• Title/Summary/Keyword: 고분자 복합재료

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Manufacturing and Mechanical Properties of Epoxy Fibers Spinning using Anhydride and Amine Hardeners (산 무수물계 및 아민계 경화제를 이용한 열경화성 에폭시 섬유 제조 및 물성)

  • Shin, Pyeong-Su;Kim, Jong-Hyun;Park, Ha-Seung;Baek, Yeong-Min;Kwon, Dong-Jun;Park, Joung-Man
    • Composites Research
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    • v.29 no.6
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    • pp.408-413
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    • 2016
  • Commonly-used polymers are manufactured as versatile forms. Furthermore, continuous polymer fibers are recently manufactured using nylon or aramid fiber. One of common epoxy was also used to make polymer fibers. Bisphenol-A type was used as base epoxy whereas amine and anhydride were used as hardeners. Epoxy fibers was cured by stepping up the temperature to maintain the shape of epoxy fiber. Surface energy was measured to confirm the degree of interfacial adhesion by modified static contact angle method. After mechanical properties were measured via fiber tensile test, the evaluation of fiber fracture was proceeded. Tensile strength of epoxy fiber using amine type hardener was higher as 138 MPa than anhydride case as 70 MPa. Fractured surface exhibited different failure patterns at the cross-section.

A Study on the Evaluation of Physical Properties of Polymer-based Composite Materials for the Brake of the Automobile (자동차 브레이크용 고분자복합재료의 물리적 특성평가에 관한 연구)

  • Son, Tae Gwan;Kim, Yun Hae;Kim, Bong Sik
    • Journal of Advanced Marine Engineering and Technology
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    • v.20 no.2
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    • pp.75-75
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    • 1996
  • The rapid expansion for the auto-industry and the worldwide trend toward non-asbestos friction materials for brake lining force our industry to transfer into non-asbestos ones from asbestos-based friction materials. Furthermore, it is imperative for the friction materials to have technological excellence and lower production cost to be competitive in the world market. There is no known theoretical procedures to formulate friction materials. It, rather, depends on the trial and error process. Thus, it is quite clear how important it is to accumulate the know-how on the formulation and manufacturing the friction material. This study concerns the practical ways of conceptualizing the formulation and optimizing the manufacturing process. This study focused on the development of formulation for non-asbestos friction material as well as deriving the physical properties of the trial product to prove its validity and applicability. Elaboration of the formula and optimizing scheme of the manufacturing process to get better quality are also sought. Physical properties were obtained by constant velocity test dynamotest, hardness test and strength test. Differential scanning calorimeter was also used to analyze the thermal reactions of organic constituents, microstructures, bond effects, and degree of mixture.

A Study on the Evaluation of Physical Properties of Polymer-based Composite Materials for the Brake of the Automobile (자동차 브레이크용 고분자복합재료의 물리적 특성평가에 관한 연구)

  • 손태관;김윤해;김봉식
    • Journal of Advanced Marine Engineering and Technology
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    • v.20 no.2
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    • pp.7-14
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    • 1996
  • The rapid expansion for the auto-industry and the worldwide trend toward non-asbestos friction materials for brake lining force our industry to transfer into non-asbestos ones from asbestos-based friction materials. Furthermore, it is imperative for the friction materials to have technological excellence and lower production cost to be competitive in the world market. There is no known theoretical procedures to formulate friction materials. It, rather, depends on the trial and error process. Thus, it is quite clear how important it is to accumulate the know-how on the formulation and manufacturing the friction material. This study concerns the practical ways of conceptualizing the formulation and optimizing the manufacturing process. This study focused on the development of formulation for non-asbestos friction material as well as deriving the physical properties of the trial product to prove its validity and applicability. Elaboration of the formula and optimizing scheme of the manufacturing process to get better quality are also sought. Physical properties were obtained by constant velocity test dynamotest, hardness test and strength test. Differential scanning calorimeter was also used to analyze the thermal reactions of organic constituents, microstructures, bond effects, and degree of mixture.

