• Polymer(Korea)
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• v.32 no.3
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• pp.276-283
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• 2008

Kind of monomer(MMA, EA, BA, St)and the monomer ratio(80/20 to 20/80) where changed in the preparation of the core shell binder, and property was improved the plasma processing. Each material changed by plasma treatment time($1{\sim}10\;s$) to change to measure the tensile strength, contact angle and adhesion peel strength for the core shell binder optimal conditions for handling the output of the surface treatment. The type of polymerization and composition of the binder is a regardless initiator of APS, the reaction temperature of $85^{\circ}C$ to 0.3 wt% of the surfactant used to indicate when the conversion rate was the highest, core shell composite particle binder got two glass temperature curves. Core shell binder after the plasma processing contact angle change is the PEA/PSt 38 percent of cases within five seconds to indicate slight decrease was a decline rapidly if not handled $0^{\circ}$ to reach. Tensile strength PSt/PMMA varies $46.71{\sim}46.27\;kg_f$/2.5 cm and adhesion strength PEA/PMMA varies $7.89{\sim}14.44\;kg_f$/2.5 cm increases. Overall, adhesion strength of core shell composite particle is in the order of order PEA>PBA>PSt for shell monomer MMA.

• Polymer(Korea)
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• v.37 no.4
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• pp.518-525
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• 2013

To improve the mechanical properties of polypropylene (PP) biocomposites reinforced with sulfuric acidtreated green algae (SGA), SGA/graphite nanoplatelets (GNP)/PP biocomposites were prepared and their properties were evaluated depending on the particle size and content of GNP. The flexural and impact strength of SGA/GNP/PP biocomposites decreased with the addition of GNP, whereas the flexrual and storage moduli were greatly improved with increasing GNP loading. SGA/GNP/PP biocomposites reinforced with GNP5 showed generally better mechanical properties compared to that reinforced with GNP15 mainly due to the improved dispersion of the smaller GNP. SGA/GNP/PP biocomposites reinforced with GNP5 showed a lower resistance to the thermal expansion because the relatively uniform dispersion of smaller GNP was responsible for the effective heat transfer to the polymer matrix. As a result, SGA/GNP/PP biocomposite was acceptable for the general purpose application due to the improved flexural resistance, storage moduli, and damping characteristics.

• Korean Chemical Engineering Research
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• v.43 no.3
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• pp.425-431
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• 2005

New type of supercapacitor using high surface area activated carbons mixed with high conductivity polypyrrole (Ppy) has been prepared in order to achieve low impedance and high energy density. Mixed carbons of BP-20 and MSP-20 were used as the active electrode material, and polypyrrole doped with 2-naphthalenesulfonic acid (2-NSA) and carbon black (Super P) as conducting agents were added to activated carbons in order to enhance good electric conductivity. Electrodes prepared with the activated electrode materials and the conducting agents were added to a solution of organic binder [P(VdF-co-HFP) / NMP]. The ratio of optimum electrode composition was 78 : 17 : 5 wt.％ of (MSP20 : BP-20=1 : 1), (Super P : Ppy=10 : 7) and P(VdF-co-HFP) respectively. The performance of unit cell with addition of 7 wt％ Ppy have shown specific capacitance of 28.02 F/g, DC-ESR of $1.34{\Omega}$, AC-ESR of $0.36{\Omega}$, specific energy of 19.87 Wh/kg and specific power of 9.77 kW/kg. With addition of Ppy, quick charge-discharge of unit cell was possible because of low ESR, low charge transfer resistance and quick reaction rate. And good stability up to 500 chargedischarge cycles were retained about 80％ of their original capacity. It was concluded that the specific capacitance originated highly from compound phenomena of the pseudocapacitance by oxidation-reduction of polypyrrole and the nonfaradaic capacitance by adsorption-desorption of activated carbons.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2011.11a
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• pp.47-47
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• 2011

