따른 양극특성)

  • Lee, Mi-Jai;Kim, Sei-Ki;Ji, Mi-Jung;Choi, Byung-Hyun;Park, Sang-Sun
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.360-363
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    • 2006
  • We synthesized $(La,\;Sr)MnO_{3+{\delta}$ as a cathode for SOFC by glycine nitrate process(GNP) and knew the different properties of $(La_{1-x}Sr_x)MnO_3$ by using nitrate solution and oxide solution as starting material. In case of using nitrate solution as a starting material, main crystal phase peak of $LaMnO_3$ increased as Sr content added up and a peak of $Sr_2MnO_4\;and\;La_2O_3$ was showed as a secondary phase. We added Mn excess to control a crystal phase. In this case, the electrical conductivity had a high value 210.3S/cm at $700^{\circ}C$ On the other side, when we used oxide solution as a starting material, we found main crystal phase of $LnMnO_3$ to increase as Sr content added up and a peak of $La_2O_3$ as a secondary phase. Similary, we added Mn excess to control a crystal phase in this case. We knew $(La,\;Sr)MnO_3$ powder to sinter well and the electrical conductivity of the sintered body at $1200^{\circ}C$ for 4hrs was 152.7s/cm at $700^{\circ}C$. The sintered $(La,\;Sr)MnO_3$ powder at $1000^{\circ}C$ for 4hrs got the deoxidization peak, depending on the temperature md in case of using nitrate solution as a start ing material the deoxidization peak was showed at $450^{\circ}C$ which is lower than used a oxide solution as a starting material. As a result, when $(La,\;Sr)MnO_3$ powder was synthesized to add Mn excess and to use nitrate solution as a starting material, we found it to have the higher deoxidization property and considered it as a cathode for m properly. And we found it to have different electrical conduct ivity the synthesized $(La,\;Sr)MnO_3$ powder by using different start ing materials like nitrate solution and oxide solution which influence a sintering density and crystal phase.

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Analysis of Environmental Impacts for the Biochar Production and Soil Application (폐목재를 이용한 바이오차 생산 및 토양적용의 환경평가)

  • Kim, Mihyung;Kim, Geonha
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.7
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    • pp.461-468
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    • 2014
  • Biochar is a carbon rich solid produced by the pyrolysis of biomass such as energy crops, forestry residues, and wood wastes. Biochar returned to soil is to mitigate climate change and the feedstock of wood wastes reduces fossil fuel consumption as well as disposal costs. This study was practiced to evaluate a biochar system by gasification in terms of global warming regarding the soil application of the produced biochar. Life cycle assessment methodology was used to analyze the environmental impacts of the system, and the functional unit was 1 tonne of wood wastes. The result shows that the biochar system by using wood wastes as feedstock produces 4.048E-01 $kgCO_2-eq$ from the pre-treatment process as chipping and drying, 4.579E-01 $kgCO_2-eq$ from the pyrolysis process, and 9.070E-02 $kgCO_2-eq$ from the spreading to agricultural land, therefore total 9.534E-01 $kgCO_2-eq$ are generated. About 252 kg of $CO_2$ is still stored in the produced biochar in soil after carbon offsetting of the system. Therefore, the net carbon of the system is -251 kg of $CO_2-eq$.

Structural and electrochemical characterization of K2NiF4 type layered perovskite as cathode for SOFCs (K2NiF4 type 층상 페롭스카이트 구조 La(Ca)2Ni(Cu)O4-δ의 SOFC 양극 특성 및 결정구조 평가)

  • Myung, Jae-ha;Hong, Youn-Woo;Lee, Mi Jai;Jeon, Dae-Woo;Lee, Young-Jin;Hwang, Jonghee;Shin, Tae Ho;Paik, Jong Hoo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.3
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    • pp.116-120
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    • 2015
  • $La_2NiO_{4+{\delta}}$ based oxides, a mixed electronic-ionic conductors (MIECs) with $K_2NiF_4$ type structure, have been considerably investigated in recent decades as electrode materials for advanced solid oxide fuel cells (SOFCs) due to their high electrical conductivity, and oxidation reduction reaction (ORR). In this study, structure properties of $La(Ca)_2Ni(Cu)O_{4+{\delta}}$ were studied as a potential cathode for intermediate temperature SOFCs (IT-SOFCs).