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Mechanical Properties of Aminosilane-Treated Wood Flour/PVC/Nanoclay Composites (아미노실란으로 개질된 목분/PVC/나노점토 복합재의 기계적 특성)

  • Park, Sol-Mon;Kim, Dae-Su
    • Polymer(Korea)
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    • v.36 no.5
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    • pp.573-578
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    • 2012
  • In general, most physical properties of wood/polyvinyl chloride (PVC) composites are lower than those of corresponding neat PVC resin because of poor interfacial adhesion between the hydrophilic wood flour and hydrophobic PVC. Therefore, in this study, we treated wood flour with three aminosilanes to improve wood/PVC interfacial adhesion strength, and eco-friendly wood/PVC/nanoclay composites were prepared by melt blending the aminosilane-treated wood flour, a heavy metal free PVC compound, and a type of nanoclay. The effects of treating wood flour with the aminosilanes and adding the nanoclay on the mechanical properties of the composites were investigated. Mechanical properties of the composites were investigated by universal testing machine (UTM), izod impact tester, dynamic mechanical analyzer (DMA), and thermomechanical analyzer (TMA). The tensile properties of the composites with the aminosilane-treated wood flour were considerably higher than those of the composites with neat wood flour. Furthermore, a small amount of the nanoclay improved mechanical properties of the composites. The performance of the wood/PVC composites was considerably improved by using the aminosilane-treated wood flour and the nanoclay.

A Study on the Coating Cracking on a Substrate in Bending II : Experiment (굽힘모드하에서의 코팅크랙킹의 분석II: 실험)

  • Sung-Ryong Kim;John A. Nairn
    • Composites Research
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    • v.13 no.3
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    • pp.48-57
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    • 2000
  • Fracture analysis of coating cracking on a substrate system described in a companion paper was applied and verified by four-point bending tests. The multiple cracking of coating was predicted using a fracture mechanics approach. The strain energy release rate (G) due to the formation of a new crack in a coating was obtained. A crack density vs. strain data of metallic and polymeric substrate was used to get the in-situ fracture toughness of coating with respect to various baking time and temperature. The $G_c$ was decreased as the baking temperature and time was increased. This paper gave insight about usefulness of four-point bending test for fracture toughness evaluation of coating and it gave a new method for in-situ coating toughness.

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An Experimental Study on the Absorbed Energy of Polymeric Foam According to Different Mass and Impact Velocity Based on the Constant Impact Energy (동일 에너지 조건하에 충격체 질량과 속도변화에 따른 발포 고분자의 흡수 에너지에 관한 실험적 연구)

  • Kim, Byeong-Jun;Kim, Han-Kook;Cheon, Seong S.
    • Composites Research
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    • v.27 no.2
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    • pp.42-46
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    • 2014
  • In the present study, impact tests were carried out to investigate the crashworthy behaviour of the expanded polypropylene under the constant incident energy (100 J and 200 J) with five different combinations of striker mass and velocity. Also, preliminary quasi-static test was performed to obtain basic characteristics of the expanded polypropylene. MTS 858 and Instron dynatup 9250 HV were used for the quasi-static test and impact tests, respectively. In consequence, it was found that the impact energy absorption characteristics of the expanded polypropylene was more influenced by the striker mass instead of the velocity of the striker.

A Study on an Ultrasonic Circular Array Transducer for Intra-vascular Ultra-sound Diagnosis (혈관 내부 진단용 원형 배열 초음파 트랜스듀서에 대한 연구)

  • 김희원;이수성;노용래
    • The Journal of the Acoustical Society of Korea
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    • v.22 no.4
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    • pp.329-336
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    • 2003
  • Intra-Vascular Ultra-Sound (IVUS) transducers were developed for the application to diagnose coronary diseases. The transducer consists of 32 piezoelectric elements with a front insulation layer and a polymeric acoustic backing layer on a hollow alumina tube. The optimal geometrical structure of the transducer was designed through theoretical analysis of radiation patterns of the transducer. Samples of the IVUS transducers of the diameter of 3㎜ were fabricated to illustrate the design scheme. For the piezoelectric elements, 2-2 mode piezocomposite materials were employed. Experimental performance of the transducers showed good agreement with the design results, which verified feasibility of the transducer for IVUS applications.