국내의 기능성 난연성 섬유 제조기술은 원사 자체에 난연제가 포함된 상태인 난연 PET 원사나, 일반 PET 원단에 후방염 처리한 원단이 사용되기에 난연 방염성능이 만족스럽지 못하고 친환경적이지 못한 실정이다. 오늘날 세계 난연섬유 시장 규모는 10조원에 이르고 있으며 국내에서도 화재에 대한 경각심이 높아지는 추세이므로 기능성을 갖춘 고부가가치 난연소재의 개발이 시급하다. 폴리페닐렌술피드(PPS)는 내열성 및 내화학약품성이 뛰어난 열가소성 고분자로 용융방사가 가능하다. 난연성이 높은 양모섬유 또는 아크릴계 난연섬유, 아라미드 섬유 등은 비용 문제로 범용화에 한계가 있으므로 비교적 저렴한 PPS 섬유가 개발될 경우 범용화를 기대할 수 있다. 현재는 PPS 섬유가 특수한 용도에 주로 사용되고 있으나 우수한 난연 특성을 이용하여 일반 용도로의 사용 및 수요가 급격히 늘어날 것으로 예상되며 우선적으로 인테리어용 원단, 특히 커튼이나 소파용 원단으로 용도 전개가 가능할 것으로 판단하였다. 본 연구에서는 소파용 PPS 원단의 후가공 조건의 선정 및 불소계 발수방오가공을 위한 최적의 조건을 선정하고자 하였다. Padding(wet pick up율 $80{\pm}3%$)-Drying($105^{\circ}C$, 2.5min)-Curing은 시간은 1분으로 고정시킨 후, 온도를 150, 160, 170, 180, 190, $200^{\circ}C$에서 처리하여 Yellowness값을 측정한 결과, 온도가 높아질수록 Yellowness값이 커지는 것으로 미루어 보아 PPS원단은 높은 열에 영향을 받아 황변 현상이 일어나는 것으로 사료된다. 특히 $180^{\circ}C$를 기점으로 값에 큰 변화를 보였으므로 최적의 열처리 온도는 $170^{\circ}C$로 선정하여 이후의 실험을 진행하였다. 또한 큐어링 시간이 황변에 미치는 영향을 분석한 결과 온도에 의한 영향에 비해 적은 편으로 사료되었으나, 1.5min을 기점으로 Yellowess값이 높아졌으므로 최적의 열처리 시간을 1분으로 선정하였다. 최종 가공조건인 $170^{\circ}C$, 1분에서 처리한 시험포는 처리전 원단과 비교하였을 때, ${\Delta}$Yellowness가 2.84 정도로 나타났다. 그 후, PPS 원단에 불소가공제 (TG-991N, 동인텍스켐)의 적정 농도를 선정하기 위해 1~7%까지 농도를 높이며 처리한 결과, 불소가공제의 농도가 높아짐에 따라 황변현상이 나타남을 알 수 있었다. 농도가 높아짐에 따라 Yellowness값은 증가하다가 4% 이후 완만해지는 것을 알 수 있었으므로 IPA/Water Drop test와 발수도시험 (KS K 0590;2008)을 통해 적정 농도를 선정하였다. PPS 원단은 불소가공제의 농도가 높아짐에 따라 발수도가 우수해졌으며, 가공제 농도 3% 처리만으로도 우수한 발수도를 나타내었으나 100% 발수를 위해서는 가공제 농도가 5% 이상 처리되어야 하는 것을 확인할 수 있었다.

• Polymer(Korea)
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• v.28 no.5
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• pp.426-432
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• 2004

To reduce volumetric shrinkage of the commercially available polymeric dental composite during curing reaction, (2,2-bis [4-(2-hydroxy-3-methacryloyloxy propoxy) phenyl] propane) (bis -GMA) derivatives, i.e., (2,2-bis[3-methyl, 4-(2-hydroxy-3-methacryloyloxy propoxy) phenyl] propan) (DMBis-GMA) and (2,2-his [3,5-dimethyl ,4- (2-hydroxy-3-methacryloyloxy propoxy) phenyl] propane) (TMBis-GMA) were synthesized and then new dental composite resin composed of Bis-GMA derivatives, diluent, spiro orthocarbonate (SOC), and inorganic filler was produced. Among the Bis-GMA derivative/Bis-GMA derivative/diluent mixtures, Bis-GMA/ TMBis-GMA/TEGDMA mixture exhibited the lowest volumetric shrinkage. Volumetric shrinkage of this mixture was further reduced by adding SOC. Volumtric shrinkage of dental composite prepared from commercially available resin monomer mixture was $2.5\%$, while that prepared from resin monomer mixture having minimum volumetric shrinkage was reduced to $0.7\%$. Mechanical strength of this dental composite was nearly the same with that of commercial products but the time required for the curing reaction was retarded.

• Polymer(Korea)
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• v.36 no.1
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• pp.59-64
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• 2012

The impact strength of material is considered the most important design factor for small and light products. Impact strength is a unique material property, thus the impact strength should not depend upon the geometry of specimen. However it varies according to specimen thickness, notching method, and notch shape. In this study, the variations of impact strength have been investigated according to thickness, notch shape, and notching method of specimen. Engineering plastics such as PC, ABS and POM have been used in this study. Experimental results showed impact strength increased as thickness decreasesd. PC showed the highest increment of impact strength when the thickness was thin. Fractured section of PC showed brittle fracture behavior when the specimen was thick. However it showed ductile fracture behavior when it was thin. The impact strength of in-mold notched specimen showed higher than that of milling notched specimen. PC showed the highest notch sensitivity among the materials used in this experiment.