Preparation and characterization of La0.8Sr0.2Ga0.8Mg0.1Co0.1O3-δ electrolyte using glycine-nitrate process (Glycine nitrate process로 합성된 La0.8Sr0.2Ga0.8Mg0.1Co0.1O3-δ 전해질의 제조 및 특성평가)

  • Ok, Kyung-Min;Kim, Kyeong-Lok;Kim, Tae-Wan;Kim, Dong-Hyun;Park, Hee-Dae;Sung, Youl-Moon;Park, Hong-Chae;Yoon, Seog-Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.1
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    • pp.37-43
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    • 2013
  • Conductivity of LSGMC materials were affected by secondary phase segregation, composition and synthetic route. $La_{0.8}Sr_{0.2}Ga_{0.8}Mg_{0.1}Co_{0.1}O_{3-{\delta}}$ (LSGMC) powders were prepared using the glycine nitrate process to produce high surface area and compositionally homogeneous powders. The powders were synthesized with different 0.5, 1, 1.5, 2, 2.5 of glycine/cation molar ratios. A single perovskite phase from the synthesized powders was characterized with X-ray diffraction patterns. The obtained sintered pellets showed the dense grain microstructure. In case of 1.5 molar ratio, its density was higher than the others. The electrical conductivity measured at $800^{\circ}C$ was observed to be 0.131 $Scm^{-1}$. In addition, the linear thermal expansion behavior was indicated between $25^{\circ}C$ and $800^{\circ}C$.

Attrition and Heat Transfer Characteristics of Fluidized Bed Materials for a Solar Hybrid Process (태양열 하이브리드 공정을 위한 유동층 입자들의 마모 및 열전달 특성 연구)

  • Kim, Hyung Woo;Lee, Doyeon;Nam, Hyungseok;Hong, Young Wan;Seo, Su Been;Go, Eun Sol;Kang, Seo Yeong;Lee, See Hoon
    • Clean Technology
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    • v.26 no.1
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    • pp.65-71
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    • 2020
  • Various solar hybrid energy conversion processes, which have both the advantages of renewable energy sources and fossil energy sources, have been developed in the world because stable and predictable energy supplies, such as electricity and natural gas, are necessary for modern societies. In particular, a solar hybrid energy conversion process based on a dual fluidized bed process concept has been expected as the promising solution for sustainable energy supply via thermochemical conversions, such as pyrolysis, combustion, gasification, and so on, because solar thermal energy could be captured and stored in fluidized bed materials. Therefore, the attrition and heat transfer characteristics of silicon carbide and alumina particles used for fluidized bed materials for the solar hybrid energy conversion process were studied in an ASTM D5757 reactor and a bubbling fluidized bed reactor with 0.14m diameter and 2m height. These characteristics of novel fluidized bed materials were compared with those of sand particles which have widely been used as a fluidized bed material in various commercial fluidized bed reactors. The attrition resistances of silicon carbide and alumina particles were higher than those of sand particles while the average values of heat transfer coefficient in the bubbling fluidized bed reactor were in the range of 125 ~ 152 W m-2K-1.

Study of Optimization and Characteristics of PSCF3737(Pr0.3Sr0.7Co0.3Fe0.7O3) for IT-SOFC (중저온형 SOFC를 위한 PSCF3737(Pr0.3Sr0.7Co0.3Fe0.7O3) 공기극 물질의 특성 및 최적화께 관한 연구)

  • Park, Kwang-Jin;Lee, Chang-Bo;Kim, Jung-Hyun;Baek, Seung-Wook;Bae, Joong-Myeon
    • Journal of the Korean Electrochemical Society
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    • v.10 no.3
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    • pp.207-212
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    • 2007
  • [ $PSCF3737(Pr_{0.3}Sr_{0.7}Co_{0.3}Fe_{0.7}O_3)$ ] is a good candidate cathode material for IT-SOFC(intermediate temperature solid oxide fuel cell) because of high MIEC(mixed ionic electronic conductor) conductivity. In this study, the characteristics of PSCF3737 was investigated and optimizations of sintering temperature and thickness for $PSCF3737(Pr_{0.3}Sr_{0.7}Co_{0.3}Fe_{0.7}O_3)$ was carried out. Impedance responses were divided into two parts by frequency region. Middle frequency part (${\sim}10^2\;Hz$) was concerned with oxygen reduction reaction on surface and low frequency part (${\sim}10^{-1}\;Hz$) was related with oxygen diffusion. The reasonable sintering temperature and thickness of cathode were $1200^{\circ}C$ and about $27\;{\mu}m$ with regard to EIS(electrochemical impedance spectroscopy). ASR(areas specific resistance) of optimized cathode is $0.115\;{\Omega}\;cm^2$ at $700^{\circ}C$.