Study on the Damage Characteristics Under the High-Velocity Impact of Composite Laminates Using Various Sensor Signals (다양한 센서 신호를 이용한 복합적층판의 고속충격 손상 특성 연구)

  • Cho, Sang-Gyu;Kim, In-Gul;Lee, Seok-Je;You, Won-Young
    • Composites Research
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    • v.24 no.6
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    • pp.49-55
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    • 2011
  • The use of advanced composite materials in main structures of military and civil aircraft has been increased rapidly because of their considerable metals in high specific strength and stiffness. However, the mechanical properties of composite materials may severely degrade in the presence of damage. Especially, the high-velocity impact such as a hailstorm, and a small piece of tire or stone during high taxing, can cause considerable damage to the structures and sub-system in spite of a very small mass. However, it is not easy to detect the damage in composite plates using a single sensor or any conventional methods. In this paper, the PVDF sensors and AE sensors were used for monitoring high-velocity impact damage initiation and propagation in composite laminates. The WT(wavelet transform) is used to decompose the sensor signals. In the PVDF sensor and AE sensor signal analysis, amounts of high-frequency signals are increased when the impact energy is increased. PVDF sensor and AE sensor signal appeared similar results. This study shows how various sensing techniques can be used to characterize high-velocity impact damage of advanced composite laminates.

Interfacial Evaluation and Microfailure Sensing of Nanocomposites by Electrical Resistance Measurements and Wettability (전기저항측정법 및 젖음성을 이용한 나노복합재료의 미세파손 감지능 및 계면물성 평가)

  • Park, Joung-Man;Kwon, Dong-Jun;Shin, Pyeong-Su;Kim, Jong-Hyun;Baek, Yeong-Min;Park, Ha-Seung
    • Composites Research
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    • v.30 no.2
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    • pp.138-144
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    • 2017
  • Damage sensing of polymer composite films consisting of poly(dicyclopentadiene) p-DCPD and carbon nanotube (CNT) was studied experimentally. Only up to 1st ring-opening polymerization occurred with the addition of CNT, which made the modified film electrically conductive, while interfering with polymerization. The interfacial adhesion of composite films with varying CNT concentration was evaluated by measuring the wettability using the static contact angle method. 0.5 wt% CNT/p-DCPD was determined to be the optimal condition via electrical dispersion method and tensile test. Dynamic fatigue test was conducted to evaluate the durability of the films by measuring the change in electrical resistance. For the initial three cycles, the change in electrical resistance pattern was similar to the tensile stress-strain curve. The CNT/p-DCPD film was attached to an epoxy matrix to demonstrate its utilization as a sensor for fracture behavior. At the onset of epoxy fracture, electrical resistance showed a drastic increase, which indicated adhesive fracture between sensor and matrix. It leads to prediction of crack and fracture of matrix.

Preparation and Physical Properties of Polypropylene/Cellulose Composites (폴리프로필렌/셀룰로오스 복합재의 제조 및 물성)

  • Jang, Song Yi;Kim, Dae Su
    • Polymer(Korea)
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    • v.39 no.1
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    • pp.130-135
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    • 2015
  • Cellulose has attracted much attention as potential reinforcements in green composites. In this study, polypropylene (PP)/cellulose composites were prepared by melt-blending followed by compression molding. To improve interfacial bonding between PP and cellulose, maleic anhydride-grafted polypropylene (MAPP) was used. Mechanical properties of the PP/cellulose composites were investigated by UTM and izod impact tester. Thermal properties of the PP/cellulose composites were investigated by TGA and DSC. SEM images for the fracture surfaces of the composites showed that the MAPP was effective in improving PP/cellulose interfacial bonding. Tensile strength and modulus of the composite were maxima when MAPP content, based on cellulose content, was 3 wt%. With increasing cellulose content, the impact strength of the composites decreased but the tensile strength and modulus increased.