• Journal of Adhesion and Interface
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• v.22 no.4
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• pp.136-143
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• 2021

Polyurea has been investigated as a polymer matrix for composite materials because of its high mechanical strength. Although polyurea has a similar chemical structure to polyurethane, it has much higher strength and durability. In this study, the fabrication of polyurea composites reinforced with carbon nanotube (CNT) and graphene oxide (GO) is demonstrated to enhance the tensile strength of the glass fibers composite. Using FTIR and Raman spectroscopies, the chemical structures of polyurea, CNT, and GO are investigated. As a result, spectroscopy analysis reveals that the chemical structure of CNT, GO, and polyurea is maintained during the fabrication of the composite structure. Scanning electron microscopy reveals the uniform distribution of CNT and GO across the polyurea matrix. The reinforcement of 1 wt% CNT in polyurea enhances the tensile strength of CNT/polyurea composites. In contrast, the reinforcement of GO in polyurea induces the degradation of the tensile strength of GO/polyurea composites.

• Journal of the Microelectronics and Packaging Society
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• v.26 no.1
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• pp.9-15
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• 2019

Here, we present a facile route to fabricate a vertically stacked 3D porous structure-based triboelectric nanogenerator (TENG) that can be used to harvest energy from the friction in a repetitive contact-separation mode. The unit component of TENG consists of thin Al foil electrodes integrated with microstructured 3D foams such as Ni, Cu, and polyurethane (PU), which provide advantageous tribo-surfaces specifically to increase the friction area to the elastomeric counter contact surfaces (i.e., polydimethylsiloxane, PDMS). The periodic contact/separation-induced triboelectric power generation from a single unit of the 3D porous structure-based TENG was up to $0.74mW/m^2$ under a mild condition. To demonstrate the potential applications of our approach, we applied our TENGs to small-scale devices, operating 48 LEDs and capacitors. We envision that this energy harvesting technology can be expanded to the applications of sustainably operating portable electronic devices in a simple and cost-effective manner by effectively harvesting wasted energy resources from the environment.

• Journal of the Korea Organic Resources Recycling Association
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• v.30 no.3
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• pp.5-12
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• 2022

This study suggests the effective recycling method of sludge waste from various industrial fields to synthesize uniform colloidal silica nanoparticles. In detail, polymers are removed from the sludge waste to attain sludge-extracted silica (s-SiO₂) micron-sized particles, and ammonia assisted sonication is applied to s-SiO₂, which has effectively extracted the silanol precursor. The nano-sized silica (n-SiO₂) particles are successfully synthesized by a typical sol-gel method using silanol precursor. Also, the yield amounts of n-SiO₂ are determined by the function of s-SiO₂ etching time. Finally, n-SiO₂-based slurry is synthesized for the practical CMP application. As a result, rough-surfaced semiconductor chip is successfully polished by the n-SiO₂-based slurry to exhibit the mirror-like clean surface. In this regard, sludge wastes are successfully prepared as valuable semicondutor grade materials.

• Membrane Journal
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• v.32 no.2
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• pp.140-149
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• 2022

In this study, the conditions of low temperature and high pressure of biogas upgrading process using polysulfone membrane have been designed and tested to achieve the high recovery and efficiency corresponding to those of the highly selective polymeric materials. Polysulfone hollow fiber membrane with 4-component dope solution was spun via non-solvent induced phase separation. The hollow fiber membrane was mounted into a 1.5 inch housing. The effective area was 1.6 m², and its performance was examined in various operation temperatures and pressures. CO₂ and CH₄ permeances were 412 and 12.7 GPU at 20℃, and 280 and 3.6 GPU at -20℃, respectively, while the CO₂/CH₄ selectivity increased from 32.4 to 77.8. Single gas test was followed by the mixed gas experiments using single-stage and double stage where the membrane area ratio varied from 1:1 to 1:3. At the single-stage, CH₄ purity increased and the recovery decreased as the stage-cut increased. At the double stage, the area ratio of 1:3 showed the higher CH₄ recovery as decreasing the operation temperature at the same purity of CH₄ 97%. Finally, polysulfone hollow fiber membranes have yielded of both CH₄ purity and recovery of 97% at -20℃ and 16 barg.